1.

NO2(g)+O(g)

a) NO(g)+O3(g)

NO2(g) J?

NO2(g)+O2(g) H=-198.9kJ

b)O3(g)

32 O2(g)

c) O2(g)

2O(g)

H=-142.3kJ
H=495.0kJ

-304.1kJ

2.
a) 1 mol 890kJ
b) -74.9kJ
c) 0.010 2.86kJ
3.

a) C(s,) + O2(g)

CO2(g)

H= -393.5kJ

b) 2H2(g) + O2(g)

2H2O(l)

H= -571.6kJ

c) 2C2H2(g) + 5O2(g)

4CO2(g) + 2H2O(l) H= -2598.8kJ

4. 720mmHg 1000
750mmHg
5. 40 50atm 10
2 atm? (
)
32atm
6. 720mmHg 1000
750mmHg, (960ml)
7. 76cmHg 27C 1500
23C 76cmHg
1250ml
8. 27C, 760mmHg 123 0.23
M=46
9. 6.0 1.0atm 4.0
0.50atm 5.0

1.6atm
10. 3.0 16.0 25C 600mmHg

PH2 =450mmHg, PO2= 150mmHg

11. 27C 2atm H2 3atm O2

2.7atm
a) (VH2 VO2)

(3:7)

b) H2 O2 mol

(2:7)

12. KClO3 O2 245 KClO3

27C1atm 27C
27mmHg, KClO3 =122.5, 2 KClO3

2KCl + 3O2

(V=77L)

13. 280cm3, 40s, 140 cm3

80s
14. x 3 56 9
112 x
72
15. SO42-, S2- Br-
A,B,C

Ba(NO3)2(aq)

D
Zn(NO3)2(aq)

E
AgNO3

16.

a) 36Kr
b) 30Zn
c) 24Cr
17. C4H8
18. C5H10
19. 1.00mol 0.100mol 0.300mol
0.600mol Cl=35.5
(249g)
20. 0.27 20%

8.0g
21. O2(g)+2NO(g)
2ICI(g) K1 NO2(g)+12O2(g)
K2 K1 K2 K3
22. 327C PCI5(g) K9 0.80
PCI5(g)

PCI3(g)+CI2g

0.10 PCI5 8.2

23. 2CrO42-(aq)+2H+(aq)
Cr2O72-(aq)+H2O(I)

a)
b)
c)
d)

K2CrO4(s)
NH3(aq)
BaCl2(s)
HCl(g)

24.
a) BaCrO4(s)
b) Hg2Cr2(s)

25. 25C 1.01.0-3M CaCl2 150mL 1.01.0-2M NaF 50mL

25C CaF2 Ksp=3.910-11
26. 1.0 1.0-3M Ca2+ 1.01.0-2M Na2SO4
CaSO4 Ksp=2.410-5
27.(s)(Ksp)
a) Ag2CrO4
b) Bi2S3

28. Hg2Cl2 Ksp=3.210-17

a) Hg2Cl2 M?
b) 250 Hg2Cl2 Hg=201

29. 298K 4.01.0-121

20.10M MgCl2+ mol/L?
30. 1.810-5 0.10M
PH log 1.3=0.1
31. 0.10 1.0 PH 11.00

32 0.10M C6H5COOH100
[H+] M? Ka=6.010-5
33.
a) KClO4
b) NH4NO3

c) NaClO
34. CO(NH2)2. 18.0 34.0
25C 25C 23.8mmHg
35. 20C2H5OH 44mmHg 18mmHg
46% 20C mmHg
36. CONH22 1 3.00
50.0
37. HOCH2CH2OH 1
3.72 100 C-1.12
38. 3.50 200 4.80C
5.50C 5.12C/m,
128
39.
a)CH4

b)CO2

c)NaCl

d)NH4+

e)HCN

40. CH4,NH3,H2O,HF H2OHF NH3

CH4

41. a)NaOH(s) b)C2H2(g) c)