GeorgiaInstituteofTechnology DepartmentofChemistry CHEM1310,IntermediateExam1 Fall2008 Dr.Wine Directions: 1. 2. Selectthebestanswerforthefollowing17multiplechoiceitems.Each itemisequallyweightedat6pointsforapossible102points. Calculatorsarepermittedprovidedtheydonothaveakeyboard.PDA, cellphones,andothercommunicationdevicesarenotpermitted. CommunicationispermittedonlywiththeinstructorandtheTAswhoare proctoringtheexam. One8.5x11handwrittencribsheet(frontonly)ispermittedontheexam. Thesemustbesubmittedwiththeexam.

m. Thescantroncardsmustbefilledoutcompletelytoinclude:exam form,GTIDnumber(makesureyoububblethisincorrectly),name, andsection. Boththescantroncardsandtheexamswillbecollectedattheendof theexamperiod.Eachstudentshouldturntheirscantronforminto theirTA. Amaximumof45minuteswillbeallottedfortheexam

3.

4. 5. 6.

Constants:

Stoichiometry:

1 mole = 6.022 x 10 23 atoms 1 mole = 6.022 x 10 23 molecules 1 mole = 6.022 x 10 23 ions h = 6.626 x10 34 Js 1 J (Joule) = 1 kg c = 3.0 x10 8 m / s Mass of an Electron = 9.10939 x 10 -31 kg Mass of a Proton = 1.67 x 10
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m2 s2

mass volume mole of solute Molarity = M = L of solvent solution mass n (number of moles) = Molar Mass M1V1 = M 2V2 Density =
Quantum Mechanics

kg kg

Mass of a Neutron = 1.67 x 10 Latm R = 0.0821 molK J R = 8.31 molK V .P.( H 2 O,373K ) = 760torr
Solubility Rules 1. 2. 3. 4. 5. 6. 7.

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c = E = mc 2 h = p H = E h 4 Maximum Occupancy = 2n 2 x * mv

All alkali metal salts are soluble. All ammonium (NH4+) salts are soluble. All chlorides, bromides, and iodides are soluble except those of Ag+, Hg22+, and Pb2+. All nitrates, chlorates, and perchlorates are soluble. All sulfates except those of Ca2+, Sr2+, Ba2+, Pb2+, Hg22+, and Ag+. All carbonates, chromates, oxalates, and phosphates are insoluble except those of the alkali metals and ammonium. All hydroxides are insoluble except those of the alkali metals.

Bonding Formal Charge = V (L + 0.5 S) V = Number of Valence Electrons L = The Number of Lone Pair Electrons S = The Number of Shared Electrons