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HASTELLOY X ALLOY
A nickel-base alloy with an exceptional combination of oxidation resistance, fabricability and high-temperature strength.
Contents
Principal Features Creep and Stress-Rupture Strength Tensile Properties Physical Properties Oxidation Carburization Health and Safety Sales Office Addresses 3 4 6 10 14 15 15 16
H-3009B
HASTELLOY X Alloy
PRINCIPAL FEATURES
Strong and Oxidation Resistance
HASTELLOY X alloy is a nickel-chromium-iron-molybdenum alloy that possesses an exceptional combination of oxidation resistance, fabricability and high-temperature strength. It has also been found to be exceptionally resistant to stress-corrosion cracking in petrochemical applications. X alloy exhibits good ductility after prolonged exposure at temperatures of 1200, 1400, 1600F (650, 760 and 870C) for 16,000 hours.
Heat-Treatment
Wrought forms of HASTELLOY X alloy are furnished in the solution heat-treated condition unless otherwise specified. X alloy is solution heat-treated at 2150F (1177C) and rapid cooled. Bright annealed products are cooled in hydrogen.
Easily Fabricated
HASTELLOY X alloy has excellent forming and welding characteristics. It can be forged and, because of its good ductility, can be cold worked. X alloy can be welded by both manual and automatic methods including shielded metal arc (covered electrodes), gas tungsten arc (TIG) and gas metal arc (MIG). The alloy can also be resistance welded.
zone components such as transition ducts, combustor cans, spray bars and flame holders as well as in afterburners, tailpipes and cabin heaters. It is recommended for use in industrial furnace applications because it has unusual resistant to oxidizing, reducing and neutral atmospheres. Furnace rolls of this alloy were still in good condition after operating for 8,700 hours at 2150F (1177C). HASTELLOY X alloy is also used in the chemical process industry for retorts, muffles, catalyst support grids, furnace baffles, tubing for pyrolysis operations and flash drier components.
Specifications
For information on specifications to which this alloy can be ordered, please contact one of the locations shown on the back cover of this brochure and ask for bulletin H-1034.
Cr
22
Fe
18
Mo
9
Co
1.5
W
0.6
C
0.10
Mn
1*
Si
1*
B
0.008*
As balance
*Maximum
HASTELLOY X Alloy
0.0001
14.7 7.2 2.7 0.7 (101) (50) (19) (5)
Average Stress for Indicated Percent/Hour Minimum Creep Rate, Ksi (MPa) 0.001 0.01
21.0 10.0 4.1 1.3 (145) (69) (28) (9) 31.0 (214) 14.0 (97) 6.2 (43) 2.2 (15) -
0.1
44.0 19.5 9.2 3.7 0.9 (303) (134) (63) (26) (6)
* Solution heat-treated. Based on over 100 tests for sheet and over 150 tests for plate and bar.
Creep, Percent
0.5 1.0 2.0 0.5 1.0 2.0 0.5 1.0 2.0 0.5 1.0 2.0 0.5 1.0 2.0
Approximate Initial Stress, Ksi (MPa) to Produce Specified Creep in: 10 Hours 100 Hours 1,000 Hours 10,000 Hours
40.0 44.0 48.0 16.5 19.0 21.0 7.8 9.0 10.5 3.1 3.6 4.2 0.8 1.1 (276) (303) (331) (114) (131) (145) (54) (62) (72) (21) (25) (29) (6) (8) 27.0 30.0 33.0 10.5 13.0 15.0 4.9 6.1 7.2 1.7 1.9 2.2 (186) (207) (227) (72) (90) (103) (34) (42) (50) (12) (13) (15) 17.5 21.0 22.5 6.5 9.0 10.8 3.1 3.6 4.3 0.9 1.0 1.1 (121) (145) (155) (45) (62) (74) (21) (25) (30) (6) (7) (8) 6.2 7.6 2.1** 2.3 -
1400
760
1600
871
1800
982
2000
1093
HASTELLOY X Alloy
Creep, Percent
1.0 5.0 1.0 5.0 1.0 5.0 1.0 5.0 1.0 5.0
Approximate Initial Stress, Ksi (MPa) to Produce Specified Creep in: 10 Hours 100 Hours 1,000 Hours 10,000 Hours
48.0 64.0 27.0 34.0 15.0 18.0 8.0 10.5 4.2 5.4 (331) (441) (186) (234) (103) (124) (55) (72) (28) (37) 32.0 43.0 19.0 24.0 10.4 13.0 5.4 6.8 2.6 3.3 (220) (296) (131) (165) (71) (89) (37) (46) (17) (22) 22.0 29.0 13.0 16.5 7.3 9.0 3.7 4.2 1.6 2.0 (151) (200) (89) (113) (50) (62) (25) (28) (11) (14) 15 (103) 20** (138) 9 (62) 11.5** (79) 5.1 (35) 6.2** (43) 2.5 (17) 2.8** (19) 1.0** (7) -
** Extrapolated *** Solution heat-treated. Based on over 90 tests for 1.0 percent creep and on over 60 tests for 5.0 percent creep.
10 Hours
67.0 32.0 17.0 6.5 2.4 (462) (221) (117) (45) (17)
Approximate Rupture Life Strength for Time Indicated, Ksi (MPa) 100 Hours 1,000 Hours 10,000 Hours
48.0 22.5 10.6 3.7 1.2 (331) (155) (73) (26) (8) 34.0 15.8 6.5 2.1 0.6 (170) (77) (28) (8) (4) 24.9 11.1 4.0 1.2 (170) (77) (28) (8)
10 Hours
72.0 36.0 21.0 12.0 7.0 3.7 1.7 (496) (248) (145) (83) (48) (26) (12)
Approximate Rupture Life Strength for Time Indicated, Ksi (MPa) 100 Hours 1,000 Hours 10,000 Hours
47.9 25.0 14.0 7.5 4.2 1.9 0.7 (330) (172) (96) (52) (29) (13) (5) 34.0 18.0 10.0 4.7 2.4 1.0** 0.3** (234) (124) (69) (32) (17) (7) (2) 24.0 12.5 6.8 3.0 1.4 (165) (86) (47) (21) (10)
* Solution heat-treated. Based on over 100 tests for sheet and over 150 tests for plate and bar. ** Extrapolated
HASTELLOY X Alloy
Condition
Heat-treated at 2150F (1177C), Rapid Cooled Heat-treated at 2150F (1177C), Rapid Cooled
Ksi 109.5
MPa 755
107.7
743
49.1
339
51
Condition
Bright Annealed at 2150F (1177C), Hydrogen Cooled
* Strain rate was 0.005-inch/inch/minute to 0.2% yield point and 0.5-inch/inch/minute to failure.
Condition
Heat-treated at 2150F (1177C), Rapid Cooled
F -321 -108 72
C -196 -78 22
HASTELLOY X Alloy
Average Short-Time Tensile Data, Cold-Reduced and Welded 0.109 in. (2.8mm) Sheet
Ultimate Tensile Strength Condition
As Cold-Reduced
Form
Reduced 5 percent Reduced 15 percent Reduced 30 percent Reduced 5 percent Reduced 15 percent Reduced 30 percent
NOTE: All cold-reduced sheet and the various weld samples were produced from material which had been solution heat-treated prior to cold reduction or welding. All data were obtained at room temperature and are the result of a limited numlber of tests.
Condition
As-Welded
Weld Method
Shielded Metal Arc (covered electrodes)
Material
Sheet, 0.125 in. (3.2mm) Plate, 0.250 in. (6.4mm) Plate, 0.375 in. (9.5mm) Sheet, 0.125 in. (3.2mm) Plate, 0.250 in. (6.4mm) Plate, 0.375 in. (9.5mm) Sheet, 0.125 in. (3.2mm) Plate, 0.250 in. (6.4mm) Plate, 0.375 in. (9.5mm)
As-Welded
As-Welded
HASTELLOY X Alloy
Form
Sheet, 0.125 in. (3.2mm) thick
Aging Temperature F C
SHT 1200 649
Aging Time,
Hours 1000 4000 8000 16000 1000 4000 8000 16000 1000 4000 8000 16000 1000 4000 8000 1000 4000 8000 1000 4000 8000 16000
1400
760
1600
871
SHT 1200
649
1400
760
1600
871
* Test data for each form are from a single heat. SHT=Solution heat-treated (not aged)
HASTELLOY X Alloy
Reduction of area
% 22 33 19 18 19 18 15 15 16 8 8 9 12 6 7 9 11
Form
1600 Plate, 1/2 in. (12.7mm) thick Gas Tungsten Arc 1200 Welded Plate, 1/2 in. (12.7mm) thick 1400
760
871 649
1400
760
1600
871
126.9 875 150.1 1035 145.5 1003 128.2 884 127.4 878 125.2 863 105.3 726 98.0 676 123.0 848 139.3 960 131.8 909 113.5 783 110.5 762 97.7 674 92.8 640 92.7 639
* Test data for each form are from a single heat. **Single test data. Gas tungsten arc welded.
HASTELLOY X Alloy
Temperature, C 22 1260-1355
72 2300-2470
72 70 200 500 1100 1300 1500 1700
46.6 microhm-in. (712 ohms per cir. mil-ft.) 63 Btu-in./ft.2 hr.-F 76 Btu-in./ft. hr.-F 98 Btu-in./ft. hr.-F 144 Btu-in./ft.2 hr.-F 159 Btu-in./ft.2 hr.-F 174 Btu-in./ft. hr.-F 189 Btu-in./ft. hr.-F 0.116 Btu/lb.-F 0.117 Btu/lb.-F 0.118 Btu/lb.-F 0.119 Btu/lb.-F 0.123 Btu/lb.-F 0.130 Btu/lb.-F 0.139 Btu/lb.-F 0.151 Btu/lb.-F 0.167 Btu/lb.-F 0.186 Btu/lb.-F 0.205 Btu/lb.-F 7.2 microinches/in.-F 7.5 microinches/in.-F 7.7 microinches/in.-F 7.9 microinches/in.-F 8.1 microinches/in.-F 8.5 microinches/in.-F 8.8 microinches/in.-F 0.328 0.320
2 2 2 2
22 21 93 200 593 704 816 927 Room 93 204 316 427 538 649 760 871 982 1093 25-100 25-200 25-300 25-400 25-500 25-600 25-700 -78 22
118.36 microhm-cm 9.1 W/m-K 11.0 W/m-K 14.1 W/m-K 20.8 W/m-K 22.9 W/m-K 25.1 W/m-K 27.2 W/m-K 486 J/Kg-K 490 J/Kg-K 494 J/Kg-K 498 J/Kg-K 515 J/Kg-K 544 J/Kg-K 582 J/Kg-K 632 J/Kg-K 699 J/Kg-K 799 J/Kg-K 858 J/Kg-K 13.0 10-6 m/m-C 13.5 10-6 m/m-C 13.8 10-6 m/m-C 14.2 10-6 m/m-C 14.5 10-6 m/m-C 15.1 10-6 m/m-C 15.6 10-6 m/m-C 0.328 0.320
Specific Heat
Room 200 400 600 800 1000 1200 1400 1600 1800 2000
-108 72 Room
HASTELLOY X Alloy
10
Condition
Heat-treated at 2150F (1177C) Rapid Cooled
Temperature, F
Room 200 400 600 800 1000 1200 1400 1600 1800
Temperature, C
Room 93 204 316 427 538 649 760 871 982
Condition
Heat Treated at 2150F (1177C), Rapid Cooled Heat-treated at 2150F (1177C), Rapid Cooled Heat-treated at 2150F (1177C), Rapid Cooled
Test Area
Weld area Heat-affected zone Base metal Weld area Heat-affected zone Base metal Weld area Heat-affected zone Base metal
Note: Sheet was solution heat-treated prior to welding. Hardness was determined at room temperature in the as-welded condition.
11
HASTELLOY X Alloy
Form
Sheet
Hardness, Rockwell A
54 56 62 63 62 61 60 61 58 55 54 57 62 63 60 59 58 56 56 54 64 65 63 62 60 60 56 55 54
1400
760
1600
871
Plate
SHT 1200
649
1400
760
1600
871
1200
649
1400
760
1600
871
SHT=Solution heat-treated (not aged) * Single tests from a single heat for each form **Gas tungsten arc welded
HASTELLOY X Alloy
12
Formability, Sheet
Condition
Heat Treated at 2150F (1177C), Rapid Cooled
Aging Time,
Hours 1000 4000 8000
1400
760
1600
871
SHT=Solution heat-treated (not aged) * Average of four tests on 1/2-in. (12.7mm) plate from a single heat.
13
HASTELLOY X Alloy
OXIDATION RESISTANCE
Comparative Static Oxidation Data in Flowing Air for 1008 Hours*
1800F (980C) Metal Loss + Metal Loss/side, CIP**/side, Mils m Mils m
0.29 0.32 0.53 0.32 0.94 0.007 0.008 0.013 0.008 0.024 0.74 0.90 1.3 0.72 1.8 0.019 0.023 0.033 0.018 0.046
Alloy
HASTELLOY X alloy INCONEL alloy 600 INCONEL alloy 601 Alloy 625 Alloy 800H
* Cycled to room temperature once a week **CIP=Continuous Internal Penetration INCONEL is a trademark of Inco Family of Companies
1. 2. 3. 4. 5.
Metal Loss = (A-B)/2 Average Internal Penetration = C Maximum Internal Penetration = D Average Metal Affected = ((A-B)/2) + C Maximum Metal Affected = ((A-B)/2) + D
C
900 900
mm
0.08 0.17
mm
0.07 0.19
mm
0.05 0.09
* All tests performed by exposure to the combustion products of No. 2 fuel oil (0.4 percent sulfur) and 5 ppm of sea salt. Gas velocity over samples was 13 ft./sec. (4m/s). Thermal shock frequency was one/hour.
HASTELLOY X Alloy
14
CARBURIZATION RESISTANCE
Tests were performed in a carburizing environment with an inlet gas mixture (volume %) of 5.0% H2, 5.0% CO, 5.0% CH 4 and the balance argon. The calculated oxygen potential and carbon activity at 1800F (980C) were 9 x 10-22 atm. and 1.0, respectively. The results are presented in terms of the mass of carbon pickup per unit area, which was obtained from the equation M = C (W/A) where M = the mass of carbon pickup per unit area (mg/cm2), C = difference in carbon (weight fraction) before and after exposure, W = weight of the unexposed specimen (mg) and A = surface area of the specimen exposed to the test environment (cm2).
5
Carbon Pickup Per Unit Area, mg/cm
15
HASTELLOY X Alloy
STANDARD PRODUCTS
By Brand or Alloy Designation: HASTELLOY Corrosion-Resistant Alloys
B-3, C-4, C-22, C-22HS, C-276, C-2000, G-30, G-35, G-50, HYBRID-BC1, and N
Wear-Resistant Alloy
6B
Standard Forms: Bar, Billet, Plate, Sheet, Strip, Coils, Seamless or Welded Pipe & Tubing, Pipe
Fittings, Flanges, Fittings, Welding Wire, and Coated Electrodes
Properties Data: The data and information in this publication are based on work conducted principally by Haynes International, Inc. and occasionally supplemented by information from the open literature, and are believed to be reliable. However, Haynes does not make any warranty or assume any legal liability or responsibility for its accuracy, completeness, or usefulness, nor does Haynes represent that its use would not infringe upon private rights.
Any suggestions as to uses and applications for specific alloys are opinions only and Haynes International, Inc. makes no warranty of results to be obtained in any particular situation. For specific concentrations of elements present in a particular product and a discussion of the potential health affects thereof, refer to the Material Safety Data Sheet supplied by Haynes International, Inc. All trademarks are owned by Haynes International, Inc.
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