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8
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1M N: KL   5 7  5J  A. C= 3.10 ms :A
': 2  5J  A G  5  ?P,3   6 On= 1,5
M 3  - E5 =RG AB F7 -S  i =30
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-1
9 X5 1-1   7   v-  (`.W
2-1 5 N:J  9 7 `?.
6c ?_ -2`? '(5 t2=0,02s Xc t3=0,025s
-3
 5 1-3 '5 < h`? M E5 -6M A A O\  W(<\ A \< 40(9 t
`?)<`? \ _M E5 -6 ?` A A O\  W(<\ (A
2-3 MM   '7`?  5  Fm=40g A
3-3 '7 m XS A(-\ ?` A F9_.A
AR -4 `? S\  M e = 102Hz FMR
4-1
 6c`? 7 ?5.uS
 4-2M A  '`M A `? .

 
2: W C1 = 0,06 mol.L-1 K-M C2H2O4 uI e  S1 X V1= 50mL  2: - 
C2=0,016mol.L-1 A  K-M (2K+,Cr2O72-)M`  A=(_ S2 X V2= 50mL
hv A Cr2O72- A=( uI e : X ?, A='` A  - N: -1
.F5 ?Z 
CO2/C2H2O4 : ? 5. L A Xm'  X7-   5 hv A ?]? 5. P N -2
Cr2O72-/Cr3+
.OS? 5. A -v  NP L A= ,' ( : -3
.OS? 5. EZI'   <' : -4
.x ?5.<' M hv A Cr3+ I -M XS HP' 7 -5
.X- `(S [Cr3+] <J 'S ?5.  2 5` PM h5 -6
: t=( E5 ?Z( ?5. X5 2M( Cr3+ I -M t(  S  7'S f. -7

A\S W  ?5.M OS? 5. ? -

.t=0s c(' 5 ?5. L6  2 5'   : -
'(5 6  X z] ` t=40s c(' 5 5 KL   , ? :  2 XS -
.uS7 ?5. t=0 c
?5. 5 E5 } m| : H5  -
.?5.
Z X'   7 -

HS ~  S I 2 X
2010





1  
v=

:( ' -1

3.108
= 6.1014 Hz :
7
5.10
c
c
n= v=
( ' -2
v
n
3.108
v=
= 2.108 m.s 1 :
1,5
v=

-3
:( '
sin i = n sin r sin r =

sin i 0,5
=
= 0,3333 r = 19,47
n
1,5

:( '
:
: r'l -S  '  - - -

A=60 H>I  G   S

r ' = 60 19,47 = 40,53
n sin r 'l = sin 90 sin r 'l =

r' = A r

sin 90 1
=
= 0,6667 r 'l = 41,81
n
1,5

r '< r 'l : F(

.AC F7S =R -' ]\' PS R , E5 ?Z( ( r '< r 'l  S -
sin i ' = n sin r ' = 1,5 * sin 40,53 = 0,9748 i ' = 77,11
:( ' - K
D = i + i ' A = 30 + 77,11 60 = 47,11
:' 2 M X
i-i-r-r-D  - _? M W =R -   -
A

E5 f:H( ( N > eSI R ,K2 L R S OP G  ,? P  S -4
.FS ]m i  -S G  X O_`( ? kS eSI R ,   \
GJ

2  
. =2*2,5= 5cm ' 2 ?,J Hm X 1-1
v=

d
d
7,5
= .v v =
=
= 100 Hz :( '
t1
.t1 5 * 0,015
d
:( ' 2-1
v=
t1
0,075
:
v=
= 5ms 1
0,015

:A  ' KL Hm 7  9 X 5\< ' '   M N2 t2c(' 5 ?` 6c ?_  -2

d=v.t2=0,1m=10cm=2
: c KL(' 5 ?` 6c

d=2,5 :A 7  9 X 5\<    ,M t3=0,025s c(' 5

: c KL(' 5 ?` 6c

-3
L=40=200cm=2m: `? 9 \A OM E5 -6 ?` A9  S 1-3
:( ' 2-3
v=

T = .v 2 =

m 2
.v
L
:

0,04
T=
. * 25 = 0,5N
2

:( ' 3-3

=

L 2
= = 0,4s
v 5

-4
E(  A ?` \S : f:H( -6 M X AJ ePS ` e R M  S -1-4
.7  J P 
: HP ' ( O<M Az`( . ?` `' -2-4
10 Hz e =

= 100Hz
k

100 100
100
100
e 10;
;12,5;
;
;20;25;
;50;100 :
9
7
6
3


   k 

 
[C2 H 2O4 ]0 =

[Cr O ]
2

C1.V1
= 3.10 2 mol.L1
V1 + V2
C .V
= 2 2 = 0,008 = 8.10 3 mol.L1
V1 + V2

-1

-2

Cr2O72 + 3C2 H 2O4 + 8 H + 2Cr 3+ + 6CO2 + 7 H 2O

2
7

Cr2O + 3C2 H 2O4 + 8 H 3O + 2Cr 3+ + 6CO2 + 15 H 2O

C2H2O4 -v 
:( '

-3
-4

ni (Cr2O72 ) = 0,016 * 0,05 = 8.10 4 mol

ni (C2 H 2O4 ) = 0,06 * 0,05 = 3.10 3 mol

 S
2
7

ni (Cr2O ) ni (C2 H 2O4 )

<
1
3

:E5 ?5.  6 '(5 ?Z( AS Cr2O72- ?  '  5. 

ni (Cr2O72 ) xmax = 0 xmax = ni (Cr2O72 ) = 8.10 4 mol

n(Cr 3+ ) = 2 x :A ,  Cr

[Cr 3+ ] =

3+

'   2 ?5. P N: -5

:E5 ?Z M X

2x
= 20 x
V1 + V2

:( ' -6
v=

3+

1 d [Cr ]
2 dt

.2 'M \- I A\S ?5.M OS? 5. -

1
t=0 c(' 5 [Cr3+]=f(t) E((   F7 ? P   a kS v = * a -
2
3+
2
1 [Cr ] 1 10
v= *
= *
= 2,5.10 4 mol.L1.s 1
2
t
2 20

2 'M (M ?5.  2 5 =  , 5 2 \ M (e.v(M H5.  -M  S -
. t=0 c(' 5 6  X z] t=40s c(' 5 6  , AS X- W
 7 -
:( ' O< t1/2 c(' 5 -
x=

xmax
[Cr 3+ ] = 20 x = 10 xmax = 8mmol.L1
2
t1 / 2 35s '2 E((  Hm X

HS ~  S I 2 X
2010

-7