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CH260

A1
(due during class on Monday January 23th 2012)

3.1. Identify a C3 axis of an NH + ion (draw a scheme). How many of these axes are there 4 in the ion? 3.2. Which of the following molecules and ions has a center of inversion or an S4 axis: (a) CO2, (b) C2H2, (c) BF3, (d) SO 2 ? 4 3.3. Identify the point groups of (a) BF3, (b) SO 2 . 4 3.4. Determine the number of degrees of vibrational freedom for each of the following: (a) BCl3, (b) SO 2 , (c) NCS . How many of them are IR active? 4

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