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Pertemuan Pertama :
Ceramic
Linear
0.155 - 0
Corners of triangle
0.225 0.155
Corners of tetrahedron
0.414 0.225
Corners of octahedron
0.732 0.414
Corners of cube
1.0 0.732
Pekerjaan rumah 1 :
Buktikanlah rasio jari-jari (r/R) pada :
a) Koordinasi tetrahedron (CN = 4) sebesar 0,225 0,414 ?
b) Koordinasi oktahedron (CN = 6) sebesar 0,414 0,732 ?
c) Koordinasi kubus (CN = 8) sebesar 0,732 1,000?
JARI-JARI IONIK ()
Ion
Valensi
Jarijari
Ion
Valensi
Jarijari
Ion
Valensi
Jarijari
Ion
Valensi
Jarijari
Ac
+3
1.15
Br
+7
0.39
-7
0.08
Pb
+2
1.24
Ag
+1
1.22
+4
0.18
-1
1.34
Pt
+4
0.65
Ag
+2
0.89
Ca
+2
1.00
Fe
+2
0.77
Rb
+1
1.48
Al
+3
0.51
Cd
+2
0.99
Ga
+3
0.62
Rh
+3
0.69
Am
+3
1.03
Ce
+3
1.13
Ge
+4
0.50
-2
1.83
Am
+4
0.91
Cl
+7
0.27
Hg
+3
1.11
Sb
+5
0.62
As
+3
0.58
Cl
-1
1.81
-1
2.18
Sn
+2
0.93
As
+5
0.47
Co
+2
0.76
+1
1.33
Ta
+5
0.68
At
+7
0.62
Co
+3
0.63
Li
+1
0.69
Ti
+4
0.65
Au
+1
1.37
Cr
+3
0.64
Mg
+2
0.69
+6
0.82
Au
+3
0.85
Cr
+6
0.45
Mn
+4
0.53
+5
0.53
+3
0.20
Cs
+1
1.70
+3
0.16
+6
0.62
Ba
+2
1.35
Cu
+1
0.96
Na
+1
1.02
+3
0.95
Be
+2
0.43
Cu
+2
0.72
Nd
+3
1.04
Zr
+4
0.81
Bi
+3
0.93
Dy
+3
0.92
Ni
+2
0.72
CO3
-2
1.31
Bi
+5
0.74
Er
+3
0.97
+6
0.10
OH
-1
1.33
Br
-1
1.96
Eu
+3
0.98
-2
1.39
NH4
-1
1.74
Pekerjaan rumah 2:
Predict the coordination number (bilangan
koordinasi) and crystal structure for the ions solids
CsCl and NaCl?
Use the following ionic radii for the prediction :
Cs+ = 0,170 nm; Na+ = 0,102 nm; Cl- = 0,181 nm
INTRODUCTION : FERROELECTRIC
MATERIAL APPLICATION
FERROELECTRIC/PYROELECTRIC MATERIAL
(a)
(b)
Ferroelectric material perovskite structure (PZT/BST)
(a) Up Polarization (b) Down Polarization
1 and 0 = binary
6.6980 gram
lead zirconate
[PbZrO3, 99,7 %]
Preparation DC
Unbalanced Magnetron
Sputtering (UBMS)
method
Stop
12 grams of
PTZT powder
PTZT thin
films of
Pt (200)/
SiO2/Si(100)
substrate
Mixing by
bowl of
polishing for
6 hours.
Analyzing and
characterizing :
the structure (XRD Diano
type 2100E), morphology
surface and films
thickness (SEM JEOL type
JSM-35C).
2d sin ,
(1)
1
h2 k 2 l 2
2
d
a2
(2)
Perhitungan lengkap dari konstanta kisi dari target PZT didadah 1.08 % Ta2O5
(PTZT) menggunakan metode analitik struktur kubik
Puncak
2
(deg.)
(deg.)
Sin2
(Sin2 )/2
(Sin2 )/3
(Sin2 )/4
(Sin2 )/5
21.85 10.925
0.03588
0.01794
0.01196
0.00897
0.00718
31.10 15.550
0.07180
0.03589
0.02393
0.01795
0.01436
38.35 19.150
0.10751
0.05375
0.03593
0.02688
0.0215
44.55 22.275
0.14354
0.07177
0.04785
0.03589
0.02871
50.15 25.075
0.17944
0.08972
0.05981
0.04486
0.03589
55.30 27.650
0.21516
0.10758
0.07172
0.05379
0.04303
64.40 32.200
0.28370
0.14185
0.09326
0.07093
0.05674
68.35 34.175
0.31525
0.15763
0.10508
0.07881
0.06305
73.10 36.550
0.59622
0.17717
0.11811
0.08858
0.07087
Puncak
2
(deg.)
(deg.)
(Sin2 )/6
(Sin2 )/A
hkl
21.85
10.925
0.00598
1.00000
100
31.10
15.550
0.01197
2.00099
110
38.30
19.150
0.01792
2.99629
111
44.55
22.275
0.02392
4.00063
200
50.15
25.075
0.02991
5.00111
210
55.30
27.650
0.03586
5.99663
211
64.40
32.200
0.04663
7.79756
220
68.35
34.175
0.05254
8.78626
300
73.10
36.550
0.05906
9.87568
10
310
sin
sin
sin
C 2 B A ,
2
2
C B A , ,
2
C B A 2 ,
(3)
2d sin ,
1 h2 k 2 l 2
2.
2
2
d
a
c
(1)
(2)
Perhitungan lengkap dari konstanta kisi dari target PZT didadah 1 % Ta2O5
(PTZT) menggunakan metode Cohen (struktur tetragonal)
No Puncak
hkl
1.
100
21,6
10,80
2.
110
31,5
15,75
3.
111
38,8
19,40
4.
200
44,7
22,35
16
5.
210
50,2
25,10
25
6.
211
55,4
27,70
25
7.
220
65,2
32,60
64
8.
300
70,2
35,10
81
9.
310
73,6
36,80
10
100
320
Sin22
Sin2
1.
0,1355157
0,0351118 1,355157
1,836450
2.
0,2730048
0,0736799 2,730048
7,453159
3.
0,3926323
0,1103310 3,926323
15,41602
4.
0,4947641
0,1446003 4,947641
24,47915
5.
0,5902596
0,1799452 5,902596
34,84064
6.
0,6775535
0,2160781 6,775535
45,90787
7.
0,8240600
0,2902740 8,240600
67,90748
8.
0,8852566
0,3306310 8,852566
78,36793
9.
0,9202833
0,3588293 9,202833
84,69214
No
360,9008
sin2
sin2
sin2
1.
1,355157
0,0351118
0,0475819
2.
5,460095
0,1473598
0,2011497
3.
3,926323
7,852647
0,2206620
0,1103310
0,4331953
4.
19,79056
0,5784011
0,7154302
5.
29,51298
0,8997258
1,0621435
6.
6,775535
33,87767
1,0803906
0,2160781
1,4640449
7.
65,92480
2,3221917
2,3920314
8.
79,67310
2,9756794
2,9269332
9.
92,02833
3,5882927
3,3022459
10,701858
335,4753
11,847815
0,3264091
12,5447559
No
7 B 335, 475300 A
0,3264091
7C
2 B 10, 701858 A .
320C
Pekerjaan Rumah ke -2
Perhitungan lengkap dari konstanta kisi dari target PZT didadah 1,08 % Ta2O5
(PTZT) menggunakan metode Cohen (struktur tetragonal).
No Puncak
hkl
1.
100
21.85
2.
110
31,10
3.
111
38,35
4.
200
44,55
5.
210
50,15
6.
211
55,30
7.
220
64,40
8.
300
68,35
9.
310
73,10
2
No
1.
2.
3.
4.
5.
6.
7.
8.
9.
Sin22
Sin2
No
1.
2.
3.
4.
5.
6.
7.
8.
9.
sin2
sin2
sin2