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Toxicity to nontarget
humans or organisms
Most insecticides have the capacity to affect non-target organisms Same as previously discussed
Highly toxic LD50 0 50 mg/kg Moderately toxic - LD50 50 500 mg/kg Low toxicity - LD50 500 5,000 mg/kg Nontoxic - LD50 <5,000 mg/kg
Environmental hazard
Environmental hazard of insecticides is generally evaluated as a function of persistence often compared to effectiveness
Environmental hazard
High Environmental persistence far greater than period of effectiveness (> 5 months and often > a year)
Environmental hazard
Intermediate Persists beyond effectiveness (3-5 month half-life)
Environmental hazard
Low Persists about the period of effectiveness (up to about 3 months) and then degrades completely over several months
Environmental hazard
Very low Persists for short periods (>45 days) and degrades completely
Resistance/Resurgence Hazard
The hazard of populations developing resistance and resurging is evaluated for most insecticides
Resistance/Resurgence Hazard
High Strong potential to develop resistance and resurge
Resistance/Resurgence Hazard
Intermediate Moderate potential to develop resistance in treated environments
Resistance/Resurgence Hazard
Low Minimal potential to develop resistance
Resistance/Resurgence Hazard
None No resistance developed, no resurgence after many treatments
IPM Attributes
IPM is especially important when discussing the use of insecticides due to the potential for the development of resistance and subsequent resurgence of pest populations repeatedly treated with a single insecticide Repeated treatment with a single pesticide imposes artificial genetic selection on insect populations
IPM Attributes
However, IPM must be effective and so there are several criteria to evaluate
Effectiveness in controlling pest populations Cost of treatment Human and nontarget-animal toxicity Environmental persistence
Insecticide groups
The following slides present a system in which insecticides are generally catagorized It is not the only system Lumpers and splitters of names have created very different categories, depending on their emphasis
Organochlorines
Organochlorines
Organochlorines
Organochlorines
Most affect a broad spectrum of nontarget organisms along with the target pests
Organochlorines
Organochlorines
Organochlorines
Organochlorines
Organochlorines
Organochlorines
Organophosphates
Organophosphates
Organophosphates
Organophosphates
Organophosphates
Organophosphates
Organophosphates
Several used in forestry or applied to forests for public health purposes
Malthion (Malathion and Cythion) Acephate (Orthene) Methyl parathion (Methyl parathion) Diazinon (Diazinon and Spectracide) Chlorpyrifos (Dursban and Lorsban) Azinphos methyl (Guthion)
Organophosphates
Most have been lost to forestry due to FQPA (Food Quality Protection Act) review performed by the EPA
Organosulfurs
Organosulfurs
Organosulfurs
Organosulfurs
Carbamates
Carbamates
Carbamates
Carbamates
Carbamates
Very few used in forestry
Carbaryl (Sevin) Aldicarb (Temik) Methomyl (Lannate)
Botanicals
Botanicals
May be present and subsequently extracted from the plant material (a constitutive chemical), or
Botanicals
Botanicals
Limited numbers of extractable chemicals have performed well enough to have been made commercially available
Botanicals
Some are chemically modified after extraction to enhance their insecticidal properties
Botanicals
Only a few have found a niche in forestry, and generally even these are subsequently replaced by more targetspecific, less persistent synthetic chemicals
Pyrethrins Resmethrin (Pyosect, Synthhrin) Azadirachtin (Azatin)
Synthetic Pyrethroids
Modified esters of chrysanthemate a chemical similar to that which is derived from chrysanthemums
Synthetic Pyrethroids
Alterations in the acid components yield a reduced degradation rate compared to natural pyrethrins
Synthetic Pyrethroids
Synthetic Pyrethroids
Synthetic Pyrethroids
Synergists or activators
Chemicals which perform any of a variety of actions which enhance the action of an insecticide
Synergists or activators
Increase the toxicity of the initial chemical above that expected from the combination of the two products
Block detoxification of insecticides by insect defensive systems Induce the functioning of otherwise benign chemicals
Synergists or activators
Produced by rending (cooking) animal fat (lard), fish oil or vegetable oil with an alkali metal such as sodium hydroxide (= hard soap) or potassium hydroxide (= soft soap)
Soft soaps from fish oils were the most common insecticidal soaps in the past since they are the most effective insecticidal soaps
Soft soaps made from vegetable oils are most common at the present time due to a better smell (not greater efficacy)
Soften or wash off the waxy epicuticle covering an insect allowing it to dehydrate
Microbial Pathogens
Fungi, bacteria, viruses, etc. which can be used to cause disease in an insect population
Microbial Pathogens
Microbial Pathogens
Several have been genetically engineered to kill target insects more rapidly
Microbial Pathogens
Bacteria in forestry
Bacillus thuringiensis var. karstaki (Dipel, Thuricide, Foray, Agrobac, Javelin, Cutlass)
Microbial Pathogens
Virus in forestry
Baculovirus (Nucleopolyhedrosis virus or NPV; Gypchek, TMBiocontrol-1)
Microbial Pathogens
Microbial Derivatives
Microbial Derivatives
Microbial Derivatives
Microbial Derivatives
Only one used in forestry at present
Avermectin (derived from Streptomyces avermitilis) Also available are:
spinosad (Tracer) pyrroles (Pirate)
Repellants
Repellants
Many experimental chemicals but to the present no truly effective forest protectant chemical
Repellants
Repellants
Forestry insect repellants include
Verbenone 4-allyl anisole (4AA) Both are anti-aggregant chemicals designed to disrupt pine beetle aggregation and thwart spot formation
Repellants
Oils
Lightweight petroleum oils mixed with emulsifiers may be used as insecticides in some cases
Oils
Broadly defined in two groups: Dormant oils are designed to be used to protect dormant plant materials and may have bad effects if used during the growing season Summer oils may be used to protect growing plants
Oils
Oils
Fumigants
Fumigants
Fumigants generally contain a halogen (chlorine, bromine, fluorine, etc.) in their molecules
Fumigants
Fumigants
Fumigants
Fumigants which have held forestry or ornamental insecticide registration
Methyl bromide (MC33, MC98, Brom-oSol, etc.) NFTA should eliminate this fumigant from the US by 2005 Dichloropropene Chloropicrin Metam-sodium (Vapam, Busan, Sectagon)