NG HSP II N I THI TH I H C L N II N M 2011 NG TIIPT CHUYN MN IIA II C M : 221 Th i gian: 90 ph i Cu 1: X l m t gluxit.

X khng tham gia ph n ng trng b c nh ng thu phn X trong mi tr ng axit th dung d ch thu c tham gia ph n ng trng b c. X c th l: A. saccaroz B. mantoz C. glucoza D. fructoz Cu 2: Hy cho bi t s s p x p no sau y ng v i chiu t ng d n v nhi t si c a cc ch t? A. metyl amin < r u metylic < r u etylic < axit fomic B. r u metylic < axit fomic < metyl amin < r u etylic . C. r u melylic < r u etylic < metyl amin < axit fomic D. axit fomic < metyl amin < r u metylic < r u etylic Cu 3: Cng th c phn t t ng qut c a este t o b i axit no n ch c, m ch h l:
A. CnH2n-2-2k02k (n > 4, k > 2) C. CnH2n-2kO2k (n>4, k>2)
-5

TR TR

n ch c m ch h v r

u khng no c 1 lin k t i

B. CnH2n-2O2 (n > 4) D. CnH2n+2-2kO2k (n>6,k>2)

Cu 4: Cho Ka (CH3 COOH) = 1,8.10 v Ka (HNO2 ) = 4,1.10-4. N u hai axit c n ng mol/1 b ng nhau v nhi t th khi qu trnh i n ly t t i tr ng thi cn b ng, nh gi no sau y l ng: A. [H ] (CH3COOH) > [H ] (HN0 2). B. [H"] (CH3COOH) < [H+] (HNO2) c. [CH3C00] = [NO2I D. [CH3COOI > [ NO2I Cu 5: Cho cc ph n ng sau, ph n ng no khng x y ra? A CILCOONa + C6H5OH B. CH3COOCH3 I NaOH C. CH3COOH + Cu(OH) D. C H5ONa + CO2 I H20
2 6

cng

Cu 6 : Cho m gam h n h p X g m Fe, Zn c t l mol 1 :1 vo 200 ml dung d ch CuS(),| 0,9M thu d t a Y. Xc nh m A. 14,85 gam
B. 16,39 gam c. 19,36 gam D. 13,96 gam

c m gam k t

Cu 7: Cho glixerol tc d
ng v
i h
n h
p 5 axi C17H35COOH, C17H33COOH, C15H31COOIL C17II31COOH, C17H29COOH. S
lo
i trieste t
i a c th


c t
o thnh l:

A. 75 B.85 c. 56 Cu 8 : Cng th c t ng qui c a amin no m ch h l :

A. CnH2n+2+mNm B. CnH2n+2Nm

D. 80

c. CnH2n+2-m(NH2)2 D. CnH2n+iNH2

Cu 9: Hy cho bi t dy cc ch t no sau y u tc d ng v i Na? A. phenol, imetyl ete, axit axetic l. glixerin, etyl fomiat, phenol c. r u etylic. axit axetic, phenol 1 ). r u etylic, an ehit axctic, axit axetic Cu 10: Th c hi n ph n ng oxi ha m gam h n h p X g m ancol n-propylic v ancol ctylic thu d c (m 14,8) gam h n h p Y g m r u d , an chit v H2 0. Hy cho bi t khi cho Y tc d ng v i AgNO;, d trong NI-I3 thu c bao nhiu gam Ag? A. 64,8 gam B. 32,4 gam c. 43,2 gam D. 21,6 gam Cu 11: Ng i ta i u ch anilin b ng cch nitro ho 500 gam benzen r i kh h p ch t nitro sinh ra. s gam anilin thu c l bao nhiu bi t r ng hi u su t m i giai o n u t 78% ? A. 346,7 gam B. 362,7 gam c. 436,4 gam 1). 358,7 gam Cu 12: t chy hon ton caosu Buna-S v i khng kh v a , sau ph n ng a h n h p kh v 136,5c th thu c h n h p kh c ch a 15,04 % CO2 v th tch. Xc nh ti l s m t xch buta-1.3- dicn v stiren trong caosu Buna trn? A. 1 : 4 B. 3 : 2 c. 1 : 2 D. 2 : 3 Cu 13: S s p x p no sau y ng v i chi u t ng d n v nhi t si c a cc ch t sau: metyl lomiat (1); axit axetic (2); r u iso-propylic (3) v natri fomiat (4).
Trang 1/4 - M d thi 221

A (1) < (2) < (3) < (4) B. (1) < (3) < (2) < (4) c. (3) < (1) < (2) < (4) D. (1) < (4) < (3) < (2)

Cu 14: Tnh kh i l

ng tinh b t c n dng iu ch

c 2 lt r

u etylic 46 (khi l

ng rieng cua r

u l 0,8

gam/ml). Bi t hi u su t chung c a qu trnh d t 80% A. 1296 gam B. 2430 gam c. 810 gam D. 1620 gam Cu 15: Cho cc ch t sau: phenol (1); natri phenolat (2) v axit benzoic (3). S s p xp no ng v i chi u t ng d n v kh n ng tham gia ph n ng c a vng benzen v i dung d ch Br2 ? A. (3) < (2) < (1) B. (2) < (3) < (1) c. (3)<(1)<(2) ^ D. (1) < (2) < (3) Cu 16: Cho 8,64 gam axit h u c X n ch c, m ch h tc d ng h t v i CaC03 thu c 10,92 gam mu i c a axit h u c . Cng th c c u t o thu g n ca X l:
A. IIOC-COOH B. CH3COOH c. CII2--CH-COOH D. CI I3-CH2-COOH

Cu 17: Hy ch n thu c th t t nh t A. N c vi trong

c. Dung d
ch FeC
2

pht hi n nhanh chng khng kh b nhi m H2 S. B. Giy tm dung d ch Pb(N 3)2

D. Dung d
ch H2SO4

Cu 18: Ho tan 30 gam glixin trong 60ml etanol (d=0,8 g/ml) r i cho thm t t kh HC1 bo ha, sau un nng kho ng 3 gi . e ngu i, cho h n h p vo n c l nh r i trung ho b ng amoniac thu c m t s n ph m h u c c kh i l ng 33 gam. Hi u su t c a ph n ng l: A. 60% B. 75% c 80% D. 85% Cu 19: Cho X l h p ch t h u c n ch c c cng th c phn t l C4 H8 O2 . un nng m gam X trong dung d ch NaOH (v a ). Sau ph n ng thu c dung d ch c ch a mi gam mu i, bi t mi > m. s cng th c c u t o ph h p v i X l A. 1 B. 3 c. 4 D. 2 + 2 2+ Cu 20. Cho bi t th i n c c chu n c a cc c p oxiha kh : Cu /Cu; Ni /Ni; Sn /Sn; Fe /Fe; Mg2+/Mg l n l t l: +0,34V ; -0,26V; -0,14V; -0,44V; -2,37V Qu trnh: Fe2+ + 2e -------------- > Fe x y ra khi ghp i n c c Fe v i i n c c no sau y? A Ni B. Mg c. Sn D. Cu Cu 21: C bao nhiu h p ch t h u c l ng phn c a nhau c cng cng th c phn t C5 H11 CI? A.6 B. 8 c. 10 D.7 Cu 22: Nh ng ion no d i y khng th t n t i trong cng m t dung d ch ? A. K\ Na', HSCV.OH', PO4 3' B. Na+, Mg2+, K+, NO3 ", SO4 2' C.Cu2+,Fe3+, SO/ 2\ cr, N03 D. Ba2+, Al3+, Cl\ Bf, NO3' Cu 23: Ch t h u c A c cng th c phn t C3 H7 O2 N. Khi cho A ph n ng v i dung d ch NaOH, un nng la c ph n ng sau: A -t- NaOI ------- > B t CH3 OI- . Cng th c cu t o c a B l A. H2N - CI- 2 - COONa B. CI-I3 - COONH4 c. K t qu khc D. CH3 - CH2 - CONH2 Cu 24: t chy hon ton a mol ch t X (ch a c, H, O) m ch th ng thu c b mol C02 v c mol H20 (C'"b-a). Cho 7,92 gam X tc d ng v i NaHC03 d thu d c 2,688 lt C02 ( ktc). Tn c a X l: A. Axit acrylic B. Axit a ipic C Axit butan-l,4- ioic D. Axit glutanc ^ ^ Cu 25: i u ch Cu t CuO, ng i ta kh CuO b ng co d . Hy cho bi t lm th no c th xc nh c CuO b kh h t.
A
cho m
t t h
n h
p sau ph
n
ng vo dd H2SO4 long. B. thy Cu mu
xut hi
n c. cho m t t vo dung d ch

NaOH

D. cho m t t vo dung d ch HNO3 long, nong c a ph n ng trn t ng ln bao nhiu l n khi t ng n ng

c. 13l n D. 12 l n d ng b t (ch dng 1 dung d ch ch a 1 ha ch t v

Cu 26: Cho ph n ng: 2S02 + O2 -> 2 SO3 . T c S02 ln g p 2 v n ng 02 ln g p 3. A. 6 l n B. 10 l n Cu 27: Tch ring Ag ra kh i h n h p Ag, Cu, Fe l ng kim lo i tch gi nguyn kh i l A. Dung d ch HNO3 c ngu i c. Dung d ch HC1

c a

ng ban u). Dung d ch cn dng l B. Dung d ch AgN 3 D. Dung d ch FeCl3

Trang 2/4 - M d thi 221

Cu 28: Ch
n tn g
c ch
c ng c
a h
p ch
t sau: CH3-CH(CH3)-CH2-C1 'A metyl propyl clorua. B. sec-butyl clorua. c.

l-clo-2-metyl propan. D. isobutyl clorua. Cu 29: Cho m gam h n h p X g m Fe203 , CuO, MgO, AI2 O3 , ZnO v FeO vo dung d ch HNO3 d c, nng thu c 3,36 lt N02 ( lctc). M t khc nung m gam h n h p X v i kh co d thu c cht r n Y v h n h p kh z. Cho z vo dung d ch Ca(OH)2 d thu c 15 gam kt t a. Cho cht r n Y vo dung ch HNO3 long, d thu c V lt kh NO (s n ph m kh duy nh t, ktc). Gi tr c a V l A. 3,36 lt B. 2,24 lt c. 4,48 lt D. 1,12 lt _ Cu 30: tch t ng mu i ra kh i h n h p r n g m: NaCl, BaS04 v MgC03 ph i dng cc ha cht sau y: A. H2 O; cc dung d ch HC1; NaCl B. H2 0; cc dung d ch H2 SO4 long; Na2 C03 c. Cc dung d ch Na2 S04; KC1; Na2 C03 D. H2 0; cc dung d ch KC1; (NI-LO2 CO3 Cu 31: T l kh i l ng phn t gi a xit cao nh t c a nguyn t R so v i h p cht kh v i hidr c a n l 5,5 : 2. Kh i l ng mol nguyn t c a R l: A. 24 B .16 c. 12 D.28 Cu 32: D n co (d ) qua 8,56 gam h n h p X g m CuO, Fe2 03, FeO v Fe3 0/ nng thu c 6,16 gam h n h p kim lo i. Kh thot ra cho vo bnh n c vi trong d c m gam k t t a. Gi tr c a m l A. 18,6 gam B. 20,5 gam c. 15 gam D. 14,5 gam Cu 33: G i tn hi rocacbon sau: (CH3 )2 -CH-CH(C2 H5 )-CH=CH-CH2 -C(CH3)3 A. 3-etyl-2,7,7-trimetyloct-4-en B. 6-isopropyl-2,2- imetyloct-4-en c. 6-etyl-2,2,7-trimetyloct-4-en D. 2,2- imetyl-6-isopropyloct-4-en Cu 34: Cho ph ng trnh ho h c sau:
a K2SO3 + b KMn04 + c KHSO4 - d K2SO4 + e MnS04 + f H20 T ng cc h s d, e, f d ng nguyn, t i gi n nh t trong cn b ng ph n ng trn l: A. 14 B.12 c. 13 D.15 Cu 35: Cho m gam h
n h
p X g
m Fe203, CuO, MgO, FeO v Fe304 vo dung d
ch H2SO.1
c. nng thu c 0 672 lt S02 ( ktc). M t khc cho kh co (d ) i qua m gam h n h p X nung nng thu c ch t r n Y v h n h p kh z. Cho z vo dung d ch Ca(OH)2 d thu c 8 gam kt tua. Cho chat lan Y vo dung d ch HNO3 long, d thu c V lt ( ktc) h n h p kh T g m NO v N2 0. T khi c a T so vi H-) b ng 18,5 (bi t s n ph m khng t o ra NH4 NO3 ). Gi tr c a V l
A. 1.12 lt B. 2,24 lt c. 0,448 lt D. 0,896 lt

Cu 36: Cho s

:
I~SO .J M c
2 i

Br^chl
>

C|H9OH(X) --------

-------- >Y

CH;, CIIBr CHBr CII3

X, Y l n l

t l:

A. CH3CH2CH(OH)CH3, CH3CH=CHCH3 B. CH3CH(OH)CH2CH3, CH3CH2CHCH2 c. CH3CH2CH2CH2OH, CH3CH2CHCH2 d. CH3CH2CH2CH2OH , CH3CH-CHCH3

Cu 37: H p th h t 1,792 lt C02 ( ktc) vo 1 lt dung d ch NaOH a (mol/1) thu c dung d ch X. Cho dung d ch X tc d ng v i dung d ch BaC 2 d thu c 7,88 gam kt t a. Gi tri ca a l A. 0,08 l. 0,24 c.0,22 D.0.12 ^ Cu 38: Cho 8 gam h n h p X g m Mg v Fe vo dung d ch MCI d hu c 4,48 lt H2 ( ktc). Nu cho 8 gam h n h p X trn vo 0,14 lt dung d ch C11 SO4 X (M) thu c 12,32 gam cht r n Y v dung d ch z. Gi tr c a X l A. 1 6 M B. 1,5 M C.1.2M D. 1 M ^ ^ ^ ^ Cu 39: Cho h n h p X g m CH,|, C?I-L| v C4 I-I4 . t chy hon ton 8,8 gam X ri dn ton b s n ph m thu c qua 400 ml dung d ch Ca(OH) 2 IM thu tr c a m l A. 25 gam
B. Ph

c m gam k t t a. Bi t 8,4 lt h n h p X (dktc) n ng 13,2 gam. Gi

D. 15 gam
Trung 3/4 - M d thi 221

ng n khc c. 40 gam

Cu 40: M t bnh c u ng y kh HC1 c y b ng m t nt cao su c m ng th ytinh yu t nh n xuyn qua. Nhng mi ng bnh c u vo m t c c th y tinh ng n c cho thm m t t dung d ch NaOH v m t vi gi t dung d ch phenolphtalein (c mu h ng). D on hi n t ng quan st c trong th nghi m trn?

A. Khng c hi n t ng g x y ra. ^ l N c trong c c th y tinh phun m nh vo bnh cu v mt mu ^ ^ C. N c trong c c th y tinh phun m nh vo bnh c u v khng m t mu h ng ban u. D N c trong c c th y tinh phun m nh vo bnh cau va oi mau ,_ Cu 41: Cho h
n h
p X ch
a a mol Mg v b mol Fe vo dung d
ch ch
a c mol C11SO4 sau khi kt thc phn ng thu c dung d ch ch a 2 mu i. Mi lin h gi a a, b, c l: Aa<T<alb l . a<b C.a<c<alb D.a-b<c<a b C u 4 2 : C h o c c dung d ch mu i: NaNOj, K2C03, AICI3, Fc(NO,)3, BaCh, dung d ch b Ihy phn t o mi tr ng axit l. ( A AICIj.NaNOj.BaCh B. Fe(NOj)j v AICI3 c. NaNO v Fe(N03)3 D K2COj v BaCk Cu 43: Tr n 0,2 lt d ng d ch ch a H2SO: 0.1M v HCl: X (M) vi 0,3 lt dung d ch BaCI2 0.1M thu c k t t a X v dung d ch Y c pH = 1. Gi tr c a X l A015M B. 0,08 M c. 0,03 M D. 0,05 M Cu 44: Cho 20,3 gam h n h p X g m Al, Zn, Mg v Cu vo dung d ch H2 SO4 c, nng v a thu c h n h p B g m 0,1 mol II2S v a mol S02. Sau ph n ng c c n dung d ch thu c 73,1 gam tnuoi khan. Gi tr c a a l A 0 14 mol B. 0,12 mol C. o,21 mol D. 0,15 mol Cu 45: Cho 19,64 gam h n h p X g m Fe, Cu, Ag vo dung d ch HCl du thu c 3,136 lt H2 ( ktc). M t khc cho lon b h n h p X vo dung d ch HN3 long, sau ph n ng thu c V lit kh NO ( ktc), dung d ch Y v 12,92 gam ch t r n z. Gi tr c a V l
A 3 36 lt
2

B. 1,792 lt

c. 4,48 lt
2

D. 2,24 lt

, ,r

Cu 46: Cation X ' c c u hnh e lp ngoi cng l 3s 3p . Xc nh v tr c a X trong b ng tun hon? A Chu k 4 nhm IIB B. Chu k 3, nhm IIIA c. Chu k 3, nhm VIA D. Chu k 4, nhm HA Cu 47: Cho m gam h n h p g m CuS04 v NaCl tan vo n c thu c dung dich X i n phn dung dich X cho den khi n c b t u b i n phn c 2 i n c c th d ng, an t thot ra 0,448 lt kh dktc), trung ho dung d ch sau i n phn c n 0,4 lt dung d ch NaOH 0,1M. Gi tr c a m l A 5 97 am B. 2,54 gam c. 4,25 gam D. 3,14 gam ^ ^ Cu 48r un nng h n h p g m 2,24 gam b t Fe v 0,64 gam b t s cho t i khi ph n ng x y ra h n ton thu c ch t rn X. Cho X vo dung d ch MCI d thu d c h n h p kh Y. Thnh phn % theo th tch hai kh trong h n h p Y l: A. 20% v 80% B. 60% v 40% c. 50% v 50% D 70% v 30% Cu 49: Hi n t ng quan st c khi cho t t dung d ch NH3 cho td vo dung d ch A1(N03 ) 3 l A. Xu t hi n k t t a mu tr ng, l ng k t t a t ng d n t n c c i ri khng i. B. Khng c ph n ng g c. Xu t hi n k t t a mu tr ng r i k t t a tan ngay. ,,X D. Xu t hi n k t t a mu tr ng, l ng k t t a t ng d n t n c c i sau kt t a tan dn Cu 50: Cho V lit dung d ch NaOH IM vo 200 ml dung d ch AICI3 0 5M sau ph n ng l c ly kt t a dem nung dn khi l ng khng i thu c m gam ch t r n. Bi t 0,27 lt < V < 0,38 lt. H i m c gi tr trong kho ng no? I 1,34 gam < m < 4,59 gam c. 1,02 g a m < m < 5,1 gam
B
1,02 gam < m < 4,59 gam
D

- 1,34 gam <m< 5,1 gam

HT

THI TH

I H C L N II N m h c 2010 - 2011
P N MN HA H C

Trang 4/4 - M d thi 221

Cu 1 2 3 4 5 6

221

222 D c B

223 D A D A c B

224

Cu 26 27 28 29 30

221 D D D A B

222 B B D I) D

223

224 A I)

A A l
B A

c A B
A A

c D B
c c D

c c c c A B
A

c B
A

c A A c A B

A B D c A B
D A

7 8 9 10
11 12 13
14 15

B D c D A
D

B A
I)

31 32 33 34
35 36 37 38 39 40 41 42 43 44 45 46 47 48
49 50

c c c
A D A I) I)

c A B
A

B A
B B I) I)

B A
A

c
/' '1

c
A

c
B I)

c
D

c
B

A D

16
17

18 19 20 21 22 23
24 25

c c B c
B B B A A
) .. A

D l c A

c c c c
A D c B

c A c I) I)
D B I) A A
I) I)

D B c B I)
D B I) A c
A c

c B A B
B A D A A c:
A I

c A c D
A

B B A D
B I) B B
B B

c
D A B A

c
D A
I) A I A

c
A

c
I) B

c
c