CHEMISTRY Paper 1 (THEORY) (Three hours) (Candidates are allowed additional 15 minutes for only reading the paper: They must NOT start writing during this time) “Answer all questions in Part I and six questions in Part IT choosing two questions ifrom each of the Sections A, B and C. “All working, including rough work, should be done on the same sheet as, and adjacent to, the rest of the answer The intended marks for questions or parts of questions are given in brackets Th Balanced equations must be given wherever possible and diagrams where they are helpful. When solving numerical problems, all essential working must be shown. In working out problems, use the following data: Gas Constant R = 1.987 cal deg-' mol! = 314. JK" mol"! = 0.0821 dm? atm K"' mol. atm =1 dm? atm=101.3J. 1 Faraday = 96540 coulombs PART I a Answer all questions. (®) Correct the following statements by changing the underli pees Se ree 5 changing srlined part of the sentence. Ss] EO) aii) For all spontaneous processes the change in entropy is Zero. Formaldehyde undergoes Cannizzaro’s reaction since it has one alpha hydrogen atom. ii) In a cocrdnaion comples, dooaton of elcian pitkes plas’ fhom to sonal @) ‘An aqueous solution of sodium sulphate is acidic in nature. o The solubility product of sliver chloride in water iti chloride tothe solution. secreases om addition of potassium ait ‘This paper consists of 7 printed pages and 1 blank page.Complete the following statements by selecting the correct altermative from the |) ‘ choives givens @ ‘The number of Faradays required to reduce one mol of Cu"? to metallic copper is: © (1) One 2) Two GQ) Thee (a) Pour, (id) When oxalic acid is heated with glycerol we get: © (1) Formic acid Q) Acetic acid (3) Lactic avid (4) Tartarie acid wo) (iii) The molecular weight of sodium chloride / pressure of its aqueous solution is: (1) Double the theoretical value (2) Same as the theoretical val (3) Half the theoretical (4) Three times by measuring the osmotic (iv) sigma bonds and two pi bonds Three pi bonds and two sigma bonds, ‘An example of an electrophil is: Q) No,’ @ Nor Q) NO, @) Nor ‘Sereonivenrerneee tonite ooeeenwen torts 1209-862 4(©) _ Fill in the blanks by choosing the appropriate word/words from th c tic, ethanol, diethyl ether, electron, praton, neutror iy, Gh (paramagnetic tron, prston dk n, inversely, Fructo ) diamagnetic, negative, two, moleculés, cleyation, a and are functional isomer @ (ii) AICh isa because it is an Jeficient m iii) ‘The of the boiling point of a solvent by the add a solute proportional to the molality of the solution (iv). The crystal of diamond is made of while that of calcium chloride is made of (v) Oxygen molecule i due to the presence unpaired 1 5 (d) Match the following 1st (i) Co-ordination compound: (a) Raputt’s law (ii) Dilute solution (b) Group displacement la (iii) Electroly (c) Werner's theory (iv) Toluene (d) ¢ Faraday’s law (v) Radioactivity (€) Friedel Craft's reaction PART II Answer six questions choosing two from Section A, two from Section B and two from Section C SECTION A Answer any two questions Question 2 ©) (The boiling point of pure water is 373K. Calculate the boiling point of an aqueous [$} “solution containing 18 gms of glucose (MW = 180) in 100 gms of water. "Molal elevation constant of water is 0.52 K kg mol”! (i) Equal weights of two substances X and Y are dissolved in equal volumes of water. The osmotic pressure of the solution containing Y is five times the osmotic pressure of the solution containing X. What is the molecular weight of X if that of Y is 60? fA) Which of the following solutions will have a lower vapour pressure and why? (1) _A.5% solution of cane sugar (C) Hz O11) @) 5% solution of urea (NHsCO NH;) (Relative atomic masses : H= 1, C= 12.0 = 16,N = 14) Turn over