KOSEN

Review

Expert

-
( )

, ,
, ,
(C-dot) . , ,
.
.

, (bioimaging), , , ,
.
,
.

1.
(C-dot) 10nm


.
,
,
.

.
,
, , ,
.
,
,
, ,
.
CdSe, PbSe
.


,
Si

.

(single walled carbon
nanotube, SWCNT)
. SWCNT
,

.

,
,
.


. m
,
(CVD),
. 98%
, , sp3

.

sp2
.

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KOSEN

Review

carbogen .
,
,
569nm
700nm

.

trap
.
2
3

, 4
bioimaging , 5

.

2.
,
,
top-down ,

bottom-up
.
, ,
.

Expert

2.1.2.


. Nd:YAG
(1064nm, 10Hz)
2.6M 12
3~10nm
.

poly(ethylene
glycol)(PEG1500N)

poly(propionylethylen-imine-co-ethylenimine)
(PPEI-EI, with an EI fraction of ca. 20%)


.
4~5nm 13C

440nm 20%
.

,
Nd:YAG
diamine hydrate,
diethanolamine, PEG200N 2


, .
3nm

0.2~0.23nm
(100) .

2.1. Top-down
2.1.1.
Xu SWCNT

3.3N
NaOH(pH
8.4) .
SWCNT,
, .

366nm , ,
. FTIR

(PAH) C-H
PAH
.

2.1.3.
CVD
(carbon paper)

(multi-walled carbon nanotube, MWCNT)
.
Pt Ag/AgClO4

0.1m
tetrabutyl-ammonium
,
+
perchlorate (TBA ClO4) acetonitrile

. -2V +2V 0.5V/s

,
MWCNT

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Review
.

(acetonitrile)

.
2.80.5nm

PL
.

MWCNT
MWCNT
.
TBA+ MWCNT
MWCNT
.
KCl KClO4

.

0.1m NaH2PO4
3V

.

.

<5, 510, 10
30, >30 kDa
.
2
(1.90.3) nm (3.20.5) nm .
,
(002)

3.28 . PL
1.9 3.2 nm
445nm 510nm
.

2.2. Bottom-up
2.2.1.

. Mao

5M HNO3 12

Expert

.

14000 rpm 10
, / /chloroform
2~6nm
. ,

.
100mg
12
(4.80.6) nm
.
. NMR FTIR
sp2 ,

sp2

.
Giannelis

. 1



.

10nm
. ,

.

.
octadecylammonium citrate

300 2
.
diethylene glycolammonium citrate

300 2
.
4-aminoantipyrine (4AAP)
300

trifluoroethylene
.
(citrate salt) 7nm
XRD

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KOSEN

Review
,


.
4-AAP
5~9nm .

XRD
.

.
Giannelis sodium

11-aminoundecanoate
300
2

1
. 10~20nm
, 5~10nm
.



.
2 pH

cetyltrimethylammonium
tetrahydrofuran

.
bottom-up

.


. Li
.
F127

resol (phenol/formaldedyde
resins, Mw<500) F127/SiO2
. F127
resol

.
900
2 /
. 2M NaOH

. sp2 sp3

Expert

(1.5~2.5nm.
90.3% C, 1.4% H, and 8.3% O (wt %))
. 3M 24

.
PEG1500N 120
72
.
400~800nm

.
Giannelis NaY
zeolites
NaY zeolite
2,4 .
diaminophenol dihydrochloride
300 2
. zeolite

zeolite
, zeolite
4~66 nm

.
PEG200 ( , )
500W

microwave oven
2~10
.
.

.

.
5 10
2.75nm 3.65nm .

. Peng

.

. 2M

.
.
.
5nm
. FT-IR C=C
CH 1572cm-1

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KOSEN

Review

Expert

1375cm-1 peak .
4,7,10
trioxa-1,13-tridecanediamine
(TTDDA),
ethylenediamine, oleylamine, or PEG1500N
120 72
. TEM
turbostratic
, XRD
3.4A (d002) .
57.0% C, 7.5% H, 8.5% N,
27.0% O (wt%) .

. 5nm
16~-20nm .

,
.



.

2.3.

SWCNT
FTIR
.

,

COOH group
.

.


.

Sun
ZnO ZnS
. 2.6M 12

5 1000g
.
. ZnO/

zinc acetate
NaOH .
4~5nm DMF

. ZnO/ ,
,
200 2 .
ZnS/ DMF
zinc acetate Na2S
.
20:1
/ZnS, /ZnO
13:1 . ZnO ZnS
,
PEG1500N
. Zn


PEG1500N
. /

.


.

ZnO ZnS

2.4.

PL

.
Ethanolamine, PEG1500N
.

1

.

3.
3.1.
1 /
3nm
(SAED)
,
3:8:11:16:19 .

(111), (220), (311),(400), (331)
.

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Review
PEG200N

. 0.2~0.23nm
(100) .

.


.
Ray
0.208nm
sp3 sp2
. NMR
sp3 sp2
. FTIR
C=C .

sp2

.

XRD
.
5nm
1590cm-1 sp2
G sp3
1320cm-1 peak .
TEM image ZnS

.
D G
. MWCNT

.

sp2

turbostratic
.
.

3.2.


. /

Expert

280nm(4.4eV)
. MWCNT
2.8nm 270nm
50nm

.
.
TTDDA
350~550nm .
PL

. PL
.
PL

.

trap
.
.

.
PL

.
Si


. Sun
trap
PL .

trap
.

Si
. ZnO ZnS
PL
PEG1500N
. , ,

.

5nm
.
4~10% ,
Si
. 1
7nm 3%

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Review

. ,

. NaY zeolite
4~6nm

.

. PPEI-EI
PEG1500N
PPEI-EI
PEG1500N
ZnS
. ZnO
PEG1500N
45~50% . 15%
. Zn

Zn PEG


. /
0.43% ,
,
60.1%, 33.4%, 36.7% .

.
blinking PL
.

4.4~5nm
,
8.7ns
(3nm)
.
, pH
.
pH 4.5

.
pH
. Liu
PL
pH7 pH

40~89% .
, ZnO ZnS/
2

Expert

2 . 2

Ti:
(800nm)
, PL
. 2
38000GM(Goeppert-Mayer
unit;
1GM=1050
cm4sphoton-1)

CdSe(780~10300GM)
CdSe/ZnS

(~50000GM) . 2


,


.

3.3.
bioimaging
.
. 0.5mg/L

90~100% ,
75% .
bioimaging

bioimaging
.

4.
4.1. Bio-imaging
CdSe core-shell

.
.
PL
. Sun
bioimaging
PPEI-EI
(MCF-7)
.
37 2

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Review

.
,
4 .

(endocytosis)
.


(endocytosis)
.
(peptide)

.

4.2.

(electron-donor)
. Wang
Ag+ Ag
. Ag

.

5.

.

.

.
. Dai
(single layer nanographene oxide, NGO)

.
NGO-PEG
.
NGO

.
Kikkawa

(graphene oxide, GO)

drop casting GO

Expert

.
Hydrazine GO
PL
2
,
gap .

Kekule
.

.
Golus
(SLG) /

. PL mapping 1~3

5~6
PL .
2


.
.
Spectral hole burning 0.5eV

SLG
.


.



.



.

6.


.
,
.

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Review
.

.
, ,
switchgrass


. , ,
, , ,
, PL
,
,
.
(GUMBOS) thiol

.


. ,



.
,


.

OLED, , , ,
,
.

Expert

5. L. Cao, X.Wang,M. J. Meziani, F. S. Lu, H.

F.Wang, P. J. G. Luo, Y. Lin, B. A. Harruff, L. M.
Veca, D. Murray, S. Y. Xie, Y. P. Sun, J. Am. Chem.
Soc. 2007, 129, 11318 11319.
6. S. L. Hu, P. K. Bai, S. R. Cao, J. Sun, Chem. J.
Chin. Univ. Chin. 2009, 30, 1497 1500.

Reference

1. Sheila N. Baker and Gary A. Baker, Luminescent

Carbon Nanodots: Emergent Nanolights, Angew.
Chem. Int. Ed. 2010, 49, 6726 6744
2. X. Y. Xu, R. Ray, Y. L. Gu, H. J. Ploehn, L.
Gearheart, K. Raker, W. A. Scrivens, J. Am. Chem.
Soc. 2004, 126, 12736 12737.
3. A. B. Bourlinos, A. Stassinopoulos, D. Anglos, R.
Zboril, V. Georgakilas, E. P. Giannelis, Chem. Mater.
2008, 20, 4539 4541.
4. A. B. Bourlinos, A. Stassinopoulos, D. Anglos, R.
Zboril, M. Karakassides, E. P. Giannelis, Small 2008,
4, 455 458.
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Review

Expert

1.

http://www.kosen21.org/

10/10

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