Bi tp t lun 1.

Cho ag hn hp A gm FeO, CuO, Fe3O4 (c s mol bng nhau) tc dng va vi 250ml dung dch HNO3 thu c dung dch B v 3,136 lit hn hp NO 2 v NO c t khi so vi hiro l 20,143. Tnh a v CM ca HNO3. 2. Ha tan ht 4,431g hn hp Al v Mg trong HNO3 long thu c dung dch A v 1,568lit (ktc) hn hp hai kh (u khng mu) c khi lng 2,59g, trong mt kh b ha nu trong khng kh. 1.Tnh thnh phn % v th tch mi kh trong hn hp. 2. Tnh s mol HNO3 tham gia phn ng. 3. C cn dung dch A thu c bao nhiu gam mui khan? 3. Thit lp cc phng trnh phn ng oxi ha - kh sau theo phng php thng bng electron: Phn ng oxi ha - kh loi khng c mi trng 1) HBr + H2SO4 c. nng Br2 + SO2 + H2O 2) Cl2 + SO2 + H2O HCl + H2SO4
0

3) C + H2SO4
o

t
0

CO2 + SO2 + H2O

t , Pt 4) NH3 + O2 N2O + H2O

5) Fe3O4 + Al

t
0

Al2O3 + Fe

6) CuO + H2

Cu + H2O

7) NO2 + O2 + H2O HNO3 8) O3 + KI + H2O O2 + I2 + KOH 9) H2S + Cl2 + H2O H2SO4 + HCl 10) H2O2 + PbS Pb(SO4) + H2O 11) Mg + HCl MgCl2 + H2 Vit cc phng trnh phn ng oxi ha - kh sau theo phng php thng bng electron: 1) H2S + SO2 ... + H2O 2) Al + HNO3 (long) ... + NO + H2O 3) SO2 + H2O + Br2 H2SO4 + ... 4) FeSO4 + HNO3 ... + NO2 + ...

5) S + H2SO4 ... + H2O 6)KMnO4 + K2SO3 + KOH K2SO4 + ... +... 4. Dn hai lung kh Cl2 i qua hai dung dch (1) KOH long v ngui; dung dch (2) KOH c v un nng. Vit v cn bng phng trnh phn ng oxi ha kh. Nu lng mui KCl sinh ra trong hai dung dch bng nhau th t l th tch clo i qua hai dung dch KOH (1) v (2) bng bao nhiu? 5: Trn 0.81 gam bt nhm vi Fe2O3 v CuO ri t nng tin hnh phn ng nhit nhm thu c hn hp A. Ha tan hon ton A trong dung dch HNO3 un nng thu c V lt kh NO ( sn phm kh duy nht ) ktc. Tnh th tch V? Bi 10: Ha tan 15 gam hn hp X gm hai kim loi Mg v Al vo dung dch Y gm HNO3 v H2SO4 c thu c 0.1 mol mi kh SO2, NO, NO2, N2O. Tnh phn trm khi lng ca Al v Mg trong X? 6: Trn 60 gam bt Fe vi 30 gam bt lu hunh ri un nng ( khng c khng kh ) thu c cht rn A. Ha tan A bng dung dch axit HCL d c dung dch B v kh C. chy C cn V lt O 2 ( ktc ). Bit cc phn ng xy ra hon ton. Tnh gi tr V? 7: Ha tan hon ton 12 gam hn hp Fe, Cu ( t l mol 1:1 ) bng axit HNO3, thu c V lt ( ktc) hn hp kh X ( gm NO v NO2 ) v dung dch Y ( ch cha 2 mui v axit d ). T khi X i vi H2 bng 19. Tnh gi tr ca V? 8: Hn hp X gm 2 kim loi A v B ng trc H trong dy in ha v c ha tr khng i trong cc hp cht. Chia m gam X thnh 2 phn bng nhau: -Phn 1: Ha tan hon ton trong dung dch cha axit HCl v H2SO4 long to ra 3.36 lt kh H2. -Phn 2: Tc dng hon ton vi dung dch HNO3 thu c V lt kh NO ( sn phm kh duy nht )? Bit cc th tch kh o KTC. Tnh gi tr ca V?