REVISI PRESENTASI HIDRO-ELEKTRO METALURGI

PRECIPITATION BY GAS CARBON MONOXIDE

RENDY HARRISTA 3334091122

UNIVERSITAS SULTAN AGENG TIRTAYASA FAKULTAS TEKNIK CILEGON-BANTEN 2012

REVISI
A. REVISI SLIDE 1. In slide number 6 I mean the true sentence is Rate of Carbon Monoxide Reduction of Silver(I) Early experiments demonstrated that at low pH the reduction of AgClO4 solutions was very slow even at temperatures of 175C and CO pressures of 20 atm. When the solutions were buffered with NaOAc and HOAc, however, the rates were readily measured under much milder conditions by the pressuredrop method. Because I mean experiment is used one temperature an one pressure.

2. In slide number10 Point white and point black is initial concentration of solution

If CO pressure increase in process, the rate of precipitation in solution increase too.

3. In slide number 11 R is total rate of CO consumption at unit pressure and if the concentration of acetic acid is increase the consumtion rate of CO increase too. Because in high concentration need many gas CO too precipitate metal in solution.

4. In slide number 12 There is many variable of temperature for CO consumption in process precipitation. When the temperature is increase, the consumption rate of CO increase too and the best temperature in curve can see in highest temperature in full black point.

5. In slide number 18 Application in industry can found in recovery of copper, from copper smelter slag and coventer slag at Ghatsila (Bihar) and Khetri (Rajasthan) India. The converter slag contained 4.03% copper and:the smelter slag contained 1.76% copper. Various parameters including the effect of stirring, leaching time, leaching temperature, concentration of ferric chloride, solidliquid ratio and particle size, on the extraction of copper, nickel and cobalt have been studied. 92% copper could be extracted from converter slag under optimum conditions, whereas 54% copper could be extracted from smelter slag.

B. QUESTION and ANSWER 1. How many method of precipitation by gas CO? There are 2 method : the first method is simply the analysis of periodic samples drawn during the course of the reaction and the second method is pressure drop.

2. Number of pH in statement in slide number 6? Number of pH is range 0.4 3.6

3. Mechanism of precipitate by gas CO?