Answers to assigned problems Gary D. Christian Analytical Chemistry, 6" edition Chem 321 Spring Quarter, 2003 Chapters 3, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 16, 18, 23 These are the minimum you should try. Do as many others as you can,Chapter 2 3. (a) determinate, methodic (b) determinate, methodic (c) indeterminate (d) determinate, instrumental le) determinate, operative 4, (a) 5 (b) 4 (el 3 ay eta) 4 (ba) (c) 5) (alls 6. Li (6.9417) +N (14,0067) + 30 (47.9982) = 8.9466 7. Pd (106.4) + 21 (70.9) = 177.3 8. 162.9 9, 0,013y - 0.0067 + 0.00098 = 0,008, “ID. To the nearest 0.01 9 for three significant figures UL. (a) mean = 100 mag/t. {b) absolute error = ~2 meq/L © (e) relative error = (2/102) x 100% = ~28 1b, (a) moan = 33.33% (Sex CD Sor Sprvedsladk calculator) x xt (xP 3.7 0.06 0.0036 S97 0.04 16 Bs 0.0L 2.0001 < 0.0053 5 = ¥(0.0053 1713-1) = 0.052% (absolute) coeff, of varn = reles = (0.052/33.93) x 100% = 0.16% (relative) (b) mean = 0,024 x xk (gx? 0,022 0.002 4x10e 0.025 9.001 1x 106 0,026 0.002 4x10 29x10 : — so V9 x 10°)1(5-1); = 0.021% (absolute) coeff. of varn = (0.0021/0.024) x 100% = 8.8% (relative)Chapher J- 45. man = 102.6 (See CD Sr spvinds Lut calewlatime) x xy 102.2 0.4 102.8 0.2 103.1 0.5 102.3 03 ty-k? foes £0.54 (a) s = ¥(0.54)/(4-1) = 0.42 ppm (b) rel. 5 = (0.42/102.6) x 100% = 0.41% (e) Sean) = 9:42/78 = 0.21 ppm (d) rel. (mean) = (0.21/102.6) x 100% = 0.20x 1S, mean = 95.6% (Ser Cry Sev Spracdslut ca lewlatins) x xF 95.67 0.02 35.61 0.04 95.71 0.05 95.60 0.05 (xe? 9.0004 (a) s = WO.0081)74-1) = 0.052% (absolute) (2) S(qean) = (0-052)WE 0. 1.026% (absolute) (C) 201. (pean) = £0.026/95.65] x 100% = 0.028% (relative) W7. (a) 4 = (1427? + (48)? + (24)? 128 + 1025 ~ 66 = 517 49 (284 2 49.2 (b) sq = (130.05)? + (30.03))4 » (20,0045)* = 20.067 . 16,25 ~ 9.43 = 682 £0.07 fo) sy = 640.4)? + (41)? 2 Gat.26)* = 21.1 46,1 + 935 = 981 21 (See. CD or sprentshast ca lenletio of S,)