B GIO DC V O TO THI TRC NGHIM TUYN SINH I HC Mn: HO HC, KHI A (M thi: 410) Thi gian lm bi: 90 pht

I. PHN CHUNG CHO TT C CC TH SINH (44 cu, t cu 1 n cu 44) Cu 1. t chy hon ton mt ru no n chc thu c 3,6 gam nc v 3,36 dm 3 CO2 (ktc). Cng thc phn t ca ru b t l: A. CH3OH. B. C2H5OH. C. C3H7OH. D. C4H9OH. Cu 2. Dung dch cha 12,2 gam cht ng ng ca phenol n chc (phn t khng cha nguyn t cacbon bc hai) tc dng vi nc brom (d) thu c 35,9 gam hp cht cha ba nguyn t brom trong phn t. Gi thit phn ng hon ton, cng thc phn t cht ng ng l: A. CH3-C6H4-OH B. (CH3)2C6H3-OH C. C2H5-C6H4-OH D. C6H5-CH2-OH Cu 3. Cho 1,52g hn hp hai amin n chc no (c trn vi s mol bng nhau) tc dng va vi 200ml dung dch HCl, thu c 2,98g mui. Kt qu no sau y khng ng ? A. Nng mol dung dch HCl bng 0,2 (M). B. S mol mi cht l 0,02 mol. C. Cng thc ca hai amin l CH5N v C2H7N. D. Tn gi hai amin l metylamin v etylamin. Cu 4. Ly 0,94 gam hn hp hai andehit n chc no k tip nhau trong dy ng ng cho tc dng ht vi dung dch AgNO3/NH3 thu c 3,24 gam Ag. Cng thc phn t hai andehit ln lt l: A. CH3CHO v HCHO B. C2H5CHO v C3H7CHO C. CH3CHO v C2H5CHO D. C3H7CHO v C4H9CHO Cu 5. Cho cc cht: andehit axetic, axit fomic, ru etylic, dimetyl ete v cc nhit si: 100,7 0C; 210C; 0C; 78,30C. Dy 23 no sau y xp nhit si ng vi mi cht ? andehit axetic axit fomic ru etylic dimetyl ete A 100,70C 210C 78,30C 230C B 210C 100,70C 78,30C 230C C 100,70C 78,30C 210C 230C D 78,30C 210C 100,70C 230C Cu 6. Cc este c cng thc C4H6O2 c to ra t axit v ru tng ng l: A. CH2=CH-COO-CH3; CH3COO-CH=CH 2; H-COO-CH2-CH=CH 2; H-COO-CH=CH-CH3 v H-COO-C(CH3)=CH2 B. CH2=CH-COO-CH3; CH3COO-CH=CH 2; H-COO-CH2-CH=CH 2; H-COO-CH=CH-CH3 C. CH2=CH-COO-CH3; H-COO-CH2-CH=CH 2 D. CH2=CH-COO-CH3; CH3COO-CH=CH 2; H-COO-CH2-CH=CH 2 Cu 7. un 12,00 gam axit axetic vi 13,80 gam ancol etylic (c axit H2SO4 c lm xc tc). n khi phn ng dng li thu c 11,00 gam este. Hiu sut ca phn ng este ho l: A. 75,0% B. 62,5% C. 60,0% D. 41,67% Cu 8. Cho cc cht: a) HOCH2-CH2OH, b) HOCH2-CH2-CH2OH, c) CH3-CHOH-CH2OH, d) HOCH 2-CHOH-CH2OH Nhng cht thuc cng dy ng ng l: A. (a) vi (c). B. (a) vi (d). C. (a) vi (b). D. (a) vi (b), (c) Cu 9. Tnh lng kt ta Ag hnh thnh khi tin hnh trng gng hon ton dung dch cha 18 gam glucoz. A. 2,16 gam. B. 5,40 gam. C. 10,80 gam. D. 21,60 gam. Cu 10. Cho xenluloz, toluen, phenol, glixerin tc dng vi HNO 3 / H2SO4 c. Pht biu no sau y sai v cc phn ng ny ? A. Sn phm ca cc phn ng u cha nit. B. Sn phm ca cc phn ng u c nc to thnh. C. Sn phm ca cc phn ng u thuc loi hp cht nitro, d chy, n. D. Cc phn ng u thuc cng mt loi phn ng. Cu 11. Cu no sau y khng ng: A. Khi nh axit HNO3 c vo lng trng trng thy xut hin mu vng. B. Phn t cc protit gm cc mch di polipeptit to nn. C. Protit rt t tan trong nc v d tan khi un nng. D. Khi cho Cu(OH) 2 vo lng trng trng thy xut hin mu tm xanh. Cu 12. Khi t chy mt loi polime ch thu c kh CO 2 v hi H2 O vi t l s mol CO 2 = s mol H2O. Polime trn thuc loi: A. Poli(vinyclorua) B. Tinh bt C. Polietilen D. Protein Cu 13. Hy cho bit c ti a bao nhiu polime c to thnh t cc ru bc 2 c mch cacbon phn nhnh cng cng thc C6H14O ? A. 6 B. 7 C. 8 D. 9 Cu 14. Mt dn xut hirocacbon mch h cha 39,2% Clo. Bit rng 0,01 mol cht ny lm mt mu dd c 1,6g brm trong bng ti. Cng thc n gin ca dn xut l: A. C4H7Cl B. C2H5Cl C. C3H5Cl D. C4H9Cl Cu 15. S ng phn cu to ca C5H12, C4H8 v C4H9Cl ln lt l: A. 3, 3, 4 B. 4, 5, 3 C. 4, 3, 4 D. 3, 5, 4

Cu 16. t chy hon ton mt hidrcacbon A thu c 4,84g CO 2 v 2,376g H2O. Cho A tc dng vi clo theo t l mol 1:1th ch thu c mt sn phm duy nht. A c gi l: A. iso-buten B. iso-pentan C. neo-pentan D. neo-hexan. Cu 17. X v Y l hai hirocacbon mch nhnh c cng cng thc phn t l C 5H8 .X l monome tng hp cao su. Y to kt ta khi phn ng vi dung dch Ag2O trong NH3, Tn gi ca X v Y tng ng l: A. Pentadien 1,3 v 3-Metyl butin 1. B. 2 - Metyl butadien 1,3 v Pentin 1. C. 2 - Metyl butadien 1,3 v 3- Metyl butin 1. D. 2 - Metyl butadien 1,3 v Pentin 2. Cu 18. Cng thc chung no sau y khng ng: A. xycloparafin: CnH2n B. diolefin: CnH2n-2. C. olefin: CnH2n D. aren: CnH2n-6. Cu 19. 3,0 lt (ktc) hn hp metan v etilen qua dung dch Br2 d to thnh 4,7 gam 1,2-dibrometan. % th tch ca metan l: A. 81,3% B. 42,0% C. 18,7% D. 89,7% Cu 20. Hp cht hu c (CH3)2CH-CBr(C2H5)-CH2-CH2-CH3 c tn gi l: A. 4-brom-4-etyl-5-metyl hexan. B. 4-brom-5,5-dimetyl-4-etyl pentan. C. 3-brom-3-etyl-2-metyl hexan. D. 3-brom-3-isopropyl hexan. Cu 21. C nhng vt bng st c m bng nhng kim loi khc nhau di y. Nu cc vt ny u b sy st su n lp st, th vt no b g st chm nht ? A. St trng km. B. St trng thic. C. St trng niken. D. St trng ng. Cu 22. Trong cc cu sau, cu no khng ng: A. n mn kim loi l s ph hu kim loi v hp kim dui tc dng ho hc ca mi trng xung quanh. B. n mn kim loi l mt qu trnh ho hc trong kim loi b n mn bi cc axit trong mi trng khng kh. C. Trong qu trnh n mn, kim loi b oxi ho thnh ion ca n. D. n mn kim loi c chia lm hai dng: n mn ho hc v n mn in ho. Cu 23. Ho tan 58 gam mui CuSO 4.5H2O vo nc c 500 ml dung dch CuSO 4. Cho dn dn bt st vo 50 ml dung dch trn, khuy nh cho n khi ht mu xanh. Lng st tham gia phn ng l A. 2,5984 gam B. 1,2992 gam C. 0,6496 gam D. 1,9488 gam Cu 24. Phn ng in phn nng chy no di y b vit sai sn phm: dpnc dpnc A. Al2O3 2Al + 3/2O2 B. 2NaOH 2Na + O2 + H2 dpnc dpnc C. 2NaCl 2Na + Cl2 D. Ca3N2 3Ca + N2 Cu 25. Chn th t gim dn hot ng ho hc ca cc kim loi kim: A. Na - K - Cs - Rb - Li B. Cs - Rb - K - Na - Li C. Li - Na - K - Rb - Cs D. K - Li - Na - Rb - Cs Cu 26. Trong qu trnh in phn dung dch NaCl, cc m xy ra: A. s kh ion Na+. B. s kh phn t nc. C. s oxi ho ion Na+. D. s oxi ho phn t nc. Cu 27. Nhng m t ng dng no di y khng chnh xc ? A. CaO lm vt liu chu nhit, iu ch CaC2, lm cht ht m. B. Ca(OH)2 dng iu ch NaOH, ch to va xy nh, kh chua t trng, ch to clorua vi. C. CaCO3 dng sn xut xi mng, vi sng, vi ti, kh cacbonic. D. CaSO4 dng sn xut xi mng, phn vit, b bt. Thch cao khan dng c tng, mu trang tr ni tht. Cu 28. Nc cng l nc c cha nhiu cc ion: A. Na+ v Mg2+ B. Ba2+ v Ca2+ C. Ca2+ v Mg2+ D. K+ v Ba2+ Cu 29. Cho dung dch NH3 n d vo dung dch cha AlCl 3 v FeCl3 thu c kt ta A. Nung kt ta A c cht rn B. Cho lung H2 i qua B nung nng s thu c cht rn l: A. Fe B. Al2O3 v Fe C. Al, Fe D. Al2O3 v Fe2O3 Cu 30. Cho 3,5 gam hn hp ba kim loi Fe, Al, Zn tan hon ton trong dung dch HCl ta thu c 2,24 lit H 2 ( ktc). Khi c cn thu c hn hp mui khan c khi lng l: A. 7,05 gam B. 5,275 gam C. 10,6 gam D. 5,3 gam Cu 31. Nhn xt v tnh cht ha hc ca cc hp cht Fe (III) no di y l ng ? Hp cht Tnh axit - baz Tnh oxi ha - kh A. Fe2O3 Axit Ch c tnh oxi ha B. Fe(OH)3 Baz Ch c tnh kh C. FeCl3 Trung tnh Va oxi ha va kh D. Fe2(SO4)3 Axit Ch c tnh oxi ha Cu 32. Phn ng no di y khng to sn phm l hp cht Fe(III) ?

A. FeCl3 + NaOH C. Fe(OH)3

B. FeCO3

Cu 33. Dung dch cha 3,25 gam mui clorua ca mt kim loi cha bit phn ng vi AgNO 3 d tch ra 8,61 gam kt ta trng. Cng thc ca mui clorua kim loi l: A. MgCl 2 B. CuCl2 C. FeCl2 D. FeCl3

D. Fe(OH)3 + H2SO4

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Cu 34. thu c cng mt th tch O2 nh nhau bng cch nhit phn KMnO 4, KClO3, KNO3, CaOCl2 (hiu sut bng nhau). Cht c khi lng cn dng t nht l: A. KMnO 4 B. KNO3 C. KClO3 D. CaOCl 2 Cu 35. S va l cht kh, va l cht oxi ha trong phn ng no sau y A. S + O2 SO2 B. S + 6HNO3 H2SO4 + 6NO2 + 2H2O C. S + Mg MgS D. S + 6NaOH 2Na2S + Na2SO3 + 3H2O Cu 36. tch kh H2S ra khi hn hp vi kh HCl, ngi ta dn hn hp qua dung dch A ly d. Dung dch l: A. Dung dch Pb(NO3)2 B. Dung dch NaOH C. Dung dch AgNO3 D. Dung dch NaHS Cu 37. Bc tip xc vi khng kh c H 2 S b bin i thnh Ag 2 S c mu en: 4Ag + 2H 2 S + O 2 2Ag 2 S + 2H 2 O. Cu no sau y din t ng tnh cht ca cc cht phn ng ? A. Ag l cht kh, H2S l cht oxi ho. B. Ag l cht kh, O2 l cht oxi ho. C. Ag l cht oxi ho, H2S l cht kh. D. Ag l cht oxi ho, O2 l cht kh. Cu 38. C sn 20 gam dung dch NaOH 30%, cn trn thm bao nhiu gam dung dch NaOH 10% thu c dung dch NaOH 25%: A. 12 g B. 6,67 g C. 3,27 g D. 11,3 g Cu 39. Axit nitric u phn ng c vi nhm cc cht no ? A. MgO, FeO, NH3, HCl. B. KOH, MgO, NH4Cl. C. NaCl, KOH, Na2CO3. D. FeO, H2S, NH3, Pt. Cu 40. Ho tan 27,2 gam hn hp bt Fe v FeO trong dung dch axit sunfuric long, sau lm bay hi dung dch thu c 111,2 gam FeSO4.7H2O. Thnh phn % khi lng cc cht trong hn hp l: A. 29,4% Fe v 70,6% FeO B. 24,9% Fe v 75,1% FeO C. 20,6% Fe v 79,4% FeO D. 26,0% Fe v 74,0% FeO Cu 41. Cho glixerin tc dng vi HCl, thu c sn phm (X) cha 32,1% clo. Cng thc cu to gn ca (X) l: A. CH2Cl - CHOH - CH2OH B. CH2Cl - CHOH - CH2Cl C. CH2OH CCl 2 - CH2OH D. CH2Cl - CHCl - CH2Cl Cu 42. Oxi ha 4 gam ru n chc R bng O 2 ( xc tc) thu c 5,6 gam hn hp X gm anehit, ru d v nc. Tn ca R v hiu sut phn ng l: A. Metanol v 80% B. Propanol-1 v 80% C. Etanol v 75% D. Metanol v75% Cu 43. 1,76 gam mt este ca axit cacboxylic no, n chc v mt ru no, n chc phn ng va ht vi 40 ml dung dch NaOH 0,50M thu c cht A v cht B. t chy hon ton 1,20 gam cht B cho 2,64 gam CO 2 v 1,44 gam nc. Cng thc cu to ca este l: A. CH3COO-CH2CH2CH3 B. CH3CH2COOCH 3 C. CH3COO-CH3 D. H-COO-CH2CH2CH3 Cu 44. Cho mt hn hp A cha NH3, C6H5NH2 v C6H5OH. A c trung ha bi 0,02 mol NaOH hoc 0,01 mol HCl. A cng phn ng va vi 0,075 mol Br2 to kt ta. Lng cc cht NH3, C6H5NH2 v C6H5OH ln lt bng: A. 0,01 mol; 0,005 mol v 0,02 mol B. 0,005 mol; 0,005 mol v 0,02 mol C. 0,005 mol; 0,02 mol v 0,005 mol D. 0,01 mol; 0,005 mol v 0,02 mol II. PHN RING: Th sinh ch c lm mt trong hai phn (phn A hoc phn B). A. Phn dnh cho th sinh chng trnh phn ban. (6 cu, t cu 45 n cu 50) Cu 45. Cho s chuyn H 2O Br2 + H 2O + CuO 4 10 1 2 3 H 2 SO4 dd OH to

Cu 49. C 5 l mt nhn cha cc dung dch: KNO 3, Cu(NO3)2, FeCl3, AlCl3, NH4Cl. Ch dng mt ho cht no sau y phn bit c 5 cht trn ? A. dung dch NaOH d B. dung dch Na2SO4 C. dung dch AgNO3 D. dung dch HCl Cu 50. Mt hn hp A gm Ba v Al. Cho m gam A tc dng vi nc d, thu c 1,344 lt kh, dung dch B v phn khng tan C. Cho 2m gam A tc dng vi dung dch Ba(OH) 2 d thu c 20,832 lt kh. (Cc phn ng u xy ra hon ton, cc th tch kh o iu kin tiu chun). Khi lng tng kim loi trong m gam A l: A. 8,220 gam Ba v 7,29 gam Al B. 8,220 gam Ba v 15,66 gam Al C. 2,055 gam Ba v 8,1 gam Al D. 2,055 gam Ba v 16,47 gam Al B. Phn dnh cho th sinh chng trnh khng phn ban: (6 cu, t cu 51 n cu 56) Cu 51. Trong cng nghip, nhm c sn xut bng cch: A. cho kim loi magie y nhm ra khi dung dch mui nhm. B. in phn dung dch nhm clorua. C. in phn nhm oxit nng chy, c xc tc criolit. D. cho st tc dng vi nhm oxit ( nhit cao). Cu 52. Trong phn ng ha hc vi dung dch axit hoc vi phi kim, st c th to ra hp cht trong st c s oxi ha A. +2 hoc +3. B. +2 hoc + 6. C. +1 hoc +2. D. 2+ hoc 3+. Cu 53. Cht no sau y c th kh c ion Cu2+ thnh nguyn t Cu? 2+ 3+ A. Fe. B. Fe . C. Ag. D. Al . Cu 54. in phn dung dch c cc mui nitrat ca cc kim loi ng, km, bc cng nng mol. Th t in phn trn cc m ca cc ion kim loi l A. Cu2+, Ag+, Zn2+. B. Ag+, Cu2+, Zn2+. C. Zn2+, Cu2+, Ag+. D. Cu2+, Zn2+, Ag+. Cu 55. Anken Y tc dng vi brom to thnh dn xut ibrom trong phn trm khi lng cacbon bng 17,82%. Cng thc phn t ca Y l A. C3H6. B. C4H8. C. C4H10. D. C5H10. Cu 56. Cht hu c X c cng thc phn t C 4H8O2 tc dng c vi natri sinh ra hiro v vi dung dch AgNO 3 trong NH3. Cng thc cu to ca X l A. CH3COOH. B. CH3COCH 2CH2OH. C. HOCH 2CH2CH2CHO. D. HCOOC3H7.

1 C 15 D 2 9 B 4 3 D

2 B 1 6 C 3 0 C 4 4 B

3 D 1 7 C 3 1 D 45 C

4 B 1 8 D 3 2 B 4 6 D

5 B 1 9 A 3 3 D 4 7 A

6 C 2 0 C 3 4 C 4 8 C

7 B 2 1 A 3 5 D 4 9 A

8 D 2 2 B 3 6 D 50 C

9 D 2 3 B 3 7 B 51 C

1 0 D 2 4 B 3 8 B 52 A

1 1 C 25 B 3 9 A 5 3 A

1 2 C 2 6 B 4 0 C 54 B

1 3 A 2 7 A 4 1 A 55 A

14 A 28 C 42 A 56 C

ho:

( X )C H O X X X Dixeton

Cng thc cu to ca X c th l : A. CH2(OH)CH 2CH2CH3 B. CH3CH(CH 3)CH2OH C. CH3CH(OH)CH 2CH3 D. CH3C(CH3)2OH Cu 46. Cu hnh electron no di y l ng vi ion Cr3+ ? 2 4 A. (Ar) 4s 3d B. (Ar) 4s23d6 C. (Ar) 4s13d4 D. (Ar) 3d3 2 Cu 47. Phn ng ( c cn bng) ca trong mi trng axit to ra v MnO 2 l: 4 4 2 A. 3 + 4H+ 2 + MnO 2 + 2H2O 4 4 2 B. 3 2 + MnO 2 + O2 4 4 2 C. 2 + 2H2O + MnO 2 + 2H2 + 2O2 4 4 2 D. 2 + 2OH + MnO 2 + H2 + O2 4 4 Cu 48. t chy bt crom trong oxi d thu c 2,28 gam mt oxit duy nht. Khi lng crom b t chy l: A. 0,78 gam B. 1,74 gam C. 1,56 gam D. 1,19 gam

MnO

MnO

MnO MnO MnO MnO

MnO MnO MnO MnO

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TRNG THPT CHUYN H TNH THI TH I HC V CAO NG 2006 2007 Mn thi: HO HC Thi gian lm bi: 90 pht Cu 1. Kt lun no biu th ng v kch thc ca nguyn t v ion ? A. Na < Na + , F > F - . B. Na < Na + , F < F - . C. Na > Na + , F > F - . D. Na > Na + , F < F - .

C.

MnO4 b oxi ho.

D.

MnO4 khng mu trong dung dch axit.

Cu 16. Cho mt gam bt st tip xc vi oxi mt thi gian thu c 1,24 gam hn hp Fe 2 O 3 v Fe d. Lng Fe d l: A. 0,036g. B. 0,44g. C. 0,87g. D. 1,62g. Cu 17. kh hon ton 6,4 gam mt oxt kim loi cn 0,12 mol kh H 2 . Mt khc ly lng kim loi to thnh cho tan hon ton trong dung dch H 2 SO 4 long th thu c 0,08 mol H2 . Cng thc oxit kim loi l: A. CuO. B. Al 2 O 3 . C. Fe 3 O 4 . D. Fe 2 O 3 . Cu 18. t chy hon ton 8,8 gam FeS v 12 gam FeS 2 thu c kh. Cho kh ny sc vo V ml dung dch NaOH 25% (d = 1,28g / ml) c mui trung ha. Gi tr ti thiu ca V l: A. 50ml. B. 75ml. C. 100ml. D. 120ml. Cu 19. Dung dch X cha NaOH 0,2M v Ca(OH) 2 0,1M. Sc 7,84 lt kh CO 2 (ktc) vo 1 lt dung dch X th khi lng kt ta thu c l: A. 15 gam. B. 5 gam. C. 10 gam. D. 0 gam. Cu 20. Cho cc phn ng: C 6 H 5 NH 3 Cl + (CH 3 ) 2 NH (CH 3 ) 2 NH 2 Cl + C 6 H 5 NH 2 (I) (CH 3 ) 2 NH 2 Cl + NH 3 NH 4 Cl + (CH 3 ) 2 NH (II) Trong phn ng t xy ra l: A. (I). B. (II). C. (I), (II).

Cu 2. Cho 0,54 gam Al vo 40 ml dung dch NaOH 1M, sau phn ng hon ton thu c dung dch X. Cho t t dung dch HCl 0,5M vo dung dch X thu c kt ta. thu c lng kt ta ln nht cn th tch dung dch HCl 0,5M l: A. 110 ml. B. 90 ml. C. 70 ml. D. 80 ml. Cu 3. Mi cht v ion trong dy sau va c tnh kh, va c tnh oxi ho: A. SO 2 , S, Fe 3+. B. Fe 2+ , Fe, Ca, KMnO 4 . C. SO 2 , Fe 2+, S, Cl 2 . D. SO 2 , S, Fe 2+, F 2 . Cu 4. Kim loi nhm b oxi ho trong dung dch kim (dung dch NaOH). Trong qu trnh cht oxi ho l: A. Al. B. H 2 O. C. NaOH. D. H 2 O v NaOH. Cu 5. Mi phn t v ion trong dy sau va c tnh axit, va c tnh baz: A. 4 2 3 3 2

HSO , ZnO, Al O , HCO , H O, CaO.

B. C. D.

+ NH 4 , HCO3 , CH 3 COO .

D. khng c.

ZnO, Al 2 O3 , HCO3 , H 2 O. HCO3 , Al 2 O3 , Al 3+ , BaO. HCO3 y mol. Khi c cn dung dch Y ta

D. 30,5g.

Cu 21. Cho a mol Cu kim loi tan hon ton trong 120ml dung dch X gm HNO 3 1M v H 2 SO 4 0,5M (long) thu c V lt kh NO duy nht (ktc). Tnh V A. 14,933a lt. B. 12,32a lt. C. 18,02a lt. D. Kt qu khc. Cu 22. Ho tan ht m gam hn hp gm FeO, Fe 2 O 3 v Fe 3 O 4 bng HNO 3 c, nng thu c 4,48 lt kh NO 2 (ktc). C cn dung dch sau phn ng c 145,2 gam mui khan. Gi tr ca m l: A. 35,7g. B. 46,4g. C. 15,8g. D. 77,7g. Cu 23. S ng phn c cng thc phn t C 4 H 10 O l: A. 5. B. 6. C. 7. D. 8.

Cu 6. Dung dch Y cha Ca 2+ 0,1 mol , Mg 2+ 0,3 mol, Cl - 0,4 mol , thu c mui khan c khi lng l: A. 37,4g. B. 49,8g. C. 25,4g.

Cu 7. Mi cht trong dy sau ch phn ng vi dung dch axit sunfuric c, nng m khng phn ng vi dung dch axit sunfuric long: A. Al, Fe, FeS 2 , CuO. B. Cu, S C. Al, Fe, FeS 2 , Cu. D. S, BaCl 2 . Cu 8. Cho s phn ng:
H 2O HCl NaOH HNO t X ddX Y KhX 3 Z T + H 2O .
o

Cu 24. Hai anken c cng thc phn t C 3 H 6 v C 4 H 8 khi phn ng vi HBr thu c 3 sn phm, vy 2 anken l: A. xiclopropan v but-1-en. B. propen v but-1-en. C. propen v but-2-en. D. propen v metyl propen. Cu 25. un nng mt ru X vi H 2 SO 4 c lm xc tc nhit thch hp thu c mt olefin duy nht. Cng thc tng qut ca X l (vi n>0, nguyn): A. C n H 2n+1OH. B. ROH. C. C n H 2n+1CH 2 OH. D. C n H 2n+2O. Cu 26. un nng hn hp etanol v propanol-2 vi axit oxalic c xc tc H 2 SO 4 m c c th thu c ti a bao nhiu este hu c a chc ? A. 2. B. 3. C. 4. D. 5. Cu 27. Khi t chy mt ru n chc (X) thu c CO 2 v hi nc theo t l th tch CO2 H 2O A. C 4 H 10 O 2 .

Trong X l: A. NH 3 .

B. CO 2 .

C. SO 2 .

D. NO 2 .

Cu 9. Cho 8,00 gam canxi tan hon ton trong 200 ml dung dch hn hp HCl 2M v H 2 SO 4 0,75M thu c kh H 2 v dung dch X. C cn dung dch X thu c lng mui khan l: A. 22,2gam. B. 25,95gam. C. 22,2gam m 25,95gam. D. 22,2gam m 27,2gam. Cu 10. Cho 1,04 gam hn hp 2 kim loi tan hon ton trong H 2 SO 4 long d thy c 0,672 lt kh thot ra iu kin tiu chun. Khi lng hn hp mui sunfat khan thu c l: A. 3,92 gam. B. 1,68 gam. C. 0,46 gam. D. 2,08 gam. Cu 11. lm sch mui n c ln tp cht CaCl 2 , MgCl 2 , BaCl 2 cn dng 2 ho cht l: A. dung dch Na 2 CO 3 , dung dch HCl B. dung dch NaOH, dung dch H 2 SO 4 . C. dung dch Na 2 SO 4 , dung dch HCl. D. dung dch AgNO 3 , dung dch NaOH. Cu 12. phn bit 3 dung dch NaOH, HCl, H 2 SO 4 ch cn dng mt thuc th l: A. Na 2 CO 3 . B. Al. C. BaCO 3 . D. Qu tm Cu 13. Mt dung dch hn hp cha a mol NaAlO 2 v a mol NaOH tc dng vi mt dung dch cha b mol HCl. iu kin thu c kt ta sau phn ng l: A. a = b. B. a = 2b. C. b = 5a. D. a < b < 5a. Cu 14. Cho 11,1 gam hn hp hai mui sunft trung ho ca 2 kim loi kim hai chu k lin tip tan hon ton trong dung dch HCl d thu c 2,24 lt kh SO 2 (ktc). Hai kim loi l: A. Li, Na. B. Na,K. C. K,Cs. D. Na, Cs. Cu 15. Khi phn ng vi Fe 2+ trong mi trng axit, l do no sau y khin A.

:V

= 4 : 5 . Cng thc phn t ca X l:

B. C 3 H 6 O.

C. C 4 H 10 O.

D. C 5 H1 2 O.

Cu 28. Cng thc n gin nht ca anehit no, mch h X l C 2 H 3 O. X c cng thc phn t l: A. C 2 H 3 O. B. C 4 H 6 O 2 . C. C 8 H 12 O 4 . D. C 12 H 18 O 6 . Cu 29. Cho s phn ng sau:

propilen + Cl2 X + NaOH Y + CuO ,t propenal . ,500 C C

Tn gi ca Y l: A. propanol. B. propenol. C. axeton. D. axit propionic. Cu 30. Trong phn ng este ho gia ru v axit hu c, yu t khng lm cn bng ca phn ng este ho chuyn dch theo chiu thun l: A. Cho ru d hay axit d. B. Dng cht ht nc tch nc. C. Chng ct ngay tch este ra. D. S dng axit mnh lm xc tc. Cu 31. Cho cht Y (C 4 H 6 O 2 ) tc dng vi dung dch NaOH thu c 2 sn phm u c kh nng phn ng trng gng. Cng thc cu to ca Y l: A. CH 3 COOCH CH 2 . B. HCOOCH 2 CH CH 2 . C. HCOOCH CHCH 3 . D. HCOOC(CH 3 ) CH 2 . Cu 32. t chy hp cht hu c X thu c CO 2 v H 2 O. Khi lng phn t ca X l 74 vc. X tc dng c vi Na, dd NaOH, dd AgNO 3 / NH 3 . Cng thc phn t ca X l: A. C 4 H 10 O. B. C 3 H 6 O 2 . C. C 2 H 2 O 3 . D. C 6 H 6 . Cu 33. Cho s bin ho (gi s cc phn ng u hon ton):

MnO4 mt mu ?
Trang 3

MnO

to phc vi Fe 2+ . 4

B.

MnO

b kh cho ti Mn 2+ khng mu. 4

C Triolein + NaOH X + HCl X 1 + H 2,t X 2 . ,t , Ni C

Tn ca X 2 l: A. Axit oleic. Cu 34. Cho phn ng: B. Axit panmitic. C. Axit stearic. D. Axit linoleic.

hiro ho hon ton cng lng hn hp X trn cn 0,2 mol H 2 thu c hn hp hai ru. t chy hon ton lng hn hp hai ru trn th s mol H 2 O thu c l: A. 0,4 mol. B. 0,6 mol. C.0,8 mol. D. 0,3mol. Cu 43. t chy hon ton hn hp gm 1 ankan v 1 anken. Cho sn phm chy ln lt i qua bnh 1 ng P 2 O 5 d v bnh 2 ng KOH rn, d, sau th nghim thy khi lng bnh 1 tng 4,14 gam bnh 2 tng 6,16 gam. S mol ankan c trong hn hp l: A. 0,06 mol. B. 0,09 mol. C. 0.03 mol. D. 0,045 mol. Cu 44. t chy hon ton m gam hn hp 2 ru ng ng lin tip thu c 0,66 gam CO 2 v 0,45 gam H 2 O. Nu tin hnh oxi ha m gam hn hp ru trn bng CuO, sn phm to thnh cho tc dng vi AgNO 3 /NH 3 d s thu c lng kt ta Ag l: A. 10,8gam. B. 3,24gam. C. 2,16gam. D. 1,62gam. Cu 45. Kt lun no sau y khng ng ? A. Cc thit b my mc bng kim loi tip xc vi hi nc nhit cao c kh nng b n mn ho hc. B. p tm km vo mn tu thu lm bng thp (phn ngm di nc) th v tu thu c bo v. C. vt bng thp ra ngoi khng kh m th vt b n mn in ho. D. hp lm bng st ty(st trng thic) b xy xt, trong khng kh m b n mn in ho th thic s b n mn trc.

Cng thc cu to ca Y l:

Cu 46. lm sch CO 2 b ln tp kh HCl v hi nc th cho hn hp ln lt i qua cc bnh ng (lng d): A. dd NaOH v dd H 2 SO 4 . B. dd Na 2 CO 3 v P 2 O 5 . C. dd H 2 SO 4 v dd KOH. D. dd NaHCO 3 v P 2 O 5 . Cu 47. kh hon ton 3,04 gam hn hp Y (gm FeO, Fe 3 O 4 , Fe 2 O 3 ) th cn 0,05 mol H 2 . Mt khc ho tan hon ton 3,04 gam hn hp Y trong dung dch H 2 SO 4 c th thu c th tch kh SO 2 (sn phm kh duy nht) iu kin tiu chun l: A. 224 ml. B. 448 ml. C. 336 ml. D. 112 ml. Cu 48. t chy hon ton 5,8 gam mt axit cacboxylic mch thng thu c 0,2 mol CO 2 v 0,1mol H 2 O. Cng thc phn t ca axit l: A. C 2 H 4 O 2 . B. C 3 H 4 O 4 . C. C 4 H 4 O 4 . D. C 6 H 6 O 6 . Cu 49. Mi ankan c cng thc trong dy sau s tn ti mt ng phn tc dng vi Clo theo t l 1:1 to ra monocloroankan duy nht ? A. C 2 H 6 ; C 3 H 8 ; C 4 H 10 ; C 6 H 14 . B. C 2 H 6 ; C 5 H 12 ; C 8 H 18 . C. C 3 H 8 ; C 6 H 14 ;C 4 H 10 . D. C 2 H 6 ; C 5 H 12 ; C6H 14 . Cu 50. Cho s chuyn ho sau:
Br2 C2 H 4 X 1 + NaOH X 2 CuO X 3 Cu (OH )2 +2 NaOH X 4 + H 2 HOOC COOH SO4

A.

B.

C.

D.

Cu 35. 1 mol aminoaxit Y tc dng va vi 1 mol HCl. 0,5mol Y tc dng va vi 1 mol NaOH. Phn t khi ca Y l: 147vc. Cng thc phn t ca Y l: A. C 5 H 9 NO 4 . B. C 4 H 7 N 2 O 4 . C. C 5 H 7 NO 4 . D. C 7 H 10 O 4 N 2 . Cu 36. Tnh cht c trng ca saccaroz l: 1. tham gia phn ng hiro ho. 2. cht rn kt tinh, khng mu. 3. khi thu phn to ra glucoz v fructoz. 4. tham gia phn ng trng gng. 5. phn ng vi ng(II) hiroxit. Nhng tnh cht no ng ? A. 3, 4, 5. B. 1, 2, 3, 5.

X3, X4 l n l t l: A. OHC-CH 2OH, NaOOC-CH 2OH. C. OHC- CHO, NaOOC-COONa.

B. OHC-CHO, CuC 2O4 . D. HOCH 2-CH 2OH, OHC-CHO.

C. 1, 2, 3, 4.

D. 2, 3, 5.

1 2 3 4 5 6 7 8 9 10

D D C B C A B A B A

11 12 13 14 15 16 17 18 19 20

A C D A B B D B B A

21 22 23 24 25 26 27 28 29 30

A B C C C B C B B D

31 32 33 34 35 36 37 38 39 40

C C C A A D A C A B

41 42 43 44 45 46 47 48 49 50

B B B B D D A C B C

Cu 37. Fructoz khng phn ng vi cht no sau y ? A. Dung dch Br 2 . B. H 2 /Ni,t o C. C. Cu(OH) 2 trong dung dch NaOH. D. Dung dich AgNO 3 trong NH 3 . Cu 38. Khi clo ho PVC thu c mt loi t clorin cha 66,6% Clo theo khi lng. S mt xch trung bnh ca PVC tc dng vi mt phn t clo l: A. 1,5. B. 3. C. 2. D. 2,5. Cu 39. Chn phn ng sai: A. Phenol + dung dch brm

axit picric + axit brmhiric.

o

C t Andehit benzoic + ng + nc. o C. Propanol-2 + ng(II) oxit t C Axeton + ng + nc. o D. Etilen glycol + ng(II) hirxit t C dung dch mu xanh thm + nc. B. Ru benzylic + ng(II) oxit Cu 40. t chy hon ton 2,6 gam hn hp (X) gm 2 anhit no, mch h c cng s nguyn t ccbon trong phn t thu c 0,12 mol CO 2 v 0,1 mol H 2 O. Cng thc phn t ca 2 anhit l: A. C 4 H 8 O, C 4 H 6 O 2 . B. C 3 H 6 O, C 3 H 4 O 2 . C. C 5 H 10 O, C 5 H 8 O 2 . D. C 4 H 6 O 2 , C 4 H 4 O 3 . Cu 41. nhn bit 3 l mt nhn: phenol, stiren, ru benzylic, ngi ta dng mt thuc th duy nht l: A. Natri. B. Nc brm. C. Dung dch NaOH. D. Ca(OH) 2 . Cu 42. t chy hon ton m gam hn hp X gm hai anehit no, n chc, mch h c 0,4 mol CO 2 . Mt khc

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TRNG THPT CHUYN HNG YN THI TH I HC CAO NG THNG 4 NM 2009 Mn: HA HC, KHI A Thi gian lm bi: 90 pht

I. PHN CHUNG CHO TT C TH SINH. (40 cu, t cu 1 n cu 40) Cu 1. Cho s :

Bit A 1, A4 u c kh nng phn ng c vi AgNO3 /NH3 . A2, A5 , A6 ln lt l: A. C4H4 ; CH3COONa; CH3 COOC2 H3. B. CH3COOH; C 3H8; C2 H4. C. CH3COONH4; CH3 COONa; CH3CHO. D. C 4 H 6 ; CH 3 COONa; CH 3 COOC 2 H 3 . Cu 2. bo qun dung dch Fe 2 (SO4 )3 , trnh hin tng thu phn, ngi ta thng nh vo dung dch vi git: A. dd NH3 B. dd NaOH C. dd H 2 SO 4 D. dd BaCl2 Cu 3. Cho cc hp cht hu c sau: Glucoz, Saccaroz, Fructoz, Tinh bt, Glyxerol. C bao nhiu cht KHNG tham gia phn ng trng bc ? A. 1 cht B. 2 cht C. 3 cht D. 4 cht Cu 4. in phn 100ml dung dch CuSO4 0,2M vi cng I = 9,65A. Tnh khi lng Cu bm bn catot sau khong thi gian in phn t 1 = 200s v t 2 = 500s (gi thit hiu sut in phn l 100%): A. 0,32g; 0,64g B. 0,64g; 1,28g C. 0,64g; 1,6g D. 0,32g; 1,28g Cu 5. Cho dung dch cha a mol NaHCO 3 vo dung dch cha b mol Ba(OH) 2 . Sau khi phn ng xong lc b kt ta, dung dch nc lc thu c cha cht g nu b < a < 2b: A. NaHCO3, Ba(HCO3 )2 B. NaHCO3 , Na2 CO3 C. NaOH, Ba(OH)2 D. NaOH, Na 2 CO 3 Cu 6. Thy phn hp cht C3H5 Cl 3 bng dung dch NaOH, kt qu thu c bao nhiu hp cht hu c n chc. A. 1 B. 2 C. 3 D. 4 Cu 7. t chy hon ton 0,1 mol ancol no, mch h X cn va 5,6 lt oxi (ktc). X cng vi axit HOOCC6 H4COOH l 2 monome c dng iu ch polime, lm nguyn liu sn xut t: A. Nilon-6,6. B. Capron. C. Lapsan. D. Enang. Cu 8. Nguyn t H ch yu c 2 ng v 1H v 2 H. Nguyn t O c 3 ng v 16O, 17 O, 18O. S phn t H 2O to ra t cc loi ng v trn ca 2 nguyn t l: A. 3 B. 6 C. 9 D. 12 Cu 9. Hn hp kh X gm hidrocacbon A v H 2 d c ng hon ton c hn hp Y c

d X / H 2 = 4,8 . Cho X qua Ni nung nng n phn

d Y / H 2 = 8 . Cng thc A l:

A. C 3 H 4 B. C2 H2 C. C2H4 D. C4 H6. Cu 10. Ho tan 20,8 gam hn hp bt gm FeS, FeS 2, S bng dung dch HNO3 c nng d thu c 53,76 lt NO2 (sn phm kh duy nht, kc v dung dch A. Cho dung dch A tc dng vi dung dch NaOH d, lc ly ton b kt ta nung trong khng kh n khi lng khng i th khi lng cht rn thu c l: A. 16 gam B. 9 gam C. 8,2 gam D. 10,7 gam Cu 11. un etylen glicol vi hn hp gm ba axit (axit axetic, axit fomic v axit propionic) c H 2 SO4 c lm xc tc. C th thu c ti a bao nhiu este a chc ? A. 8. B. 6. C. 4. D. 10. Cu 12. Cho 11,2 gam hh Cu v kim loai M tc dng vi dung dch HCl d thu c 3,136 lt (ktc). Cng lng hn hp ny cho tc dng ht vi dung dch HNO 3 long thu c 3,92 lt kh NO (ktc, sn phm kh duy nht). Kim loi M l: A. Mg B. Fe C. Mg hoc Fe D. Mg hoc Zn. Cu 13. C cc cht sau: 1. magie oxit; 2. cacbon; 3. kali hiroxit; 4. axit flohiric; 5. axit clohiric. Silic ioxit phn ng vi tt c cc cht trong nhm no sau y ? A. 1, 2, 3, 4 B. 1, 2, 3, 4, 5 C. 1, 2, 3, 5 D. 1,3, 4, 5 Cu 14. Thu phn cc hp cht sau trong mi trng kim: 1. CH3 CHCl2 2. CH3 COO CH = CH CH3 3. CH3 COOCH2 CH = CH2 4. CH3 CH2 CCl3 5. (CH3 COO)2 CH2. Nhng cht sau khi thy phn trong mi trng kim cho sn phm c phn ng trng bc l: A. 1, 2, 4, 5. B. 1, 3, 5. C. 1, 2, 5 D. 1, 2, 4 Cu 15. Cho cc cht: ancol etylic ; glixerol ; axit focmic ; axit acrylic; phenol ; andehit axetic; axeton. t a l s cht c phn ng vi Na, b l s cht c phn ng vi NaOH, c l s cht c phn ng vi dung dch Br 2 , d l s cht c phn ng vi AgNO3 / NH3 , e l s cht c phn ng vi Cu(OH) 2 trong iu kin thng. Gi tr ca a, b, c, d, e ln lt l:

A. 5, 3, 3, 2, 3 B. 5, 3, 4, 2, 3 C. 5, 3, 3, 2, 1 D. 5, 3, 4, 2, 2 Cu 16. Cho cc dung dch: dung dch H 2SO4 , dung dch Al 2 (SO4 )3 , dung dch Na 2CO3 , dung dch Ba(OH)2, dung dch NaNO3 , dung dch NH4 NO3, dung dch Cu(NO3) 2, dung dch KHSO4, dung dch NaCl. Dy gm cc dung dch lm qu tm i sang mu l: A. dd H2SO4 , dd Al 2(SO4) 3, dd NH4 NO3, dd Na 2CO3 . B. dd H2SO4 , dd Al 2(SO4) 3, dd NH4 NO3, dd NaCl. C. dd H2SO4 , dd Al 2(SO4) 3, dd NH4 NO3, Ba(OH)2. D. dd H 2 SO 4 , dd Al 2 (SO 4 ) 3 , dd NH 4 NO 3 , dd Cu(NO 3 ) 2 , dd KHSO 4 . Cu 17. Xem cc cht: (I): CH3 COONa; (II): ClCH2 COONa; (III): CH3 CH2COONa; (IV): NaCl. So snh s thy phn ca cc dung dch cng nng mol/l ca cc mui trn: A. (I) < (II) < (III) < (IV) B. (IV) < (III) < (II) < (I) C. (IV) < (II) < (I) < (III) D. (IV) < (II) < (III) < (I) Cu 18. Cho 20,7 gam hn hp CaCO 3 v K 2CO3 phn ng ht vi dung dch HCl d, thu c kh Y. Sc ton b kh Y t t vo dung dch ch cha 0,18 mol Ba(OH) 2 , thu c m gam kt ta. Hi m c gi tr trong khong no: A. 35,46 m > 29,55 B. 30,14 m > 29,55 C. 35,46 m 30,14 D. 40,78 m > 29,55 Cu 19. Cho cht v c X tc dng vi mt lng va dung dch KOH, un nng, thu c kh X 1 v dung dch X2 . Kh X1 tc dng vi mt lng va CuO nung nng, thu c kh X3, H2 O, Cu. C cn dung dch X2 c cht rn khan X4 (khng cha clo). Nung X 4 thy sinh ra kh X5 (M = 32 vC). Nhit phn X thu c kh X6 (M = 44 vC) v nc. Cc cht X1 , X3, X4 , X5, X6 ln lt l: A. NH3; NO; KNO3 ; O2; CO2 . B. NH 3 ; N 2 ; KNO 3 ; O 2 ; N 2 O. C. NH3; N2 ; KNO3; O2 ; CO2. D. NH3; NO; K2 CO3; CO2 ; O2. Cu 20. Trong cc cng thc nghim (cng thc nguyn): (CH 2O)n; (CHO2 )n ; (CH3Cl)n ; (CHBr2 )n ; (C2H6 O)n ; (CHO)n ; (CH5 N)n th cng thc no m cng thc phn t ch c th l cng thc n gin nht ? A. (CH3 Cl)n; (C2H6 O)n B. (CH2O)n; (CH3Cl)n ; (C2 H6O)n C. (CH3 Cl)n; (CHO)n ; (CHBr2) n D. (C 2 H 6 O) n ; ; (CH 3 Cl) n ; (CH5 N ) n Cu 21. A l cht hu c c thnh phn nguyn t l C, H, O v Cl. Khi lng mol phn t ca A l 122,5 gam. T l s mol ca C, H, O, Cl ln lt l 4 : 7 : 2 : 1. em thy phn A trong dung dch xt th thu c hai cht c th cho c phn ng trng gng. A l: A. HCOOCH2 CH(Cl)CHO B. HCOOCH=CH2 CH2Cl C. HOC-CH2CH(Cl)OOCH D. HCOO-CH(Cl)CH 2 CH 3 Cu 22. Ho tan hon ton FeS 2 vo cc cha dung dch HNO 3 long c dung dch X v kh NO thot ra. Thm bt Cu d v axit sunfuric vo dung dch X, c dung dch Y c mu xanh, nhng khng c kh thot ra. Cc cht tan c trong dung dch Y l: A. Cu(NO3 )2 ; Fe(NO3) 3; H2 SO4. B. Cu(NO3 )2 ; Fe(NO3) 2; H2 SO4. C. CuSO4; Fe 2(SO4) 3; H2 SO4. D. CuSO 4 ; FeSO 4 ; H 2 SO 4 . Cu 23. A l mt este c cng thc phn t C 16H14O4 . Mt mol A tc dng c vi bn mol NaOH. Mui natri thu c sau phn ng x phng ha nu em t chy ch thu c CO 2 v xa. A c cu to i xng. A l: A. Este ca axit sucxinic (HOOCCH2 CH2COOH) vi phenol. B. Este ca axit malonic (HOOCCH2 COOH) vi mt phenol thng v mt Cresol (Metylphenol). C. Este ca axit oxalic vi hai cresol (CH 3 C 6 H 4 OOC-COOC 6 H 4 CH 3 ). D. C A., B, C. Cu 24. C hai ng nghim, mt ng ng dung dch Na 2 SO4, mt ng ng dung dch Na 2CO3 . Ch dng 1 ha cht trong s cc ha cht sau: dung dch HCl, dung dch BaCl 2 , dung dch NaHSO4 , dung dch NaHSO3 , dung dch AlCl 3 th s ha cht c th phn bit hai dung dch trn l: A. 5 B. 2 C. 4 D. 3 Cu 25. Cho 0,04 mol bt Fe vo mt bnh cha dung dch c 0,08 mol HNO 3 thy thot ra kh NO. Khi phn ng hon ton c cn bnh phn ng th khi lng cht rn thu c bng: A. 5,96 gam B. 3,60 gam C. 4,84 gam D. 7,2 gam Cu 26. Thu phn hp cht:

thu c cc aminoaxit: A. H2N-CH2-COOH; H2 N-CH(CH2 -COOH)-CO-NH2 v H2 N-CH(CH2 -C6 H5)-COOH B. H 2 N-CH 2 -COOH; HOOC-CH 2 -CH(NH 2 )-COOH v C 6 H 5 -CH 2 -CH(NH 2 )-COOH. C. H2N-CH2-COOH; H2 N-CH2 -CH(NH2 )-COOH v C6 H5-CH(NH2)-COOH. D. H2N-CH2-COOH; HOOC-CH(NH2)-COOH v C6H5 -CH(NH2 )-COOH. Cu 27. Phn ng este ha gia axit axetic vi ancol etylic to etyl axetat v nc c hng s cn bng lin h n nng mol/l ca cc cht trong phn ng lc t trng thi cn bng l K c = 4. Nu 1 lt dung dch phn ng lc u c cha a mol CH 3 COOH v a mol CH3 CH2OH, th khi phn ng t trng thi cn bng, s thu c bao nhiu mol sn phm trong 1 lt dung dch ? A. 2a/3 mol CH 3 COOCH 2 CH 3 ; 2a/3 mol H 2 O

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B. a/3 mol CH3 COOCH2 CH3; a/3 mol H2 O C. 2a/3 mol CH3COOCH3; 2a/3 mol H2 O D. 0,25a mol CH3 COOCH2 CH3; 0,25a mol H2O Cu 28. Nguyn t R l phi kim thuc nhm A trong bng tun hon. T l phn trm nguyn t R trong oxit cao nht v phn trm R trong hp cht kh vi hiro bng 0,5955. Cho 4,05 gam mt kim loi M cha r ho tr tc dng ht vi n cht R th thu c 40,05 gam mui. Cng thc ca mui c th l: A. CaCl 2 B. Al2S 3 C. MgBr2 D. AlBr 3 Cu 29. Mt bnh kn dung tch 1,0 lt cha 1,5 mol H2 v 1,0 mol N2 (c cht xc tc v nhit thch hp). trng thi cn bng c 0,2 mol NH 3 c to thnh. Mun hiu sut t 25% th phi thm vo bnh bao nhiu mol N2 ? A. 0,83 B. 1,71 C. 2,25 D. Kt qu khc Cu 30. Ho tan hon ton 9,94 gam hn hp Al, Fe, Cu trong dung dch HNO 3 long d, thy thot ra 3,584 lt kh NO ( ktc; l sn phm kh duy nht). Tng khi lng mui to thnh l: A. 29,7g. B. 37,3g C. 39,7g D. 27,3g Cu 31. Hn hp A gm 0,1 mol anehit metacrylic v 0,3 mol kh hiro. Nung nng hn hp A mt thi gian, c mt cht xc tc Ni, thu c hn hp hi B gm hn hp cc ancol, cc anehit v hiro. T khi hi ca B so vi He bng 95/12. Hiu sut anehit metacrylic tham gia phn ng cng hiro l: A. 100% B. 80% C. 70% D. 65% Cu 32. C dung dch X gm (KI v mt t h tinh bt). Cho ln lt tng cht sau: O 3, Cl2, H2 O2, FeCl3 , AgNO3 tc dng vi dung dch X. S cht lm dung dch X chuyn sang mu xanh l: A. 4 cht B. 6 cht C. 5 cht D. 3 cht Cu 33. A l mt cht hu c mch khng nhnh cha mt loi nhm chc m mui natri ca n khi em nung vi vi ti xt th thu c kh metan. B l mt ancol mch h m khi cho a mol B tc dng ht vi Na th thu c a/2 mol H2 . a mol B lm mt mu va dung dch c ha tan a mol Br 2. t a mol B thu c 3a mol CO2. A tc dng B th thu c mt hp cht hu c a chc X. X l cht no ? A. CH3COOCH2CH2 CH2OOCCH3 B. CH3CH2 CH2OOCCH2COOCH2CH2 CH3 C. CH3COOCH2CHCHOOCCH3 D. CH 2 CHCH 2 OOCCH 2 COOCH 2 CHCH 2 Cu 34. X phng ho 100 gam cht bo c ch s axit bng 7 cn a gam dung dch NaOH 25%, thu c 9,43 gam glyxeryl v b gam mui natri. Gi tr ca a v b l: A. 49,2g v 103,37g B. 49,2g v 103,145g C. 51,2g v 103,145g D. 51,2g v 103,37g Cu 35. Hai nguyn t A v B ng k tip nhau trong cng mt chu k ca bng tun hon, c tng s n v in tch ht nhn l 23, s n v in tch ht nhn ca B ln hn A. Kt lun no sau y v A v B l khng ng ? A. Tnh kim loi ca A mnh hn B. B. Cu hnh electron ca A khng c electron c thn no. C. A, B thuc chu k 3 trong bng tun hon. D. Cu hnh electron ca B khng c electron c thn. Cu 36. M t hin tng no di y l khng chnh xc ? A. un nng dung dch lng trng trng thy hin tng ng t li, tch ra khi dung dch. B. Trn ln lng trng trng, dung dch NaOH v mt t CuSO4 thy xut hin mu c trng. C. Nh vi git axit nitric c vo dung dch lng trng trng thy kt ta mu vng. D. t chy mt mu lng trng trng thy xut hin mi kht nh mi tc chy. Cu 37. Cho phng trnh phn ng: Al + HNO3 Al(NO3 )3 + N2 + N2O + H2O. Bit khi cn bng t l s mol gia N2O v N2 l 3 : 2, hy xc nh t l mol nAl : nN2 O : nN2 trong s cc kt qu sau: A. 44 : 6 : 9 B. 46 : 9 : 6 C. 46 : 6 : 9 D. 44 : 9 : 6 Cu 38. S ng phn cu to ca C 4H11N v C3 H7Cl ln lut l: A. 8 v 3 B. 7 v 2 C. 8 v 2 D. 7 v 3 Cu 39. Ho tan 23,6 gam hn hp gm 2 axit cacboxylic vo nc c dung dch A. Chia A thnh 2 phn bng nhau. Cho phn th nht phn ng vi dung dch AgNO 3 / NH3 d thu c 21,6 gam bc kim loi. Phn th 2 c trung ho hon ton bi 200 ml dung dch NaOH 1M. Vy cng thc ca 2 axit trong hn hp l: A. Axit focmic v axit axetic B. Axit focmic v axit propionic C. Axit focmic v axit oxalic D. Axit focmic v axit acrylic Cu 40. Thc hin phn ng nhit nhm m gam hn hp A gm Al, Fe 2 O3 c hn hp B (H = 100%). Chia B thnh 2 phn bng nhau. Ho tan phn 1 trong H 2SO4 long d, thu c 1,12 lt kh (ktc). Ho tan phn 2 trong dung dch NaOH d th khi lng cht khng tan l 4,4 gam. Gi tr ca m bng: A. 6,95g. B. 13,9g. C. 8,42g. D. 15,64g. II. PHN RING [10 cu]: Th sinh ch c lm mt trong hai phn (phn A hoc phn B) A. Theo chng trnh Chun. (t cu 41 n cu 50) Cu 41. Xt cc cht: (I): Amoniac; (II): Anilin; (III): Metylamin; (IV): imetylamin; (V): iphenylamin; (VI): Nc. mnh tnh baz cc cht tng dn nh sau: A. (VI) < (I) < (III) < (IV) < (II) < (V). B. (V) < (II) < (VI) < (I) < (III) < (IV).

C. (VI) < (V) < (II) < (I) < (III) <(IV). D. (VI) < (II) < (V) < (IV) < (III) < (I). Cu 42. T 10kg go np (c 80% tinh bt), khi ln men s thu c bao nhiu lt cn 96 o . Bit hiu sut ca qu trnh ln men t 80% v khi lng ring ca ancol etylic l 0,807 g/ml. A. 4,7 lit B. 4,5 lit C. 4,3 lit D. 4,1 lit. Cu 43. Nung 6,58 gam Cu(NO3 )2 trong bnh kn, sau mt thi gian thu c 4,96 gam cht rn v hn hp kh X. Hp th hon ton hn hp X vo nc, c 300 ml dung dch Y. Dung dch Y c pH l: A. pH = 1 B. pH = 2 C. pH = 3 D. pH = 4 Cu 44. C 6 dung dch long ca cc mui. BaCl 2 , ZnCl2 , Pb(NO3 )2 , CuSO4, FeCl 2, FeCl 3. Khi cho dung dch H2S d vo cc dung dch mui trn th s trng hp c phn ng to kt ta l. A. 3 B. 4 C. 5 D. 1 Cu 45. Cho A gam hp cht thm c cng thc phn t chnh l cng thc n gin nht. t chy hon ton 1,24 gam A ch thu c 1,568 lt CO2 (kc) v 0,72 gam H2O. Cho a mol A tc dng vi Na d thu c s mol kh bng a mol. Mt khc a mol A tc dng va vi a mol NaOH. S cng thc cu to c th c ca A l: A. 1 B. 2 C. 3 D. 4 Cu 46. Cho 2,16 gam bt Al vo 600 ml dung dch cha hn hp gm CuCl2 0,2M v FeCl3 0,1M. Sau khi phn ng xy ra hon ton thu c cht rn A. Khi lng (gam) ca A l: A. 5,28 B. 7,68 C. 5,76 D. 1,92 Cu 47. Trong nc ngm thng tn ti dng ion trong st (II) hirocacbonat v st (II) sunfat. Hm lng st trong nc cao lm cho nc c mi tanh, lu c mu vng gy nh hng xu n sc khe ca con ngi nn cn phi loi b. Ta c th dng cc phng php no sau y loi b st ra khi nc sinh hot ? A. Sc clo vo b nc mi ht t ging khoan ln vi liu lng thch hp. (2) B. Dng gin phun ma hoc b trn cho nc mi ht t ging khoan ln c tip xc nhiu vi khng kh ri lng, lc. (1) C. Sc khng kh giu oxi vo nc mi ht t ging khoan ln. (3) D. (1), (2), (3) ng. Cu 48. (X) l hp cht hu c c cng thc phn t C 5 H11O2 N. un X vi dd NaOH thu c mt hn hp cht c cng thc phn t C 2 H4O2 NNa v cht hu c (Y), cho hi (Y) qua CuO/t o thu c cht hu c (Z) c kh nng cho phn ng trng gng. Cng thc cu to ca (X) l: A. CH3(CH2) 4NO2 B. NH2 - CH2 - COO - CH(CH3 )2 C. NH 2 - CH 2 COO - CH 2 - CH 2 - CH 3 D. H2N - CH2 - CH2 - COOC2H5 Cu 49. Cho mt lung kh CO i qua ng s ng 0,04 mol hn hp X gm FeO v Fe 2O3 t nng. Kt thc th nghim, thu c hn hp Y gm 4 cht, nng 4,784 gam. Kh i ra khi ng s c hp th vo dung dch Ca(OH)2 d th thu c 4,6 gam kt ta. Phn trm khi lng ca FeO trong X l: A. 10,40% B. 13,04% C. 89,60% D. 86,96% Cu 50. Cht X (C8 H14O4 ) tho mn s cc phn ng sau: a) C8 H14O4 + 2NaOH X1 + X2 + H2 O. b) X1 + H2SO4 X3 + Na2 SO4. c) nX3 + nX 4 Nilon-6,6 + nH2 O. d) 2X2 + X3 X5 + 2H2 O. Cng thc cu to ca X (C8H14O4) l: A. HCOO(CH2) 6OOCH B. CH3 OOC(CH2) 4COOCH3 C. CH3OOC(CH2 )5 COOH D. CH 3 CH 2 OOC(CH 2 ) 4 COOH B. Theo chng trnh Nng cao. (t cu 51 n cu 60) Cu 51. Dy mui nitrat vo di y khi b nhit phn cho sn phm l oxit kim loi, NO2 v O 2: A. NaNO3 , KNO3 , LiNO3 B. Al(NO 3 ) 3 , Zn(NO 3 ) 2 , Ni(NO 3 ) 2 C. Ca(NO3 )2 , Pb(NO3 )2 , Fe(NO3 )2 D. Hg(NO3) 2 , AgNO3 , Mn(NO3 )2 Cu 52. em oxi ha 2,76 gam ancol etylic bng CuO un nng, thu c dung dch A c cha anehit, axit, ancol v nc. Mt na lng dung dch A cho tc dng hon ton vi lng d dung dch AgNO 3 trong amoniac, thu c 3,024 gam bc kim loi. Mt na dung dch A cn li trung ha va 10 ml dung dch NaOH 1M. Phn trm khi lng ancol etylic b CuO oxi ha l: A. 80% B. 90% C. 95% D. 1 kt qu khc Cu 53. in phn 100 ml dung dch CuSO4 0,2 M v AgNO3 0,1 M.vi cng dng in I = 3,86 A. Tnh thi gian in phn c mt khi lng kim loi bm bn catot l 1,72g. A. 250s B. 1000s C. 500s D. 750s Cu 54. un nng mt dung dch c cha 0,1 mol Ca 2+ , 0,5 mol Na +, 0,1 mol Mg 2+ , 0,3 mol Cl - , 0,6 mol

HCO3 thy xut hin m gam kt ta. Gi tr ca m l:

A. 10 B. 8,4 C. 18,4 D. 55,2 Cu 55. A l mt -amino axit. Cho bit 1 mol A phn ng va vi 1 mol HCl, hm lng Clo c trong mui thu c l 19,346%. A l cht no trong cc cht sau: A. CH3CH(NH2 )COOH B. CH3 (NH2 )CH2 COOH C. HOOCCH 2 CH 2 CH(NH 2 )COOH D. HOOCCH2 CH(NH2)CH2COOH Cu 56. Cho s sau:

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Cng thc ng ca (X), (Y) l: A. (X) l CH3 CH2Cl v (Y) l CH2 = CH2 B. (X) l CH2 = CH2 v (Y) l C2 H5OH C. (X) l CH3COOH v (Y) l CH3COOCH2 CH3 D. (X) l CH 2 = CHCl v (Y) l CH 3 CHCl 2 Cu 57. trng mt chic gng soi, ngi ta phi un nng dung dch cha 18g glucoz vi lng va dung dch bc nitrat trong ammoniac. Khi lng bc sinh ra bm vo mt knh ca gng l bao nhiu gam ? A. 16,2g B. 21,6g C. 32,4g D. 43,2g Cu 58. Tr s hng s phn ly ion K a ca cc cht: Phenol; p-Cresol; p-Nitrophenol; 2,4,6-Trolitrophenol -15 -11 -10 -8 -1 (Axit picric); Glixerol l: 7.10 ; 6,7.10 ; 1,28.10 ; 7.10 ; 4,2.10 . Hy chn cht c tr s K a thch hp tng dn cho trn: A. Phenol < p-Cresol < p-Nitrophenol < Axit picric < Glixerol B. Glixerol < p-Cresol < Phenol < p-Nitrophenol < Axit picric C. p- Nitrophenol < Axit picric < Phenol < Glixerol < p-Cresol D. Glixerol < p-Nitrophenol < Phenol < p-Cresol < Axit picric Cu 59. Ngi ta t chy pyrit st (FeS 2) sn xut kh sunfur (SO2 ) 2FeS 2 + 11/2O2 Bin php k thut no sau y khng c s dng tng tc phn ng ? A. Thi khng kh nn vo l t FeS 2. B. Tng nng kh sunfur. C. Tng nhit phn ng ln khong 800oC. D. p nh FeS 2 vi kch thc khong 0,1 mm. Cu 60. Lng Cl 2 v NaOH tng ng c s dng oxi ha hon hon 0,01 mol Cr 2 O3 thnh Na2 CrO4 l: A. 0,015 mol v 0,08 mol B. 0,030 mol v 0,16 mol C. 0,03 mol v 0,10 mol D. 0,030 mol v 0,14 mol

Fe 2 O3 + 4SO2

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TRNG THPT LNG I THI TH TUYN SINH I HC, CAO NG LN 2 2009 Mn thi: HO HC Thi gian lm bi: 90 pht (khng k thi gian giao )

A. (3), (4).

B. (1), (2), (3), (4).

C. (1), (2).

D. (1), (2), (4).

Cho bit khi lng nguyn t (theo u) ca cc nguyn t: H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52; Fe = 56; Cu = 64; Br = 80; Ag = 108; Ba = 137; Au = 197; I = 127. I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40) Cu 1: Cho 300 ml dung dch NaHCO3 x (M) v Na2CO3 y (M). Thm t t dung dch HCl q (M) vo dung dch trn n khi bt u c kh bay ra th dng li thy ht h (ml). Mi lin h gia x, y, q, h l A. q.h = 300xy. B. q.h = 300y. C. q.h = 150xy. D. q.h = 100xy. Cu 2: iu no sau y sai A. ng vi cng thc phn t C4 H8 c 3 anken mch h. B. Tch mt phn t H2 t butan thu c 3 anken. C. Cho propen i qua dung dch H3 PO4 thu c 2 ancol. D. t chy bt k mt anken no u thu c s mol nc v s mol CO2 nh nhau. Cu 3: em nung hn hp A, gm hai kim loi: x mol Fe v 0,15 mol Cu, trong khng kh mt thi gian, thu c 63,2 gam hn hp B, gm hai kim loi trn v hn hp cc oxit ca chng. em ha tan ht lng hn hp B trn bng dung dch H2 SO4 m c, th thu c 0,3 mol SO2. Tr s ca x l A. 0,7 mol. B. 0,5 mol. C. 0,6 mol. D. 0,4 mol. Cu 4: Ha tan ht 17,84 gam hn hp A gm ba kim loi l st, bc v ng bng 203,4 ml dung dch HNO3 20% (c khi lng ring 1,115 gam/ml) va . C 4,032 lt kh NO duy nht thot ra (ktc) v cn li dung dch X. em c cn dung dch X, thu c m gam hn hp ba mui khan. Gi tr ca m l A. 54,28 gam. B. 51,32 gam. C. 45,64 gam. D. 60,27 gam. Cu 5: Cho bt kim loi nhm vo mt dung dch HNO3 , khng thy kh bay ra. Nh vy c th A. Al khng phn ng vi dung dch HNO3. B. Al phn ng vi dung dch HNO3 to NH4 NO3. C. Al phn ng to kh NO khng mu bay ra nn c cm gic l khng c kh. D. (a), (b). Cu 6: Cho cc cht: isobutan (1), isopentan (2), neopentan (3), pentan (4). Sp xp cc cht trn theo chiu nhit si tng dn l A. 1, 4, 2, 3. B. 1, 4, 3, 2. C. 1, 3, 2, 4. D. 1, 2, 3, 4. Cu 7: Cho 250 ml hn hp A gm cc kh Cl 2 , HCl v H2 (ktc) vo lng d dung dch KI (trong bng ti), c 1,27 gam I2 to ra. Phn kh thot ra khi dung dch KI c th tch 80 ml (ktc). Phn trm th tch HCl trong hn hp A l A. 44,8%. B. 32%. C. 25%. D. 23,2%. Cu 8: Cho 6,48 gam bt kim loi nhm vo 100 ml dung dch hn hp Fe 2(SO4)3 1M v ZnSO4 0,8M. Sau khi kt thc phn ng, thu c m gam hn hp cc kim loi. Tr s ca m l A. 14,5 gam. B. 16,4 gam. C. 15,1 gam. D. 11,2 gam. Cu 9: phn ng va vi 200 ml dung dch CrCl3 1M cn m gam Zn. Gi tr m l A. 19,5. B. 6,5. C. 13. D. 9,75. Cu 10: Kh than t l A. Hn hp kh: CO CO2 H2 . C. Hn hp: C hi nc. B. Hn hp: C O2 N2 H2O. D. Hn hp kh: CO H2.

Cu 15: Axit salixylic (axit o-hidroxibenzoic) tc dng vi cht X c xc tc H2 SO4 to ra metyl salixylat dng lm thuc xoa bp, cn tc dng vi cht Y to ra axit axetyl salixylic (aspirin) dng lm thuc cm. Cc cht X v Y ln lt l A. metan v anhirit axetic. B. metan v axit axetic. C. metanol v anhirit axetic. D. metanol v axit axetic. Cu 16: Cho cc cht sau: axit oxalic, axit acrylic, axit oleic, axit silixic, axit clohiric, axit hipoclor, natriclorua. C bao nhiu cht v c A. 5. B. 2. C. 3. D. 4. Cu 17: Cho Na tc dng vi 100ml dd AlCl3 thu c 5,6 lt H2 (ktc) v kt ta. Lc kt ta ri em nung n khi lng khng i thu c 5,1 gam cht rn. Nng mol/l ca dd AlCl3 l A. 1,5M. B. 2,5M. C. 1,0M. D. 2,0M. Cu 18: Cho dung dch KHSO4 vo lng d dung dch Ba(HCO3 )2 c hin t ng g xy ra A. C si bt kh CO2, to cht khng tan BaSO4, phn dung dch c K2SO4 v H2 O. B. C si bt kh, to cht khng tan BaSO4 , phn dung dch c cha KHCO3 v H2O. C. Khng hin tng g v khng c phn ng ha hc xy ra. D. C to hai cht khng tan BaSO4 , BaCO3 , phn dung dch cha KHCO3, H2 O. Cu 19: Cho hn hp X gm CH 3 OH, v C 3H7OH, mi cht 0,02 mol tc dng vi CuO d un nng (hiu sut 100%) thu c hn hp cht hu c Y. Cho Y tc dng vi dung dch AgNO 3 /NH3 d thu c m (g) kt ta. Gi tr ca m l A. 8,64g v 12,96g. B. 12,96g. C. 8,64g. D. Kt qu khc. Cu 20: Cho x mol Al v y mol Zn vo dung dch cha z mol Fe 2+ v t mol Cu2+. Cho bit 2t/3 < x . Tm iu kin ca y theo x, z, t dung dch thu c c cha 3 loi ion kim loi (cc phn ng xy ra hon ton) A. y < z 3x/2 + t. B. y < z 3x + t. C. y < 2z 3x + 2t. D. y < 2z + 3x t. Cu 21: Chia hn hp 2 kim loi c ho tr khng i lm 2 phn bng nhau. Phn 1 tan ht trong dung dch HCl to ra 1,792 lt H2 (ktc). Phn 2, nung trong oxi thu c 2,84 gam hn hp oxit. Khi lng hn hp 2 kim loi ban u l A. 2,2 gam. B. 3,12 gam. C. 2,4 gam. D. 1,56 gam. Cu 22: Cho cc cht C 2H2, C2 H4 , CH3 CH2OH, CH3 CHBr2 , CH3 CH3, CH3COOCH=CH2, C2 H4 (OH)2 . C bao nhiu cht bng mt phn ng trc tip to ra c axetanehit A. 5. B. 7. C. 6. D. 4. Cu 23: Trong phn t hp cht hu c Y (C4 H10O3) ch cha chc ancol. Bit Y tc dng c vi Cu(OH)2 cho dung dch mu xanh da tri. S cng thc cu to ca Y l A. 3. B. 4. C. 2. D. 5. Cu 24: C bao nhiu ng phn amin mch khng phn nhnh ng vi cng thc phn t C4 H11N A. 4. B. 5. C. 3. D. 6. Cu 25: Thy phn este X trong mi trng axit thu c hai cht hu c Y v Z. Oxi ha Y to sn phm l cht Z. Cht X khng th l A. isopropyl propionat. B. vinyl axetat. C. etilenglicol oxalat. D. etyl axetat. Cu 26: Cht geranial c cng thc phn t C10 H16O (cht X). Bit X mch h v c mt chc anehit. 4,56 gam X tc dng va vi V ml dung dch Br2 0,1M (trong CCl4 ). Gi tr ca V l A. 500. B. 600. C. 900. D. 300. Cu 27: Cho cc cht sau: HCl, NaCl, LiCl, NH4Cl, HF. S cht m phn t ch gm lin kt cng ho tr l A. 1. B. 3. C. 4. D. 2. Cu 28: Ho tan hn hp gm: a mol Na2 O v b mol Al2 O3 vo nc th ch thu c dung dch cha cht tan duy nht. Khng nh no ng A. a b. B. a = b. C. a = 2b. D. a b. Cu 29: Cng thc tng qut ca este thun chc to bi ru no hai chc v axit khng no c mt ni i 3 chc l: A. Cn H2n6 O4 . B. Cn H2n10 O6. C. Cn H2n18 O12 . D. C nH2n16 O12.

Cu 11: Ho hi 6,7 gam hn hp A gm CH 3 COOH + CH3 COOC2 H5 + HCOOCH3 thu c 2,24 lt hi (ktc). t chy hon ton 6,7g hn hp A th s gam nc sinh ra l A. 4,5g. B. 5g. C. 4g. D. Khng xc nh. Cu 12: Cu hnh electron lp v ngoi cng ca mt ion l 2p 6. Cu hnh electron ca nguyn t to ra ion l A. 1s2 2s2 2p5. B. 1s2 2s2 2p4 . C. 1s2 2s2 2p6 3s 1. D. Tt c u c th ng. Cu 13: Cho -amino axit mch khng phn nhnh A c cng thc H 2 NR(COOH)2 phn ng ht vi 0,1 mol NaOH to 9,55 gam mui. A l A. axit 2-aminopentanioic. B. axit 2-aminobutanioic. C. axit 2-aminohexanioic. D. axit 2-aminopropanioic. Cu 14: Cho cc cht : phenol (1), anilin (2), toluen (3), metyl phenyl ete (4). Nhng cht tc dng vi nc Br2 l

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Cu 30: Cho 2,72 gam CH3 COOC6 H5 vo 500 ml dung dch NaOH 0,1M. C cn dung dch sau phn ng thu c s gam cht rn l A. 1,64g. B. 3,96g. C. 2,84g. D. 4,36g. Cu 31: Mt hn hp lng X gm ancol etylic v 2 hirocacbon ng ng k tip nhau. Chia hn hp X thnh 2 phn bng nhau. - Phn 1: Cho bay hi th thu c 1 th tch ng bng th tch ca 3,3 gam CO2 (cng iu kin) - Phn 2: t chy hon ton th cn 6,44 lit O 2 (ktc). Sn phm chy c dn qua bnh 1 ng H 2SO4 c, ri qua bnh 2 ng dung dch Ca(OH) 2 d sau th nghim thu c 17,5 gam kt ta. Hai hirocacbon trn l A. C2 H2 v C3 H4 . B. C2 H6 v C3 H8 . C. C3 H8 v C4 H10. D. C 2H4 v C3H6. Cu 32: ng vi cng thc C3 H8 On c bao nhiu ng phn ch cha nhm chc OH trong phn t c th ho tan c Cu(OH)2 A. 3. B. 2. C. 1. D. 4. Cu 33: Kt lun no sau y khng ng A. Cc thit b my mc bng kim loi khi tip xc vi hi nc nhit cao c kh nng b n mn ha hc. B. Mt ming v hp lm bng st ty (st trng thic) b xy st tn bn trong, trong khng kh m th thic b n mn trc. C. Ni thanh Zn vi v tu thy bng thp th v tu thy s c bo v. D. vt bng thp ngoi khng kh m th vt s b n mn in ha. Cu 34: Trong nc t nhin thng c ln nhng lng nh cc mui: Ca(NO3 )2, Mg(NO3)2 , Ca(HCO3 )2, Mg(HCO3 )2. C th dng mt ha cht no sau y loi ng thi cc cation trong cc mui trn A. K2 SO4 . B. NaHCO3. C. NaOH. D. Na 2SO4. Cu 35: un nng 4,03 kg cht bo tripanmitin vi lng d dung dch NaOH. Khi lng glixerol v khi lng x phng cha 72% mui natri pamitat iu ch c ln lt l A. 0,41 kg v 5,97 kg. B. 0,42 kg v 6,79 kg. C. 0,46 kg v 4,17 kg. D. 0,46 kg v 5,79 kg. Cu 36: Mt loi cao su lu ho cha 1,714% lu hunh. Hi c khong bao nhiu mt xch isopren c mt cu ni isunfua SS, gi thit rng S thay th cho H nhm metylen trong mch cao su A. 52. B. 25. C. 46. D. 54. Cu 37: L do m ngi ta dng Al lm dy dn in thay th ng: (I) Al l kim loi c tnh dn in tng i tt; (II) Al l kim loi nh hn ng; (III) Al bn trong khng kh; (IV) Al rt do A. I, IV. B. II, IV. C. I, II. D. I, III. Cu 38: Hn hp A gm hai kim loi Al, Ba. Cho lng nc d vo 4,225 gam hn hp A, khuy u phan ing xay ra hon ton, c kh thot, phn cht rn cn li khng b ha tan ht l 0,405 gam. Khi lng mi kim loi trong 4,225 gam hn hp A l A. 1,485 g; 2,74 g. B. 1,62 g; 2,605 g. C. 2,16 g; 2,065 g. D. 0,405g; 3,82g Cu 39: Cho 15,2 gam hn hp gm glixerol v mt ancol no, n chc phn ng ht vi natri d thy thot ra 4,48 lt kh (ktc). Cng lng hn hp trn ch c th ho tan c ti a 4,9 gam Cu(OH) 2. Cng thc ca ancol cha bit l A. C2 H5 OH. B. C3 H7 OH. C. C4 H9 OH. D. CH3 OH. Cu 40: in phan dung dch NaCl n ht (c mng ngn, in cc tr), cng dng n 1,61A th ht 60 pht. Thm 0,03 mol H2SO4 vo dung dch sau in phan th thu c mui vi khi lng A. 4,26 gam. B. 8,52 gam. C. 2,13 gam. D. 6,39 gam. II. PHN RING [6 cu] Th sinh ch c lm mt trong hai phn (phn A hoc phn B) A. Phn dnh ring cho chng trnh nng cao (10 cu, t cu 41 n cu 50) Cu 41: Cht geranial c cng thc phn t C10H16 O (cht X). Bit X mch h v c mt chic anehit. 4,56 gam X tc dng va vi V ml dung dch Br2 0,1M (trong CCl4 ). Gi tr ca V l A. 900. B. 300. C. 600. D. 500. Cu 42: Cho cc cht sau: Ancol benzylic; benzyl clorua; phenol; phenyl clorua; p-crezol; axit axetic. Trong s cc cht trn c bao nhiu cht c th tc dng vi Na0H c nhit cao v p sut cao A. 4. B. 6. C. 3. D. 5.

Cu 43: Trong bnh kn dung tch 1 lt, ngi ta cho vo 5,6 gam kh CO v 5,4 gam hi nc. Phn ng xy ra l: CO + H 2 O CO2 + H2 . 850oC hng s cn bng ca phn ng trn l K = 1

[CO2 ][ H 2 ] K = . Nng mol ca CO v H O khi t n cn bng ha hc ln lt l [CO][ H 2 O]

2

A. 0,2 M v 0,3 M. C. 0,12 M v 0,12 M. Cu 44: Ion icromat

B. 0,08 M v 0,2 M. D. 0,08 M v 0,18 M.

Cr2 O72 , trong mi trng axit, oxi ho c

3+

mui Fe 2+ to mui Fe3+, cn

icromat b kh to mui Cr . Cho bit 10 ml dung dch FeSO4 phn ng va vi 12 ml dung dch K2 Cr2 O7 0,1M, trong mi trng axit H2 SO4 . Nng mol/l ca dung dch FeSO4 l A. 0,82M. B. 7,2M. C. 0,72M. D. 0,62M. Cu 45: Xt phn ng ho tan vng bng xianua (phn ng cha c cn bng): Au + O 2 + H2O + NaCN Na[Au(CN)2] + NaOH. Khi lng vng b ha tan l 1,97 gam th lng NaCN dng l A. 0,01 mol. B. 0,04 mol. C. 0,02 mol. D. 0,03 mol. Cu 46: Cho dung dch metylamin d ln lt vo tng dung dch FeCl3, AgN03, NaCl, Cu(N03)2 . S trng hp thu c kt ta sau phan ing l A. 3. B. 1. C. 2. D. 4. Cu 47: Ha tan m gam hn hp saccaroz v mantoz vo nc thu c dung dch X. Chia X thnh hai phn bng nhau. Phn th nht tc dng vi lng d dung dch AgNO 3 trong NH 3, thu c 10,8 gam kt ta. Phn th hai un hi lu trong mi trng axit (HCl long) thu c dung dch Y. Dung dch Y phn ng va ht vi 40 gam Br 2 trong dung dch. Gi thit cc phn ng u xay ra hon ton. Khi lng m bng A. 68,4 gam. B. 273,6 gam. C. 205,2 gam. D. 136,8 gam. Cu 48: Khi ngi th hn hot ng cng nh khi ct kim loi bng m hn (dng nhit cao ca m hn in kim loi nng chy v t ra), ngoi cc ht kim loi chi sng bn ra cn c mi kht rt kh chu. Mi kht ny ch yu l mi ca cht no A. Mi ca oxit kim loi. B. Mi ca cc tp cht trong kim loi chy to ra (nh do tp cht S chy to SO2 ). C. Mi ca hi kim loi bc hi nhit cao. D. Mi ca ozon to ra t oxi nhit cao. Cu 49: Cho m gam Fe tc dng hon ton vi dung dch chia 0,42 mol H 2 SO4 c nng, thu c dung dch 28,56 gam mui. Gi tr m l A. 23,52 gam. B. 7,84 gam. C. 7,9968 gam. D. 8,4 gam. Cu 50: Tin hnh phn ng este ha t 1 mol CH3 COOH v 1 mol C 2H5OH th hiu sut phan ing l 66,67%. hiu sut t 90%, cn tin hnh este ha 1 mol CH3 COOH vi s mol ancol bng A. 0,342 mol. B. 2,925 mol hoc 3,042 mol. C. 2,925 mol. D. 2,925 mol hoc 0,342 mol. B. Phn dnh ring cho chng trnh chun (10 cu, t cu 51 n cu 60) Cu 51: in phn dung dch hn hp chia 0,1 mol FeCl3, 0,2 mol CuCl2 v 0,1 mol HCl (in cc tr, mng ngn xp). Khi catot bt u si bt kh th dng in phn. Ti thi im ny khi lng catot tng A. 0,0 gam. B. 18,4 gam. C. 12,8 gam. D. 5,6 gam. Cu 52: Trong cc cht sau, H 2N-CH2-COOH, H2 N-CH2 -CH2-CH(NH2)-COOH, CH3-CH2 -NH2 , HOOCCH2-CH2 -CH(NH2 )-COOH. S cht lm qu tm chuyn sang mu hng l A. 2. B. 4. C. 1. D. 3. Cu 53: t chy m (g) hn hp gm 1 axit no, n chic v 1 este no, n chc u mch h cn va 4,48 lit O2 (ktc). Sn phm chy cho qua bnh ng dung dch Ca(OH)2 d thy to ra 20g kt ta. m c gi tr l A. 6. B. 8. C. 7. D. Khng xc nh. Cu 54: Hai kim loi bn trong khng kh v nc nh c lp mng oxt rt mng bo v l A. Al v Cr. B. Al v Mg. C. Fe v Cr. D. Fe v Al. Cu 55: T glucoz iu ch cao su buna theo s sau y: glucoz ru etylic buta-1,3-ien cao su buna. Hiu sut ca qu trnh iu ch l 75%, mun thu c 32,4kg cao su th khi lng glucoz cn dng l

Trang 9

A. 81kg.

B. 108kg.

C. 144kg.

D. 96kg.

Cu 56: Cho cc ancol sau : CH 3CH2 CH2OH (1); CH3 CH(OH)CH3 (2); CH3 CH2CH(OH)CH2 CH3 (3); CH3CH(OH)C(CH3)3 (4). Dy gm cc ancol khi tch nc t mi ancol ch cho 1 olefin duy nht l A. 1, 2. B. 1, 2, 3, 4. C. 1, 2, 4. D. 1, 2, 3. Cu 57: Ngi ta nhn thy ni cc mi hn kim loi d b r (g, mau h) hn so vi kim loi khng hn, nguyn nhn chnh l A. Do ni mi hn thng l hai kim loi khc nhau nn c s n mn in ha hc. B. Do kim loi lm mi hn khng chc bang kim loi c hn. C. Do kim loi ni mi hn d b n mn ha hc hn. D. Tt ca cc nguyn nhan trn. Cu 58: Nhng bc tranh c thng c v bng bt trng ch c cng thc l Pb(OH) 2 .PbCO3 lu ngy thng b xm en l do to thnh A. PbO. B. PbSO3. C. PbS. D. PbO2. Cu 59: C cc hp cht sau : C 2 H5 OH, n-C10H21 OH, C6 H5 OH, C6 H5 NH2, CH3 COOH, n-C6 H14, HOCH2CHOHCH2 OH, C6 H6 v C6 H12O6 (glucoz). Trong cc cht ny c x cht tan tt trong nc, y cht t tan trong nc v z cht hu nh khng tan. Cc gi tr x, y v z ln lt bng A. 2, 3 v 4. B. 4, 3 v 2. C. 3, 3 v 3. D. 3, 4 v 2. Cu 60: Khi cho 41,4 gam hn hp X gm Fe 2 O3 , Cr2 O3 v Al2 O3 tc dng vi dung dch NaOH c (d), sau phn ng thu c cht rn c khi lng 16 gam. kh hon ton 41,4 gam X bng phn ng nhit nhm, phi dng 10,8 gam Al. Thnh phn phn trm theo khi lng ca Cr2 O3 trong hn hp X l (Cho: hiu sut ca cc phn ng l 100%) A. 26,08%. B. 36,71%. C. 50,67%. D. 66,67%.

Trang 10

 THI TH TUYN SINH I HC, CAO NG NM 2009 Mn thi: HA HC - KHI A, B (M thi 531) Thi gian lm bi: 90 pht PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40).
24 25 26

Cu 10.

Cu 1.

Trong t nhin magie c 3 loi ng v bn l 12 Mg, 12 Mg v 12 Mg, vi t l phn trm s nguyn t tng ng l 78,99%; 10,00% v 11,01%. Cho rng gi tr nguyn t khi ca cc ng v bng s khi ca chng v s Avogadro bng 6,02.1023 . S nguyn t magie c trong 20 gam magie bng A. 3,01.1023 nguyn t. B. 4,95.1023 nguyn t. C. 7,32.1023 nguyn t. D. 2,93.1026 nguyn t.

Cu 2.

,Y

,Z

v T
2

2+

l cc ion c cu hnh electron ging cu hnh electron ca Ar. Kt ,Z

+

lun no di y l ng ? A. Bn knh ca cc ion X ,Y

v T

2+

l bng nhau.

B. Bn knh nguyn t tng dn theo trt t RY < RX < RT < RZ .. C. Hydroxit tng ng vi ha tr cao nht ca X c lc axit mnh hn ca Y. D. Hydroxit tng ng vi ha tr cao nht ca T c lc baz mnh hn ca Z. Cu 3. Trn 3 dung dch HCl 0,3M; H2SO4 0,2M v H3PO4 0,1M vi nhng th tch bng nhau thu c dung dch A. trung ha 300 mL dung dch A cn va V (mL) dung dch B gm NaOH 0,1M v Ba(OH)2 0,2M. Gi tr ca V l: A. 200. B. 333,3. C. 600. D. 1.000. Cu 4. C 3 bnh ng ln lt cc dung dch KOH 1M, 2M v 3M, th tch mi bnh l 1,0 L. Cn ly t mi bnh tng ng l bao nhiu lit pha thnh dung dch KOH 1,8M c th tch ln nht? A. 0,75 lit; 0,75 lit; 1,0 lit. B. 1,0 lit; 1,0 lit; 0,5 lit. C. 1,0 lit; 0,75 lit; 0,75 lit. D. 0,5 lit; 1,0 lit; 1,0 lit. Cu 5. Pht biu lin quan trng thi cn bng ha hc no di y l khng ng ? A. trng thi cn bng ha hc cc phn ng thun v nghch vn tip tc xy ra vi vn tc bng nhau. B. trng thi cn bng nng cc cht tham gia phn ng v nng cc cht sn phm u khng i. C. S thay i yu t nhit , nng hoc p sut c th ph v trng thi cn bng ha hc v to ra s chuyn di cn bng. D. T l gia nng cn bng cc cht sn phm v cc cht tham gia (u c s m bng h s t lng) l khng i mi nhit . Cu 6. Thm mt t phenolphtalein vo dung dch NH3 long ta thu c dung dch A. Tc ng no di y khng lm nht mu dung dch A? A. un nng dung dch hi lu. B. Thm HCl bng s mol NH3 . C. Thm mt t Na2CO3 . D. Thm AlCl3 ti d. Cu 7. Xt cc phng trnh chuyn ha: A + O2 B + ... A + Br2 C + ... A + B C + ... C + H2 SO4 (c) B + ... Cht A trong cc phn ng ny l: A. SiH4 . B. PH3. C. H2S. D. HCl. Cu 8. Xt cc qu trnh: (X) Gi l cy chm, lc ly dung dch mu nhum si, vi. (Y) Nu ru ung. (Z) Ngm ru thuc, ru rn. (T) Lm ng ct, ng phn t nc ma. Trong cc qu trnh ny, qu trnh no s dng k thut chit tch cc hp cht hu c? A. X. B. Y. C. Z. D. T. Cu 9. t chy hn hp A gm 3 cht thuc dy ng ng ca benzen cn dng V lit khng kh ktc. Cho hp th sn phm chy vo bnh ng nc vi, thu c 3 gam kt ta, khi lng dung dch tng 12,012 gam. un nng dung dch, thu thm 12 gam kt ta na. Cc phn ng xy ra hon ton. Khng kh gm 20% O2 v 80% N2. Tr s ca V l: A. 39,984 lit. B. 31,9872 lit C. 7,9968 lit. D. 31,234 lit.

Trong bnh kn cha hydrocacbon X v hydro. Nung nng bnh n khi phn ng hon thu c ankan Y duy nht. cng nhit , p sut trong bnh trc khi nung gp hai ln p sut trong bnh sau khi nung. t chy mt lng Y thu c 8,8 gam CO 2 v 5,4 gam H2 O. T cc cht CH3 CH3, CH3CH2 OH, CH3CH2 Cl, CH2 Cl-CH2Cl, CH3CH2 CH3, v CH2=CH-COOH, c bao nhiu cht ch bng mt phn ng iu ch trc tip c cht X? A. 3 cht. B. 4 cht. C. 5 cht. D. 6 cht. Cu 11. Pht biu no sau y khng ng? A. C th phn bit tinh bt v bt giy bng dung dch I2. B. C th phn bit saccaroz v mantoz bng dung dch AgNO3 /NH3. C. C th phn bit glucoz v fructoz bng dung dch nc brm. D. C th phn bit mantoz v fructoz bng Cu(OH)2 trong dung dch NaOH nng. Cu 12. Pht biu no di y l khng ng? A. Lc axit ca phenol yu hn lc axit ca axit cacbonic, nhng mnh hn lc axit ca ancol etylic. B. Dung dch phenol c mi trng axit rt yu, nn khi cho qu tm vo dung dch phenol, qu khng i mu. C. Tng t ancol etylic, phenol phn ng d dng vi axit cacboxylic to este v vi axit halogenhidric to dn xut halogen. D. Phenol tham gia phn ng th vo nhn thm d hn axit benzoic v khc axit benzoic phn ng th ca phenol u tin vo v tr ortho, para. Cu 13. xc nh ru ca mt ru etylic (k hiu ru X) ngi ta ly 10 mL ru X cho tc dng ht vi Na thu c 2,564 lit H2 ktc. Tnh ru ca X bit rng dru =0,8 gam/mL: A. 87,5o. B. 85,7o. C. 91o. D. 92,5o . Cu 14. Pht biu no di y khng ng? A. Nhit si ca CH3 COOH cao hn nhit si ca CH3COOC2H5. B. Cc ancol v cc axit cacboxylic t C1 n C4 u tan v hn trong nc. C. Cc hp cht HCHO, CH3 CHO v CH3 COCH3 u tan tt trong nc. D. Glyxin H2NCH2COOH iu kin thng l cht rn, tan tt trong nc. Cu 15. So snh no sau y l ng? A. Trt t tng dn lc baz: CH3 NH2 < NH3 < C6H5NH2 . B. Trt t tng dn lc baz: C3H7NH2 < CH3NHC2H5 < (CH3)3 N. C. Trt t tng dn lc axit: HCOOH < CH3COOH < CH3 CH2COOH. D. Trt t tng dn lc axit: CH2 ClH2 COOH < CH3CHClCOOH < CH3 CHFCOOH. Cu 16. Hai cht ng phn A, B (A c ly t ngun thin nhin) c thnh phn 40,45%C, 7,86%H; 15,73% N v cn li l O. T khi hi ca cht lng so vi khng kh l 3,069. Khi phn ng vi NaOH, A cho mui C3 H6 O2 NNa, cn B cho mui C2 H4 O2 NNa. Nhn nh no di y l ng? A. A l alanin, B l metyl amino axetat. B. iu kin thng A l cht lng, B l cht rn. C. A v B u tc dng vi HNO2 to kh N2. D. A c tnh lng tnh nhng B ch c tnh baz. Cu 17. Khi cho m(g) hn hp 2 kim loi l Fe v Cu ( Fe chim 30% v khi lng) vo HNO 3 c khi lng l 44,1 gam. Khuy u n khi phn ng xy ra hon ton thu c cht rn A nng 0,75m (g) , dung dch B v 5,6 lt hn hp kh NO 2 v NO (ktc). C cn dng dch th thu c bao nhiu gam mui khan: A. 40,5 gam. B. 36,3 gam. C. 50,2 gam. D. 50,4 gam. Cu 18. Cho 250 gam dung dch FeCl3 6,5% vo 150 gam dung dch Na2CO3 10,6% thu c kh A, kt ta B v dung dch X. Thm m gam dung dch AgNO 3 21,25% vo dung dch X thu c dung dch Y c nng % cu NaCl l 1,138%. Gi tr ca m l ? A. 140 gam. B. 120 gam. C. 100 gam. D. 160 gam.

Cu 19.

Ch dng Cu(OH)2/OH

c th nhn bit c cc dung dch ring bit sau:

A. Glucoz, mantoz, glyxerin, andehyt axetit. B. Lng trng trng, glucoz, fructoz, glyxerin. C. Saccaroz, glyxerin, andehyt axetit, ancol etylic. D. Glucoz, lng trng trng, glyxerin, ancol etylic. Cu 20. un nng hn hp X gm hai ru n chc A, B lin tip nhau trong dy ng ng vi H2 SO4 c 1400C thu c hn hp 3 ete. t chy mt phn hn hp ete trn thu c 33 gam CO 2 v 19,8 gam H2O. A v B l:

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A. C 3H7OH v C4H9OH. B. C 3H5OH v C4H7OH. C. C 2H5OH v C3H7OH. D. CH3OH v C2H5OH. Cu 21. Xt cc cht ancol metylic, metyl clorua v andehyt fomic. Trong ba cht ny c mt cht lng v hai cht kh, cht lng l X1. Trong ba cht ny c mt cht t tan trong nc v hai cht tan tt trong nc, cht t tan l X2. Cc cht X1 v X2 ln lt l: A. Ancol metylic v mtylclorua. B. Ancol metylic v andehyt fomic. C. Andehyt fomic v metyl clorua. D. Andehyt fomic v ancol metylic. Cu 22. Cho khi lng ring ca cn nguyn cht l (d=0,8 gam/mL). Hi t 10 tn v bo cha 80% xenluloz c th iu ch c bao nhiu tn cn thc phm 45 o . Bit hiu sut ton b qu trnh iu ch l 64,8%? A. 2,94 tn. B. 7,44 tn. C. 9,30 tn. D. 11,48 tn. Cu 23. Ba amin A, B v C (C l hp cht thm) khi tc dng vi HCl ch to ra mui c dng RNH3Cl (R l gc hydrocacbon). Thnh phn phn trm v khi lng ca N trong A l 45,16%; trong B l 23,73% v trong C l 15,05%. Trt t tng dn mnh lc baz ca ba cht ny l: A. C < B < A. B. C < B < A. C. A < B < C. D. A < C < B. Cu 24. un nng mnh 23 gam etanol vi 100 gam dung dch H 2SO4 98% sau mt thi gian thu c dung dch H2SO4 80% v hn hp kh X ch gm cc cht hu c. (Gi s ch xy ra phn ng loi nc). t chy hon ton hn hp kh X thu c m gam H2O. Tr s ca m l: A. 5,4 gam. B. 4,5 gam. C. 10,8 gam. D. 9,0 gam. Cu 25. Cho 19,2 gam hn hp gm hai amino axit no cha mt chc axit v mt chc amin (t l khi lng phn t ca chng l 1,373) tc dng vi 110 mL dung dch HCl 2M, c dung dch A. tc dng ht vi cc cht trong dung dch A cn dng 140 mL dung dch KOH 3M. Phn trm s mol ca mi aminoaxit trong hn hp ban u bng: Ch s iot ca loi lipit ny bng : A. 25% v 75%. B. 20% v 80%. C. 50% v 50%. D. 40% v 60%. Cu 26. Cho 3 amino axit sau: C2H5CH(NH2)COOH (X); CH3CH(NH2)COOH (Y) v CH3CH(NH2 )CH2COOH (Z). S cht c hai lin kt peptit c to thnh t 1, 2 hoc 3 trong s 3 aminoaxit trn l: A. 18. B. 30. C. 27. D. 21. Cu 27. Hn hp X gm ru metylic v mt ru no n chc A. Cho 7,6 gam X tc dng vi Na d thu c 1,68 lit H2 ktc. Mt khc, oxy ha hon ton 7,6 gam X bng CuO ri cho ton b sn phm thu c tc dng vi dung dch AgNO3 /NH3 d c 21,6 gam kt ta. Cng thc cu to ca A l: A. C 2H5OH. B. CH3 CH2CH2 CH2OH. C. CH3 -CH(OH)CH3 . D. CH3CH2 CH2OH. Cu 28. Cho 0,1 mol este no, n chc, mch h vo cc cha 30 mL dung dch MOH 20% (d=1,2 gam/mL). Sau khi phn ng hon ton, c cn dung dch ri t chy hon ton cht rn cn li. Sau phn ng ch thu c 9,54 gam M 2CO3 v 8,26 gam hn hp gm CO 2 v H2 O. Hi kim loi kim v axit to ra este ban u l: A. K; HCOOH. B. Na; CH3COOH. C. K; CH3 COOH. D. Na; CH3 COOH. Cu 29. Cho tt c cc ng phn c cng thc phn t C2H4O2 ln lt tc dng vi Na, NaOH, NaHCO3, AgNO3/NH3 , dung dch Br2. S phn ng xy ra l: A. 9. B. 6. C. 7. D. 8. Cu 30. T qu cy hi ngi ta tch c 4-metoxibenzandehyt, t qu cy hi hoang tch c p-isopropylbenzandehyt, t qu cy vanilla tch c 4-hidroxi-3-metoxibenzandehyt (vanilin, dng lm cht thm cho bnh ko). Trong ba cht ny, cht tan trong nc nhiu nht v cht c nhit si cao nht l: A. u l 4-metoxibenzandehyt. B. u l 4-hidroxi-3-metoxibenzandehyt. C. ln lt l 4-metoxibenzandehyt v p-isopropylbenzandehyt. D. ln lt l 4-hidroxi-3-metoxibenzandehyt v p-isopropylbenzandehyt . Cu 31. Trong phn ng clo ha nh xc tc FeCl3, kh nng phn ng tng i cc v tr khc nhau trong cc phn t biphenyl v benzen nh sau:

0
790
(4)

250
(3) (2) (1)

250
(3) (2) (4) (1)

1
790

1 1

1 1 1

250

250

Tc monoclo ha biphenyl v benzen hn km nhau bao nhiu ln v nu thu c 10 gam 2clobiphenyl th s thu c bao nhiu gam 4-clobiphenyl? A. 1050 v 10. B. 1050 v 20. C. 430 v 15,8. D. 1050 v 525. Cu 32. Cho 1 mol CH3COOH tc dng vi 1 mol iso-propylic. Khi phn ng t cn bng th c 0,6 mol este c to thnh. Nu sau thm 1 mol CH 3 COOH, th s mol este trong hn hp sau cn bng l bao nhiu? A. 0,6 mol. B. 0,18 mol. C. 0,78 mol. D. 1,22 mol. Cu 33. Mt mu cht bo c ch s axit bng 7, ch s x phng ha l 196. X phng ha hon ton 1 tn mu cht bo trn thu c m kg x phng ca natri. Bit rng 5% cht bo ny khng phi l triglixerit hoc axit bo v hiu sut ca qu trnh x phng ha t 80%. Gi tr ca m l: A. 1034,25. B. 747,4. C. 789,2. D. 984,25. Cu 34. Xt phn ng : 2SO3 (k) 2SO2 (k) + O2 (k). Trong bnh nh mc 1,00 L, ban u cha 0,777 mol SO3 (k) ti 1100 K. Ti cn bng c 0,520 mol SO3 . Hng s cn bng ca phn ng ny bng: A. 0,0314. B. 0,0635. C. 31,847. D. 0,0628. Cu 35. t chy hon ton 0,1 mol hn hp cc hp cht hu c n chc l ng phn ca nhau thu c 8,96 lit kh CO 2 ktc v 7,2 gam H 2 O. Trong hn hp c ng phn X mch cacbon khng phn nhnh tc dng c vi Na v NaOH. Cng thc cu to ca X v tng s cc ng phn c th c trong hn hp tha mn iu kin trn l: A. CH3 -CH2-CH2 -COOH v c 2 ng phn. B. CH3 -CH2-CH2 -COOH v c 6 ng phn. C. C 2H5COOCH3 v c 4 ng phn. D. CH3-CH(CH3 )-COOH v c 6 ng phn. Cu 36. Nhit phn 3,0 gam MgCO3 mt thi gian thu c kh X v hn hp rn Y. Hp th hon ton X vo 100 mL dung dch NaOH x (mol/L) thu c dung dch Z. Dung dch Z phn ng vi BaCl 2 d to ra 3,94 gam kt ta. trung ha hon ton dung dch Z cn 50 mL dung dch KOH 0,2M. Ga tr ca x v hiu sut phn ng nhit phn MgCO3 ln lt l: A. 0,75 v 50%. B. 0,5 v 84%. C. 5 v 66,67%. D. 0,75 v 90%. Cu 37. Nhng mt thanh Fe nng 100 gam vo 500 ml dung dch hn hp CuSO4 0,08M v Ag2SO4 0,004M. Gi s Cu, Ag thot ra u bm vo Fe. Sau mt thi gian ly thanh ra v cn li c 100,48 gam. Tnh khi lng cht rn A thot ra bm ln thanh Fe? A. 2,352 gam. B. 1,832 gam. C. 1,712 gam. D. 2,992 gam. Cu 38. Trong 3 chn A, B, C ba loi mui nitrat X, Y, Z tng ng. Nung trong khng kh nhit cao n phn ng hon ton, ngi ta nhn thy trong chn A khng cn du vt g c, khi cho dung dch HCl vo chn B thy bay ra mt cht kh khng mu (cht kh ny sau chuyn sang mu nu ), cn trong chn C cn li b rn c mu nu . Kt lun no sau y l khng ng? A. X c th l NH4NO3 hoc Hg(NO3)2 . B. Y c th l NaNO3 hoc KNO3 . C. Z c th l Fe(NO3 )2 hoc Fe(NO3)3 . D. Y d b nhit phn hn X v Z. Cu 39. Theo s :

Z C2H5OH

Y
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Vi mi mi tn l mt phn ng th X, Y, Z, T l : A. Etilen, axetilen, glucoz, etyl clorua. B. Etylen, natri etylat, glucoz, etyl axetat. C. Andehyt axetic, vinylaxetat, etyl clorua. D. Etilen glycol, natri etylat, glucoz, andehyt axetit. Cu 40. Cho cc phn ng sau: (A) + Cl2 (B) + (C) (B) + NaOH (D) + (E) (C) + NaOH (E) + (F) (A) + O2 (G) + (F) (D) + O2 (G) + (F) (G) + (H) HCOOH + Ag (G) + (H)

Cu 49.

Cc cht A, G v Z ln lt c th l: A. CH3 COOH; CH3CHO v CH3-CH(OH)(SO3 Na). B. C 2H6; CH3 CHO v CH3 -CH(OH)(SO3Na). C. C 2H5OH; HCHO v CH3-CH(OH)(SO3 Na). D. CH4; HCHO v CH2(OH)(SO3 Na).

(F) + (L) + Ag

(G) + ?

(Z) (mu trng)

Cho hn hp X cha 23,2 gam Fe3O4 v 25,6 gam Cu tc dng vi 400 mL dung dch HCl 2M cho n khi phn ng hon ton v lc phn khng tan thu c dung dch B. Dung dch B cha x mol FeCl 2, y mol FeCl3 v z mol CuCl2 . Cc gi tr x, y, z ln lt l: A. 0,1 mol; 0,2 mol v 0,0 mol. B. 0,2 mol; 0,1 mol v 0 mol. C. 0,2 mol; 0,0 mol v 0,1 mol. D. 0,3 mol; 0,0 mol v 0,1 mol. Cu 50. tch c lu hunh ra khi hn hp bt gm S, CuSO4 v ZnCl2 ngi ta dng cch no sau y? A. Ha tan hn hp vo dung dch Ba(OH)2 d ri lc. B. Ho tan hn hp vo nc d ri lc. C. Ha tan hn hp vo dung dch AgNO3 d ri lc. D. Thm H2SO4 c. Phn II. Theo chng trnh C BN (10 cu, t cu 50 n cu 60). Cu 51. Cho cc cht sau y:

PHN RING: Th sinh ch c chn lm 1 trong 2 phn sau (Phn I hoc Phn II). Phn I. Theo chng trnh NNG CAO (10 cu, t cu 40 n cu 50) Cu 41. Cho x mol Al vo dung dch c cha a mol AgNO 3 v b mol Zn(NO3)2. Phn ng kt thc thu c dung dch X cha 2 mui. Cho dung dch X tc dng vi NaOH d khng c kt ta. Gi tr ca x l: A. a 3x < a+2b. B. 2a < x < 4b. C. x = a+2b. D. a+2b < 2x < a+3b. Cu 42. Vai tr ca vi ti trong qu trnh sn xut ng t ma l: A. Cht xc tc cho qu trnh thy phn ng. B. Kt ta cc axit hu c v protid trong nc ma. C. Loi b cc ion kim loi di dng kt ta. D. Tng khi lng ring ca nc ng b ma ni ln trn. Cu 43. Gi cho b mt kim loi lun lun sch, khng c bn t bm vo l mt bin php bo v kim loi khi b n mn. Nh vy l p dng phng php chng n mn: A. Dng phng php in ha. B. Cch ly kim loi vi mi trng. C. Dng phng php bin i ha hc lp b mt. D. Dng phng php ph. Cu 44. Cho 24,64 lit hn hp X (27,3oC; 1atm) gm 3 hydrocacbon. t chy hon ton hn hp X, sn phm chy c hp th hon ton vo dung dch Ca(OH) 2 d thy khi lng bnh tng thm 98,6 gam. Cc hydrocacbon trong hn hp X thuc loi: A. Olefin. B. Ankin. C. Parafin. D. Diolefin. Cu 45. t hai cc A, B c khi lng bng nhau ln 2 a cn: cn thng bng. Cho 10,6 gam Na 2 CO3 vo cc A v 11,82 gam BaCO3 vo cc B, sau thm 12 gam dung dch H 2SO4 98% vo cc A th cn mt thng bng. Nu thm t t mt dung dch HCl 14,6% vo cc B ti khi cn tr li thng bng th tn bao nhiu gam dung dch HCl: A. 3,498 gam. B. 6,38 gam. C. 6,996 gam. D. 7,3 gam. Cu 46. Trong dy in ha ca kim loi, v tr ca mt s cp oxy ha-kh c sp xp nh sau: Mg2+ /Mg; Fe 2+/Fe; Ni 2+/Ni; Fe3+/Fe 2+; Ag+ /Ag. Trong s cc kim loi Mg, Fe, Ni, Ag c x kim loi phn ng c vi dung dch mui Fe(III), y kim loi c Fe y ra khi dung dch mui st (III). Cc gi tr x v y l lt l: A. 2 v 1. B. 2 v 0. C. 1 v 1. D. 1 v 0. Cu 47. Ngi ta nng mt tn qung calcoxit c hm lng 9,2% Cu2S. Kh hon ton lng oxit bng CO thu c ng kim loi. Bit hiu sut tch v kh ch t 75%. Khi lng ng thu c bng: A. 92,0 kg B. 27,6 kg. C. 55,2 kg. D. 73,6 kg. Cu 48. Nhng qung v khong vt cho di y ch yu sn xut nhng kim loi g: Criolit, manhetit, cancopirit (CuFeS2), boxit, xiderit, dolomit v vi, mui n, cromit, apatit, ct, pirit, cacnalit. A. Fe, Al, Na, Cr, Ag. B. Fe, Cu, Al, Cu, Cr, P. C. Fe, Cu, Al, Ca, Mg, Na, Cr, K. D. Fe, Cu, Al, Ca, Mg, Na, Si.

N H Pirol (I)

N H

Piridin(II)

Piperidin (III)

Tnh baz gim dn theo trt t no sau y? A. I > II > III. B. III > II > I. C. II > I > III. D. II > III > I. Cu 52. Cho xenluloz phn ng hon ton vi anhiric axetic [(CH3CO)2O] th sn phm to thnh gm 6,6 gam CH3 COOH v 11,1 gam hn hp X gm xeluloz triaxetat v xenluloz iaxetat. Thnh phn phn trm v khi lng ca xenluloz triaxetat trong hn hp X l: A. 22,16%. B. 75%. C. 77,84%. D. 25%. Cu 53. Thy phn hon ton 200 gam mt hn hp gm t tm v lng cu thu c 31,7 gam glixin. Bit thnh phn phn trm v khi lng ca glixin trong t tm v lng cu ln lt l 43,6% v 6,6%. Thnh phn phn trm v khi lng ca t tm trong hn hp k trn l: A. 62,5%. B. 50%. C. 25%. D. 75%. Cu 54. Phn ng sau y ca xicloankan (CnH2n) c th xy ra vi n bng bao nhiu?

CH2

(CH2) n-2 CH2

A. n = 3.

+Br2

CH2Br (CH2) n-2 CH2Br

B. n = 3,4. C. n = 5. D. n bt k. Nhng ngun nng lng no sau y c coi l nhng ngun nng lng sch khng gy nhim mi trng? A. Nng lng ht nhn, nng lng mt tri. B. Nng lng thy lc, nng lng gi, nng lng mt tri. C. Nng lng than , du m, nng lng thy lc. D. Nng lng than , nng lng mt tri v nng lng ht nhn. Cu 56. Hn hp X c C 2H5OH; C2H5COOH; CH3CHO trong C2H5OH chim 50% theo s mol. t chy m gam hn hp X thu c 3,06 gam H 2O v 3,136 lit CO2 ktc. Mt khc 13,2 gam hn hp X thc hin phn ng trng bc thy c p gam kt ta Ag. p c gi tr l: A. 9,72 gam. B. 6,48 gam. C. 8,64 gam. D. 10,8 gam. Cu 57. SO2 b ln tp cht SO3 dng cch no sau y thu c SO2 nguyn cht ? A. Sc hn hp kh qua dung dch BaCl2 long d.

Cu 55.

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B. Sc hn hp kh qua nc vi trong d. C. Sc hn hp kh t t qua dung dch Na2 CO3. D. Cho hn hp kh sc t t qua dung dch nc brom. Cu 58. Hin tng no di y c m t khng ng ? A. Thm vi git dung dch H2 S vo ng nghim cha dung dch FeCl3, thy xut hin kt ta mu nu. B. Nh t t dung dch KMnO 4 vo ng nghim cha dung dch hn hp FeSO 4 v H2SO4, Thuc tm mt mu v dung dch thu c chuyn t mu xanh nht sang mu vng nu. C. Ct mt ming natri kim loi, trong khng kh, b mt Na t mu trng bc chuyn sang mu xm. D. Cho mt inh st c nh ra sch vo ng nghim cha dung dch CuSO 4, lp b mt Fe chuyn t mu trng bc sang mu . Dung dch thu c nht mu xanh. Cu 59. Th nghim no di y thu c lng kt ta l ln nht ? A. Cho 0,20 mol K vo dung dch cha 0,20 mol CuSO4 . B. Cho 0,35 mol Na vo dung dch cha 0,10 mol AlCl3. C. Cho 0,10 mol Ca vo dung dch cha 0,15 mol NaHCO3 . D. Cho 0,10 mol Ba vo dung dch cha 0,10 mol H2 SO4 (trong dung dch long). Cu 60. Cho bit th in cc chun ca Ag+/Ag l 0,8V; ca Fe2+/Fe l -0,44V; ca Cu2+/Cu l +0,34 V; ca Fe3+/Fe 2+ l +0,77V; ca 2H+/H2 l 0,00V; ca Zn2+/Zn l -0,76V. Hy sp xp tnh oxy ha tng dn ca cc ion kim loi: A. Zn2+ < Fe2+ < Fe 3+ < H+ < Cu2+ < Ag+ . B. Zn2+ < Fe2+ < Cu2+ < H+ < Fe 3+ < Ag+ . C. Zn2+ < Fe2+ < H+ < Cu2+ < Fe 3+ < Ag+ . D. Zn2+ < Fe 2+ < Cu2+ < Fe 3+ < H+ < Ag+.

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TRNG THPT M C A THI TH TUYN SINH I HC, CAO NG LN II (30 4 2009) Mn thi: HO HC Thi gian lm bi: 90 pht (khng k thi gian giao ) Cu 1: Cho 9,3 gam dung di c h phenol 50,6% tan trong r u etylic tc du n g vi natri d th th ti c h kh H 2 bay ra ktc l A. 0,672 li t . B. 2,24 li t . C. 1,68 li t . D. 0,56 li t . Cu 2: H n h p X g m FeO, Fe 2 O 3 va Fe 3 O 4 trong o s mol FeO b n g s mol Fe 2 O 3 . Dung di ch Y g m HCl 1,5M v H 2 SO 4 0,25M. T n g kh i l ng mu i khan thu c trong phn ng ca X va vi 400 ml dung dch Y l A. 47,7 gam. B. 74,7 gam. C. 117,3 gam. D. 54,1 gam. Cu 3: Nhn bit 4 gi bt mu en: CuO, MnO 2 , Ag 2 O v FeO, ta c th dng A. dung dch HNO 3 long. B. dung dch H 2 SO 4 . C. dung dch NaOH. D. dung dch HCl. Cu 4: Dung dch X c pH = 13. Dung dch Y c pH = 1. Trn 2,75 lt dung dch X vi 2,25 lt dung dch Y. Tnh pH ca dung dch to ra A. 13. B. 12. C. 2. D. 10. Cu 5: Hn hp X gm N 2 , H 2 c

C. Ion Fe 3+ c cha 5 electron c thn. D. Bn knh nguyn t Fe nh hn bn knh ion Fe 2+ . Cu 15: Cho 0,2 mol Fe vo dung dch hn hp cha 0,3 mol Fe(NO 3 ) 3 v 0,2 mol AgNO 3 . Khi phn ng hon ton, s mol Fe(NO 3 ) 3 trong dung dch bng A. 0,0 mol. B. 0,1 mol. C. 0,3 mol. D. 0,2 mol. Cu 16: Cacbohirat Z tham gia chuyn ha: Z

Cacbohirat Z khng th l cht no trong cc cht cho di y A. Mantoz. B. Fructoz. C. Glucoz.

Cu ( OH ) 2 / OH

dung dch xanh lam

C t kt ta gch. D. Saccaroz.

Cu 17: Cho X gm H 2 v 2 olefin ng ng k tip. Cho 9,52 lt X ktc qua Ni un nng c hn hp Y. t hon ton Y c 43,56 gam CO 2 v 20,43 gam H 2 O. Tm 2 olefin A. C 2 H 4 v C 4 H 8 . B. C 3 H 6 v C 4 H 8 . C. C 2 H 4 v C 3 H 6 . D. C 4 H 8 v C 5 H 10 . Cu 18: Cho 6,48 gam hn hp 2 axit cacboxylic no n chc mch h ng ng k tip tc dng vi 400 ml dung dch hn hp NaOH 0,1M v KOH 0,2M (d), sau phn ng thu c dung dch X. C cn dung dch X c 11,12 gam cht rn khan. Cng thc phn t ca 2 axit ln lt l A. C 2 H 4 O 2 v C 3 H 6 O 2 . B. CH 2 O 2 v C 2 H 4 O 2 . C. C 4 H 8 O 2 v C 5 H 10 O 2 . D. C 3 H 6 O 2 v C 4 H 8 O 2 . Cu 19: Dung dch X c cha: Ca 2+ 0,1 mol; Mg 2+ 0,3 mol; Cl - 0,4 mol;

d x / He = 2,45. un X vi bt Fe sau 1 thi gian c hn hp Y, d Y / H 2 =

C. 42,86%. D. 54,5%.

6,125. Tnh hiu sut phn ng A. 33,33%. B. 35,46%.

HCO3

y mol. C cn dung dch X thu

Cu 6: Cho t t 100 ml dung dch A cha H 2 SO 4 1M v HCl 1M vo 200 ml dung dch B gm KHCO 3 1M v Na 2 CO 3 1M. thu c V (lit) kh CO 2 (ktc) v dung dch X. Cho dung dch Ba(OH) 2 n d vo dung dch X thu c m gam kt ta. Gi tr ca m v V ln lt l A. 82,4 gam v 2,24 lit. B. 43 gam v 2,24 lit. C. 49,25 gam v 3,36 lit. D. 9,85 gam v 3,36 lit. Cu 7: Xt cc pin in ha c to thnh t cc cp oxi ha kh sau: Fe 2+ /Fe v Pb 2+ /Pb; Fe 2+/Fe v Zn 2+/Zn; Fe 2+ /Fe v Sn 2+/Sn; Fe 2+ /Fe v Ni 2+/Ni; Fe 2+ /Fe v Mg 2+/Mg. S trng hp Fe ng vai tr cc m l A. 1. B. 4. C. 3. D. 2. Cu 8: Cu no sau y l ng khi ni v hiu ng nh knh v ma axit A. Kh gy ra hiu ng nh knh l NO 2 , kh gy ra ma axit l SO 2 ; CO 2 . B. Kh gy ra hiu ng nh knh l SO 2 , kh gy ra ma axit l CO 2 ; NO 2 . C. Kh gy ra hiu ng nh knh l SO 2 ; CO 2 , kh gy ra ma axit l NO 2 . D. Kh gy ra hiu ng nh knh l CO 2 , kh gy ra ma axit l SO 2 ; NO 2 . Cu 9: Hn hp A gm Fe, FeO, Fe 2 O 3 , Fe 3 O 4 vi s mol mi cht bng 0,2. Ha tan ht hn hp A vo dung dch B cha HCl v H 2 SO 4 long, d c dung dch X. Nh t t dung dch Cu(NO 3 ) 2 1M vo dung dch X cho ti khi ngng thot kh NO (sn phm kh duy nht). Tnh th tch kh (ktc) thu c v th tch dung dch Cu(NO 3 ) 2 ti thiu dng A. 1,12 lit; 50 ml. B. 4,48 lit; 100 ml. C. 22,4 lit; 100 ml. D. 2,24 lit; 50 ml. Cu 10: Ta c th chn ti thiu bao nhiu mui v c bao nhiu cch chn khc nhau khi ho tan cc mui + vo nc c dung dch cha cc ion , K + , Cl - , , CH 3 COO 3 4 A. 3; 6. B. 5; 7. C. 4; 2. D. 3; 5.

c cht rn Y. Nung Y trong khng kh n khi lng khng i thu c cht rn Z. Khi lng ca Z l A. 26,8 gam. B. 37,4 gam. C. 28,6 gam. D. 31,8 gam. Cu 20: Cho 7,68 gam hn hp 2 axit n chc, mch h tc dng vi 3,60 gam Na. Phn ng xong c 10,98 gam mui. Tnh th tch H 2 thu c (ktc) A. 1,68 lt. B. 0,84 lt. C. 3,36 lt. D. 6,72 lt. Cu 21: Cho 21 gam hn hp X gm kim loi kim R v Al vo H 2 O d c 11,2 lt kh (ktc) v 4,5 gam cht rn khng tan. Tm R A. K. B. Rb. C. Na. D. Li. Cu 22: Chn cu khng chnh xc A. bo qun dung dch FeSO 4 , cho thm inh st vo. B. Hn hp Cu v Fe 3 O 4 c th b tan hon ton trong dung dch KHSO 4 . C. Na phn ng c vi H 2 O, Cl 2 , dung dch HCl, H 2 , du ho. D. Dung dch 2 mui KHSO 4 v KNO 3 ho tan c Cu, Ag. Cu 23: Nc cng khng gy ra tc hi no di y A. Gy ng c nc ung. B. Gy hao tn nhin liu v khng an ton cho cc ni hi, lm tc cc ng ng dn nc. C. Lm mt tnh ty ra ca x phng, lm h hi qun o. D. Lm hng cc dung dch pha ch, lm thc phm lu chn v gim mi v thc phm. Cu 24: Cho Fe phn ng va ht vi H 2 SO 4 c kh SO 2 v dung dch ch cha 16,5 gam mui. Tnh khi lng ca Fe phn ng, bit s mol Fe phn ng bng 37,5% s mol H2 SO 4 phn ng. A. 4,62 g. B. 5,02 g. C. 6,078 g. D. 2,31 g. Cu 25: Cho cc phn ng : (1) O 3 + dung dch KI (2) F 2 + H 2 O (3) MnO 2 + HCl c (5) Cl 2 + kh H 2 S t oC (4) NH 4 NO 3 (6) SO 2 + dung dch Cl 2

NH

NO

Cu 11: Xp theo th t phn cc tng dn ca lin kt OH trong phn t ca cc cht sau: C 2 H 5 OH (1), CH 3 COOH (2), CH 2 =CHCOOH (3), C 6 H 5 OH (4), CH 3 C 6 H 4 OH (5), C 6 H 5 CH 2 OH (6) l A. (6) < (1) < (5) < (4) < (2) < (3). B. (1) < (3) < (2) < (4) < (5) < (6). C. (1) < (6) < (5) < (4) < (2) < (3). D. (1) < (2) < (3) < (4) < (5) < (6). Cu 12: Phn ng no sau y khng to xeton A. CH 3 CCl 2 CH 3 + NaOH d (t o ). B. CH 3 COOCHClCH 3 + NaOH d (t o ). C. CH 3 CH(OH)CH 3 + CuO (t o ). D. CH 3 COOC(CH 3 )=CH 2 + NaOH d (t o ). Cu 13: Mt hn hp A gm hai ancol c khi lng 16,6 gam un vi dung dch H 2 SO 4 m c thu c 13 gam hn hp B gm hai olefin ng ng lin tip, 3 ete v hai ancol d. t chy hon ton 13 gam hn hp B trn thu c 0,8 mol CO 2 v 0,9 mol H 2 O. Cng thc phn t v % (theo s mol) ca mi ancol trong hn hp l A. C 2 H 5 OH 66,67% v C 3 H 7 OH 33.33%. B. C 2 H 5 OH 50% v C 3 H 7 OH 50%. C. C 2 H 5 OH 33,33% v C 3 H 7 OH 66.67%. D. CH 3 OH 50% v C 2 H 5 OH 50%. Cu 14: Pht biu no di y khng ng A. Cu hnh electron ca ion Fe 2+ l [Ar] 3d 6 . B. Mc oxi ha c trng ca Fe trong hp cht l +2 v +3.

t oC (7) NH 4 NO 2 S phn ng to ra n cht l A. 5. B. 7.

C. 6.

D. 4.

Cu 26: Nhng thanh Al trong dung dch cha 0,09 mol Cu(NO 3 ) 2 mt thi gian (kim loi ng sinh ra bm ht ln thanh nhm). Khi s mol Cu(NO 3 ) 2 cn li 0,03 mol th thanh Al c khi lng A. tng ln 3,84 gam. B. gim i 1,08 gam. C. tng ln 2,76 gam. D. tng ln 1,38 gam. Cu 27: Hy chn h s ng ca cht oxi ho v ca cht kh trong phn ng sau Al + H 2 SO 4 Al 2 (SO 4 ) 3 + SO 2 + H2 O A. 2 v 6. B. 6 v 2. C. 2 v 3. D. 3 v 2. Cu 28: Cho cng thc cht A l C 3 H 5 Br 3 . Khi tc dng vi dung dch NaOH d to mt hp cht tp chc ca ancol bc hai v anehit. CTCTca A l A. CH 2 Br-CH 2 -CHBr 2 . B. CH 3 -CBr 2 -CH 2 Br. C. CH 3 -CH 2 -CBr 3 . D. CH 3 -CHBr-CHBr 2 . Cu 29: T metan cn t nht my phn ng iu ch Poli (vinyl axetat)

Trang 15

A. 6.

B. 3. C t C OH ,t
o o

C. 4.

D. 5.

Cu 30: Phn ng no di y l phn ng lm gim mch polime A. cao su thin nhin + HCl B. poli (vinyl axetat) + H 2 O C. amiloz + H 2 O D. poli (vinyl
+ o

Cu 45: Cho 1 mol KOH vo dung dch cha a mol HNO 3 v 0,2 mol Al(NO 3 ) 3 . thu c 7,8 gam kt ta th gi tr ln nht ca a tha mn l A. 0,75 mol. B. 0,7 mol. C. 0,5 mol. D. 0,3 mol. Cu 46: S anehit c cng thc phn t C5 H 10 O l A. 4. B. 3. C. 5. D. 2.

H ,t C t oC clorua ) + Cl
2

Cu 47: Oxi ho 0,9 gam HCHO thnh axit, sau mt thi gian c hn hp A gm HCOOH v HCHO d. Cho A tc dng vi AgNO 3 d trong dung dch NH 3 un nng, thy sinh ra 10,8 gam Ag. Hiu sut phn ng oxi ho HCHO l A. 33,33%. B. 83,33%. C. 66,67%. D. 70,335%. Cu 48: tng hiu sut nung vi : CaCO 3 (r) C t CaO
o
(r)

+ CO 2 (k) H>0. Ngi ta khng thc hin bin

Cu 31: Ho tan mt oxit kim loi M (c ho tr III) trong mt lng va dung dch H 2 SO 4 25%, sau phn ng thu c dung dch mui c nng 29,5181%. Cng thc oxit l A. Ni 2 O 3 . B. Cr 2 O 3 . C. Al 2 O 3 . D. Fe 2 O 3 . Cu 32: Hp cht A c cng thc phn t C 4 H 6 Cl 2 O 2 . Cho 0,1 mol A tc dng va vi dung dch c cha 0,3 mol NaOH, thu c dung dch hn hp trong c 2 cht hu c gm ru etylic v cht hu c X, c cn dung dch sau phn ng thu c m gam cht rn khan. Gi tr m l A. 9,6 gam. B. 11,3 gam. C. 23,1 gam. D. 21,3 gam. Cu 33: Phng trnh ion thu gn ca phn ng no di y khng c dng: A. KHCO 3 + NH 4 HSO 4 . C. Ca(HCO 3 ) 2 + HCl. B. NaHCO 3 + HF. D. NH 4 HCO 3 + HClO 4 .

php no A. Qut l ui CO 2 . B. Tng nhit hp l. C. Gh nh va phi CaCO 3 . D. H thp nhit .

Cu 49: Thu phn hon ton 1 mol pentapeptit A th thu c 3 mol glyxin; 1 mol alanin v 1mol valin. Khi thu phn khng hon ton A th trong hn hp sn phm thy c cc ipeptit Ala-Gly; Gly-Ala v tripeptit Gly-Gly-Val. Amino axit u N, amino axit u C pentapeptit A ln lt l A. Ala, Val. B. Gly, Gly. C. Gly, Val. D. Ala, Gly. Cu 50: C cc nhn xt sau 1. Protiein l hp cht cao phn t thin nhin c cu to phc tp. 2. Protein ch c trong c th ngi v ng vt. 3. C th ngi v ng vt khng th tng hp c protein t nhng cht v c, m ch tng hp c t aminoaxit. 4. Protein bn i vi nhit, i vi axit v baz kim. 5. Trong thnh phn ca protein lun lun c C, H, O, N. Nhng nhn xt sai l A. 2, 5. B. 2, 3, 4. C. 1, 3, 5. D. 2, 4. P N 1C 2A 3D 4B 5C 6A 7C 8D 9B 10A 11C 12B 13C 14D 15B 16D 17B 18D 19C 20A 21A 22C 23A 24B 25A 26C 27D 28D 29D 30C 31B 32D 33B 34C 35A 36D 37B 38A 39C 40C 41A 42B 43B 44A 45B 46A 47A 48D 49C 50D

HCO3

+ H + H 2 O + CO 2 .

Cu 34: Cho 0,0125 mol este n chc M vi dung dch KOH d thu c 1,4 gam mui. T khi ca M i vi CO 2 bng 2. M c cng thc cu to l A. C 2 H 3 COOCH 3 . B. HCOOC 3 H 7 . C. C 2 H 5 COOCH 3 . D. CH 3 COOC 2 H 5 . Cu 35: Cht X bng mt phn ng to ra C 2 H 5 OH v t C 2 H 5 OH bng mt phn ng to ra cht X .Trong cc cht C 2 H 2 , C 2 H 4 , C 2 H 5 COOCH 3 , CH 3 CHO, CH 3 COOH, CH 3 COOC 2 H 5 , C 2 H 5 ONa, C 2 H 5 Cl s cht ph hp vi X l A. 5. B. 3. C. 4. D. 6. Cu 36: Trong phng th nghim thng iu ch CO 2 t CaCO 3 v dung dch HCl, do CO 2 b ln mt t hi nc v kh hiro clorua. c CO 2 tinh khit nn cho hn hp kh ny ln lt qua cc bnh cha A. dd Na 2 CO 3 v dd H 2 SO 4 c. B. dd NaHCO 3 v CaO khan. C. P 2 O 5 khan v dd NaCl. D. dd NaHCO 3 v dd H 2 SO 4 c. Cu 37: Ho tan 0,24 mol FeCl 3 v 0,16 mol Al 2 (SO 4 ) 3 vo 0,4 mol dung dch H 2 SO 4 c dung dch X. Thm 2,6 mol NaOH nguyn cht vo dung dch X thy xut hin kt ta Y. Khi lng Y l A. 15,6 g. B. 41,28 g. C. 50,64 g. D. 25,68 g. Cu 38: Oxit ca X tan trong nc to ra dung dch lm qu tm. Oxit ca Y phn ng vi nc to ra dung dch lm xanh qu tm. Oxit ca Z tc dng vi c dung dch axit v dung dch kim. X, Y, Z l cc nguyn t cng chu k, th t sp xp theo theo chiu tng dn s hiu nguyn t ca chng l A. Y, Z, X. B. X, Z, Y. C. X, Y, Z. D. Z, Y, X. Cu 39: Cp Ancol v Amin c cng bc A. C 6 H 5 N(CH 3 ) 2 v C 6 H 5 CH 2 OH. C. (C 6 H 5 ) 2 NH v C 6 H 5 CH(OH)CH 3 . B. (CH 3 ) 3 COH v (CH 3 ) 3 CNH 2 . D. (CH 3 ) 2 CHNH 2 v (CH 3 ) 2 CHOH.

Cu 40: X phng ho hon ton 2,5g cht bo cn 50ml dung dch KOH 0,1M. Ch s x phng ho ca cht bo l A. 140. B. 280. C. 112. D. 224. Cu 41: Hin tng ln lt xy ra khi cho t t n d dung dch NaOH vo dung dch CrCl 3 , thm tip H 2 O 2 d, ri cho dung dch BaCl 2 vo l A. to kt ta xanh lc ri tan, dung dch mu vng, kt ta mu vng. B. to kt ta xanh lc, thnh dung dch da cam, kt ta mu vng. C. to kt ta xanh lc ri tan, dung dch mu xanh, kt ta mu vng. D. to kt ta xanh lc ri tan, dung dch mu vng, kt ta da cam. Cu 42: nhn bit cc cht etanol, propenol, etilenglicol, phenol c th dng cc cp cht A. Nc Br 2 v NaOH. B. Nc Br 2 v Cu(OH) 2 . C. KMnO 4 v Cu(OH) 2 . D. NaOH v Cu(OH) 2 . Cu 43: Cho V lt CO 2 ktc vo 200 ml dung dch hn hp KOH 1M v Ba(OH) 2 0,75M c 23,64 gam kt ta. Tnh V lt CO 2 hp th nhiu nht khi c lng kt ta trn A. 2,688 lt. B. 8,512 lt. C. 3,36 lt. D. 11,2 lt. Cu 44: Pht biu no di y khng ng A. Hiro ho du thc vt lng s to thnh cc m ng vt rn. B. Cht bo nh hn nc v khng tan trong nc. C. M ng vt ch yu cu thnh t gc axit bo, no, tn ti trng thi rn. D. Du thc vt ch yu cha gc axit bo khng no tn ti trng thi lng.

Trang 16

------------------- ------------------Cu 1: Cho cht X tc dng vi mt lng va dung dch NaOH, sau c cn dung dch thu c cht rn Y v cht hu c Z. Cho Z tc dng vi AgNO 3 (hoc Ag2 O) trong dung dch NH 3 thu c cht hu c T. Cho cht T tc dng vi dung dch NaOH li thu c cht Y. Cht X c th l cht no trong s cc cht cho di y? A. HCOOCH=CH 2 B. CH 3 COOCH=CH-CH 3 C. CH 3 COOCH=CH 2 D. HCOOCH 3 Cu 2: Ch c dng mt ho cht no trong cc ho cht cho di y nhn bit cc dung dch C cc dung dch sau: AlCl 3 , NaCl, MgCl 2 , H 2 SO 4 ; ng ring bit trong cc l mt nhn? A. Dung dch NaOH B. Dung dch AgNO 3 C. Dung dch BaCl 2 D. Dung dch qu tm Cu 3: Cc cht trong dy cht no sau y u c th tham gia phn ng trng gng? A. imetyl xeton; metanal; matoz B. saccaroz; anehit fomic; metyl fomiat C. Metanol; metyl fomiat; glucoz D. Axit fomic; metyl fomiat; benzanehit

Cu 16:

So snh tnh kh ca 4 kim loi A, B, C, D. Bit rng: Ch c A v C tc dng c vi dung dch HCl gii phng kh. C y c cc kim loi A, B, D ra khi dung dch mui ca chng v D tc dng c vi ion B n+ theo phng trnh phn ng: D + B n+ D n+ + B. A. A < B < C < D B. B < D < A < C C. A < C < B < D D. D < B < A < C Cu 17: Xc nh cc cht hu c X, Y, Z, T trong s phn ng sau: Butilen

Axetilen

A. X: Butan; Y: But- 2- en; Z: Propen, T: Metan C. X: Butan; Y: Propan; Z: Etan; T: Metan

B. X: Butan; Y: Etan; Z: Clo etan; T: iclo etan D. X: Butan; Y: Propan; Z: Etilen; T: iclo etan

Cu 18: Cu 19: Cu 20:

Trng hp no sau y xy ra phn ng v c kh thot ra khi trn cc cht vi nhau? A. Dung dch Na 2 CO 3 v dung dch AlCl 3 B. Bt rn CuS v dung dch HCl C. Dung dch NaHCO 3 v dung dch Ba(OH) 2 D. Dung dch NaHSO 4 v dung dch MgCl 2

Cu 4:

Cho cn bng ho hc: 2SO 2(k) + O 2(k)

2SO 3(k)

(H < 0). iu khng nh no sau y l

Cho 40,3g trieste X (este ba chc) ca glyxerol vi axit bo tc dng va vi 6g NaOH. Khi lng mui thu c sau phn ng l: A. 38,1g B. 41,7g C. 45,6g D. 45,9g Thc hin phn ng nhit nhm hon ton m gam Fe 2 O 3 vi 8,1g Al. Ch c oxit kim loi b kh to kim loi. em ha tan hn hp cc cht thu c sau phn ng bng dung dch NaOH d th thy thot ra 3,36lt H 2 ktc. Gi tr ca m l: A. 16g B. 24g C. 8g D. 4g

ng? A. Cn bng chuyn dch theo chiu thun khi tng nhit . B. Cn bng chuyn dch theo chiu thun khi gim p sut ca h phn ng. C. Cn bng chuyn dch theo chiu nghch khi gim nng ca O 2 D. Cn bng chuyn dch theo chiu nghch khi gim nng ca SO 3 Cu 5: Trong mt bnh kn dung tch khng i c cha a mol O 2 v 2a mol SO 2 100 0c, 10 atm v mt t bt xc tc V 2 O 5 (th tch khng ng k). Nung nng bnh mt thi gian sau lm ngui ti 100 0 c, p sut trong bnh lc l p; hiu sut phn ng l h. mi lin h gia p v h uc biu th bng biu thc no sau y? A.

Cu 21: Cu 22:

C 1 tn qung FeCO 3 hm lng 80% em luyn thnh gang (cha 95% Fe) th thu c 378kg gang thnh phm. Vy hiu sut qu trnh sn xut l bao nhiu? A. 93,98% B. 95% C. 94,8% D. 92,98% Mt hn hp X gm 2 amin no, n chc ng ng k tip phn ng va vi 0,1lt dung dch H 2 SO 4 1M cho ra mt hn hp 2 mui c khi lng l 17,4g. Cng thc phn t v khi lng ca mi amin c trong hn hp X l: A. 4,5g C 2 H 5 - NH 2 v 2,8g C 3 H 7 - NH 2 B. 3,1g CH 3 - NH 2 v 4,5g C 2 H 5 - NH 2 C. 1,55g CH 3 - NH 2 v 4,5g C 2 H 5 - NH 2 D. 3,1g CH 3 - NH 2 v 2,25g C 2 H 5 - NH 2

h p = 10(1 + ) 3

B.

h p = 10(1 ) 2

C.

h p = 10(1 ) 3

D.

h p = 10(1 + ) 2

Cu 6:

Cht A cng thc phn t dng CxHyOz; trong oxi chim 29,09% v khi lng. Bit A tc dng vi NaOH theo t l mol 1 : 2 v tc dng vi Br2 trong dung dch theo t l 1 : 3. Tn gi ca A l: A. o - ihiroxibenzen B. m - ihiroxibenzen C. p - ihiroxibenzen D. axit benzoic Cu 7: Cho 200 ml dung dch Al2(SO4)3 tc dng vi dung dch NaOH 1M ngi ta thy khi dng 220ml hay 60ml dung dch NaOH trn th vn thu c lng kt ta nh nhau. Nng mol/lt ca dung dch Al 2 SO 4 dng l: A. 0,125M B. 0,25M C. 0,075M D. 0,15M Cu 8: Thu phn hon ton 1mol cht hu c X trong dung dch axit HCl sinh ra 1mol ancol no Y v x mol axit hu c n chc Z. Cng thc phn t ca X c dng: A. (C n H 2n+1COO) x C m H 2m+2-x B. (RCOO) x C n H 2n+2-x C. R(COOC n H 2n+2-x ) x D. C n H 2n+1(COOC n H 2n+2-x ) x Cu 9: Trn 3 dung dch H 2SO 4 1M; HNO 3 0,2 M; HCl 0,3M vi nhng th tch bng nhau c dung dch A. Ly 300ml dung dch A cho phn ng vi Vlt dung dch NaOH 1M thu c dung dch C c pH = 2. Gi tr ca V l: A. 0,1235lt B. 0,3735lt C. 0,2446lt D. 0,424lt Cu 10: Cho hn hp X gm 0,01mol FeS2 v 0,01mol FeS tc dng vi H2SO4 c to thnh Fe2(SO4)3, SO 2 v H2 O. Lng SO 2 sinh ra lm mt mu Vlt dung dch KMnO 4 0,2M. Gi tr ca V l: A. 0,12lt B. 0,24lt C. 0,36lt D. 0,48lt Cu 11: Trong 1 bnh kn dung tch khng i cha bt lu hunh v cacbon (th tch khng ng k). Bm khng kh vo bnh n p sut p = 2atm; 25 o C. Bt tia la in cacbon v lu hunh chy ht ri a v 25 o C. p sut trong bnh lc l: A. 1,5atm B. 2,5atm C. 2atm D. 4atm Cu 12: Cho t t dung dch c 0,4mol HCl vo dung dch hn hp cha 0,2mol NaHCO 3 v 0,3mol Na 2CO 3 th th tch kh CO 2 thu c ktc l: A. 2,24lt B. 2,128lt C. 6,72lt D. 3,36lt Cu 13: Hn hp A gm hai ankanal X, Y c tng s mol l 0,25mol. Khi cho hn hp A tc dng vi dung dch AgNO 3 /NH 3 d th to ra 86,4g kt ta v khi lng dung dch gim 77,5g. Bit MX < M Y . Cng thc phn t ca X l: A. HCHO B. CH 3 CHO C. C 2 H 5 CHO D. C 2 H 3 CHO Cu 14: C hai axit hu c no, trong A n chc, cn B a chc. Hn hp X cha A v B, t chy hon ton 0,3mol hn hp X thu c 11,2lt kh CO 2 ktc. Cng thc phn t ca A l: A. HCOOH B. CH 3 COOH C. C 2 H 5 COOH D. C 2 H 3 COOH Cu 15: Tin hnh cc th nghim sau: 1. un nng dung dch amoni nitrit 2. un nng dung dch hn hp gm amoniclorua v natri nitrit 3. un nng dung dch amoni nitrat 4. un nng dung dch hn hp gm amoniclorua v natri nitrat C bao nhiu th nghim trong cc th nghim trn c dng iu ch nit trong phng th nghim? A. 1 B. 2 C. 3 D. 4

Cu 23: Cu 24: Cu 25:

Ho tan 17g hn hp X gm K v Na vo nc c dung dch Y v 6,72lt kh H2 ktc. trung ho mt na dung dch Y cn dung dch hn hp H 2 SO 4 v HCl (t l mol 1 : 3). Khi lng mui khan thu c l: A. 41,3g B. 20,65g C. 34,2g D. 20,83g Cho 5,1g hn hp X gm Al v Mg tc dng va vi dung dch HCl thy khi lng dung dch tng ln 4,6g. Khi lng ca Mg c trong 5,1g hn hp u l: A. 1,2g B. 1,8g C. 3,6g D. 2,4g Ho tan ht 10,5g hn hp 2 kim loi gm Al v mt kim loi kim M vo nc, c dung dch B v 5,6lt kh ktc. Cho t t dung dch HCl vo dung dch B thu c mt lng kt ta ln nht nng 7,8g. Kim loi kim cho l: A. Rb B. K C. Na D. Li Cu 26: t chy 6g cht hu c X ch thu c 4,48lt kh CO 2 ktc v 3,6g nc. S lin kt ti a cha trong X l: A. 0 B. 1 C. 2 D. 3 Cu 27: Cho 15,8g hn hp gm CH 3 OH v C 6H 5OH tc dng vi dung dch brom d, th lm mt mu va ht 48g Br 2 . Nu t chy hon ton hn hp trn th th tch CO 2 thu c ktc l: A. 22,4lt B. 17,92lt C. 1,792lt D. 11,2lt

Cu 28:
A. 70g

Ho tan hon ton 49,6g hn hp X gm Fe, FeO, Fe 3 O 4 , Fe 2 O 3 bng dung dch H 2 SO 4 c, nng, d thu c dung dch Y v 8,96lt kh SO 2 ktc. C cn dung dch Y thu c m gam mui khan. Gi tr ca m l: B. 175g C. 140g D. 105g

Cu 29:
A. 3

T benzen v etilen v cc cht v c cn thit khc, cn phi thc hin t nht bao nhiu phn ng iu ch c hp cht hu c c tn gi 1,2 iclo 1 phenyl etan? B. 4 C. 5 D. 6

Cu 30:

Khi oxi ho (c xc tc) m gam hn hp Y gm HCHO v CH 3CHO bng oxi ta thu c (m + 1,6) gam hn hp Z gm 2 axit. Cn nu cho m gam hn hp Y tc dng vi dung dch AgNO3/NH3 d th thu c 25,92g bc. Phn phn trm theo khi lng ca CH 3 CHO trong hn hp Y l: A. 85,44% B. 14,56% C. 83,9% D. 16,1%

Cu 31:
A. 1

X l hp cht hu c mch h n chc c cha oxi. t chy hon ton 1mol X cn 4mol oxi thu c CO 2 v hi nc vi th tch bng nhau (o cng iu kin). C bao nhiu cht X tho mn iu kin trn? B. 2 C. 3 D. 4

Cu 32: Trang 17

M t nhin l A. mui ca axit bo

B. este ca axit panmitic (C 15 H 31 COOH)

C. hn hp ca cc loi lipit khc nhau

D. este ca axit oleic (C 17 H 33 COOH)

Cu 33:
l: A. Alanin

Cho 0,2mol X (-amino axit dng H 2 NR(COOH)2 ) phn ng ht vi HCl to 36,7g mui. Tn gi ca X B. Axit glutamic C. Glixin D. Valin

A. XOH < Y(OH) 2 < Z(OH) 3 C. Y(OH) 2 < Z(OH) 3 < XOH

B. Z(OH) 3 < Y(OH) 2 < XOH D. XOH < Z(OH) 3 < Y(OH) 2

Cu 48:

Cu 34: Cu 35: Cu 36:

Cho sut in ng chun E0 ca cc pin in ha: E 0 (Fe-Z) = 1,24V; E 0 (T-Fe) = 1,93V; E 0 (Y-Fe) = 0,32V. Dy c sp xp theo chiu tng dn tnh kh cc kim loi l: A. Z, Y, Fe, T B. Z, Fe, Y, T C. T, Y, Fe, Z D. Z, Y, T, Fe Cho cc cht sau CH2=CH2 (I), CH2=CH-CN (II), C6H5-CH=CH 2 (III), CH2=CH-CH=CH 2 (IV). Cc monome to nn cao su buna-N l: A. (I) v (II) B. (II) v (IV) C. (III) v (IV) D. (II) v (III) Cho 8,96lt kh CO 2 ktc vo 250ml dung dch NaOH 2M c dung dch X. Cho X tc dng vi dung dch Ca(OH) 2 d c a gam kt ta. Nu cho X tc dng vi dung dch CaCl 2 d c b gam kt ta. Gi tr ca a v b ln lt l: A. 40g v 10g B. 30g v 10g C. 30g v 15g D. 25g v 15g

Cho s phn ng: + H 2O men Tinh bt A H+ Cht E trong s phn ng trn l: A. Cao su buna B. buta-1,3-ien

ZnO ; MgO t o , p , xt B D E 500o C

C. axit axetic

D. polietilen

Cu 49:

X, Y, Z l 3 nguyn t thuc cng mt chu k ca bng tun hon. Bit oxit ca X khi tan trong nc to thnh mt dung dch lm hng qu tm, Y phn ng vi nc lm to dung dch lm xanh giy qu tm, cn Z phn ng c vi c axit v kim. Dy no sau y c sp xp theo chiu tng dn s hiu nguyn t? A. X < Y < Z B. Z < Y < X C. Y < Z < X D. X < Z < Y

Cu 50:

Cu 37:

X phng ho hon ton 9,7g hn hp hai este n chc X v Y cn 100ml dung dch NaOH 1,5M. Sau phn ng, c cn dung dch thu c hn hp 2 ancol ng ng k tip v mt mui duy nht. Cng thc cu to ca hai este l: A. HCOOCH 3 v HCOOCH 2 CH 3 B. CH 3 COOCH 3 v CH 3 COOCH 2 CH 3 C. HCOOCH 3 v HCOOCH 2 CH 2 CH 3 D. C 2 H 5 COOCH 3 v C 2 H 5 COOCH 2 CH 3

iu khng nh no sau y l ng khi so snh tnh cht ho hc ca cc cht: saccaroz; glucoz; fructoz v xenluloz? A. Chng u d tan trong nc v u c cha nhm -OH B. Tr xenluloz cn saccaroz; glucoz v fructoz u c th tham gia phn ng trng gng C. Khi t chy 4 cht trn th u cho s mol nc bng s mol CO 2 D. C bn cht trn u khng phn ng vi natri

Cu 38: Cu 39:

C 4 ng nghim mt nhn ng ring bit cc cht lng khng mu gm NH 4 HCO 3 ; NaAlO 2 ; C 6 H 5 ONa; C 2 H 5 OH. Ch dng mt ho cht no sau y phn bit bn dung dch trn? A. Dung dch NaOH B. Dung dch HCl C. Kh CO 2 D. Dung dch BaCl 2 Oxi ha hon ton m gam Fe thu c 12g hn hp B gm 4 cht rn. Ha tan hn hp B cn va 200ml dung dch HNO 3 aM thy thot ra 2,24lt kh NO duy nht ktc v dung dch thu c ch cha mt mui tan. Gi tr ca a l: A. 3M B. 2M C. 2,5M D. 3,2M Cu 40: t chy hon ton 0,1mol este X thu c 0,3mol CO 2 v 0,3 mol H2 O. Nu cho 0,1mol X tc dng ht vi NaOH th thu c 8,2g mui. Cng thc cu to ca X l cng thc no cho di y? A. CH 3 COOCH 3 B. CH 3 COOC 2 H 5 C. HCOOC 2 H 5 D. HCOOCH 3 Cu 41: Cho Vlt Cl 2 ktc i qua dung dch KOH long, ngui, d thu c m 1 gam mui. Mt khc khi cho cng Vlt Cl 2 ktc i qua dung dch KOH c, nng, d thu c m 2 gam mui. T l m 1 : m 2 c gi tr l: A. 0,985 B. 1 C. 1,025 D. 0,909 Cu 42: X, Y l hai cht ng phn, X tc dng vi Na cn Y th khng tc dng. Khi t 13,8g X thu c 26,4g CO 2 v 16,2g H 2 O. Tn gi ca X v Y ln lt l: A. Ancol propylic, etyl metyl ete B. Ancol etylic, imetyl ete C. Ancol etylic, ietyl ete D. Ancol metylic, imetyl ete

Cu 43: Cu 44:

Khi cho m gam mt hiroxit ca kim loi M (ho tr n khng i) tc dng vi dung dch H 2 SO 4 th thy lng H 2 SO 4 cn dng cng l m gam. Kim loi M cho l: A. Al B. Mg C. Zn D. Cu Cht hu c A cha 10,33% hiro. t chy A ch thu c CO 2 v H 2 O vi s mol bng nhau v s mol oxi tiu tn gp 4 ln s mol A. Bit A tc dng CuO un nng c cht hu c B. A tc dng KMnO 4 c cht hu c D. D mt nc c B. Cng thc ca cc cht A, B, D ln lt l: A. C3 H4 (OH)3 , C2 H5 CHO, C3 H5 (OH)3 B. C2 H3 CH2 OH, C2 H3 CHO, C3 H5 (OH)3 C. C3 H4 (OH)2 , C2 H5 CHO, C3 H5 OH D. C2 H3 CH2 OH, C2 H4 (OH)2 , CH3 CHO

Cu 45:

Cho phng trnh phn ng: K 2 SO 3 + KMnO 4 + H 2 O X + Y + Z. Cc cht X, Y, Z trong phng trnh phn ng trn l: A. MnO 2 ; KOH; K 2 SO 4 B. K 2 MnO 4 ; K 2 SO 4 ; H 2 O C. MnO 2 ; K 2 SO 4 ; H 2 O D. MnSO 4 ; KOH; H 2 O

Cu 46:

1. C 6 H 5 CH(CH 3 ) 2

Cho cc phn ng ho hc sau: 1) O2 ( kk );2) H 2 SO4

t , xt
o

4. CH 3 CH 2 OH + CuO

t HgSO4 ,t
o o

2. CH 2 = CH 2 + O 2 3. CH 4 + O 2
o

5. CH 3 C CH + H 2 O 6. CH CH + H 2 O

t , xt

HgSO4 ,t

C bao nhiu phn ng trong s cc phn ng trn c th to ra anehit hoc xeton? A. 3 B. 4 C. 5

D. 6

Cu 47:

Xt 3 nguyn t c cu hnh electron ln lt l: (X): 1s 2 2 2 2p 6 3s 1 (Y): 1s 2 2 2 2p 6 3s 2 (Z): 1s 2 2 2 2p 6 3s 2 3p 1 Dy no trong cc dy cho di y c sp xp theo chiu tng dn tnh baz ca cc hiroxit?

Trang 18

 THI TH TUYN SINH VO I HC NM 2009 MN: HO HC, KHI A (Thi gian lm bi: 90 pht) I. PHN CHUNG CHO TT C CC TH SINH (40 cu, t cu 1 n cu 40) * Cho nguyn t khi cc nguyn t cn dng trong (gi tr trong ngoc n): H (1); Na (23); O (16); Fe (56); C (12); S (32); Cu (64); Cl (35,5); N (14); Ba (137); He (4); Zn (65); Cr (52); K (39); Mn (55); Mg (24); Li (7); Rb (85). Cu 1. trng thi c bn, nguyn t ca nguyn t (A) c tng s electron p l 11. Hy cho bit nguyn t (A) c bao nhiu electron ngoi cng ( trng thi c bn)? A. 7 B. 5 C. 11 D. 17 Cu 2. Chn pht biu ng trong s cc pht biu sau: A. Trong bng tun hon, tt c cc chu k cc chu k u bt u l mt kim loi kim v kt thc l mt kh him. B. Trong mt chu k, theo chiu tng Z, bn knh nguyn t cc nguyn t tng dn. C. Cc nguyn t Ca (Z = 20); Sc (Z = 21) v K (Z = 19) c th c cng s ntron. D. Nguyn t cc nguyn t trong mt nhm B c s e ngoi cng nh nhau. Cu 3. Cho phn ng Mg + H 2 SO 4 c, nng MgSO 4 + H 2 S + H 2 O (cha cn bng h s). Tng h s ca cc cht (gm c cht tham gia v sn phm to thnh) trong phn ng ny ( dng s nguyn v ti gin) l: A. 18 B. 9 C. 17 D. 19 Cu 4. Cho phn ng: 2A
(kh)

C. dung dch (A) cha cc ion: H + ; Mg 2+ ; D. dung dch (A) cha cc ion: H + ; Mg2+ ;

SO42 SO42

v Cl - cn dung dch (B) cha cc ion cn li. v

NO3

cn dung dch (B) cha cc ion cn li.

(kh)

+C

(kh)

. Hng s K ca phn ng t 0 C l

1 729

. Tnh % ca A cha b

phn hu ti t 0 C. A. 6,9% B. 6,45% C. 93,7% D. 93,1% Cu 5. Khi pha long mt dung dch axit yu (bng nc ct) th: A. in li v hng s cn bng in li ca axit u tng. B. in li ca axit tng v hng s cn bng in li ca axit khng i. C. in li ca axit tng v hng s cn bng in li ca axit gim. D. in li ca axit gim v hng s cn bng in li ca axit khng i. Cu 6. Axit xitric (acid citric hay axit 2-hidroxipropan-1,2,3-tricacboxylic) c cng thc phn t C 6 H 8 O 7 , l axit c nhiu trong qu chanh, hng s phn li ion nc th nht ca axit xitric l K 1 = 7,110 -4 . Nu ch xt n s phn li nc th nht th pH v in li ca axit xitric 0,1 M ln lt l: A. pH = 1,83; = 8,5%. B. pH = 2,09; = 8,08%. C. pH = 2,10; = 7,5%. D. pH = 3,15; = 5,2%. Cu 7. t chy hon ton 3,00 gam mt mu than c cha tp cht lu hunh. Ton b sn phm kh cho vo dung dch NaOH d thu c dung dch (A). Cho nc brm d vo dung dch (A), sau cho thm dung dch BaCl 2 d vo ta c kt ta (B). Ho tan kt ta (B) trong dung dch HCl d thy cn li 3,495 gam cht rn khng tan. Thnh phn % v khi lng ca tp cht lu hunh trong mu than trn l: A. 16% B. 7,1% C. 17,18% D. 19,39%. Cu 8. Chn pht biu ng trong s cc pht biu sau A. Dung dch cc mui nitrrat u khng mu. B. Khi nhit phn mui amoni, sn phm ca phn ng lun c NH 3 . + C. Khi NH 3 tan trong nc to thnh dung dch ch c cc ion ; OH - v nc. 4 D. Tt c cc mui nitrat u tan trong nc v u l cht in li mnh. Cu 9. Chn pht biu ng trong cc pht biu sau A. Khi in phn dung dch CuSO 4 th pH ca dung dch tng dn. B. Khi in phn dung dch NaCl th pH ca dung dch gim dn. C. Khi in phn dung dch cha hn hp NaCl v CuSO 4 th pH ca dung dch khng i. D. Khi in phn dung dch hn hp HCl v NaCl th pH ca dung dch tng dn. Cu 10. Khi cho tc dng vi dung dch FeCl 3 th dung dch no sau y ch cho kt ta mu trng? A. AgNO3 B. Na 2 CO 3 C. AgNO 3 v Na 2 CO 3 D. NaOH hoc AgNO 3 Cu 11. em t chy ht mt lng kim loi st ( dng bt), thu c hn hp gm ba oxit ca st c khi lng l 101,6 gam. em ha tan ht lng oxit st ny bng dung dch HCl c d, sau c cn dung dch thu c 162,5 gam FeCl 3 v m gam FeCl 2 . Khi lng st em t chy l A. 72,8 B. 38,1 C. 76,2 D. 44,8 Cu 12. Cho hai dung dch (A) v (B). Mi dung dch ch cha 2 cation v 2 anion trong s cc ion sau: K + (0,15 + 2 mol), Mg 2+ (0,1 mol), (0,25 mol), H + (0,2 mol), Cl (0,1 mol), (0,075 mol), (0,25 mol) v 3 4 4

NH

Cu 13. Cho 17,8 gam kim loi R tc dng vi kh clo d thu c 54,2 gam mui clorua (hiu sut phn ng bng 100%). Kim loi R l: A. Cr B. Al C. Fe D. Mg Cu 14. Cho mt t bt st vo dung dch HCl d thu c dung dch (A) v kh (B). Sau cho tip dung dch AgNO 3 d vo dung dch (A) th thu c dung dch (D) v cht rn (E). Bit cc phn ng xy ra hon ton, s cht trong dung dch (D) v cht rn (E) ln lt l: A. dung dch (D) cha 2 cht v cht rn (E) cha 2 cht. B. dung dch (D) cha 3 cht v cht rn (E) cha 1 cht. C. dung dch (D) cha 2 cht v cht rn (E) cha 1 cht. D. dung dch (D) cha 1 cht v cht rn (E) cha 3 cht. Cu 15. Cho 3,76 gam hn hp (B) cha Mg v MgO (vi t l mol tng ng 14:1). Cho hn hp (B) tc dng ht vi dung dch HNO 3 va , sau phn ng thu c 0,672 lit kh (X) v dung dch (Y). C cn cn thn dung dch (Y) thu c 22,6 gam mui khan. Bit cc th tch kh u o ktc, cng thc phn t kh (X) l: A. N 2 B. NO C. N 2 O D. NO 2 Cu 16. Trong mt bnh kn c cha hn hp (D) gm ba kh O 2 ; CH 4 v H 2 . T khi ca hn hp (D) so vi Heli 0 bng 5,7. Bt tia la in t chy hon ton hn hp (D), sau lm lnh bnh v 0 C th ch cn li 6 gam hn hp kh (E) gm hai kh c t khi so vi Heli l 10. Dn hn hp (E) qua bnh ng dung dch Ba(OH) 2 d th thu c 19,7 gam kt ta. Thnh phn % v th tch ca cc kh trong hn hp (D) l: A. CH 4 (30%); O 2 (40%) v H 2 (30%). B. CH 4 (20%); H 2 (30%) v O 2 (50%). C. CH 4 (14,035%); O 2 (84,21%) v H 2 (1,755%). D. CH4 (20%); H2 (20%) v O2 (60%). Cu 17. Khi crcking V lit butan thu c hn hp (A) ch gm cc ankan v anken. T khi ca hn hp (A) so vi hidro bng 21,75. Tnh hiu sut phn ng crcking butan. A. H = 33,33% B. H = 25% C. H = 75% D. H = 66,67% Cu 18. (X) l mt ankadien c mch cacbon khng phn nhnh. t chy hon ton 1 mol (X) thu c 132,4 lit CO 2 ( ktc). (X) c ba ng phn hnh hc, tn gi ca (X) l: A. 2-metylpenta-1,3-dien B. Hexa-1,3-dien C. Hexa-1,4-dien D. Hexa-2,4-dien Cu 19. Cht no sau y khng dng lm khan ru? A. CaO. B. C 2 H 5 ONa. C. Mg(ClO 4 ) 2 . D. H2 SO 4 . Cu 20. iu ch 2-clobutan, ngi ta dng phng php no trong s cc phng php sau thu c sn phm c tinh khit cao? A. Cho n-butan tc dng vi kh clo (askt, t l mol 1:1). B. Cho but-2-en tc dng vi kh HCl. C. Cho but-1-en tc dng vi kh HCl. D. Cho but-2-in tc dng vi clo (t l mol 1:1) Cu 21. Trong cc cht: propan-2-ol; axetilen; metylfomiat; vinylclorua; metan; vinylaxetat. S cht c th to ra andehit ch bng mt phn ng l A. 4 B. 3 C. 5 D. 2 Cu 22. pK a l i lng dng nh gi mnh ca cc axit (pK a = - lgK a ). pK a ca axit cng nh, tnh axit cng mnh. Cc gi tr 1,24; 1,84; 4,18; 4,25 l pK a (khng theo th t cc axit tng ng) ca 4 axit sau: C 6 H 5 COOH; CH 2 =CH-COOH; CHC-COOH; CHF 2 COOH. Gi tr pK a ca axit CHC-COOH l A. 1,24 B. 1,84 C. 4,18 D. 4,25 Cu 23. Cho dy chuyn ho sau:

(A) O2; Pt

O2; Mn2+

(B) H2SO4

CH3CH2CH2OH H2SO4; 1800C (D) H2O; H+

(X)

NH

SO

NO

CO

2 (0,15 mol). Hy cho bit cc ion trong mi dung dch (A) v (B). 3

A. dung dch (A) cha cc ion: H + ; K + ; Cl - v B. dung dch (A) cha cc ion: H + ; K + ;

NO3
v

cn dung dch (B) cha cc ion cn li. cn dung dch (B) cha cc ion cn li. 3

(E)

2 SO4

NO

Cng thc cu to thu gn ca hp cht (X) l: A. iso-C 3 H 7 OCOC2 H 5 B. n-C 3 H 7 O(iso-C 3 H 7 )

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C. C 2 H 5 OCOCH(CH 3 ) 2 D. n-C 3 H 7 OCOC 2 H 5 Cu 24. S dng ho cht no di y phn bit du m ng, thc vt v du m bi trn my? A. Nc nguyn cht un nng. B. Benzen nguyn cht un nng C. Dung dch NaOH un nng. D. Ru etylic nguyn cht un nng. Cu 25. Mt loi protein (A) c cha 0,16% lu hunh v khi lng. Bit trong phn t (A) c 2 nguyn t S. Phn t khi gn ng ca loi protein l: A. 10.240 B. 20.000 C. 20.480 D. 40.000 Cu 26. Amin RNH 2 c iu ch theo phn ng : NH 3 + RI RNH 2 + HI. Trong RI, iot chim 81,44%. t 0,15 mol RNH 2 cn bao nhiu lt O 2 (ktc) ? A. 7,56 lt B. 12,6 lt C. 17,64 lt D. 15,96 lt Cu 27. ng vi cng thc phn t C 2 H 7 O 2 N c bao nhiu cht khi phn ng vi NaOH cho ra kh c mi khai? A. 2 B. 3 C. 4 D. 1 Cu 28. Mt nh my ng mi ngy p 30 tn ma. Bit mi t ma cho 63 lt nc ma vi nng ng l 7,5% v khi lng ring bng 1,103 gam/ml. Khi lng ng thu c mi ngy l: A. 1613,1 kg B. 1163,1 kg C. 1631,1 kg D. 1361,1 kg Cu 29. Chn cu sai trong cc cu sau: A. Sn phm ca phn ng trng ngng axit H2N(CH2)5COOH (axit - aminocaproic) l polipeptit. B. Sn phm ca phn ng trng ngng phenol vi fomandehit trong mi trng axit l polime mch khng nhnh. C. Etylenglicol (etan-1,2-diol) c th tham gia phn ng trng ngng to thnh polime. D. Cao su buna-S khng cha lu hunh, nhng cao su buna-N c cha nit. Cu 30. em nitro ho 9,36 gam benzen bng 13,37 ml dung dch HNO 3 60,67% (khi lng ring bng 1,37 gam/ml) thu c 12,3 gam nitrobenzen. Hiu sut phn ng nitro ho l A. 66,67%. B. 70%. C. 80%. D. 83,33%. Cu 31. Chn pht biu sai A. Nhit si ca ng phn cis- cao hn nhit si ca ng phn trans-. B. Ankan mch phn nhnh c nhit si thp hn ankan mch khng phn nhnh. C. Xicloankan c nhit si cao hn ankan c cng s nguyn t cacbon. D. Trong ba cht C 4 H9 Cl; C4 H9 CHO; C3 H7 NO2 ; cht c nhit si cao nht l C 4 H 9 Cl. Cu 32. Thc hin phn ng tch hidro t mt hidrocacbon (A) thuc dy ng ng ankan bng cch dn (A) i qua cht xc tc nhit cao th thu c hn hp gm hidro v 3 hidrocacbon (B), (C), (D). t chy hon ton 4,48 lit kh (B) hoc (C) hoc (D) u thu c 17,92 lit CO 2 v 14,4 gam H 2 O. Tn gi ca (A) l: A. iso-Butan B. Butan C. iso-Pentan D. Pentan Cu 33. Phn ng este ho (c xc tc axit H 2 SO 4 ) no di y vit khng chnh xc? A. CH3 COOH + C2 H3 OH CH3 COOC2 H3 + H 2 O B. 2CH 3 COOH + C 2 H 4 (OH) 2 (CH 3 COO) 2 C 2 H 4 + 2H 2 O C. (COOH) 2 + 2C 2 H 5 OH (COOC 2 H 5 ) 2 + 2H 2 O D. C n H 2n (COOH) 2 + 2C m H 2m+1OH (C m H 2m+1OCO) 2 C n H 2n + 2H 2 O Cu 34. Chn pht biu ng A. Amilopectin trong tinh bt c cu trc mch thng. B. Khi x phng ho este anlyl axetat bng NaOH thu c mui v andehit. C. Phenol tan t trong nc lnh nhng tan v hn trong nc nng trn 700 C. D. lipit l trieste ca glixerol v cc axit bo. Cu 35. ng vi cng thc phn t C 4 H 8 O 2 c bao nhiu ng phn n chc, mch h? A. 6 B. 5 C. 4 D. 8 Cu 36. Hin tng xy ra khi cho Na kim loi vo dung dch CuSO 4 l A. B mt kim loi c mu , c bt kh khng mu v c kt ta mu xanh. B. Si bt kh khng mu v c kt ta mu xanh. C. Si bt kh khng mu v c kt ta mu trng. D. C kh khng mu bay ln v b mt kim loi c mu . Cu 37. Cho 2,3 gam hn hp (A) gm Rb v mt kim loi kim R khc tc dng vi nc (d) thu c dung dch (B). trung ho mt na dung dch (B) cn 200 ml dung dch HCl 0,25M. Kim loi R l: A. Li B. Na C. K D. Cs Cu 38. Cho 27,4 gam kim loi bari vo dung dch cha 0,1 mol CuSO 4 . Khi phn ng xy ra hon ton th khi lng kt ta thu c l A. 9,8 gam. B. 23,3 gam. C. 33,1 gam. D. 46,6 gam. Cu 39. Cho 11,2 gam bt st vo dung dch HNO 3 long thu c 3,36 lit kh NO (o ktc, NO l sn phm kh duy nht) v dung dch (X). C cn dung dch (X) thu c m gam mui khan. Gi tr ca m l A. 39,1 B. 29,8 C. 36 D. 42,2 Cu 40. Cho 13,5 gam hn hp cc kim loi Al, Cr, Fe tc dng vi lng d dung dch H2SO4 long, nng (trong iu kin khng c khng kh), thu c dung dch (X) v 7,84 lt kh H2 ( ktc). C cn dung dch (X) (trong iu kin khng c khng kh) c m gam mui khan. Gi tr ca m l A. 42,6. B. 45,5. C. 48,8. D. 47,1. II. PHN RING: Th sinh ch c lm mt trong hai phn (phn A hoc phn B). A. Theo chng trnh Chun. (10 cu, t cu 41 n cu 50)

Cu 41. Mt hn hp gm 4 mol N 2 v 8 mol H 2 c cho vo bnh kn c dung tch 5 lit v gi nhit khng i. Khi phn ng t trng thi cn bng th p sut bng 10/12 p sut kh trong bnh trc phn ng. Hiu sut phn ng tng hp NH 3 l: A. 25%. B. 20%. C. 37,5%. D. 50%. Cu 42. Cho m gam hn hp etanal v propanal phn ng hon ton vi lng d dung dch AgNO 3 trong NH 3 thu c 43,2 gam kt ta v 17,5 gam hn hp mui ca hai axit hu c. Gi tr ca m l: A. 9,5 B. 10,2 C. 10,9 D. 19,0. Cu 43. Cho s chuyn ho sau: cao CH 4 t A1 + H 2 A2 A3 A1 A4 A5 + A2 O , He Cc cht A 5 v A 2 c th l: A. HCOONa v CH 3 CHO. B. CH3 COONa v CH3 CHO. C. CH 3 COONa v CH 2 =CH-OH. D. CH 3 COONa v HCHO. Cu 44. Cho 0,1mol Fe vo 500 ml dung dch AgNO 3 1M th dung dch thu c cha: A. AgNO 3 B. Fe(NO 3 ) 3 C. AgNO 3 v Fe(NO 3 ) 2 D. AgNO3 v Fe(NO3 ) 3 Cu 45. Pht biu no sau y khng ng? A. Crom l kim loi c tnh kh yu hn km. B. Crom l kim loi lng tnh. C. Crom c th c iu ch bng phng php nhit nhm. D. hidroxit cao nht ca crom l axit Cu 46. Cho 19,375 gam hn hp (A) gm Zn v Cu vo 1 lit dung dch Fe 2 (SO 4 ) 3 0,25M. Phn ng kt thc thu c dung dch (B) v 3,2 gam cht rn (D). Cho (D) vo dung dch H 2 SO 4 long khng thy kh thot ra. Khi lng ca Cu trong 17,8 gam hn hp (A) l: A. 8,0 gam B. 4,8 gam C. 3,2 gam D. 9,6 gam. Cu 47. phn bit 3 bnh mt nhn cha cc kh N 2 ; O 2 ; O 3 (mi bnh cha 1 kh) c bn hc sinh thc hin theo 4 cch di y. Cch no sai? A. dng Ag un nng, que m. B. dng que m, l Ag un nng. C. dng dung dch KI/ h tinh bt, que m. D. dng dung dch KI/ h tinh bt, l Ag un nng Cu 48. Khi tch nc ancol 2,4,4-trimetylpentan-2-ol thu c sn phm chnh l anken: A. 2,4,4-trimetylpent-2-en B. 2,2,4-trimetylpent-2-en. B. 2,4,4-trimetylpent-3-en. D. 2,2,4-trimetylpent-4-en. Cu 49. ng vi cng thc phn t C 4 H 11 N c bao nhiu amin bc 1? A. 4 B. 8 C. 7 D. 6 Cu 50. Tinh bt c phn t khi khong 200.000 n 1.000.000. Vy s mt xch trong phn t tinh bt nm trong khong A. 2000 n 6000. B. 600 n 2000. C. 1000 n 5500. D. 1000 n 6000. B. Theo chng trnh nng cao. (10 cu, t cu 51 n cu 60) Cu 51. Cho hn hp kh (A) gm N 2 v H 2 (c t l mol tng ng l 1:3). Cho hn hp kh (A) i qua xc tc un nng mt thi gian thu c hn hp kh (B). T khi ca hn hp (A) so vi hn hp (B) l 0,6. Hiu sut phn ng tng hp NH 3 l; A. 33,33% B. 50% C. 66,67% D. 80% Cu 52. iu ch axeton trong cng nghip, ngi ta dng phng php A. Oxi ho cumen bng oxi khng kh (c mt xc tc thch hp). B. Oxi ho propan-2-ol bng oxi khng kh (c xc tc Cu un nng). C. Oxi ho 2,3-dimetylbut-2-en bng dung dch KMnO 4 un nng. D. Thu phn 2,2-diclopropan bng dung dch kim un nng. Cu 53. (A) l mt cht hu c. t chy 1 mol (A) thu c 4 mol CO 2 v 3 mol H 2 O. Cng 1 mol (A) tc dng c KHCO 3 d to 1 mol CO 2 , cn cho 1 mol (A) tc dng ht vi Na th thu c 1 mol kh H 2 . (A) khng cho c phn ng trng hp. (A) l cht no trong cc cht cho di y? A. HOOC-CH 2 -CH 2 -COOH. B. HO-CH2 -CO-CH2 -COOH. C. HO-CH 2 -CH 2 -O-CH 2 -COOH. D. HO-CH 2 -CH=CH-COOH. Cu 54. Cho 0,02 mol bt st vo dung dch cha 0,07 mol AgNO 3 , khi phn ng hon ton th khi lng cht rn thu c l A. 1,12 gam B. 4,32 gam C. 6,48 gam D. 7,56 gam. Cu 55. oxi ha hon ton 0,02 mol CrCl 3 thnh K 2 CrO 4 bng Cl 2 khi c mt KOH, lng ti thiu Cl 2 v KOH cn dng tng ng l A. 0,03 mol v 0,08 mol. B. 0,03 mol v 0,16 mol. C. 0,06 mol v 0,16 mol. D. 0,06 mol v 0,08 mol. Cu 56. Cho 9,7 gam hn hp (X) gm Cu v Zn vo 0,5 lit dung dch FeCl 3 0,5M. Phn ng kt thc thu c dung dch (Y) v 1,6 gam cht rn khng tan (Z). Cho (Z) vo dung dch H 2 SO 4 long khng thy kh bay ln. Dung dch (Y) phn ng va vi 200 ml dung dch KMnO 4 a mol/lit (trong mi trng H 2 SO 4 ). Gi tr ca a l: A. 0,25 B. 0,20 C. 0,50 D. 0,40. Cu 57. Chn cu sai trong cc cu sau A. loi kh clo sinh ra d trong phng th nghim, ngi ta s dng kh NH3 . B. gom thu ngn ri ra khi nhit k thu ngn b v, ngi ta dng bt lu hunh.
o 2+

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C. nhn bit ion SO 4 2- trong dung dch, ngi ta dng mui tan ca bari nh BaCl 2 ; Ba(NO 3 ) 2 (trong mi trng axit long d). D. thc hin phng php chun pemanganat, ngi ta dng dung dch KMnO4 v dung dch chun l dung dch H 2 SO4 Cu 58. Chn cu sai trong cc cu sau A. Mentol (C 10 H 20 O) v menton (C 10 H 18 O) l nhng dn xut cha oxi ca tecpen. B. Cho phenylclorua (C 6 H 5 Cl) vo dung dch NaOH, un nng, sau axit ho bng HNO 3 , tip cho dung dch AgNO 3 khng thy c kt ta trng. C. Khi cho C 2 H5 Cl tc dng vi nc nhit cao thu c ancol C2 H 5 OH. D. Etilen khng tc dng vi dung dch HCl 30%. Cu 59. ng vi cng thc C 5 H 13 N c bao nhiu amin bc II? A. 5 B. 6 C. 4 D. 7 Cu 60. Cho 6,84 gam hn hp saccaroz v mantoz tc dng vi lng d dung dch AgNO 3 /NH 3 thu c 1,08 gam Ag kim loi. S mol saccaroz v mantoz trong hn hp ln lt l A. 0,005 v 0,015 B. 0,010 v 0,010 C. 0,015 v 0,015 D. 0,015 v 0,005.

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S GIO DC V O TO THNH PH NNG TRNG THPT CHUYN L QU N THI TH TUYN SINH I HC, CAO NG LN 1, NM 2009 Mn thi: HO HC Thi gian lm bi: 90 pht (khng k thi gian giao ) Cho bit khi lng nguyn t (theo vC) ca cc nguyn t: H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52; Fe = 56; Cu = 64; Br = 80; Ag = 108; Ba = 137. I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40) Cu 1: Cho 28g bt st vo dung dch AgNO3 d, gi s phn ng xy ra hon ton th khi st tc dng ht s thu c bao nhiu gam cht rn A. 162g. B. 216g. C. 270g. D. 108g. Cu 2: C bao nhiu ipeptit c th to ra t hai axit amin l alanin (Ala) v glixin (Gli) A. 5. B. 2. C. 4. D. 3. Cu 3: Cho cc dung dch c nh s th t nh sau: 1. KCl; 2. Na2 CO3; 3. CuSO4; 4. CH3COONa; 5. Al2 (SO4 )3; 6. NH4 Cl; 7. NaBr; 8. K2S. Cc dung dch c pH < 7 l A. 3, 5, 6. B. 6, 7 , 8. C. 2, 4, 6. D. 1, 2, 3. Cu 4: Trong cc cht p.O2 N-C6H4-OH, m.CH3 -C6 H4 -OH, p.NH2-C 6H4-CHO, m.CH3-C 6H4-NH2. Cht c lc axit mnh nht v cht c lc baz mnh nht tng ng l A. p.O2 N-C6H4-OH v m.CH3 -C6 H4 -NH2 . B. m.CH3-C 6H4-OH v m.CH3 -C6 H4 -NH2 . C. p.O2 N-C6H4-OH v p.NH2-C 6H4-CHO. D. m.CH3 -C6 H4 -OH v p.NH2 -C6 H4 -CHO. Cu 5: Nhn xt no di y khng ng A. CrO, Cr(OH)2 c tnh baz; Cr2O3, Cr(OH)3 c tnh lng tnh B. Hp cht Cr(II) c tnh kh c trng; Cr(III) va c tnh oxi ha, va c tnh kh; Cr(VI) c tnh oxi ha. C. Cr(OH)2, Cr(OH)3 c th b nhit phn. D. Cr2+, Cr3+ c tnh trung tnh;

Cu 13: nhn ra ion SO

2 trong dung dch hn hp c ln cc ion 4

3 CO32 , PO4 , SO32 , v

HPO42 , nn dng thuc th l dung dch cht no di y

A. H2 SO4 c d. C. Ca(NO3 )2. B. Ba(OH)2. D. BaCl2 / H2SO4 long d. Cu 14: Cho m gam bt st vo dung dch hn hp cha 0,16 mol Cu(NO3)2 v 0,4 mol HCl, lc u cho phn ng xy ra hon ton. Sau phn ng thu c hn hp kim loi c khi lng bng 0,7m gam v V lt kh (ktc). Gi tr ca V v m ln lt l A. 1,12 lt v 18,20 gam. B. 4,48 lt v 21,55 gam. C. 2,24 lt v 33,07 gam. D. 4,48 lt v 33,07 gam. Cu 15: Cho cc hp cht sau: 1. CH3 -CH(NH2 )-COOH 2. HO-CH2-COOH 3. CH2 O v C6H5OH 4. C 2H4(OH)2 v p-C6 H4 (COOH)2 5. (CH2 )5(NH2)2 v (CH2 )4(COOH)2. Cc trng hp no sau y c kh nng tham gia phn ng trng ngng A. 3, 5. B. 1, 2, 3, 4, 5. C. 1, 2. D. 3, 4. Cu 16: Cho 4,48 lt CO2 (ktc) hp th ht vo 500ml dung dch hn hp NaOH 0,1M v Ba(OH) 2 0,2M thu c m gam kt ta. Gi tr ng ca m l A. 20,4g. B. 15,2g. C. 9,85g. D. 19,7g. Cu 17: Hn hp (X) gm metanal v etanal. Khi oxi ha (hiu sut 100%) m (g) hn hp (X) thu c hn hp (Y) gm hai axit hu c tng ng, c t khi hi ca hn hp Y so vi hn hp X bng x .Gi tr x trong khong no A. 1,62 < x < 1,53. B. 1,36 < x < 1,47. C. 1,45 < x < 1,53. D. 1,36 < x < 1,53. Cu 18: Aminoaxit Y cha 1 nhm COOH v 2 nhm - NH 2 cho 1 mol Y tc dng ht vi dung dch HCl v c cn th thu c 205g mui khan. Tm cng thc phn t ca Y A. C6 H14N2O2. B. C4 H10N2O2. C. C5 H10N2O2. D. C 5H12 N2 O2 . Cu 19: C 4 kim loi : Mg, Ba, Zn, Fe. Ch dng thm 1 cht th c th dng cht no trong s cc cht cho di y nhn bit kim loi A. dung dch Ca(OH)2. B. dung dch H2SO4 long. C. dung dch NaOH. D. khng nhn bit c. Cu 20: un nng phenol vi anehit fomic theo t l mol 1:1 trong mi trng axit ta thu c A. hn hp hai cht hu c tan vo nhau v khng c phn ng. B. polime c cu trc mch khng phn nhnh. C. polime c cu trc mng khng gian bn. D. polime c cu trc mch h phn nhnh. Cu 21: Cho hn hp gm FeO, CuO, Fe 3O4 c s mol 3 cht u bng nhau tc dng ht vi dung dch HNO3 thu c hn hp kh gm 0,09 mol NO2 v 0,05 mol NO. S mol ca mi cht l A. 0,21. B. 0,12. C. 0.36. D. 0,24. Cu 22: Ho tan hon ton 1,4 gam bt Fe kim loi bng dung dch HNO3 nng 2M ly d thu c V lt (ktc) hn hp kh NO v NO2 c t khi hi so vi hiro l 17. Gi tr ca V l A. 0,448 lt. B. 0,672 lt. C. 0,896 lt. D. 0,112 lt. Cu 23: Cho hn hp cha x mol Mg, y mol Fe vo dung dch cha z mol CuSO4 . Sau khi kt thc cc phn ng thu c cht rn gm 2 kim loi. Mun tho mn iu kin th A. x < z < y. B. z x. C. x z < x +y. D. z = x + y. Cu 24: Trong cc qu trnh di y 1) H2 + Br2 (t o) 3) PBr3 + H2O Qu trnh no khng iu ch c HBr A. (3) v (4). B. (1) v (3). 2) NaBr + H2SO4 (c, to d) 4) Br2 + P + H2O C. (2). D. (3).

Cr (OH ) 4

c tnh baz.

Cu 6: Thi kh CO2 vo dung dch cha 0,02 mol Ba(OH) 2 . Gi tr khi lng kt ta bin thin trong khong no khi CO2 bin thin trong khong t 0,005 mol n 0,024 mol A. 0,985 gam n 3,94 gam. B. 0 gam n 3,94 gam. C. 0 gam n 0,985 gam. D. 0,985 gam n 3,152 gam. Cu 7: Dy gm cc cht sau y u tc dng vi dung dch NaOH A. C 6H5NH2 , C6 H5 OH. B. C6 H5 OH ,C2 H5 OH. C. CH3COOC2H5, NH2CH2 COOH. D. CH3COOH, C2H5OH. Cu 8: Tng s ht trong ion M3+ l 37. V tr ca M trong bng tun ha l A. chu k 3, nhm IIA. B. chu k 4, nhm IA C. chu k 3, nhm IIIA. D. chu k 3, nhm VIA Cu 9: To lipit t glixerin phn ng vi 2 axit bo RCOOH v R'COOH, ta thu c hn hp cc trieste. Tnh s trieste ny A. 8. B. 4. C. 6. D. 5. Cu 10: Cho 0,3 mol Fe xOy tham gia phn ng nhit nhm thy to ra 0,4 mol Al 2 O3 . Cng thc oxit st l: A. FeO. B. Fe 2 O3 C. Khng xc nh.D. Fe 3O4. Cu 11: Cho dy cc cht: Ca(HCO3 )2, NH4 Cl, (NH4)2 CO3, ZnSO4 , Al(OH)3 , Zn(OH)2 . S cht trong dy c tnh cht lng tnh l A. 2. B. 3. C. 4. D. 5. Cu 12: Cho 2,54g este (X) mch h bay hi trong 1 bnh kn dung tch 0,6 lt (lc u l chn khng). Khi este bay hi ht th p sut 136,5 oC l 425,6 mmHg. Thu phn 25,4 gam (X) cn 0,3 mol NaOH thu c 28,2 g mt mui duy nht. Xc nh tn gi (X) bit rng (X) pht xut t ru a chc A. Glixerin triaxetat. B. Etylenglicoliaxetat. C. Glixerin tripropionat. D. Glixerin triacrylat.

Cu 25: Cho 6,76 gam oleum H2SO4.nSO3 vo nc thnh 200ml dung dch. Ly 10 ml dung dch ny trung ho va vi 16 ml dung dch NaOH 0,5 M. Gi tr ca n l A. 2. B. 1. C. 4. D. 3.

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Cu 26: Chia hn hp 2 kim loi c ho tr khng i lm 2 phn bng nhau. Phn 1 tan ht trong dung dch HCl to ra 1,792 lt H2 (ktc). Phn 2, nung trong oxi thu c 2,84 gam hn hp oxit. Khi lng hn hp 2 kim loi ban u l A. 1,8 gam. B. 2,4 gam. C. 3,12 gam. D. 2,2 gam. Cu 27: C bn ng nghim ng cc hn hp sau: 1) Benzen + phenol; 2) Anilin + dung dch H 2 SO4 (ly d); 3) Anilin +dung dch NaOH; 4) Anilin + nc. Hy cho bit trong ng nghim no c s tch lp A. 1, 2, 3. B. 1, 4. C. 3, 4. D. Ch c 4. Cu 28: Thu phn cc hp cht sau trong mi trng kim 1. CH3 ClCHCl 2. CH3 COOCH=CH2 3. CH3 COOCH2 -CH=CH2 4. CH3CH2 CHOHCl 5. CH3 COOCH3 . Sn phm to ra c phn ng trng gng l A. 1, 2, 4. B. 1, 2. C. 3, 5.

Cu 40: Hp cht X khng no mch h c cng thc phn t C 5H8O2, khi tham gia phn ng x phng ho thu c mt anehit v mt mui ca axit hu c. C bao nhiu cng thc cu to ph hp vi X (khng k ng phn hnh hc) A. 4. B. 3. C. 2. D. 5. II. PHN RING [10 cu] Th sinh ch c lm mt trong hai phn (phn A hoc phn B) A. Theo chng trnh chun (10 cu, t cu 41 n cu 50) Cu 41: Bnh 1 ng O2, bnh 2 ng O2 v O3 th tch nhit p sut ca 2 bnh u nh nhau. Khi lng kh bnh 2 nng hn bnh 1 l 1,6g tnh s mol O3 c trong bnh 2 A. Khng xc nh. B. 1/3 mol. C. 0,1 mol. D. 0,5 mol. Cu 42: Mt hn hp X gm 1 ankan A v 1 ankin B c cng s nguyn t cacbon. Trn X vi H 2 (va ) c hn hp Y. Khi cho Y qua Pt, xc tc th thu c kh Z c t khi i vi CO2 bng 1

D. 2.

Cu 29: X l dung dch AlCl3 Y l dung dch NaOH 2M thm 150ml dung dch Y vo cc cha 100 ml dung dch X khuy u n khi phn ng hon ton thy trong cc c 7,8g kt ta. Thm tip vo cc 100ml dung dch Y khuy u ti khi kt thc phn ng thy trong cc c 10,92 g kt ta. Nng mol ca dung dch X bng A. 3,2 M. B. 2,0 M. C. 1,6 M. D. 1,0 M. Cu 30: Hn hp X gm FeO, Fe 3 O4 v Fe2O3. kh hon ton 3,04 gam hn hp X cn va 0,1 gam H2 . Ho tan ht 3,04 gam hn hp X bng dung dch H2 SO4 c, nng th th tch kh SO2 (sn phm kh duy nht) thu c ktc l A. 0,224 lt. B. 0,336 lt. C. 0,896 lt. D. 0,448 lt. Cu 31: C hin tng g xy ra khi cho t t n d dung dch FeCl3 v dung dch Na2 CO3 A. Ch c kt ta nu . B. C kt ta nu v si bt kh. C. Ch c si bt kh. D. C kt ta trng xanh v si bt kh. Cu 32: phn bit 2 dung dch KI v KCl bng h tinh bt ngi ta phi dng thm 1 cht no sau y? p n no khng ng A. FeCl3 . B. O3. C. Khng cn dng cht no. D. Cl2 hoc Br2. Cu 33: Hp cht X (C8H10 )c cha vng benzen, X c th to ra 4 dn xut C8 H9 Cl. Vy X l A. p-xilen. B. Etylbenzen. C. o-xilen. D. m- xilen. Cu 34: Thm NH3 n d vo dung dch hn hp cha 0,01 mol FeCl 3 v 0,01 mol CuCl2 . Khi cc phn ng xy ra hon ton, khi lng kt ta thu c bng A. 0,90 gam. B. 1,07 gam. C. 2,05 gam. D. 0,98 gam. Cu 35: C 4 dung dch khng mu: glucoz, glixerol, h tinh bt v lng trng trng. Hy chn cht no trong s cc cht cho di y c th nhn bit c c 4 cht A. Cu(OH)2 trong dd NaOH, nhit . B. I2 . C. AgNO3 trong dung dch NH3 . D. HNO3 c nng, nhit . Cu 36: Cho 2,24 lt NO2 (ktc) hp th ht vo 500ml dung dch NaOH 0,4M thu c dung dch X. Gi tr pH ca dung dch X l A. pH < 7. B. pH > 7. C. pH = 7. D. C th pH > hoc pH < 7. Cu 37: C 4 hp cht hu c c cng thc phn t ln lt l: CH2 O, CH2O2, C2 H2 O3 v C3 H4 O3 . S cht va tc dng vi Na, va tc dng vi dung dch NaOH, va c phn ng trng gng l A. 4. B. 3. C. 2. D. 1. Cu 38: in phn dung dch hn hp cha 0,1 mol FeCl3, 0,2 mol CuCl2 v 0,1 mol HCl (in cc tr, mng ngn xp). Khi catot bt u si bt kh th dng in phn. Ti thi im ny khi lng catot tng A. 0,0 gam. B. 5,6 gam. C. 12,8 gam. D. 18,4 gam. Cu 39: Phn ng: Fex Oy + 2yHI xFeI2 + (y-x)I2 + yH2 O khng phi l phn ng oxi ha kh nu A. lun lun l phn ng oxi ho kh, khng ph thuc vo gi tr x, y. B. x = 2; y = 3. C. x = 3; y = 4. D. x = y = 1.

(phn ng cng H2 hon ton). Bit rng Vx = 6,72 lt v A, B trong hn hp X. Cc th tch kh c o ktc A. C3 H8 , C3 H4 , 0,2 mol C 3H8, 0,1 mol C3 H4 . B. C 3H8,C3 H4 , 0,1 mol C 3H8, 0,2 mol C3 H4 . C. C2 H6 , C2 H2 , 0,2 mol C 2H6, 0,2 mol C2 H2 . D. C2 H6 ,C 2H2, 0,1 mol C2 H6 , 0,2 mol C 2H2.

VH 2 = 4,48 lt. Xc nh CTPT v s mol ca

Cu 43: Hn hp (X) gm 2 kim loi kim v 1 kim loi kim th tan hon ton vo nc, to ra dung dch (C) v gii phng 0,12 mol H 2. Th tch dung dch H2 SO4 2M cn thit trung ho dung dch (C) l A. 1,2 ml. B. 60 ml. C. Kt qu khc. D. 120 ml. Cu 44: lm sch CO2 c ln hn hp HCl v hi nc. Cho hn hp ln lt i qua cc bnh A. H2 SO4 v KOH. B. NaOH v H2SO4. C. Na 2 CO3 v P2 O5 . D. NaHCO3 v P2 O5 . Cu 45: Cho cc kim loi sau: Zn, Fe, Cu, Ag. Kim loi no va phn ng vi dung dch HCl, va phn ng vi dung dch FeCl 2 A. Cu. B. Zn. C. Ag. D. Fe. Cu 46: t chy hon ton 0,25 mol hn hp hai este no, mch h, n chc l ng ng lin tip thu c 19,712 lit kh CO2 (ktc). X phng ha cng lng este trn bng dung dch NaOH to ra 17 gam mt mui duy nht. Cng thc ca hai este l A. HCOOC2 H5 v HCOOC3 H7 . B. HCOOC3H7 v HCOOC4H9. C. CH3COOC2H5 v HCOOC2H5. D. CH3COOCH3 v CH3 COOC2 H5 . Cu 47: Phn ng no di y lm thay i cu to ca nhn thm A. Stiren + Br2 C. Benzen + Cl2
C as ,50
o

B. Toluen + Cl2

as

D. Toluen + KMnO4 + H2SO4

Cu 48: Nguyn t X c ho tr i vi H bng 2 v ho tr ti a i vi O bng 6. Bit X c 3 lp electron. Tnh Z ca X A. 15. B. 16. C. 14. D. 10. Cu 49: Cho cc cht: benzen, toluen, stiren, propilen, axetilen. S cht lm mt mu thuc tm nhit thng l A. 5. B. 3. C. 4. D. 2. Cu 50: Cho a gam hn hp Mg v Al vo 250 ml dung dch X cha 2 axit : HCl 1M v H 2SO4 0,5M c dung dch B v 4,368 lt H2 (ktc) th trong dung dch B s A. Thiu axit. B. Tt c u sai. C. Dung dch mui. D. D axit. B. Theo chng trnh nng cao (10 cu, t cu 51 n cu 60) Cu 51: Khi ho tan Al bng dd HCl, nu thm vi git dung dch Hg2+ vo th qu trnh ho tan Al s A. Xy ra nhanh hn. B. Khng thay i. C. Xy ra chm hn. D. Tt c u sai. Cu 52: Nguyn t oxi trng thi c bn c s obitan cha electron l A. 5. B. 6. C. 3. D. 4.

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Cu 53: Dung dch HCl v dung dch CH3COOH c cng nng mol/lt, pH ca 2 dung dch l x v y. Quan h gia x v y l (gi thit c 100 phn t CH3COOH th c 1 phn t in li) A. y = x + 2. B. y = 100x. C. y = x 2. D. y = 2x. Cu 54: Cho cn bng H2 (k)+ Cl2 (k) 2HCl phn ng to nhit (H<0), phn ng chuyn dch theo chiu thun cn tng A. Nng H2 hoc Cl2. B. Nhit . C. p sut. D. Cht xc tc. Cu 55: Khi thay i nhit ca dung dch cht in li th A. in li thay i v hng s in li khng i. B. in li v hng s in li u thay i. C. in li khng i v hng s in li thay i. D. in li v hng s in li u khng i. Cu 56: Pht biu no di y l khng ng A. Trong phn ng oxi ha - kh t xy ra, th in cc chun ca cht kh ln hn th in cc chun ca cht oxi ha. B. Kim loi trong cp oxi ha - kh c th in cc chun nh hn 0,00 V c th y c hiro ra khi dung dch axit. C. Cation kim loi trong cp oxi ha - kh c th in cc chun ln hn c th oxi ha c kim loi trong cp c th in cc chun nh hn. D. Sut in ng chun ca pin in ha bng th in cc chun ca cc dng tr th in cc chun ca cc m. Cu 57: in phn 100 ml dung dch CuSO 4 0,2 M vi I = 9,65Ampe. Tnh khi lng Cu bm ln catt khi thi gian in phn t1 = 200 s, t2 = 500s ln lt l A. 0,32g v 0,64g. B. 0,64g v 1,28g. C. 0,64g v 1,32g. D. 0,32g v 1,28g. Cu 58: Trong cng nghip, khi in phn dung dch NaCl c mng ngn thu c hn hp gm NaOH v NaCl khu vc catot. tch c NaCl khi NaOH ngi ta s dng phng php A. chit. B. kt tinh phn on. C. chng ct. D. lc, tch. Cu 59: Cho bit th in cc chun ca cc cp oxi ho kh: 2H+ /H2 ; Zn2+ /Zn; Cu2+ /Cu; Ag+/Ag ln lt l 0,00V; -0,76V; +0,34V; +0,80V. Sut in ng ca pin in ho no sau y ln nht A. 2Ag + 2H+ 2Ag+ + H2. B. Cu + 2Ag+ Cu2+ + 2Ag C. Zn + 2H+ Zn2+ + H2. D. Zn + Cu2+ Zn2+ + Cu Cu 60: Hirat ho hon ton 1,56 gam mt ankin (A) thu c mt anehit (B). Trn (B) vi mt anehit n chc (C). Thm nc c mt 0,1 lit dung dch (D) cha (B) v (C) vi nng mol tng cng l 0,8M. Thm t t vo dung dch (D) vo dung dch cha Ag 2 O/NH3 d thu c 21,6g Ag kt ta. Xc nh CTCT v s mol ca (B) v (C) trong dung dch (D). A. (B): CH3-CHO 0,1 mol, (C): H-CHO 0,15 mol. B. (B): CH3 -CHO 0,08 mol, (C): H-CHO 0,05 mol. C. (B): CH3-CHO 0,06 mol, (C): H-CHO 0,02 mol. D. (B): CH3-CHO 0,1 mol, (C): C2H5CHO 0,2 mol.

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S GIO DC V O TO THNH PH NNG TRNG THPT PHAN CHU TRINH THI TH I HC, CAO NG NM 2009 LN 1 Mn: HA HC Khi A, B M : 169 Thi gian lm bi: 90 pht, (khng k thi gian pht ) Cu 1: Dung dch CH3 COOH 0,01M c: A. pH = 2 B. 2< pH < 7 C. pH = 12 D. 7 < pH < 12 Cu 2: Khi cho hn hp MgSO4, Ba3 (PO4 )2, FeCO3 , FeS, Ag2 S vo dung dch HCl d th phn khng tan cha A. FeS, AgCl, Ba3 (PO4 )2. B. FeS, AgCl, BaSO4 . C. Ag2S, BaSO4. D. Ba 3(PO4)2 ,Ag2 S. Cu 3: Cho V ml dung dch NaOH 1M vo 20ml dung dch AlCl3 1M. Sau khi phn ng hon ton thu c 0,39 gam kt ta. V ng vi gi tr no sau y ? A. 15 ml hay 75 ml B. Ch c th l 15 ml C. 35 ml hay 75 ml D. Ch c th l 75 ml Cu 4: t nng kim loi X trong khng kh th khi lng cht rn thu c sau phn ng tng 38% so vi ban u. X l: A. Mg B. Al C. Cu D. Fe Cu 5: Cho x mol kh Cl 2 vo bnh cha KOH long ngui v y mol kh Cl 2 vo bnh cha KOH c nng, sau phn ng s mol KCl thu c 2 th nghim bng nhau. Ta c t l: A. x : y = 5 : 3 B. x : y = 3 : 5 C. x : y = 3 : 1 D. x : y = 1 : 3 Cu 6: (Bit: C=12; O=16; H=1; N=14) X l mt aminoaxit c phn t khi l 147. Bit 1mol X tc dng va vi 1 mol HCl v 0,5mol X tc dng va vi 1mol NaOH. Cng thc phn t ca X l: A. C4 H7 N2 O4. B. C 8H5NO2. C. C5 H9 NO4. D. C5 H25NO3. Cu 7: Nhn nh no sau y khng ng: A. Dung dch axit aminoetanoic tc dng c vi dung dch HCl. B. Trng ngng cc -aminoaxit ta c cc hp cht cha lin kt peptit. C. Dung dch aminoaxit phn t cha 1 nhm NH2 v 1 nhm -COOH c pH=7. D. Hp cht + NH3C xHyCOO tc dng c vi NaHSO4 . Cu 8: (Bit: C=12; O=16; H=1; N=14; Mg=24; Ca=40; Ba=137; Na=23) Thm x ml dung dch Na 2CO3 0,1M vo dung dch cha hn hp: Mg 2+, Ba2+, Ca2+, 0,01 mol HCO3 , 0,02 mol NO 3 th thu c lng kt ta ln nht. Gi tr ca X l: A. 300 B. 400 C. 250 D. 150 Cu 9: Hirat ha 2 hirocacbon (cht kh iu kin thng, trong cng mt dy ng ng), ch to ra 2 sn phm u c kh nng tc dng vi Na (theo t l mol 1:1). Cng thc phn t ca hai hirocacbon c th l: A. C2 H2 v C3 H4 . B. C 3H4 v C4H6. C. C3 H4 v C4 H8 . D. C2 H4 v C4 H8 . Cu 10: Cho dung dch HNO3 long phn ng vi FeS, cc sn phm to thnh l: A. Fe(NO3)3 , H2S B. Fe(NO3 )2, H2 S C. FeSO4 , Fe(NO3)2 , NO, H2 O D. Fe 2 (SO4 )3, Fe(NO3 )3, NO, H2O Cu 11: Cho H (Z=1), N(Z=7), O (Z=8). Trong phn t HNO3 , tng s cp electron lp ngoi cng khng tham gia lin kt ca 5 nguyn t l A. 7. B. 8. C. 9. D. 6. Cu 12: Cho 0,5 lt hn hp gm hyrocacbon v kh cacbonic vo 2,5 lt oxi (ly d) ri t. Th tch ca hn hp thu c sau khi t l 3,4 lt. Cho hn hp qua thit b lm lnh, th tch hn hp kh cn li 1,8 lt v cho li qua dung dch KOH ch cn 0,5 lt kh. Th tch cc kh c o trong cng iu kin. Tn gi ca hyrocacbon l: A. propan B. xiclobutan C. propen D. xiclopropan Cu 13: Cc cht c th lm mm nc cng tm thi l: A. Ca(OH)2 v BaCl2 B. Ca(OH)2 v HCl C. Ca(OH)2 , NaOH D. Na 2 CO3 v H2 SO4 Cu 14: phn bit vinyl fomiat v metyl fomiat ta dng: A. Cu(OH)2/NaOH, un nng B. nc Br2 C. dung dch AgNO3 /NH3 D. dung dch Br2 tan trong CCl4 Cu 15: Phenyl axetat c iu ch trc tip t: A. axit axetic v ancol benzylic B. anhiric axetic v ancol benzylic C. anhiric axetic v phenol D. axit axetic v phenol Cu 16: (Bit: O=16; H=1; N=14) Nhit phn mt mui nitrat kim loi c ha tr khng i thu c hn hp kh X v oxit kim loi. Khi lng ring ca hn hp kh X iu kin chun l: A. 1,741 gam/l. B. 1,897 gam/l. C. 1,929 gam/l. D. 1,845 gam/l.

Cu 17: Pht biu no sau y khng ng ? A. 4 nguyn t cacbon trong phn t but-2-in cng nm trn ng thng. B. Ankin c 5 nguyn t cacbon tr ln mi c mch phn nhnh. C. Tt c cc nguyn t cacbon trong phn t isopentan u c lai ha sp3. D. 3 nguyn t cacbon trong phn t propan cng nm trn ng thng. Cu 18: S ng phn axit v este mch h c CTPT C4H6O2 l: A. 9 B. 10 C. 8 D. 12 Cu 19: Cht no sau y l thnh phn chnh b bt khi xng b gy ? A. CaCO3 B. CaSO4.2H2O C. Polime D. Vt liu compozit Cu 20: Cht no di y khng th iu ch axit axetic bng mt phn ng? A. CH4O B. CH3 CH2CH2 CH3 C. CH3CH2 OH D. HCOOCH2CH3 Cu 21: (Bit: C=12; O=16; H=1) Thy phn hon ton 6,84 gam saccaroz ri chia sn phm thnh 2 phn bng nhau. Phn 1 cho tc dng vi lng d dung dch AgNO 3 /NH3 th thu c x gam kt ta. Phn 2 cho tc dng vi dung dch nc brom d, th c y gam brom tham gia phn ng. Gi tr x v y ln lt l: A. 2,16 v 1,6 B. 2,16 v 3,2 C. 4,32 v 1,6 D. 4,32 v 3,2 Cu 22: Th nghim no sau y khi hon thnh to ra Fe(NO3 )3 ? A. Fe (d) tc dng vi dung dch HNO3 long. B. Fe(NO3 )2 tc dng vi dung dch HCl. C. Fe (d) tc dng vi dung dch AgNO3. D. Fe tc dng vi lng d dung dch Cu(NO3 )2 . Cu 23: Trong cc cht sau: HCHO, CH 3 Cl, CO, CH3 COOCH3 , CH3 ONa, CH3 OCH3 , CH2 Cl2 c bao nhiu cht to ra metanol bng 1 phn ng ? A. 5 B. 6 C. 3 D. 4 Cu 24: Cng thc tng qut ca mt este to bi axit no, n chc, mch h v ancol khng no c mt ni i, n chc, mch h l: A. Cn H2n-2kO2 B. C nH2n-2O2 C. Cn H2n-1 O2 D. Cn H2nO2 Cu 25: Cng thc cu to no sau y khng ph hp vi cht c cng thc phn t l C6H10 ?

A. B. C. D. Cu 26: (Bit: C=12; O=16; H=1) Hp cht hu c n chc X (cha C, H, O) c t khi hi vi H 2 l 43. Cho X tc dng vi dung dch NaOH ta c hp cht hu c Y c kh nng tham gia phn ng trng gng. S ng phn cng chc ca X l : A. 5 B. 4 C. 6 D. 3 Cu 27: Pht biu no sau y ng ? A. Dy ng ng ankin c cng thc chung l Cn H2n-2 B. Cc hirocacbon no u c cng thc chung l CnH2n+2 C. Cng thc chung ca hirocacbon thm l CnH2n-6 D. Cc cht c cng thc n gin nht l CH2 u thuc dy ng ng anken. Cu 28: Phng php iu ch kim loi no sau y khng ng?

t 2Cr + Al O o B. HgS + O t Hg + SO o o C. CaCO t CaO + CO,t Ca D. Ag S + NaCN Na[Ag(CN) ] + Zn Ag

A. Cr2 O3 + 2Al
2 2 3 2 3 2 2

Cu 29: Chiu tng dn nng lng ion ha th nht ca 3 nguyn t: X (Z=11), Y(Z=12), Z (Z=13) c xp theo dy trt t: A. X, Z, Y. B. Z, X, Y. C. X, Y, Z. D. Z, Y, X. Cu 30: So snh pin in ha v n mn kim loi, iu no sau y khng ng ? A. Kim loi c tnh kh mnh hn lun l cc m B. Pin in ha pht sinh dng in, n mn kim loi khng pht sinh dng in. C. Cht c tnh kh mnh hn b n mn D. Tn cc in cc ging nhau: catot l cc m v anot l cc dng Cu 31: Nhn nh no sau y khng ng ? A. Axeton khng lm mt mu dung dch KMnO4 iu kin thng.

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B. Cc xeton khi cho phn ng vi H2 u sinh ra ancol bc 2. C. Tr axetilen, cc ankin khi cng nc u cho sn phm chnh l xeton. D. Cc hp cht c cha nhm >C=O u phn ng vi dung dch Br2. Cu 32: Trong cc kim loi sau: Fe, Ni, Cu, Zn, Na, Ba, Ag, Al. S kim loi tc dng c vi dung dch Ba(OH)2 l: A. 5. B. 2. C. 3. D. 4. Cu 33: Nhn xt no sau y khng ng ? A. MgO khng phn ng vi nc iu kin thng. B. Mg(OH)2 tan c trong nc nng. C. Mg phn ng vi N2 khi c un nng. D. Mg chy trong kh CO2 nhit cao. Cu 34: (Bit: Na=23; Al=27) Cho 7,3 gam hn hp gm Na v Al tan ht vo nc c dung dch X v 5,6 lt kh (ktc). Th tch dung dch HCl 1M cn cho vo dung dch X c lng kt ta ln nht l A. 150ml B. 200ml C. 100ml D. 250ml Cu 35: (Bit: Cr=52; O=16; H=1; N=14; Zn=65) Ho tan ht 18,2 gam hn hp Zn v Cr trong HNO 3 long thu c dung dch A ch cha hai mui v 0,15 mol hn hp hai kh khng mu c khi lng 5,20 gam trong c mt kh ho nu ngoi khng kh. S mol HNO3 phn ng l: A. 0,9 mol B. 0,7 mol C. 0,2 mol D. 0,5 mol Cu 36: (Bit: C=12; O=16; H=1; N=14; Mg=24; Ca=40; Ba=137; Na=23; Al=27; S=32; Cl=35,5) Th nghim no di y to thnh s gam kt ta ln nht ? A. Cho 0,20 mol K vo dung dch cha 0,20 mol CuSO4. B. Cho 0,35 mol Na vo dung dch cha 0,10 mol AlCl3. C. Cho 0,10 mol Ca vo dung dch cha 0,15 mol NaHCO3 . D. Cho 0,05 mol Ba vo dung dch long cha 0,10 mol H2 SO4 . Cu 37: Nhn nh no sau y ng ? A. Mt phn t tripeptit phi c 3 lin kt peptit. B. Thy phn n cng protein lun thu c -aminoaxit. C. Trng ngng n phn t aminoaxit ta c hp cht cha (n-1) lin kt peptit. D. Hp cht glyxylalanin phn ng vi Cu(OH)2 to sn phm c mu tm. Cu 38: C cc cp cht sau: Cu v dung dch FeCl3; H2 S v dung dch Pb(NO3 )2; H2S v dung dch ZnCl2; dung dch AgNO3 v dung dch FeCl3. S cp cht xy ra phn ng iu kin thng l : A. 3 B. 2 C. 1 D. 4 Cu 39: (Bit: C=12; O=16; H=1; Ag=108) Khi cho hn hp gm 0,44 gam anehit axetic v 4,5 gam mt anehit n chc X tc dng vi dung dch AgNO3 trong NH3 d thu c 66,96 gam Ag. Cng thc cu to ca X l: A. HCHO. B. CH2 =CHCHO. C. CH3CH2 CH2CHO. D. CH3CH2 CHO. Cu 40: Dy cc cht u tc dng c vi phenol l: A. CH3COOH (xc tc H2 SO4 c, t o), Na, dung dch NaOH B. C 2H5OH (xc tc HCl, to ), Na, nc Br2 C. Na, dung dch NaOH, CO2 D. Dung dch Ca(OH)2 , nc Br2, Ba Cu 41: Trong cng nghip, t etylen iu ch PVC cn t nht: A. 2 phn ng B. 5 phn ng C. 3 phn ng D. 4 phn ng Cu 42: Cho cc hirocacbon di y phn ng vi Cl2 theo t l mol 1:1, trng hp to c nhiu sn phm ng phn nht l: A. isopentan. B. buta-1,3-ien. C. etylxiclopentan. D. neoheptan. Cu 43: Pht biu no sau y ng ? A. Cht git ra l nhng cht c tc dng ging nh x phng nhng c tng hp t du m. B. Cht git ra l nhng cht khi dng cng vi nc th c tc dng lm sch cc cht bn bm trn cc vt rn m khng gy ra phn ng ho hc vi cc cht bn. C. Cht git ra l nhng cht khi dng cng vi nc th c tc dng lm sch cc vt bn bm trn cc vt rn m khng gy ra phn ng ho hc vi vt rn. D. Cht git ra l nhng cht c tc dng lm sch cc cht bn bm trn b mt vt rn. Cu 44: un nng este E vi dung dch kim ta c 2 ancol X, Y. Khi tch nc, Y cho 3 olefin, cn X cho 1 olefin. E l: A. isoproyl metyl etanioat B. etyl sec-butyl etanioat C. imetyl butanioat D. etyl butyl etanioat Cu 45: Cho dung dch AgNO3 vo dung dch X c kt ta to thnh, lc ly kt ta cho vo dung dch NH3 thy kt ta tan. Vy X A. ch c th l NaCl. B. ch c th l Na3 PO4 .

C. l NaCl hay NaBr. D. l NaCl, NaBr hay NaI. Cu 46: (Bit: Cu=64; O=16) in phn dung dch CuSO4 vi in cc tr, cng dng 5A. Khi anot c 4g kh oxi bay ra th ngng. iu no sau y lun ng ? A. Khi lng ng thu c catot l 16g. B. Thi gian in phn l 9650 giy. C. pH ca dung dch trong qu trnh in phn lun tng ln. D. Khng c kh thot ra catot. Cu 47: Cho cc cht sau: FeBr 3 , FeCl2 , Fe3 O4 , AlBr3, MgI, KBr, NaCl. Axit H2SO4 c nng c th oxi ha bao nhiu cht ? A. 4 B. 5 C. 7 D. 6 Cu 48: (Bit: C=12; O=16; H=1; N=14) un nng mt este n chc c phn t khi l 100, vi dung dch NaOH thu c hp cht c nhnh X v ru Y. Cho hi Y qua CuO t nng ri hp th sn phm vo lng d dung dch AgNO3 trong NH3 thu c dung dch Z. Thm H2 SO4 long vo Z th thu c kh CO2 . Tn gi ca este l: A. etyl isobutirat B. metyl metacrilat C. etyl metacrilat D. metyl isobutirat Cu 49: t chy hon ton este X thu c s mol CO2 bng s mol H2 O. Vy X l: A. este n chc, mch h, c mt ni i. B. este n chc, c 1 vng no C. este n chc, no, mch h. D. este hai chc no, mch h. Cu 50: (Bit: C=12; O=16; H=1; Ag=108) Thy phn hon ton 3,42 gam hn hp X gm saccaroz v mantoz thu c hn hp Y. Bit rng hn hp Y phn ng va 0,015 mol Br 2. Nu em dung dch cha 3,42 gam hn hp X cho phn ng lng d AgNO3 trong NH3 th khi lng Ag to thnh l: A. 2,16 gam B. 3,24 gam C. 1,08 gam D. 0,54 gam P N: 1 2 3 4 5 6 7 8 9 10 B C A D A C C D D D 11 12 13 14 15 16 17 18 19 20 A A C D C C D B B D 21 22 23 24 25 26 27 28 29 30 C B A B C B A C A B 31 32 33 34 35 36 37 38 39 40 D D A B A D B A A D 41 42 43 44 45 46 47 48 49 50 C C B B A B D B C C

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TRNG THPT GIA NH THI TH TUYN SINH I HC, CAO NG Mn thi: HO HC Thi gian lm bi: 90 pht (khng k thi gian giao ) Cho: Mg = 24, Al = 27, K = 39, Ca = 40, Cr = 52, Fe = 56, Cu = 64, Ag = 108, Cl = 35,5, S = 32, O = 16, N = 14, C = 12, H = 1. I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 44) Cu 1: phn bit cc dung dch ring bit: HCl, HNO 3, H2SO4 c th dng kim loi no sau y lm thuc th A. Na. B. Ba. C. Mg. D. Fe. Cu 2: Thuc th thch hp lm mm nc cng vnh cu l A. dd Na 2CO3. B. dd Ca(OH) 2 . C. dd Na 3PO4 . D. dd Na 2CO3 hoc dd Na 3PO4 Cu 3: Hn hp X gm hai ng phn, cng thc C 2H7 NO2 tc dng vi dung dch NaOH/t o thu c dung dch Y v 4,48 lt (kc) hn hp Z cha hai kh (u lm xanh qu tm m, t khi hi so vi hiro l 13,75). Khi lng mui trong dung dch Y l A. 8,9 gam. B. 14,3 gam. C. 15,7 gam. D. 16,5 gam. Cu 4: Ha tan ht 10,2 gam hn hp X gm Al, Mg trong dung dch H 2SO4 c nng. Kt thc phn ng thu c 4,48 lt kh (ktc) hn hp 2 kh H 2 S v SO2, c t l th tch l 1:1. Phn trm khi lng ca Al trong X l A. 40,76%. B. 35%. C. 52,94%. D. 53%. Cu 5: 35,2 gam hn hp gm hai este no n chc l ng phn ca nhau c t khi i vi O2 bng 2,75 tc dng vi hai lt dung dch NaOH 0,4M ri c cn dung dch va thu c ta c 44,6 g rn B, cng thc cu to 2 este l A. HCOOC 3H7 v CH3COOC 2 H5. B. HCOOC 3H7 v CH3COOCH3 . C. C2H5 COOCH 3 v CH3 COOC 2H5 . D. HCOOC 2H5 v CH3COOCH3 . Cu 6: Ch dng H2 O nhit thng c th phn bit c tt c cc cht ca dy ha cht no trong cc dy ha cht sau y A. Na 2O; K; Na; Al2 O3 ; Fe. B. Na; BaO; Al; Na 2 O; Fe. C. BaO; Na; K2 O; Al; Al2O3. D. BaO; K; Al; Al2 O3 ; Fe. Cu 7: Ha tan m gam Mg vo 1 lt dung dch Fe(NO 3) 2 0,1M v Cu(NO3 )2 0,1M. Lc ly dung dch X. Thm NaOH d vo dung dch X , thu c kt ta Y, nung Y ngoi khng kh n khi lng khng i, cn li 10gam cht rn Z. Gi tr ca m l A. 7,2 gam. B. 3,6 gam. C. 4,8 gam. D. 1,8 gam. Cu 8: Cho x gam bt Fe tan va ht trong dung dch cha y mol H 2 SO4 c, nng thu c 0,12 mol kh v dung dch A, c cn cn thn dung dch A thu c 16,56 gam mui khan. Gi tr ca x v y tng ng l A. 6,72 gam v 0,12 mol. B. 13,44 gam v 0,12 mol C. 5,04 gam v 0,24 mol. D. 4,48 gam v 0,24 mol 3 Cu 9: Cho ln men 1m nc r ng glucoz thu c 60 lt cn 96 o. Tnh khi lng glucoz c trong thng nc r ng trn, bit khi lng ring ca ancol etylic bng 0,789 g/ml 20o C v hiu sut qu trnh ln men t 80% A. 71 kg. B. 111 kg. C. 74 kg. D. 89 kg. Cu 10: PVC c iu ch t kh thin nhin theo s :

CH4 C2H2 CH2 = CHCl PVC Th tch kh thin nhin (kc) cn ly iu ch mt tn PVC l bao nhiu (kh thin nhin cha 95% metan v th tch) A. 5883,246 m3 . B. 6154,144 m3. C. 2915 m3. D. 1414 m3. Cu 11: x phng ha 100 kg du n thuc loi triolein glixerol c ch s axit bng 7 cn 14,1 kg NaOH. Gi s phn ng xy ra hon ton, khi lng mui natri thu c l
15% 95% 90%

A. 103,445 kg. B. 118,245 kg. C. 108,6 kg. D. 117,89 kg. Cu 12: Hp cht X c cng thc phn t l C 4 H8O. X tc dng vi dung dch AgNO 3 /NH3 sinh ra Ag kt ta, X tc dng vi H 2 to Y. un Y vi H 2 SO4 sinh ra anken mch khng nhnh. Tn ca X l A. Butanal. B. 2-Metylpropanal. C. Andehit isobutyric. D. Butan-2-on. Cu 13: Bn kim loi Na; Al; Fe v Cu c n nh khng theo th t X; Y; Z; T. Bit rng: - X; Y c iu ch bng phng php in phn nng chy. - X y c kim loi T ra khi dung dch mui ca T. - Z tc dng c vi dung dch H 2SO4 c nng nhng khng tc dng c vi dung dch H2SO4 c ngui. X; Y; Z; T theo th t l A. Na; Al; Fe; Cu. B. Al; Na; Fe; Cu. C. Al; Na; Cu; Fe. D. Na; Fe; Al; Cu. Cu 14: Tnh khi lng kh clo thu c ( kc) khi cho 100 ml dung dch HCl 36,5% (D = 1,18g/ml) tc dng vi 29,4 gam kali icromat (hiu sut phn ng l 70%) l A. 17,652 gam. B. 15,267 gam. C. 12,567 gam. D. 16,752 gam. Cu 15: Cho hn hp X (dng bt) gm 0,01 mol Al v 0,025 mol Fe tc dng vi 400ml dung dch hn hp Cu(NO3 )2 0,05M v AgNO3 0,125M. Kt thc phn ng, lc kt ta cho nc lc tc dng vi dung dch NaOH d thu c m gam kt ta. Gi tr ca m l A. 2,740 gam. B. 35,2 gam. C. 3,52 gam. D. 3,165 gam. Cu 16: T hidrocacbon X khng no s to ra c bao nhiu loi polime bng phn ng trng hp, bit rng khi t chy hon ton 1 mol X th cn 6 mol oxi v sinh ra 4 mol kh CO2 A. 5. B. 3. C. 4. D. 2. Cu 17: Ha tan ht 25,4 gam hn hp 4 kim loi A, B, C, D trong dung dch hn hp 2 axit HNO 3 c v H 2 SO4 c nng thy thot ra 0,15mol NO v 0,2mol SO 2. C cn dung dch sau phn ng, khi lng mui khan thu c l A. 72,5 gam. B. 53,9 gam. C. 48,3 gam. D. 42,7 gam. Cu 18: 3,7 gam mt axit n chc tc dng ht vi dung dch c 3,2 gam NaOH. C cn dung dch sau phn ng thu c 6 g cht rn. Cng thc phn t ca axit l A. HCOOH. B. C2 H3COOH. C. CH3 COOH. D. C2 H5COOH. Cu 19: em 6,34 gam hn hp gm cc oxit MgO, Al 2 O3 , ZnO, Fe 3O4, tc dng ht vi dung dch H2 SO4 long, d thy sinh ra 1,98 gam nc v m gam mui. Gi tr ca m l A. 15,14. B. 16,9. C. 17,12. D. 15,5. Cu 20: Ch dng ha cht no trong cc ha cht di y nhn bit cc kim loi Na, Ba, Al, Ag A. H2O. B. Dung dch NH 3. C. Dung dch H2 SO4 long. D. Dung dch NaOH. Cu 21: Nhm nhng cht no c th to ra FeCl 2 bng phn ng trc tip A. Fe; Cu; Cl2 ; HCl; FeSO4. B. Fe; Cu; HCl; FeSO 4; CuSO4. C. Fe; Cu; HCl; FeSO 4; FeCl 3 . D. Fe; Cu; Cl2 ; HCl; FeCl 3; CuCl2 Cu 22: Hp kim no sau y ca Fe b n mn chm nht A. Fe Ag. B. Fe Ni. C. Fe Sn. D. Fe Cu. Cu 23: t chy hon ton mt ancol n chc, sn phm thu c cho qua bnh ng dung dch Ca(OH) 2 d, thy bnh tng 3,55 g, ng thi trong bnh c 5 g kt ta, cng thc phn t ca ancol l A. C4H9 OH. B. CH3OH. C. C2H5 OH. D. C3 H7OH. Cu 24: Cht X c cng thc phn t l C 4H8 O. Bit X + H 2 butan-2-ol. S cht X tho mn l A. 1. B. 2. C. 4. D. 3. Trang 27

Cu 25: Sp xp cc hp cht sau theo th t gim dn tnh baz (1) C6H5 NH2 . (2) C2 H5NH 2. (3) (C6H5 )2 NH. (4) (C2H5 )2 NH. (5) NaOH. (6) NH3 . A. (1) > (3) > (5) > (4) > (2) > (6). B. (5) > (4) > (2) > (6) > (1) > (3). C. (6) > (4) > (3) > (5) > (1) > (2). D. (5) > (4) > (2) > (1) > (3) > (6). Cu 26: Hin tng no di y c m t khng ng A. Thm d NaOH vo dung dch K 2 Cr 2O7 th dung dch chuyn t mu da cam sang mu vng. B. Thm d NaOH v Cl 2 vo dung dch CrCl 2 th dung dch t mu xanh chuyn thnh mu vng. C. Thm t t dung dch NaOH vo dung dch CrCl 3 thy xut hin kt ta vng nu tan li trong NaOH d. D. Thm t t dung dch HCl vo dung dch Na[Cr(OH) 4 ] thy xut hin kt ta lc xm, sau tan li. Cu 27: thu phn 11,1 g hn hp este HCOO-C 2H5 v CH3COOCH3 cn va 100 ml dung dch NaOH. CM ca dung dch NaOH l A. 1,25M. B. 1,75M. C. 1M. D. 1,5M. Cu 28: Phng trnh phn ng khng ng trong cc phng trnh phn ng di y l A. Au + HNO 3 + 3HCl AuCl3 + NO + 2H2 O. B. Pb + 3H2SO4 c Pb(HSO4 )2 + SO2 + 2H2O. C. Ni(OH) 2 + 4NH3 [Ni(NH3 )4 ](OH) 2 . D. AgCl + 2NH3 [Ag(NH3) 2]Cl. Cu 29: C cc kim loi Cu, Ag, Fe, Al, Zn. dn in ca chng gim dn theo th t A. Cu, Ag, Fe, Al, Zn. B. Al, Zn, Fe, Cu, Ag. C. Al, Fe, Zn, Cu, Ag. D. Ag, Cu, Al, Zn, Fe. Cu 30: phn bit glucoz v fructoz th nn chn thuc th no di y A. Dung dch nc brom. B. Dung dch AgNO3 trong NH 3. C. Cu(OH) 2 trong mi trng kim. D. Dung dch CH3COOH/H2 SO4 c. Cu 31: Trong cc dy ha cht sau y, dy no gm tt c cc cht tc dng vi dung dch HNO 3 c nng sinh ra kh NO2 . A. Fe; FeO; Fe 3 O4 ; Fe(OH) 2; FeS 2 . B. Fe; Fe 3O4; FeS; FeCO3 ; Fe 2O3. C. FeS; FeS 2; Fe(OH) 3 ; FeO; Fe. D. FeCO3 ; Fe(OH) 2; Fe 2 O3 ; FeSO3 ; Fe. Cu 32: Trong s : C2H2 A1 A2 A3 A4 C2H2 . A1; A2; A3; A4 ln lt l A. CH3 CHO; CH3 COOH; C2 H4; C2H6 . B. C2H6 ; C2 H4; C2H5 OH; CH4 . C. CH3 CHO; CH3 COOH; CH3COONa; CH4 . D. CH3 CHO; C2 H5OH; CH3COOH; CH4 . Cu 33: Cn bao nhiu tn qung manhetit cha 80% Fe 3 O4 c th luyn c 800 tn gang c hm lng st 95%. Lng st b hao ht trong sn xut l 1% A. 3512,61 tn. B. 1325,16 tn. C. 5213,61 tn. D. 2351,16 tn. Cu 34: t chy hon ton 125 ml dung dch ancol etylic, lng CO2 sinh ra cho qua dung dch Ca(OH) 2 d thu c 300g kt ta, bit dancol etylic = 0,8 g/ml. ru ca ancol l A. 75 o. B. 79o . C. 82o. D. 69o . Cu 35: em 11,06 gam hn hp MgCO3 , CaCO3 , K2CO3 tc dng ht vi dung dch HCl ly d thy sinh ra 2,016 lt CO2 (ktc) v m gam mui. Gi tr ca m l A. 14,12. B. 15,2. C. 11,24. D. 12,05. Cu 36: Trong cc ng phn ca C 8H10O, s cht ch tc dng vi Na, khng tc dng vi NaOH l A. 1. B. 4. C. 3. D. 5.

Cu 37: C bao nhiu dn xut C4 H9Br khi tc dng vi dung dch KOH + etanol trong mi trng hp ch to ra anken duy nht A. 1 cht. B. 3 cht. C. 4 cht. D. 2 cht. Cu 38: Hp cht X cha cc nguyn t C, H, O, N v c phn t khi l 89. Khi t chy hon ton 1 mol X thu c hi nc, 3 mol CO2 v 0,5 mol N2. Bit rng X l hp cht lng tnh v tc dng c vi nc brom. X c cng thc cu to l: A. CH3 CH(NH2 ) COOH. B. CH2 = CH(NH2 ) COOH. C. CH2 = CH COONH 4 . D. H2N CH = CH COOH. Cu 39: Oxi ha 1,5 g HCHO thnh HCOOH vi hiu sut H% c hn hp A, A tc dng vi AgNO3 d/NH 3 to ra 12,96 g Ag. Hiu sut phn ng l A. 40%. B. 20%. C. 80%. D. 60%. Cu 40: ng vi cng thc C4 H6O2 c bao nhiu este mch h l ng phn ca nhau A. 5. B. 6. C. 4. D. 3. II. PHN RING [10 cu] Th sinh ch c lm mt trong hai phn (phn A hoc phn B) A. Theo chng trnh chun (10 cu, t cu 41 n cu 50) Cu 41: Dy gm tt c cc cht tc dng c vi Al 2O3 l A. Dung dch NaHSO 4, dung dch KOH, dung dch HBr. B. CO, dung dch H2 SO4, dung dch Na 2 CO3 . C. Dung dch HNO3 , dung dch Ca(OH) 2, dung dch NH 3. D. Ba, dung dch NaOH, dung dch Cu(NO3) 2. Cu 42: Kh 4,8 gam mt oxit kim loi nhit cao cn 2,016 lt hiro (kc). Kim loi thu c em ha tan ht trong dung dch HCl thot ra 1,344 lt kh (kc). Cng thc ha hc ca oxit kim loi l A. CuO. B. Fe2 O3 . C. Fe 3O4. D. MnO 2. Cu 43: Trong s cc polime sau y: t tm; si bng; len; t visco; nilon-6,6; t axetat. Loi t c ngun gc xenluloz l A. t tm; si bng; nilon-6,6. B. si bng; len; t axetat. C. si bng; len; nilon-6,6. D. t visco; nilon-6,6; t axetat Cu 44: iu no l ng A. Ancol isopropylic l ancol bc hai. B. Ancol isobutylic l ancol bc mt. C. Ancol bc ba phi c s C 4. D. C ba cu trn u ng. Cu 45: Ha tan 5,6 gam bt Fe vo 250ml dung dch AgNO 3 1M, kt thc phn ng thu c m gam cht rn, gi tr m l A. 2,7 gam. B. 2,16 gam. C. 21,6 gam. D. 27 gam Cu 46: Trng hp no sau y khng xy ra phn ng khi trn ln 2 dung dch vo nhau A. NaOH v NaAlO2 . B. HNO3 v NaHCO3 . C. NaCl v AgNO3. D. AlCl3 v Na 2 CO3 . Cu 47: Ln lt t hai mu qung xirit (FeCO 3) v pyrit st (FeS 2 ) bng mt lng oxi d thu c hai kh tng ng l X v Y. Dng thuc th no trong cc thuc th sau y nhn bit X v Y ng trong hai l mt nhn khc nhau A. Dung dch BaCl 2. B. Dung dch H2 SO4 long. C. Dung dch Ba(OH) 2 d. D. Dung dch Br 2 . Cu 48: Ancol no n chc mch h X to c ete Y. T khi ca Y so vi X gn bng 1,61. X l A. etanol. B. propanol. C. propan-2-ol. D. metanol. Cu 49: Nhn bit cc cht sau: C2 H5OH, C2 H4(OH) 2 , CH3 CHO, CH3 COOH, ch cn dng mt ha cht l A. Cu(OH) 2/OH-. B. Na 2 CO3 . C. NaOH. D. Na. Trang 28

Cu 50: Trong phn t andehit no, n chc, mch h X c % khi lng oxi bng 27,586%. X c cng thc phn t l A. CH2 O. B. C4 H8O. C. C2H4 O. D. C3 H6O B. Theo chng trnh nng cao (10 cu, t cu 51 n cu 60) Cu 51: un hn hp glixerol v axit stearic, axit oleic (c axit H 2 SO4 lm xc tc) c th thu my loi Trieste ng phn cu to ca nhau A. 4. B. 5. C. 6. D. 3. Cu 52: M t nhin l A. este ca axit oleic v ng ng. B. mui ca axit bo. C. este ca axit panmitic v ng ng. D. hn hp ca cc triglixerit khc. Cu 53: Bit

E o ( Ni Ag ) = 1,06V pin
+

v E Ni 2 + / Ni

= 0,26V

, th in cc chun ca

cp oxi ha kh Ag /Ag l A. 0,8V. B. 0,76V. C. 1,32V. D. 0,85V. Cu 54: Chn hin tng c m t khng ng A. Dung dch CuSO4 c pH < 7. B. Ngm dy ng vo dung dch HCl c ha tan oxi mt thi gian, ng phn ng vi HCl to thnh dung dch c mu xanh. C. Cho t t dung dch NH 3 n d vo dung dch CuSO4 th c kt ta xanh nht, sau kt ta tan chuyn thnh dung dch xanh m. D. Nung Cu vi O2 1000o C thu c sn phm l CuO. Cu 55: C hai bnh in phn mc ni tip nhau. Bnh 1 cha dung dch CuCl 2, bnh 2 cha dung dch AgNO3 . Tin hnh in phn vi in cc tr, kt thc in phn thy catot ca bnh 1 tng ln 1,6gam. Khi lng catot ca bnh 2 tng ln l A. 10,80 gam. B. 5,40 gam. C. 2,52 gam. D. 3,24 gam. Cu 56: Mt on t nilon-6,6 c khi lng 0,15 gam. S mt xch ca on t l gi tr no trong cc gi tr sau A. 4.1019. B. 3,998.1019. C. 39,98.1019. D. 4.1018. Cu 57: Thu phn peptit

Sn phm no di y l khng th c A. Ala. B. Gli ala. C. Glu gli. D. Ala glu. Cu 58: C 4 -amino axit X, Y, Z, T c th to thnh tetrapeptit. S lng tetrapeptit to thnh trong c cha c X, Y, Z, T l A. 16. B. 12. C. 20. D. 24. Cu 59: Cho 9,6 gam Cu vo 100ml dung dch hai mui (NaNO 3 1M v Ba(NO 3) 2 1M) khng thy hin tng g, cho thm vo 500ml dung dch HCl 2M thy thot ra V lt kh (ktc) kh NO duy nht. Gi tr ca V l A. 4,48. B. 2,24. C. 5,6. D. 3,36. Cu 60: Thnh phn no di y khng cn thit trong qu trnh sn xut gang A. Gang trng hoc gang xm, st thp ph liu. B. Than cc (khng c trong t nhin, phi iu ch t than m). C. Cht chy (CaCO3, dng to x silicat). D. Qung st (cha 30 95% oxit st, khng cha hoc cha rt t S, P).

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