CHNG 3: AMIN, AMINO AXIT, PROTEIN

AMIN
A. L THUYT
1. Mt s khi nim:
- Amin no, n chc: C
n
H
2n+3
N (n > 1) =>
Amin no, n chc, bc 1: C
n
H
2n+1
NH
2
(n > 1)
- Amin n chc, bc 1: RNH
2

2. Tn amin = tn gc ankyl + amin
- CH
3
NH
2
: metyl amin (bc 1); (CH
3
)
2
NH: imetyl
amin (bc 2);

(CH
3
)
3
N: trimetyl amin (bc 3);

-
C
2
H
5
NH
2
: etyl amin ; C
3
H
7
NH
2
: propyl amin ;
CH
3
NHC
2
H
5
: etyl metyl amin.
- C
6
H
5
NH
2
: phenyl amin (anilin).

3. Tnh cht ha hc:
T/c hh c trng ca amin l tnh baz (do trn N
cn mt cp electron t do cha lin kt).
- Lm qu tm ha xanh (tr anilin-C
6
H
5
NH
2

l baz rt yu khng lm i mu qu tm)
- Tc dng vi axit (HCl,): RNH
2
+ HCl
RNH
3
Cl (mui)
* Lu : vi anilin (C
6
H
5
NH
2
) cn c p. th
trn nhn thm.
+ C
6
H
5
NH
2 +
3Br
2
C
6
H
2
(B r)
3
NH
2 +
(trng) + 3HBr
(2,4,6-tribrom
anilin)
+ Anilin c tnh baz yu, b baz mnh
y ra khi dd mui:
C
6
H
5
NH
2
+ HCl C
6
H
5
NH
3
Cl
(phenyl amoni clorua)
C
6
H
5
NH
3
Cl + NaOH C
6
H
5
NH
2

+ NaCl + H
2
O


+ /ch anilin theo s : C
6
H
6

3
HNO

C
6
H
5
NO
2
Fe HCl +
C
6
H
5
NH
2



Benzen Nitro benzen Anilin
B. MT S DNG BI TP
DNG 1: DA VO PHN NG GIA AMIN
VI AXIT HOC VI BROM TNH KHI
LNG MUI THU C V KHI
LNG AMIN BAN U
Cu 1: Cho 9,3 gam anilin (C
6
H
5
NH
2
) tc dng
va vi axit HCl. Khi lng mui thu c l
A. 11,95 gam. B. 12,95 gam.
C. 12,59 gam. D. 11,85 gam.
Cu 2: Cho 5,9 gam etylamin (C
3
H
7
NH
2
) tc dng
va vi axit HCl. Khi lng mui
(C
3
H
7
NH
3
Cl) thu c l (Cho H = 1, C = 12, N =
14)
A. 8,15 gam. B. 9,65 gam. C.
8,10 gam. D. 9,55 gam.
Cu 3: Cho 4,5 gam etylamin (C2H5NH2) tc
dng va vi axit HCl. Khi lng mui thu
c l
A. 7,65 gam. B. 8,15 gam. C.
8,10 gam. D. 0,85 gam.
Cu 4: Cho anilin tc dng va vi dung dch
HCl thu c 38,85 gam mui. Khi lng anilin
phn ng l
A. 18,6g B. 9,3g
C. 37,2g D. 27,9g.
Cu 5: Cho anilin tc dng vi va vi dd cha
24 gam brom thu c m (gam) kt ta trng. Gi
tr ca m l:
A. 16,8 g. B. 16,5 g. C. 15,6 g. D. 15,7
g.
Cu 6: Cho m (gam) anilin tc dng vi va vi
nc brom thu c 3,3 gam kt ta trng. Gi tr
ca m l:
A. 0,93 g. B. 1,93 g. C. 3,93 g. D. 1,73
g.
Cu 7: Cho nc brom d vo anilin thu c 16,5
g kt ta. Gi s hiu sut p. t 100%. Khi
lng anilin trong dd l: A. 4,50. B.
9,30. C. 46,50. D.
4,65.
Cu 8: Ngi ta iu ch anilin bng cch nitro
ha 39 g benzen ri kh hp cht nitro sinh ra. Bit
hiu sut mi giai on l 80%. Khi lng anilin
thu c l:
A. 29,76 g. B. 37,20 g. C. 43,40 g. D.
46,05 g.
Cu 9: Ngi ta iu ch anilin bng cch nitro
ha 500 g benzen ri kh hp cht nitro sinh ra.
Bit hiu sut mi giai on l 78%. Khi lng
anilin thu c l:
A. 346,7 g. B. 362,7 g. C. 463,4 g. D.
465,0 g.
DNG 2: XC NH CU TO AMIN DA
VO PHN NG TO MUI
Cu 10: Cho 2,25 gam mt amin (X) no, n chc,
bc 1, tc dng va vi 500ml dd HCl 0,1M. CT
ca X l: A. CH
3
NH
2
. B. C
3
H
7
NH
2
.
C. C
4
H
9
NH
2
. D. C
2
H
5
NH
2
.
Cu 11: Cho 10,95 gam mt amin (X) no, n
chc, bc 1, tc dng va vi 150ml dd HCl
1M. CT ca X l:
A. CH
3
NH
2
. B. C
3
H
7
NH
2
.
C. C
4
H
9
NH
2
. D. C
2
H
5
NH
2
.
Cu 12: Cho 0,4 mol mt amin (X) no, n chc,
bc 1, tc dng vi lng d dd HCl thu c
32,6g mui. CT ca X l: A. CH
3
NH
2
.
B. C
3
H
7
NH
2
. C. C
4
H
9
NH
2
. D.
C
2
H
5
NH
2
.
Cu 13: Cho 5,9 gam mt amin (X) no, n chc,
bc 1, tc dng vi lng d dd HCl thu c
9,55g mui. CT ca X l: A. CH
3
NH
2
.
B. C
3
H
7
NH
2
. C. C
4
H
9
NH
2
. D.
C
2
H
5
NH
2
.
Cu 14: Cho 6,2 gam mt amin (X) no, n chc,
bc 1, tc dng vi lng d dd HCl thu c
13,5g mui. CT ca X l: A. CH
3
NH
2
.
B. C
3
H
7
NH
2
. C. C
4
H
9
NH
2
. D.
C
2
H
5
NH
2
.
DNG 3: XC NH CU TO AMIN DA
VO PHN NG T CHY
+ Amin n chc (ch c mt nguyn t N):
C
x
H
y
N + ( )
4
y
x + O
2
x CO
2
+
y
2
H
2
O +
1
2
N
2
=> Tm x,
y ?
+ Amin no, n chc: C
n
H
2n+3
N + (
6 3
2
n +
)
O
2
nCO
2
+
2n+3
2
H
2
O +
1
2
N
2
=> Tm n ?
(T amin no, n chc C
n
H
2n+3
N => Suy ra
amin no, n chc bc 1 C
n
H
2n+1
NH
2
).
Cu 15: t chy hon ton mt amin n chc X
thu c 9 g H
2
O; 2,24 lt CO
2
v 1,12 lt N
2

ktc. CTPT ca X l:
A. CH
5
N. B. C
2
H
7
N. C.
C
3
H
9
N. D. C
4
H
11
N.
Cu 16: t chy hon ton mt amin n chc X
thu c 10,125g H
2
O; 8,4 lt CO
2
v 1,4 lt N
2

ktc. CTPT ca X l:
A. CH
5
N. B. C
3
H
7
N. C.
C
3
H
9
N. D. C
4
H
11
N.
Cu 17: t chy hon ton 0,1 mol mt amin n
chc X thu c 4,48 lt CO
2
v 6,3g H
2
O. CTPT
ca X:
A. CH
5
N. B. C
2
H
7
N. C.
C
3
H
9
N. D. C
4
H
11
N.
Cu 18: t chy hon ton hn hp 2 amin no,
n chc, bc 1, l ng ng k tip nhau, thu
c CO
2
v H
2
O vi t l s mol l: n
CO2
:n
H2O
=
1:2. Hai amin trn l:
A. CH
3
NH
2
v C
2
H
7
NH
2
. B. C
2
H
5
NH
2

v C
3
H
7
NH
2
.
C. C
3
H
7
NH
2
v C
4
H
9
NH
2
. D.
C
4
H
9
NH
2
v C
5
H
11
NH
2
.
Cu 19: t chy hon ton hn hp 2 amin no,
n chc, bc 1, l ng ng k tip nhau, thu
c CO
2
v H
2
O vi t l s mol l: n
CO2
:n
H2O
= 7 :
10. Hai amin trn l:
A. CH
3
NH
2
v C
2
H
7
NH
2
. B.
C
2
H
5
NH
2
v C
3
H
7
NH
2
.
C. C
3
H
7
NH
2
v C
4
H
9
NH
2
. D.
C
4
H
9
NH
2
v C
5
H
11
NH
2
.
C. MT S CU TRC NGHIM
Cu 1: S ng phn amin c cng thc phn t
C
2
H
7
N l
A. 4. B. 3. C. 2.
D. 5.
Cu 2: S ng phn amin c cng thc phn t
C
3
H
9
N l
A. 4. B. 3. C. 2.
D. 5.
Cu 3: S ng phn amin c cng thc phn t
C
4
H
11
N l
A. 5. B. 7. C. 6.
D. 8.
Cu 4: S ng phn amin bc mt ng vi cng
thc phn t C
3
H
9
N l
A. 4. B. 3. C. 2.
D. 5.
Cu 5: S ng phn amin bc mt ng vi cng
thc phn t C
4
H
11
N l
A. 4. B. 3. C. 2.
D. 5.
Cu 6: C bao nhiu amin cha vng benzen c
cng cng thc phn t C
7
H
9
N ?
A. 3 amin. B. 5 amin. C. 6 amin.
D. 7 amin.
Cu 7: Anilin c cng thc l
A. CH
3
COOH. B. C
6
H
5
OH. C.
C
6
H
5
NH
2
. D. CH
3
OH.
Cu 8: Trong cc cht sau, cht no l amin bc 2?
A. H
2
N-[CH
2
]
6
NH
2
B. CH
3

CH(CH
3
)NH
2
C. CH
3
NHCH
3
D. C
6
H
5
NH
2

Cu 9: Trong cc tn gi di y, tn no ph
hp vi cht CH
3
CH(CH
3
)NH
2
?
A. Metyletylamin. B.
Etylmetylamin. C. Isopropanamin.
D. Isopropylamin.
Cu 10: Trong cc tn gi di y, tn no ph
hp vi cht C
6
H
5
-CH
2
-NH
2
?
A. Phenylamin. B. Benzylamin. C. Anilin.
D.Phenylmetylamin.
Cu 11: Cht khng c kh nng lm xanh nc
qu tm l
A. Anilin B. Natri hiroxit. C. Natri
axetat. D. Amoniac.
Cu 12: tch ring tng cht t hn hp
benzen, anilin, phenol ta ch cn dng cc ho cht
(dng c,iu kin th nghim y ) l
A. dung dch NaOH, dung dch HCl, kh CO
2
.
B. dung dch Br
2
, dung dch HCl, kh CO
2
.
C. dung dch Br
2
, dung dch NaOH, kh CO
2
.
D. dung dch NaOH, dung dch NaCl, kh CO
2
.
Cu 13: Dy gm cc cht u lm giy qu tm
m chuyn sang mu xanh l:
A. anilin, metyl amin, amoniac. B.
amoni clorua, metyl amin, natri hiroxit.
C. anilin, amoniac, natri hiroxit. D.
metyl amin, amoniac, natri axetat.
Cu 14: Kt ta xut hin khi nh dung dch brom
vo
A. ancol etyliC. B. benzen. C. anilin.
D. axit axetic.
Cu 15: Cht lm giy qu tm m chuyn thnh
mu xanh l
A. C
2
H
5
OH. B. CH
3
NH
2
. C.
C
6
H
5
NH
2
. D. NaCl.
Cu 16: Anilin (C
6
H
5
NH
2
) phn ng vi dung dch
A. NaOH. B. HCl. C. Na
2
CO
3
.
D. NaCl.
Cu 17: C 3 cht lng benzen, anilin, stiren, ng
ring bit trong 3 l mt nhn. Thuc th phn
bit 3 cht lng trn l
A. dung dch phenolphtalein. B. nc brom.
C. dung dch NaOH. D. giy qu tm.
Cu 18: Anilin (C
6
H
5
NH
2
) v phenol (C
6
H
5
OH)
u c phn ng vi
A. dung dch NaCl. B. dung dch HCl.
C. nc Br
2
. D. dung dch NaOH.
Cu 29: Dung dch metylamin trong nc lm
A. qu tm khng i mu. B. qu
tm ha xanh.
C. phenolphtalein ho xanh. D.
phenolphtalein khng i mu.
Cu 20: Cht c tnh baz l
A. CH
3
NH
2
. B. CH
3
COOH. C.
CH
3
CHO. D. C
6
H
5
OH.
Cu 21: Pht biu no sau y khng ng ?
A. Cc amin u c tnh baz.
B. Tnh baz ca cc amin u mnh hn NH
3
.
C. Anilin c tnh baz rt yu nn khng lm
i mu qu tm.
D. Amin c tnh baz do trn N c cp e cha
tham gia lin kt.
Cu 22: Dung dch C
2
H
5
NH
2
trong H
2
O khng
phn ng vi cht no sau y ?
A. HCl. B. H
2
SO
4
.
C. Qu tm. D. NaOH
Cu 23: Nhn nh no sau y khng ng?
A. Amin c tnh baz v trn nguyn t N c i
e t do nn c kh nng nhn proton.
B. Trong phn t anilin c nh hng qua li
gia nhm amino v gc phenyl.
C. Anilin c tnh baz mnh nn lm mt mu
nc brom.
D. Anilin khng lm i mu qu tm.
Cu 24: Cho cc hp cht hu c sau: C
6
H
5
NH
2

(1); C
2
H
5
NH
2
(2); CH
3
NH
2
(3); NH
3
(4). mnh
ca cc baz c sp xp theo th t tng dn l:
A. 1 < 4 < 3 < 2. B. 1 < 3 < 2 < 4.
C. 1 < 2 < 4 <3. D. 1 < 2 < 3 < 4.
Cu 25: Cho cc hp cht hu c sau: C
6
H
5
NH
2

(1); C
2
H
5
NH
2
(2); (C
2
H
5
)
2
NH (3); NaOH (4); NH
3

(5). mnh ca cc baz c sp xp theo th
t tng dn l:
A. 1 < 5 < 2 < 3 < 4. B. 1 < 5 < 3 < 2
< 4. C. 5 < 1 < 2 < 4 <3. D. 1 < 2 < 3
< 4 < 5.
Cu 26: Cho cc hp cht hu c sau: C
6
H
5
NH
2

(1); C
2
H
5
NH
2
(2); (C
2
H
5
)
2
NH (3); NaOH (4); NH
3

(5); CH
3
NH
2
(6); C
2
H
5
OH (7). mnh ca cc
baz c sp xp theo th t tng dn l:
A. 7 < 5 < 6 < 2 < 1 < 3 < 4. B. 7 <
5 < 6 < 1 < 3 < 2 < 4.
C. 4 < 5 < 6 < 1 < 2 < 3 < 7. D. 7 < 1 <5 < 6 < 2
< 3 < 4.
Cu 27: Amin c CTPT C
4
H
11
N c s ng phn
amin bc 2 l:
A. 4. B. 3. C. 1.
D. 8
Cu 28: Amin c CTPT C
3
H
9
N c s ng phn
amin bc 1 l:
A. 1. B. 2. C. 3.
D. 4.

AMINO AXIT
A. L THUYT
1. Mt s khi nim
- Cng thc chung : (NH
2
)
x
R(COOH)
y
. Khi
x=1; y=1 => NH
2
R COOH
- Amino axit l hchc tp chc, phn t cha ng
thi nhm amino (NH
2
) v nhm cacboxyl
(COOH).
- Trong dung dch, tn ti dng ion lng cc:
NH
3
+

RCOO
-


- Tn amino axit = axit + v tr nhm amino (-
NH
2
) + tn axit
7 6 5 4 3 2 1 (v tr C)
C C C C C C COOH (v tr
- l v tr C mang nhm chc -COOH).
e
+ Glyxin: NH
2
CH
2
COOH (axit -amino
axetic)
+ Alanin: CH
3
CH(NH
2
)

COOH hay
NH
2
CH(CH
3
)COOH (axit -amino propionic)
2. Tnh cht ha hc:
a. Tnh cht lng tnh (tnh baz l do nhm
NH
2
v tnh axit l do nhm COOH)
- Tnh baz (tc dng vi axit):
NH
2
RCOOH + HCl NH
3
Cl

RCOOH
(mui)
- Tnh axit (tc dng vi baz):
NH
2
RCOOH + NaOH NH
2
RCOONa +
H
2
O
b. Tham gia p. este ha (tc dng vi
ancol/HCl)
NH
2
R COOH + C
2
H
5
OH/HCl
NH
3
Cl R COOC
2
H
5
+ H
2
O
c. Phn ng trng ngng to polime +
H
2
O
n NH
2
R COOH
, ,
o
xt t p
[-NHRCO-]
n
+
nH
2
O

Tm li: Amino axit tc dng vi:


- Axit

- Kim loi (Na,)
- Oxit baz (CuO,)
- Baz tan (NaOH,)
- Mui (Na
2
CO
3
; CaCO
3
; )

NH
2
COOH
R


B. MT S DNG BI TP
DNG 1: XC NH CU TO AMINO AXIT
DA VO PHN NG TO MUI
Cu 1: X l mt amino axit no ch cha 1
nhm NH
2
v 1 nhm COOH. Cho X tc dng
va vi 100ml dd HCl 1M, thu c 12,55g
mui. CTCT ca X l:
A. H
2
N-CH
2
-COOH. B.
CH
3
-CH(NH
2
)-COOH.
C. C
2
H
5
-CH(NH
2
)-COO D.
H
2
N- CH
2
-CH
2
-COOH.
Cu 2: X l o-amino axit axit no ch cha 1 nhm
NH
2
v 1 nhm COOH. Cho 10,3 g X tc dng
vi axit HCl (d), thu c 13,95 g mui khan.
CTCT thu gn ca X l:
A. CH
3
CH
2
CH(NH
2
)COOH. B.
H
2
NCH
2
CH
2
COOH.
C. CH
3
CH(NH
2
)COOH. D. H
2
NCH
2
COOH.
Cu 3: X l mt amino axit no (ch cha 1
nhm NH
2
v 1 nhm COOH). Cho 15,1 g X tc
dng vi HCl d thu c 18,75 g mui. CTCT
ca X l:
A. H
2
N-CH
2
-COOH. B.
CH
3
-CH(NH
2
)-COOH.
C. C
6
H
5
-CH(NH
2
)-COOH. D.
H
2
N-CH
2
-CH
2
-COOH.
Cu 4: X l mt amino axit no ch cha 1
nhm NH
2
v 1 nhm COOH. Cho X tc dng
va vi 150ml dd HCl 1M, thu c 16,725 g
mui. CTCT ca X l:
A. H
2
N-CH
2
-COOH. B. CH
3
-
CH(NH
2
)-COOH.
C. C
2
H
5
-CH(NH
2
)-
COOH. D. H
2
N- CH
2
-CH
2
-COOH.
Cu 5: X l mt amino axit no, ch cha 1
nhm NH
2
v 1 nhm COOH. Cho X tc dng
vi 100ml dd NaOH 1M, thu c 11,1 g mui.
CTCT ca X l:
A. H
2
N-CH
2
-COOH. B.
CH
3
-CH(NH
2
)-COOH.
C. C
2
H
5
-CH(NH
2
)-COOH D. H
2
N- CH
2
-CH
2
-
COOH.
Cu 6: X l mt amino axit no ch cha 1
nhm NH
2
v 1 nhm COOH. Cho 7,5 g X tc
dng vi dd NaOH, thu c 9,7 g mui. CTCT
ca X l:
A. H
2
N-CH
2
-COOH. B.
CH
3
-CH(NH
2
)-COOH.
C. C
2
H
5
-CH(NH
2
)-COOH D. H
2
N- CH
2
-CH
2
-
COOH.
Cu 7: X l mt amino axit no ch cha 1
nhm NH
2
v 1 nhm COOH. Cho 5,15 g X tc
dng vi dd NaOH, thu c 6,25 g mui. CTCT
ca X l:
A. H
2
N-CH
2
-COOH. B. CH
3
-CH(NH
2
)-
COOH.
C. C
2
H
5
-CH(NH
2
)-COOH. D. H
2
N- CH
2
-CH
2
-
COOH.
Cu 8: Trung ho 1 mol o-amino axit X cn 1 mol
HCl to ra mui Y c hm lng clo l 28,286% v
khi lng. CTCT ca X l:
A. H
2
N-CH
2
-CH(NH
2
)-COOH. B.
H
2
N-CH
2
-COOH.
C. CH
3
-CH(NH
2
)-COOH. D. H
2
N-CH
2
-CH
2
-
COOH.
Cu 9: Trung ho 1 mol o-amino axit X cn 1 mol
HCl to ra mui Y c hm lng clo l 32.127% v
khi lng. CTCT ca X l: A.
H
2
N-CH
2
-CH(NH
2
)-COOH. B. H
2
N-CH
2
-COOH.
C. CH
3
-CH(NH
2
)-COOH. D.
H
2
N-CH
2
-CH
2
-COOH.
Cu 10: Cho 0,02 mol amino axit A tc dng va
vi 80 ml dd HCl 0,25M. C cn dung dch sau
phn ng thu c 3,67 g mui. Phn t khi ca
A l:
A. 134. B. 146.
C. 147. D. 157.
DNG 2: XC NH CU TO AMIN DA
VO PHN NG T CHY
Lu :
- Amino axit ch cha mt nhm amino (-NH
2
) v
mt nhm cacboxyl (-COOH)
C
x
H
y
NO
2
+ ( 1)
4
y
x + O
2
x CO
2
+
2
y
H
2
O +
1
2
N
2
=> Tm x, y ?
- Amino axit no, ch cha mt nhm amino (-
NH
2
) v mt nhm cacboxyl (-COOH):
C
n
H
2n+1
NO
2
+
(6 3)
4
n
O
2
n CO
2
+
2 1
2
n +
H
2
O +
1
2
N
2
=> Tm n ?
Cu 1: t chy hon ton 0,01 mol hn hp 2
amino axit no X, Y l ng ng k tip nhau, mi
cht u cha 1 nhm (NH
2
) v 1 nhm (-COOH),
thu c 0,56 lt CO
2
(ktc). CTPT ca X, Y ln
lt l:
A. CH
3
NO
2
v C
2
H
7
NO
2
. B.
C
2
H
5
NO
2
v C
3
H
7
NO
2
.
C. C
3
H
7
NO
2
v C
4
H
9
NO
2
. D. C
4
H
9
NO
2
v
C
5
H
11
NO
2
.
Cu 2: t chy hon ton 0,2 mol hn hp 2
amino axit no, l ng ng k tip nhau, mi cht
u cha 1 nhm (NH
2
) v 1 nhm (-COOH), ri
cho sn phm chy qua bnh ng dd NaOH d,
thy khi lng bnh tng 32,8 g. CTCT ca 2
amino axit l:
A. H
2
NCH(CH
3
)COOH, C
2
H
5
CH(NH
2
)COOH.
B. H
2
NCH
2
COOH, H
2
NCH(CH
3
)COOH.
C. H
2
NCH(CH
3
)COOH, H
2
N[CH
2
]
3
COOH.
D. H
2
NCH
2
COOH, H
2
NCH
2
CH
2
COOH
Cu 3: Este X c iu ch t amino axit Y v
ancol etylic. T khi hi ca X so vi H
2
bng 51,5.
t chy hon ton 10,3 gam X thu c 17,6 gam
kh CO
2
; 8,1 gam nc v 1,12 lt nit (ktc). Cng
thc cu to thu gn ca X l:
A. H
2
N-[CH
2
]
2
-COO-C
2
H
5
B. H
2
N-CH
2
-
COO-C
2
H
5

C. H
2
N-CH(CH
3
)-COO-H

D. H
2
N-CH(CH
3
)-
COO-C
2
H
5

Cu 4: Mt hp cht hu c cha cc nguyn t C,
H, N, O c phn t khi bng 89. t chy hon
ton 1 mol hp cht thu c 3 mol CO
2
; 0,5 mol
N
2
v a mol hi nc. Cng thc phn t ca hp
cht l
A. C
4
H
9
O
2
N B. C
2
H
5
O
2
N C. C
3
H
7
NO
2
D.
C
3
H
5
NO
2

C. MT S CU HI TRC NGHIM
Cu 1: Amino axit l hp cht hu c trong phn
t
A. cha nhm cacboxyl v nhm amino. B.
ch cha nhm amino.
C. ch cha nhm cacboxyl. D. ch
cha nit hoc cacbon.
Cu 2: C
4
H
9
O
2
N c my ng phn amino axit c
nhm amino v tr ?
A. 4. B. 3. C. 2.
D. 5.
Cu 3: C bao nhiu amino axit c cng cng thc
phn t C
4
H
9
O
2
N?
A. 3 cht. B. 4 cht. C. 5 cht.
D. 6 cht.
Cu 4: C bao nhiu amino axit c cng cng thc
phn t C
3
H
7
O
2
N?
A. 3 cht. B. 4 cht. C. 2 cht.
D. 1 cht.
Cu 5: Trong cc tn gi di y, tn no khng
ph hp vi cht CH
3
CH(NH
2
)COOH ?
A. Axit 2-aminopropanoic. B. Axit o-
aminopropionic. C. Anilin. D. Alanin.
Cu 6: Trong cc tn gi di y, tn no khng
ph hp vi cht CH
3
-CH(CH
3
)-CH(NH
2
)-COOH?
A. Axit 3-metyl-2-aminobutanoic. B.
Valin.
C. Axit 2-amino-3-metylbutanoic. D.
Axit o-aminoisovaleriC.
Cu 7: Trong cc cht di y, cht no l glixin?
A. H
2
N-CH
2
-COOH B. CH
3

CH(NH
2
)COOH
C. HOOC-CH
2
CH(NH
2
)COOH D.
H
2
NCH
2
-CH
2
COOH
Cu 8: Dung dch ca cht no sau y khng lm
i mu qu tm :
A. Glixin (CH
2
NH
2
-COOH) B.
Lizin (H
2
NCH
2
-[CH
2
]
3
CH(NH
2
)-COOH)
C. Axit glutamic (HOOCCH
2
CHNH
2
COOH)
D. Natriphenolat (C
6
H
5
ONa)
Cu 9: Cht X va tc dng c vi axit, va tc
dng c vi baz. Cht X l
A. CH
3
COOH. B. H
2
NCH
2
COOH. C.
CH
3
CHO. D. CH
3
NH
2
.
Cu 10: Cht no sau y va tc dng c vi
H
2
NCH
2
COOH, va tc dng c vi CH
3
NH
2
?
A. NaCl. B. HCl. C. CH
3
OH.
D. NaOH.
Cu 11: Cht rn khng mu, d tan trong nc,
kt tinh iu kin thng l
A. C
6
H
5
NH
2
. B. C
2
H
5
OH. C.
H
2
NCH
2
COOH. D. CH
3
NH
2
.
Cu 12: Cht tham gia phn ng trng ngng l
A. C
2
H
5
OH. B. CH
2
= CHCOOH. C.
H
2
NCH
2
COOH. D. CH
3
COOH.
Cu 13: Cho dy cc cht: C
6
H
5
NH
2
(anilin),
H
2
NCH
2
COOH, CH
3
CH
2
COOH, CH
3
CH
2
CH
2
NH
2
,
C
6
H
5
OH (phenol). S cht trong dy tc dng
c vi dung dch HCl l
A. 4. B. 2. C. 3.
D. 5.
Cu 14: chng minh aminoaxit l hp cht
lng tnh ta c th dng phn ng ca cht ny ln
lt vi
A. dung dch KOH v dung dch HCl. B.
dung dch NaOH v dung dch NH
3
.
C. dung dch HCl v dung dch Na
2
SO
4
.
D. dung dch KOH v CuO.
Cu 15: Cht phn ng c vi cc dung dch:
NaOH, HCl l
A. C
2
H
6
. B. H
2
N-CH
2
-COOH. C.
CH
3
COOH. D. C
2
H
5
OH.
Cu 16: Axit aminoaxetic (H
2
NCH
2
COOH) tc
dng c vi dung dch
A. NaNO
3
. B. NaCl. C. NaOH.
D. Na
2
SO
4
.
Cu 17: Dung dch ca cht no trong cc cht
di y khng lm i mu qu tm ?
A. CH
3
NH
2
. B. NH
2
CH
2
COOH

C. HOOCCH
2
CH
2
CH(NH
2
)COOH. D.
CH
3
COONa.
Cu 18: phn bit 3 dung dch H
2
NCH
2
COOH,
CH
3
COOH v C
2
H
5
NH
2
ch cn dng mt thuc
th l
A. dung dch NaOH. B. dung dch HCl.
C. natri kim loi. D. qu tm.
Cu 19: Glixin khng tc dng vi
A. H
2
SO
4
long. B. CaCO
3
. C.
C
2
H
5
OH. D. NaCl.
Cu 20: Cho hp cht H
2
NCH
2
COOH

ln lt tc
dng vi cc cht sau: Br
2
, CH
3
OH/HCl, NaOH,
CH
3
COOH, HCl, CuO, Na, Na
2
CO
3
. S phn ng
xy ra l:
A. 5. B. 6. C. 8. D. 7.
Cu 21: Dung dch cht no di y lm qu tm
ha xanh ?
A. C
6
H
5
NH
2
. B. H
2
NCH
2
COOH.
C. CH
3
CH
2
NH
2
.
D. H
2
NCHCOOH
CH
2
CH
2
COOH


Cu 23: C 5 dd cha: CH
3
COOH, glixerol, dd
glucoz, h tinh bt, lng trng trng. S cht tc
dng vi Cu(OH)
2
/OH
-
l:
A. bn cht. B. hai cht.
C. ba cht D. nm cht.
Cu 24: C cc cht: lng trng trng (anbumin),
dd glucoz, dd anilin, dd anehit axetic. Nhn bit
chng bng thuc th no?
A. dd Br
2
. B. Cu(OH)
2
/OH
-
. C.
HNO
3
c. D.ddAgNO
3
/NH
3
.



PEPTIT PROTEIN
A. L THUYT
PEPTIT PROTEIN
(lng trng trng -
anbumin)
Cu
to
phn
t
- gm t 2 n 50
gc -amino axit
lin kt vi nhau
bng lin kt peptit
(- CONH-) theo
mt trt t nht
nh.



Vd: - Peptit to
nn t glyxin v
alanin l:
NH
2
-CH
2
-CO-
NH-CH
2
-COOH
- gm nhiu gc -
amino axit lin kt vi
nhau bng lin kt
peptit (- CONH-)
khng theo mt trt t.
- thnh phn, s lng,
trt t sp xp cc -
amino axit thay i
to ra cc protein khc
nhau (tnh a dng ca
protein).
V d: -NH-CH-CO-
NH-CH-CO-
R
1
R
2

. Hay [-NH-CH-


Lk
peptit
=> peptit ny
thuc loi
ipeptit
CO-]
n
R
i

Tnh
cht
1/. Phn ng
thy phn ( trong
mi trng axit
(H
+
), baz (OH
-
)
hoc enzim )
to ra cc -
amino axit.
2/. Phn ng
mu biure: Tc
dng vi
Cu(OH)
2
to
hp cht mu tm
(/v peptit c t 2
1/. Phn ng thy
phn ( trong mt axit
(H
+
), baz (OH
-
) hoc
enzim ) to ra cc
-amino axit.
2/. Phn ng mu
biure: Tc dng vi
Cu(OH)
2
to hp
cht mu tm.

*Lu : Protein b
ng t khi un nng
lin kt peptit tr).


hoc khi gp axit,
baz, mt s mui

B. MT S CU HI TRC NGHIM
Lu :
- T n phn t -amino axit khc nhau th c
n! ng phn peptit (peptit cha n gc -amino
axit khc nhau)
- T n phn t -amino axit khc nhau th c
n
2
s peptit c to thnh
- S lng peptit cha n gc -amino axit (c
th trng nhau) t a phn t -amino axit (n>a) l
a
n

- S phn t -amino axit to peptit = s lin
kt peptit +1
Cu 1: Tripeptit l hp cht
A. m mi phn t c 3 lin kt peptit.
B. c lin kt peptit m phn t c 3 gc amino
axit ging nhau.
C. c lin kt peptit m phn t c 3 gc
amino axit khc nhau.
D. c 2 lin kt peptit m phn t c 3 gc -
amino axit.
Cu 2: C bao nhiu tripeptit m phn t cha 3
gc amino axit khc nhau?
A. 3 cht. B. 5 cht. C. 6 cht.
D. 8 cht.
Cu 3: Trong cc cht di y, cht no l
ipeptit ?
A. H
2
N-CH
2
-CO-NH-CH
2
-CH
2
-COOH.
B. H
2
N-CH
2
-CO-NH-CH(CH
3
)-COOH.
C. H
2
N-CH
2
-CO-NH-CH(CH
3
)-CO-NH-CH
2
-
COOH.
D. H
2
N-CH(CH
3
)-CO-NH-CH
2
-CO-NH-
CH(CH
3
)-COOH
Cu 4: T glyxin (Gly) v alanin (Ala) c th to
ra my cht ipeptit ?
A. 1 cht. B. 2 cht. C. 3
cht. D. 4 cht.
Cu 5: Sn phm cui cng ca qu trnh thy
phn cc protein n gin nh cht xc tc thch
hp l
A. -aminoaxit. B. -aminoaxit. C. axit
cacboxyliC. D. este.
Cu 6: S ng phn ipeptit to thnh t 1 phn
t glyxin v 1 phn t alanin l
A. 3. B. 1. C. 2.
D. 4.
Cu 7: Hp cht no sau y thuc loi ipeptit ?
A. H
2
N-CH
2
CONH-CH
2
CONH-CH
2
COOH.
B. H
2
N-CH
2
CONH-CH(CH
3
)-COOH.
C. H
2
N- CH
2
CH
2
CONH-CH
2
CH
2
COOH.
D. H
2
N-CH
2
CH
2
CONH-CH
2
COOH.
Cu 8: Mt trong nhng quan im khc nhau gia
protein so vi lipit v cacbohidrat l :
A. protein lun cha chc ancol (-OH). B.
protein lun cha nit.
C. protein lun l cht hu c no. D.
protein c phn t khi ln hn.
Cu 9: Sn phm cui cng ca qu trnh thy
phn cc protein n gin nh xc tc thch hp l:
A. amino axit. B. amino axit.
C. axit cacboxylic. D.
este.
Cu 10: Khi thy phn tripeptit H
2
N
CH(CH
3
)CO-NH-CH
2
-CO-NH-CH
2
-COOH s to
ra cc amino axit
A. H
2
NCH
2
COOH v CH
3
CH(NH
2
)COOH.
B. H
2
NCH
2
CH(CH
3
)COOH v H
2
NCH
2
COOH.
C. H
2
NCH(CH
3
)COOH v H
2
NCH(NH
2
)COOH.
D. CH
3
CH(NH
2
)CH
2
COOH v H
2
NCH
2
COOH.
Cu 11: Tn gi no sau y ph hp vi peptit c
CTCT: H
2
NCH
2
CONHCH(CH
3
)CONHCH
2
COOH
?
A. alanin -alanin-glyxin. B. alanin-glyxin-
alanin
C. glyxin -alanin-glyxin.
D. glyxin-glyxin- alanin.
Cu 12: Protein phn ng vi dung dch Cu(OH)
2

to sn phm c mu c trung l:
A. Mu tm B. mu vng C. mu
D. mu da cam
Cu 13: S tripeptit to thnh t 1 phn t glyxin
v 1 phn t alanin l
A. 8 B. 3. C. 5.
D. 4.
Cu 14: S tripeptit to thnh t 1 phn t glyxin,
1 phn t alanin v 1 phn t valin
A. 8 B. 16 C. 27
D.9
Cu 15: S kt ta protit bng nhit c gi l
A. s ngng t B. s trng ngng C.
s ng t D. s phn hu
Cu 16: Pht biu no di y v protein l
khng ng?
A. Protein l nhng polipeptit cao phn t (phn
t khi t vi chc ngn n vi triu vC)
B. Protein phc tp l nhng protein c to
thnh t protein n gin v lipit, gluxit, axit
nucleic,..
C. Protein n gin l nhng protein c to
thnh ch t cc gc - v -amino axit
D. Protein c vai tr l nn tng v cu trc v
chc nng ca mi s sng------