Redox- Cambridge 21. 10.0 cm of 0.100 mol dm aqueous iron (II) sulphate is titrated against 88n 0.

0250 mol dm aqueous potassium permanganate (VII) in the presence of both hydrogen ions and fluoride ions. It is found that exactly 10.00 cm of manganate (VII) solution is required to reach the endpoint. What is the oxidation number of manganese at the endpoint? 2c) Suggest why potassium manganate (VII) rather than potassium dichromate (VI) 92j3 is used to titrate Fe (II) in volumetric analysis. 1. Sodium thiosulphate is used in the textile industry to remove excess chlorine 95s from bleaching processes by reducing it to chloride ions. S2O3 + 4Cl2 + 5H2O 2HSO4 + 8H + 8Cl In this reaction, how many moles of electrons are supplied per mole of thiosulphate? a. 1 b. 2 c. 4 d.8 3c. 0.013 mol of a vanadium complex was dissolved in 100 ml of water. 99n1 To oxidize all the vanadium to the +5 state, 20.8 ml of 0.025 mol dm KMnO4 was needed for 10 ml of the solution. Calculate the original oxidation number of the vanadium. [3] 13 In an experiment, 50.0 cm3 of a 0.10 mol dm 3 solution of a metallic salt s02, reacted exactly with 25.0 cm3 of 0.10 mol dm 3 aqueous sodium sulphite. c07n9 The half-equation for oxidation of sulphite ion is shown below. If the original oxidation number of the metal in the salt was +3, what would be the new oxidation number of the metal? A +1 +4 D +5 9. 25cm of 0.20 mol dm TiNO3 needs s07 25cm of 0.10 mol dm acidified KMnO4 solution to oxidise it to Ti. What is the oxidation state of the manganese after the reaction?

B +2 C