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    Metallic bonding size-dependency on the optical properties of CdSe nanocrystals. With decreasing size, the fluorescence peak is shifted to shorter wavelengths. Au Ag properties vary with size color Specific heat melting point Bandgap conductivity Density of states (DOS) for electrons in bulk semiconductors (3-D, blue), quantum wells (, (2-D, red), quantum wires (1-D, green), and quantum dots (0-D, black)

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    Nano Materials Ppt

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    Metallic bonding size-dependency on the optical properties of CdSe nanocrystals. With decreasing size, the fluorescence peak is shifted to shorter wavelengths. Au Ag properties vary with size color Specific heat melting point Bandgap conductivity Density of states (DOS) for electrons in bulk semiconductors (3-D, blue), quantum wells (, (2-D, red), quantum wires (1-D, green), and quantum dots (0-D, black)

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    46 views16 pages

    Nano Materials

    Uploaded by

    ektapatil
    Metallic bonding size-dependency on the optical properties of CdSe nanocrystals. With decreasing size, the fluorescence peak is shifted to shorter wavelengths. Au Ag properties vary with size color Specific heat melting point Bandgap conductivity Density of states (DOS) for electrons in bulk semiconductors (3-D, blue), quantum wells (, (2-D, red), quantum wires (1-D, green), and quantum dots (0-D, black)

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    of 16

    11/28/2011

    Metallicbonding

    11/28/2011

    Metallicbonding

    sizedependencyontheopticalproperties

    ThesizedependencyontheopticalpropertiesofCdSe nanocrystals.Withdecreasing size,thefluorescencepeakisshiftedtoshorterwavelengths

    11/28/2011

    Au

    Ag

    Propertiesvarywithsize

    color Specificheat meltingpoint Bandgap conductivity

    11/28/2011

    Densityofstates(DOS)forelectronsinbulksemiconductors(3D,blue),quantumwells ( , (2D,red),quantumwires(1D,green),andquantumdots(0D,black). ), q ( ,g ), q ( , )

    Nanoscale=HighRatioofSurfaceAreatoVol.
    Repeat 24 times

    For example, 5 cubic centimeters about 1.7 cm per side of material divided 24 times will produce 1 nanometer cubes and spread in a single layer could cover a football field
    Source: Clayton Teague, NNI

    11/28/2011

    11/28/2011

    11/28/2011

    MBEsetup

    11/28/2011

    Physicalvapour depositin a) Electronbeamevaporation b) IonPlatingProcess c) Sputtering

    torusshapedargonplasma

    11/28/2011

    11/28/2011

    LayerbyLayerdeposition

    Selforganizeonasubstratesurface

    Functionalization ofNPs

    10

    11/28/2011

    Carbonnanotubes

    Semimetallic orsemiconductor

    metallic

    VerticallyalignedCNTs

    11

    11/28/2011

    Functionalization ofCNTs

    Functionalization ofCNTs

    12

    11/28/2011

    Functionalization ofCNTs

    Fullerene

    13

    11/28/2011

    Functionalization ofFullerene

    SEMofTiO2

    14

    11/28/2011

    TEMofTiO2

    TEMofTiO2

    15

    11/28/2011

    TEMofCuO

    TEMofCuO

    16

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