S Gio D c v o T o B c Giang chnh th c

thi ch n h c sinh gi i c p t nh Mn thi: Ho h c L p 12 - Nm h c 2005-2006 Ngy thi: 02 thng 4 nm 2006

Th i gian lm bi: 180 pht. Cu I: (3,0 i m) 1- Vi t cc phng trnh ph n ng ho h c x y ra khi l n l t cho kh SO2 tc d ng v i cc dung d ch sau (dung mi n c): H2S, Br2 , KMnO4. Cho bi t vai tr c a t ng ch t trong m i ph n ng ho h c . 2- a) So snh tnh ch t ho h c c a CO2 v SO2? Vi t cc phng trnh ph n ng ho h c minh ho . b) B ng phng php ho h c hy phn bi t cc bnh kh khng nhn sau: SO2, SO3, CO2, C2H2, C 2 H4 . c) B ng phng php ho h c hy tm cch lo i b cc kh c l n trong cc h n h p kh sau: HCl trong h n h p CO2 v HCl ; HCl trong h n h p H2S v HCl ; H2S trong h n h p HCl v H2S. Cu II: (3,0 i m) 1- Ch t h u c A khng no, ch a cc nguyn t C, H, O. Cho A tc d ng v i hi ro d (c xc tc Ni nung nng) c ch t h u c B. un B v i H2SO4 c 170oC, thu c ch t h u c C. Trng h p C c poliisobutilen. a) Xc nh cng th c c u t o c a A v vi t cc phng trnh ph n ng x y ra. b) T ch t A v metan cng v i cc ch t v c v i u ki n c n thi t, vi t cc phng trnh ph n ng i u ch thu tinh h u c (polimetyl metacrylat). 2- Pht bi u qui lu t th vng benzen? Cho v d minh ho . 3- H p ch t Q c cng th c phn t l C2D6O (D l teri). Q tc d ng v i Na gi i phng m t ch t kh. Xc nh cng th c c u t o c a Q v vi t cc phng trnh ph n ng i u ch Q t cc ch t v c thch h p. Cu III: (3,0 i m) 1- Lm th no c th lo i b : a) M t l ng l n kh clo trong phng th nghi m. b) Cc ion kim lo i Cu2+, Pb2+ c trong n c th i cng nghi p. Vi t cc phng trnh ph n ng ho h c x y ra. 2- Ho tan m gam h n h p Cu v Fe (trong Fe chi m 30% v kh i l ng) b ng 50 ml dung d ch HNO3 63% (d = 1,38 g/ml), khu y u cho t i ph n ng hon ton thu c ch t r n X n ng 0,75m gam, dung d ch Y v 6,104 lt h n h p kh NO v NO2 ( ktc). H i khi c c n dung d ch Y th thu c bao nhiu gam mu i khan? (Gi thi t khi c c n khng c ph n ng ho h c x y ra). Cu IV: (3,0 i m) 1- So snh nhi t si c a cc h p ch t sau: H2O, C2H5OH, CH3COOH. Gi i thch? 2t chy h t 5,1 gam este P c n 7,56 lt O2 ( ktc), ch sinh ra CO2 v H2O v i t l s mol n 2 : H2O CO n = 2. M t khc un nng 0,015 mol P v i dung d ch NaOH (d) th y c 0,03 mol NaOH tham gia ph n ng. P khng c ch c ete, khng ph n ng v i Na trong i u ki n bnh th ng v khng kh c AgNO3 trong dung d ch NH3 ngay c khi un nng. Hy xc nh cng th c phn t , vi t cng th c c u t o c a P, bi t MP < 140. Cu V: (4,0 i m) H n h p B g m hai kim lo i Cu v Al. Ho tan hon ton 4,82 gam h n h p B vo 40 ml dung d ch D g m H2SO4 15M v HNO3 1M, un nng, thu c dung d ch B1 v 2,688 lt h n h p kh E ( ktc) g m NO v m t ch t kh X khng mu. H n h p kh E c t kh i so v i hi ro b ng 26,34. 1- Tnh kh i l ng m i kim lo i trong 4,82 gam h n h p B ban u. 2- Tnh kh i l ng m i mu i trong dung d ch B1. Cu VI: (4,0 i m)

Cho h n h p M g m hai h p ch t h u c (ch ch a C, H, O, c m ch cacbon khng phn nhnh) tc d ng v a v i 60 gam dung d ch NaOH 20%, thu c m t r u n ch c v hai mu i c a hai axit h u c n ch c k ti p nhau trong dy ng ng. L y ton b l ng r u thu c cho tc d ng v i Na d, thu c 3,36 lt kh ( ktc). M t khc, n u cho 15,42 gam h n h p M tc d ng v a v i NaOH, thu c 12,72 gam mu i; cn n u t chy h t 30,84 gam h n h p M c n 42,336 lt O2 ( ktc), thu c kh CO2 v 22,68 gam H2O. Xc nh cng th c c u t o v tnh ph n trm kh i l ng c a m i ch t h u c trong h n h p M ni trn. Cho: H = 1; C =12; N = 14; O =16; Na = 23; Al = 27; S =32; Fe = 56; Cu = 64. Cn b coi thi khng gi i thch g thm. H v tn th sinh:.................................................... danh:.................... S bo