BI TP V ANKAN Cu 1: Khi cho hirocacbon no X tc dng vi brom, ch thu c mt dn xut cha brom c t khi hi i vi khng kh bng 5,207.

Xc nh cng thc cu to v tn gi ca X? Cu 2: t chy hon ton a gam hirocacbon X, thu c 1,12 lt CO 2 (ktc) v 1,008 gam H2O a) Tnh a? b) Xc nh CTPT ca X? c) Xc nh cng thc cu to ca X bit khi cho X tc dng vi Cl 2 chiu sng, t l mol 1 : 1 thu c 4 sn phm th m phn t ch cha mt nguyn t clo? Cu 3: Tr hai th tch bng nhau ca C3H8 v O2 ri bt tia la in t chy ht hn hp. Sau lm lnh hn hp sn phm ri a v iu kin ban u. Hi th tch hn hp sn phm ca phn ng thay i nh th no so vi th tch hn hp ban u? Cu 4: Cn ly metan v hiro theo t l nh th no v th tch khi t chy hon ton mt th tch hn hp cn mt th tch oxi (cc th tch o trong cng iu kin)? Cu 5: Mt ankan Y c cha 84,21% cacbon (v khi lng) a) Xc nh CTPT? b) to thnh hn hp c kh nng n mnh nht cn trn Y v khng kh theo t l no v th tch? Cu 6: Thc hin phn ng n ca metan vi mt th tch khng kh thch hp trong mt bnh thp kn. Sau phn ng, hn hp kh c a v iu kin ban u (hi nc ngng t). Xc nh % theo th tch cc kh cn li trong bnh sau phn ng n? Cu 7: T khi ca mt hn hp kh gm metan v etan so vi khng kh bng 0,6. Hi phi dng bao nhiu lt kh oxi t chy hon ton 3 lt hn hp trn (th tch o ktc)? Cu 8: Trong mt bnh kn 1500C cha nhng th tch bng nhau propan v oxi. Sau khi t chy hn hp, a bnh v nhit ban u. Hi p sut trong bnh thay i nh th no? Cu 9: Kh CO2 sinh ra khi t 3,36 lt hn hp propan v butan c dn vo dung dch NaOH sau phn ng to ra 28,62 gam Na2CO3 v 25,2 gam NaHCO3. Xc nh % v th tch ca mi kh trong hn hp trn? Cu 10: t chy 13,7 ml hn hp X gm metan, propan v cacbon oxit, ta thu c 25,7 ml CO2 (cc th tch o trong cng iu kin). a) Tnh % th tch propan trong X? b) Hn hp X nng hay nh hn nit? Cu 11: t chy hon ton 3 lt hn hp hai ankan ng ng k tip, ton b sn phm chy ln lt c dn qua bnh (1) ng CaCl2 khan, ri bnh (2) ng dung dch KOH d. Sau th nghim, khi lng bnh (1) tng 6,43 gam cn bnh (2) tng 9,82 gam a) Xc nh CTPT ca hai ankan?

b) Tnh % v th tch ca mi ankan trong hn hp? Cu 12: Hn hp E gm hai ankan X, Y k tip nhau trong dy ng ng c t khi hi so vi hiro l 33,2. Xc nh CTPT v tnh % v th tch mi cht trong Y? Cu 13: T khi ca hn hp gm H2, CH4 v CO so vi hiro bng 7,8. t chy hon ton mt th tch hn hp trn cn 1,4 th tch oxi. Xc nh % v th tch cc kh trong hn hp? Cu 14: t chy hon ton mt hirocacbon X, thu c CO2 v hi nc c t l th tch tng ng l 4 : 5 (cc th tch o trong cng nhit v p sut).Xc nh CTPT v vit cc CTCT c th c ca X? Cu 15: ot chay hoan toan a gam hon hp hai ankan A, B, hn kem nhau k nguyen t cacbon trong phan t, th thu c b gam kh cacbonic. Hay tm khoang xac nh cua so nguyen t cacbon trong phan t ankan cha t nguyen t cacbon hn theo a,b, k? Bi Tp Trc Nghim v Ankan. Cu 1. Cho 2 hidrocacbon X v Y l ng ng ca nhau, phn t khi ca X gp i phn t khi ca Y. 1. Cng thc tng qut ca 2 hidrocacbon l: A. CnH2n - 2 B. CnH2n + 2 C. CnH2n- 6 D. CnH2n 2. Bit rng t khi hi ca hn hp ng th tch X v Y so vi kh C2H6 bng 2,1. Cng thc phn t ca X v Y ln lt l: A. C3H8 v C6H14 B. C3H4 v C6H8 C. C3H6 v C6H12 D. Tt c u sai Cu 2. Cho cc cht kh sau: SO2, O2, CH4 v N2. nhn bit cc cht kh trn, trnh t no sau y l ng. A. dung dch Ca(OH)2, que m. B. dung dch Br2, que m C. dung dch clo, que m. D. A, B v C u ng. Cu 3. t 10 cm3 mt hidrocacbon bng 80 cm3 oxi (ly d). Sn phm thu c sau khi cho hi nc ngng t cn 65 cm3 trong c 25 cm3 oxi d. Cc th tch trong cng

iu kin. Xc nh CTPT ca hidrocacbon. A. C4H10 B. C4H6 C. C5H10 D. C3H8 Cu 4. Mt hidrocacbon X c cng thc CnH2n+2-2k. Khi t X ta c t l s mol ca CO2 v H2O bng 2 (k hiu b), ng vi k nh nht. Cng thc phn t ca X l: A. C2H4 B. C2H6 C. C2H2 D. C6H6 Cu 5. Mt hn hp 2 ankan lin tip trong dy ng ng c t khi hi vi H2 l 24,8. 1. Cng thc phn t ca 2 ankan l: A. C2H2 v C3H4 B. C2H4 v C4H8 C. C3H8 v C5H12 D. Kt qu khc 2. Thnh phn phn trm v th tch ca 2 ankan l: A. 30% v 70% B. 35% v 65% C. 60% v 40% C. 50% v 50% Cu 6. iu kin tiu chun c 1 hn hp kh gm 2 hidrocacbon no A v B, t khi hi ca hn hp i vi H2 l 12. 1. Khi lng CO2 v hi H2O sinh ra khi t chy 15,68 lit hn hp ( kc). A. 24,2 gam v 16,2 gam B. 48,4 gam v 32,4 gam C. 40 gam v 30 gam D. Kt qu khc 2. Cng thc phn t ca A v B l: A. CH4 v C2H6

B. CH4 v C3H8 C. CH4 v C4H10 D. C 3 cu A, B v C. Cu 7. Cho hn hp 2 ankan A v B th kh, c t l s mol trong hn hp: nA : nB = 1 : 4. Khi lng phn t trung bnh l 52,4. Cng thc phn t ca hai ankan A v B ln lt l: A. C2H6 v C4H10 B. C5H12 v C6H14 C. C2H6 v C3H8 D. C4H10 v C3H8. Cu 8. Hidrocacbon A c cng thc phn t l C4H8. C bao nhiu ng phn cu to ng vi cng thc phn t ca A. A. 4 B. 5 C. 6 D. 7 Cu 9.Cho cc hp cht sau: CH3CH2CH2CH3 (A) CH3CH(CH3)CH3 (B) CH4 (C) CH3CH2CH3 (D). Theo th t tng dn nhit si th: A. (A) < (B) < (C) < (D) B. (D) < (C) < (B) < (A) C. (B) < (C) < (A) < (D) D. (A) < (C) < (B) < (D) Cu 10. Trong cc tn gi di y, tn gi no khng ng: 4- metylhexan (1); n-hexan (2); 3- metyl-4-clohexan (3); 2-metylbutan (4); 2-dimetylpropan (5) A. (1), (5) v (3) B. (1), (2) v (5) C. (4), (5) v (1) D. (4), (3) v (1)