The concept of the relativistic crystal field was first introduced by Wybourne. He used the effective operator technique developed by Sandars and Beck. The method is numerically illustrated for the Mn2+ ion in an environment of C3 symmetry. New information on the role of configuration mixing interactions is obtained.
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Original Title
J.A. Tuszynski and R. Chatterjee- Comments on the Use of the Effective Operator Method in the Relativitstic Crystal Field Model
The concept of the relativistic crystal field was first introduced by Wybourne. He used the effective operator technique developed by Sandars and Beck. The method is numerically illustrated for the Mn2+ ion in an environment of C3 symmetry. New information on the role of configuration mixing interactions is obtained.
The concept of the relativistic crystal field was first introduced by Wybourne. He used the effective operator technique developed by Sandars and Beck. The method is numerically illustrated for the Mn2+ ion in an environment of C3 symmetry. New information on the role of configuration mixing interactions is obtained.
J.A. Tuszynski and J.M. Dixon - A Study of Effective Crystal Fields, Spin-Orbit Coupling and Residual Interactions, Due To Relativistic Effects and Configuration Mixing, For GD 3+ in C3h Symmetry