Cc bi ton chng oxi Lu hunh (tip theo)

III. Kim lo i tc d ng v i l u hunh Phn ng gia kim loi (M) v lu hunh (S) M + S > mui sunfua Phn ng c th hon ton hoc khng hon ton

* Ph n ng hon ton th sau p thu c :

- Mui sunfua ( Kim loi M ht, S ht) - Hoc mui sunfua, Kim loi (M) d: khi cho hh cc cht trn tc dng vi dung dch axit s cho hn hp kh H2S v H2 - Hoc mui sunfua, lu hunh (S) d: khi cho cc cht trn tc dng vi dung dch axit s cho kh H2S v cht rn (S) khng tan.

* N u ph n ng khng hon ton th sau p thu c:

- Mui sunfua, S d, M d: khi ho tan trong axit th thu uc hn hp 2 kh H2S v H2 v 1 cht rn (S) khng tan

V d :
1) un nng hon ton hn hp bt gm st v lu hunh. em ho tan cht rn sau phn ng trong dung dch HCl d thy c 4,48 lit kh thot ra. Nu em ht lng kh ny cho vo dung dch Pb(NO3)2 d th cn li 2,24 lit kh. Cc th tch u o ktc.Tnh % khi lng ca st v lu hunh trong hn hp u v tnh khi lng kt ta to thnh trong dung dch Pb(NO3)2? Gii

2) Cho sn phm to thnh khi nung hn hp 5,6 gam st v 1,6 gam bt lu hunh vo 500 ml dung dch HCl th c 1 hn hp kh bay ra v mt dung dch A ( hiu sut phn ng 100%). a) Tnh thnh phn phn trm th tch hn hp kh to thnh? b) trung ho HCl cn d trong dung dch A phi dng 125 ml dung dch NaOH 0,1 M. Tnh nng mol ca dung dch HCl? 3) Cho 6,45 gam mt hn hp gm lu hunh v 1 kim loi M ( ho tr 2) vo mt bnh kn khng cha Oxi. Nung bnh cho n khi phn ng hon ton thu c hn hp B. Cho hn hp B tc dng vi dung dch HCl d thu oc kh C v 1,6 gam cht rn D khng tan. Cho kh C i t t qua 1 dung dch Pb(CH3COO)2 c kt ta cn nng 11,95 g. Xc nh kim loi M v tnh khi lng M v lu hunh trong hn hp ban u? 4) Mt hn hp X gm bt lu hunh v mt kim loi M ho tr 2 c khi lng l 25,9 g. Cho X vo 1 bnh kn khng cha khng kh. Thc hin phn ng gia M v S ( phn ng hon ton) thu c cht rn A. khi cho A tc dng vi dung dch HCl d, A tan ht to ra hn hp kh B c V=6,72 lit

(kc) v t khi i vi Hiro bng 11,666. Xc nh thnh phn hn hp kh B, tn kim loi M v khi lng S v M trong hn hp X? 5) Mt hn hp Y gm Zn v lu hunh; Cho M v S phn ng hon ton vi nhau to ra cht rn C. Khi cho C tc dng vi dung dch HCl d th cn li 1 cht rn D khng tan cn nng 6 gam v thu c 4,48 lit kh E c t khi ca E i vi hiro l 17. Tnh khi lng Y? 6) Mt hn hp Z gm km v lu hunh; nung nng hn hp trong bnh kn khng c oxi thu c cht rn F. Khi cho F tc dng vi dung dch HCl d li mt cht rn G khng tan cn nng 1,6 gam v to ra 8,96 lit hn hp kh (kc) c t khi i vi hiro bng 17. Tnh khi lng hn hp Z v hiu sut phn ng gia M v S? IV. Cc oxit axit ( CO 2 , SO 2 ) ho c cc a axit ( H 2 S, H 3 PO 4 ,) tc d ng v i dung d ch ki m: NaOH, Ca(OH) 2 , Ba(OH) 2 , Bi 1: Tnh khi lng cc cht thu c sau phn ng trong cc trng hp sau: a) Dn 2,24 lit kh hirosunfua vo 300 ml dung dch NaOH 1M b) Dn 13,44 lit SO2 vo 200 ml dung dch NaOH 2M c) Dn 0,672 lit SO2 vo 1 lit dung dch Ca(OH)2 0.02 M Bi 2: Dn 12, 8 gam SO2 vo 50 ml dung dch NaOH 25% ( d= 1,28 gam /ml). Mui no c to thnh? Tnh C% ca n trong dung dch thu c? Bi 3: t chy hon ton 8,96 lit H2S (ktc) ri ho tan tt c sn phm sinh ra vo 80 ml dung dch NaOH 25% ( d= 1,28 g/ml). Tnh nng phn trm ca cc cht trong dung dch thu c? Bi 4: Mt hn hp X gm 2mui sunfit v hirosunfit ca cng mt kim loi kim - Cho 43,6 gam hn hp X tc dng vi dung dch H2SO4 long d. Cht kh A sinh ra lm mt mu va 400 ml dung dch KMnO4 0,3M 2KMnO4 + 5SO2 +2 H2O 2MnSO4 + 2KHSO4 + H2SO4 - Mt khc, 43,6 gam hn hp X cng tc dng va vi 100 ml dung dch NaOH 1M. a) Xc nh tn kim loi kim? % khi lng mi mui trong hn hp X? b) Cho ton b kh A sinh ra hp th vo 500 gam dung dch Ba(OH)2 6,84%. Tnh nng phn trm ca dung dch thu c? c) Tnh khi lng dung dch Ba(OH)2 6,84% ti thiu dng hp thu ton b lng kh A ni trn? Bi 5: Dn V lit (kc) kh CO2 qua dung dch c cha 0,1 mol Ca(OH)2 thu c 6 gam kt ta. Lc b kt ta, ly dung dch nc lc un nng li thu c kt ta na. Tnh V? Bi 6: Cho 16,8 lit kh CO2 (ktc) hp th hon ton vo 600 ml dung dch NaOH 2M thu c dung dch X. Nu cho mt lng d dung dch BaCl2 vo dung dch X th thu oc lng kt ta bao nhiu? Bi 7: Dn V lit kh CO2 (kc) hp th vo dung dch c cha 0,5 mol Ca(OH)2 thy c 25 gam kt ta. Tnh V?