S GIO DC V O TO

THA THIN HU
THI CHNH THC

K THI CHN HC SINH GII TNH

KHI 12 THPT - NM HC 2006-2007

Mn: HO HC ( vng 1 )
Thi gian lm bi : 150 pht

Bi 1: (5 im)
1. Cc vi ht c cu hnh electron phn lp ngoi cng: 3s1, 3p6 l nguyn t hay ion?
Ti sao? Hy dn ra mt phn ng ha hc (nu c) minh ha tnh cht ha hc c
trng ca mi vi ht. Cho bit cc vi ht ny l ion hoc nguyn t ca nguyn t thuc
nhm A.
2. Hon thnh cc phng trnh phn ng sau y:
a. NaClO + PbS
b. NaBr + H2SO4 (c, nng)
c. KMnO4 + Na2O2 + H2SO4
d. NaNO2 + H2SO4 (long)
3. Nu cc yu t nh hng n tnh axit-baz ca cc hydroxit. p dng gii
thch cho dy: NaOH Mg(OH)2 Al(OH)3 H4SiO4 H3PO4 H2SO4 HClO4.
Bi 2: (3,75 im)
1. pH ca dung dch baz yu A bng 11,5. Hy xc nh cng thc ca baz, nu
thnh phn khi lng ca n trong dung dch ny bng 0,17%, cn hng s ca baz
Kb= 10-4. T khi ca dung dch bng 1g/cm3.
2. 3000K, in ly ca dung dch NH3 0,17g/l bng 4,2%. Tnh:
a. Nng mol/l ca cc phn t ( phn t v ion) trong dung dch lc cn bng.
b. Hng s baz ca NH3.
c. in ly ca dung dch khi thm 0,535 gam NH4Cl vo 1 lt dung dch ny.
Bi 3: (4 im)
1. Cho kim loi M tc dng vi phi kim B to hp cht D c mu vng. Cho 0,1mol
hp cht D tc dng vi CO2 ly d to thnh cht E v 2,4 gam B. Ha tan hon ton E
vo nc, dung dch E phn ng ht 100ml dung dch HCl 1M gii phng 1,12 lt kh
CO2 (ktc). Hy xc nh M, B, D, E v vit cc phng trnh phn ng xy ra. Bit hp
cht D cha 45,07% B theo khi lng, hp cht E khng b phn hy khi nng chy.
2. Cho cc gi tr th kh chun sau y:
E0 I 2 ( r ) / 2 I = 0,536V
E0Cu 2+ / Cu + = 0,153V ; E0Cu 2 + / Cu = 0,337V ; E0 Cu 2+ / CuI = 0,860V
Hy tnh : a. Tch s tan ca CuI ?
b. Hng s cn bng ca cc phn ng sau:
2Cu2+ + 2I- (1)
2Cu+ + I2 (r)
2Cu+ + 2I- (2)
2Cu(r) + I2 (r)
Bi 4: (3,75 im)
Mt dung dch X gm FeSO4, H2SO4 v MSO4 c th tch 200ml. Cho 20ml dung
dch Y gm BaCl2 0,4M v NaOH 0,5M vo dung dch X th dung dch X va ht H2SO4.
Cho thm 130ml dung dch Y na, th c mt lng kt ta. Lc ly kt ta, nung
trong khng kh n khi lng khng i c 10,155 gam cht rn v trung ha
dung dch sau khi loi kt ta phi dng 20ml dung dch HCl 0,25M.
a. Xc nh kim loi M.
b. Xc nh nng mol/l ca cc cht trong dung dch X.
(Bit: hydroxit ca M khng tan, khng c tnh lng tnh).

Bi 5: (3,5 im)
1. a. Th chun ca cp Cu2+/Cu bng 0,34V. Mt dy Cu nhng vo dung dch
CuSO4 10-2M. Tnh th in cc.
b. Ha tan 0,1mol NH3 vo 100ml dung dch trn (b qua s thay i v th tch)
Cu(NH3)42+ .Th in cc
v chp nhn rng ch xy ra phn ng: Cu2+ + 4NH3
o c gim i 0,40V. Xc nh hng s bn ng (II) tetramin Cu(NH3)42+.
2. Ngi ta thc hin mt pin gm hai na pin sau:
Zn Zn(NO3)2 0,1M v Ag AgNO3 0,1M. C th chun tng ng bng -0,76V v 0,80V.
a. Thit lp s pin vi cc du ca hai cc.
b. Vit phn ng khi pin lm vic.
c. Tnh E ca pin.
d. Tnh cc nng khi pin khng c kh nng pht in (pin dng ht).
Cho :

Na: 23 ; K: 39 ; Fe: 56 ; Cu: 64 ; Zn: 65 ; Ag: 108

Cl: 35,5 ; C: 12 ; N: 14 ; O: 16 ; S: 32 ; H: 1
-----------------------------------------------------------------------------------(Gim th khng gii thch g thm)