> restart; #Y.Y. Chuang, R. Schmid, and Y. A. Chang, J. Mater.

Sci. 16, 153 (1985). Calculation of the free energy associated

with the magnetic disordering of bcc Fe.
> assume(T > 0, TC > 0, k > 0, T1 > 0, T1 < TC, T2 > 0, T2 > TC,
klow > 0, khi > 0,z>1,zl>0,zl<1);
> cmhi(t):=subs([fs=0.285,m=2.216,p=1,k=0.00831451],8*p*fs*k*ln(1+
m)*t*exp(8*p*(1-t))); #energy in kJ/mol Fe atoms (k=0.00831451
kJ/mol)
0.01895708280 ln 3.216 t e8 K 8 t
> cmlow(t):=subs([fs=0.285,m=2.216,k=0.00831451],4*(1-fs)*k*ln(1+m)
/(1/(1-exp(-4)))*t*exp(-4*(1-t)));
0.02377949860 ln 3.216 1 KeK4 t eK4 C 4 t
?
> Gmlow(T,TC):=simplify(combine(subs(TC=1043,TC*int(cmlow(t),t=0..
T/TC)-T*int(cmlow(t)/t,t=0..T/TC))));
0.03255781462 K1.810761705 eK4. C 0.003835091084 T~ C1.810761705 eK8. C 0.003835091084 T~
K 2. 10-12 eK4. C 0.003835091084 T~ T~ C2. 10-12 eK8. C 0.003835091084 T~ T~
C 0.0001248621846 T~
> G1:=evalf(subs(T=TC,Gmlow(T,TC)));
0.03255781462 K1.810761705 eK4. C 0.003835091084 TC~ C1.810761705 eK8. C 0.003835091084 TC~
K 2. 10-12 eK4. C 0.003835091084 TC~ TC~ C2. 10-12 eK8. C0.003835091084 TC~ TC~
C 0.0001248621846 TC~
> Gmhi(T,TC):=simplify(combine(subs(TC=1043,G1+TC*int(cmhi(t),t=1..
T/TC)-T*int(cmhi(t)/t,t=1..T/TC))));
K0.002768061930 T~ K3. 10-9 T~ eK0.007670182167 T~ C1.633167290
K 1075.786226 eK0.007670182167 T~
?
> plot([[T,subs(TC=1043,Gmlow(T,TC)),T=0..1043],[T,subs(TC=1043,
Gmhi(T,TC)),T=1043..1500]],linestyle=[1,4],thickness=[3,5]);
#energy in kJ/mol Fe atoms, Temperature in Kelvin

(1)

(2)
(3)

(4)

(5)

(6)
(7)

K0.5

K1

K1.5

K2

K2.5
0

500

1000

1500