Nguyn nh Hnh THCS Chu Vn An, ak P, Gia Lai

S GIO DC V O TO GIA LAI CHNH THC

K THI TUYN SINH VO LP 10 CHUYN Nm hc 2006-2007

MN THI : HO HC Thi gian lm bi: 150 pht (khng k thi gian pht ) Cu 1: (1,5 im) Dung dch M c cha CuSO4 v FeSO4 a) Cho Al vo dung dch M. Sau khi phn ng kt thc thu c dung dch A cha 3 mui tan. b) Cho Al vo dung dch M. Sau khi phn ng kt thc thu c dung dch B cha 2 mui tan. c) Cho Al vo dung dch M. Sau khi phn ng kt thc thu c dung dch C cha 1 mui tan. Gii thch mi trng hp v vit phng trnh ho hc ca cc phn ng. Cu 2: (1,5 im) Xc nh cc cht A, B, C, D, E, F v hon thnh cc phng trnh ho hc sau: t0 KClO3 A + B
p A + C D + E + F Co m.n

D + E A + KClO + C ( xy ra nhit thng ) Cu 3: (1,5 im) Ba hp cht A, B, C c cng cng thc phn t : C2H4O2 . - A tc dng c vi Na v NaOH; - B tc dng c vi Na, khng tc dng vi NaOH; - C tc dng c vi NaOH, khng tc dng vi Na; Hy xc nh cng thc cu to ca cc cht A, B, C v vit phng trnh ho hc ca cc phn ng trn. Cu 4: (1,5 im) C 5 l khng nhn, mi l ng mt trong nhng cht rn sau: ZnCl 2 , NaCl, Na2CO3 ,MgCO3 , BaCO3 . Hy chn thm mt thuc th nhn bit c c 5 cht trn. Vit phng trnh ho hc (nu c). Cu 5: (1,5 im) Hai nguyn t X, Y thuc cng mt nhm v hai chu k k tip nhau trong bng tun hon, c tng s n v in tch ht nhn l 24. Xc nh hai nguyn t X v Y. Cu 6: (2,5 im) Dn hn hp X gm 1,12 lt kh H2 v 0,896 lt kh C2H2 qua ng ng Ni nung nng. Sau mt thi gian thu c 1,344 lt hn hp kh Y. Cho lng hn hp kh Y trn qua bnh ng dung dch brm (d) n khi phn ng hon ton, thy bnh dung dch brm tng thm 0,8 gam. a) Vit phng trnh ho hc ca cc phn ng xy ra b) Tnh thnh phn phn trm (theo th tch) ca cc kh trong hn hp Y (th tch cc kh iu kin tiu chun). -------HT-----Ghi ch : Hc sinh c s dung bng tun hon cc nguyn t ho hc v my tnh b ti theo quy nh
H v tn th sinh : ......................................... SBD : ....................... Phng thi: ...................... Ch k gim th 1: .............................................. Ch k gim th 2: ........................................

Nguyn nh Hnh THCS Chu Vn An, ak P, Gia Lai

S GIO DC V O TO GIA LAI D B

K THI TUYN SINH VO LP 10 CHUYN Nm hc 2006-2007

MN THI : HO HC Thi gian lm bi: 150 pht (khng k thi gian pht ) Bi 1: (1 im) Mt hc sinh pht biu : oxit axit l oxit ca phi kim, oxit baz l oxit ca kim loi. Theo em c ng hon ton khng ? Cho v d minh ho. Bi 2: (1,5 im) C 5 l khng nhn, mi l ng mt trong nhng cht rn sau: ZnCl 2, NaCl, Na2CO3, MgCO3 v BaCO3. Ch c chn thm mt thuc th nhn bit c c 5 cht trn. Vit phng trnh ho hc (nu c) Bi 3: (1 im) T tinh bt v cc ho cht cng vi cc iu kin cn thit. Hy vit cc phng trnh ho hc iu ch etyl axetat. Bi 4: (1 im ) Du, m dng lm thc phm c c im g ging v khc vi du, m dng bi trn xe my (c tch t du m) v thnh phn v cu to. Nu cch phn bit hai loi cht trn. Bi 5: (1 im) Nguyn t R to thnh hp cht kh vi hyr c cng thc ho hc chung l RH4. Trong hp cht c ho tr cao nht ca R vi xi th oxi chim 72,73% (theo khi lng). Xc nh tn nguyn t R. Bi 6: (2 im ) Cho 2,24l hn hp kh A gm N2 v CO2 qua bnh cha 2 lt dung dch Ca(OH)2 0,02M. Khi phn ng kt thc, thu c 3 gam kt ta. a) Tm thnh phn phn trm (theo th tch) cc cht kh trong A (th tch iu kin tiu chun). b) Bng phng php ho hc em hy trnh by cch tch ring cc kh c trong A. Vit phng trnh ho hc minh ha. Bi 7: (2,5 im) Hn hp X gm axt axetc v mt axt ha c A c cng thc CnH2n+1COOH. Cho a gam hn hp X phn ng va vi 300ml dung dch NaOH 1M ri c cn th thu c 27,4g hn hp mui khan. a) Xc nh cng thc phn t ca axt ha c (A).Bit t l s mol ca 2 axt l 1:2 b)Tnh thnh phn phn trm (theo khi lng) ca mi axt trong hn hp X -----HT---Lu : Hc sinh c s dng bng tun hon cc nguyn t ho hc v my tnh b ti.
H v tn th sinh:,s bo danh:., phng:.... Ch k ca gim th 1:., Ch k ca gim th 2:..............

Nguyn nh Hnh THCS Chu Vn An, ak P, Gia Lai

S GIO DC V O TO GIA LAI

CHNH THC

K THI TUYN SINH VO LP 10 CHUYN Nm hc 2007-2008

MN THI : HA HC (Chuyn) Thi gian lm bi: 150 pht (khng k thi gian pht ) Bi 1: (1 im) Bng cch no tch ring tng mui trong hn hp rn gm: Amoniclorua, bariclorua, magieclorua. Vit phng trnh ho hc ca cc phn ng xy ra. Bi 2: (1,5 im) Vit cc phng trnh ha hc thc hin dy chuyn ha sau : (1) (2) (3) (4) (5) (6) X 2On X Ca(XO2 )2n 4 X(OH)n XCln X(NO ) X 3 n Bi 3: (2 im) (A) l hn hp Zn v Cu c chia lm hai phn bng nhau: - Phn I: Ha tan trong dung dch HCl d th cn li 1 gam cht rn. - Phn II: Thm vo 4 gam Cu c hn hp (B) th phn trm theo khi lng ca Zn trong (B) nh hn so vi trong (A) l 33,33%. Bit rng khi ngm (B) vo dung dch NaOH (d) n khi phn ng kt thc th th tch kh hiro thot ra vt qu 0,6 lt o iu kin tiu chun. Tm phn trm khi lng Cu trong (A). Bi 4: (1,25 im) C 3 hp cht hu c A, B, C u c phn t khi bng 46 (vC) bit: A. Phn ng c vi kim loi Natri v Natri hiroxit B. Phn ng c vi kim loi Natri, khng phn ng vi Natri hiroxit. C. Khng phn ng c vi kim loi Natri. Hy xc nh cng thc cu to ca: A, B, C Bi 5: (1,25 im) Hn hp kh A (gm CO v O2) c khi lng mol bng 30,8 gam. Bt tia la in t chy hon ton hn hp A thu c hn hp kh B. Tnh thnh phn phn trm theo th tch ca cc kh trong hn hp B. Bi 6: (1 im) Cho 40 gam kim loi Canxi vo 1 lt nc nguyn cht th thu c bao nhiu gam cht rn? Bit tan ca Ca(OH)2 iu kin th nghim l 0,15 gam, gi s khng b tht thot nc do bay hi. Bi 7: (2 im) t chy hon ton 2,24 lt hn hp kh iu kin tiu chun gm hai hirocacbon phn t c cng s nguyn t cacbon, bng lng kh oxi va . Sn phm chy cho hp th hon ton ln lt vo cc bnh ng H2SO4 c v dung dch KOH th khi lng bnh ng H2SO4 c tng thm 2,7gam, bnh ng dung dch KOH tng thm 8,8 gam. a. Xc nh cng thc phn t ca hai hirocacbon trong hn hp. b. Tnh thnh phn phn trm theo th tch ca mi hirocacbon. -----HT----Ghi ch: Th sinh c s dng bng tun hon cc nguyn t ha hc H v tn th sinh:............................, s bo danh:................, phng:................. Ch k ca gim th s 1:.........................., Ch k ca gim th s 2:........................

Nguyn nh Hnh THCS Chu Vn An, ak P, Gia Lai

S GIO DC V O TO GIA LAI D B

K THI TUYN SINH VO LP 10 CHUYN Nm hc 2007-2008

MN THI : HO (Chuyn) Thi gian lm bi: 150 pht (khng k thi gian pht ) Cu 1: (1 im) C th dng dung dch NaOH phn bit c dung dch mui no sau y : CuSO4, Fe2(SO4)3, FeCl2 , ZnCl2. Vit phng trnh ha hc gii thch. Cu 2: (1,5 im) Vit phng trnh ha hc ca cc phn ng thc hin dy chuyn ha sau :
(1) (2) (3) (4) (5) (6) CH 4 A B C D E CH4

Cu 3: (1 im) Cho 24,5gam H3PO4 vo 300ml dung dch NaOH 1M. Tnh khi lng mui thu c sau phn ng. Cu 4: (1,5 im) Hai l kim loi R c khi lng bng nhau, l th nht cho vo dung dch Cu(NO3)2, l th hai cho vo dung dch Pb(NO3)2. Sau mt thi gian phn ng ly hai l kim loi ra ra nh, sy kh thy khi lng l th nht gim 0,2% v khi lng l th hai tng 28,4% so vi khi lng l kim loi ban u. Xc nh tn kim loi R, bit rng khi lng kim loi R tham gia phn ng trong hai trng hp bng nhau v lng kim loi Cu v Pb sinh ra u bm vo l kim loi. Cu 5: (1,5 im) Hn hp kh gm CO2, C2H4, C2H2, C2H6. Trnh by phng php ha hc tch ring tng kh . Cu 6: (1,75 im) Mt dung dch cha hai mui clorua ca kim loi M c ha tr II, III vi s mol bng nhau. Cho Al va phn ng hon ton vi dung dch trn. a/ Xc nh t l gia khi lng Al tham gia phn ng vi hai mui trn. b/ Tnh s gam Al phn ng vi mi mui . Bit khi lng Al dng l 1,35 gam. c/ Xc nh tn kim loi M, bit rng khi lng M thu c sau phn ng l 3,36 gam. Cu 7: (1,75 im) t chy s mol nh nhau ca 3 hp cht hirocacbon A,B,C thu c lng CO2 nh nhau v c t l s mol H2O v CO2 sinh ra trong mi phn ng i vi A, B, C tng ng bng 0,5; 1; 1,5. Xc nh cng thc phn t ca A, B, C. ----HT---Lu : Th sinh c s dng bng tun hon cc nguyn t ha hc v my tnh b ti.
H v tn th sinh:, s bo danh:., phng:.. Ch k ca gim th s 1:., Ch k ca gim th s 2:.

Nguyn nh Hnh THCS Chu Vn An, ak P, Gia Lai

S GIO DC V O TO GIA LAI --------------- CHNH THC

K THI TUYN SINH VO LP 10 CHUYN Nm hc 2008-2009 -------------------------

Mn thi: Ha hc ( chuyn) Thi gian lm bi: 150 pht (khng k thi gian pht )
---------------------------------------------------------CU 1: (1,5 im) 1. T cc nguyn liu chnh: qung pyrit st, mui n, nc (cc cht xc tc c sn). Vit phng trnh phn ng iu ch: Fe(OH)3, FeSO4, Fe2(SO4)3. 2. Hai nguyn t X,Y 2 chu k lin tip, thuc hai nhm A lin tip trong bng h thng tun hon. Bit tng s proton trong 2 ht nhn l 23 (s proton ca Y ln hn s proton ca X). Bit X,Y trng thi n cht tha mn theo s chuyn ha sau: +O2 +O2 +H +Cu X X1 X2 2O ,O2 X3 X2 +O2 +O2 +H 2O +Cu Y Y1 Y2 Y3 Y1 Lp lun xc nh tn hai nguyn t X,Y v cng thc ha hc ca cc cht trong 2 s trn. CU 2: (1,5 im) 1. Axit metaacrylic (CH2=C COOH) c tnh cht ha hc va ging axit axetic, va ging etylen. CH3 Vit phng trnh phn ng khi cho Axit metaacrylic ln lt tc dng vi cc cht sau: dung dch brom, natri, natri hiroxit, ru etylic (xc tc H2SO4 .). 2. T Axit metaacrylic c th iu ch thy tinh hu c (poly metyl metaacrylat) theo s sau: CH3OH t0 , p CH2=C COOH c,t0 A B H2SO4a xt CH3 Xc nh cng thc ca A v B. Vit phng trnh phn ng theo s cho. CU 3 (1,0 im) Cho m (gam) dung dch H2SO4 x% tc dng vi mt lng hn hp hai kim loi K v Mg (ly d). Sau khi phn ng kt thc, lng kh H2 thu c c gi tr 0,05m (gam). Tm gi tr x. CU 4: (1,5 im) t chy hon ton mt hirocacbon A mch thng thu c VH2O : VCO2 = 1:2. Mt khc, nu ly 0,2 mol A tc dng ht vi dung dch AgNO3 trong NH3 (d) thu c 58,4 gam cht kt ta. Xc nh cng thc phn t, cng thc cu to ca A. CU 5: (2,0 im) Cho mt lung kh CO d i qua mt ng s nung nng cha 4,8 gam hn hp X gm CuO v mt oxit kim loi ha tr II (khng i) t l mol 1: 2. Sau khi phn ng kt thc thu c cht rn Y. ha tan ht Y th cn 80ml HNO3 2,5M, thy thot ra mt kh NO duy nht v dung dch thu c ch cha hai mui ca hai kim loi. Vit phng trnh phn ng. Xc nh cng thc ha hc ca oxit kim loi. CU 6: (2,5 im) Hn hp X gm hai cht hu c CH3COOH (A) v RCOOC2H5 (B) (t l s mol 1 :1). Cho X tc dng ht vi 200ml dung dch NaOH un nng, sau phn ng thu c dung dch Y. C cn Y thu c hi ru v 36,6 gam cht rn Z (trong Z c 2 cht vi s mol bng nhau). Ngng t ht hi ru, cho tc dng ht vi Na gii phng 1,68 lt H2 (ktc). 1. Vit phng trnh phn ng. Xc nh cng thc cu to ca B. Bit MB < 168. 2. Xc nh nng mol ca dung dch NaOH ban u. ----------------- HT -------------------S GIO DC V O TO K THI TUYN SINH VO LP 10 CHUYN

Nguyn nh Hnh THCS Chu Vn An, ak P, Gia Lai

6 Nm hc 2008-2009

GIA LAI --------------------- D B

Mn thi: Ha hc Thi gian lm bi: 150 pht ( khng k thi gian pht ) -------------------------------------------------------Cu 1(1,5 im) 1. Mt nguyn t R c cng thc hp cht vi hiro l RH. Trong oxit bc cao nht, R chim 74,2% theo khi lng. Xc nh tn nguyn t R. 2. Bng phng php ha hc tch cc mui ra khi hn hp : AlCl3, FeCl2, CuCl2 ( Khi lng cc cht c tch ra khng i so vi ban u ). Cu 2( 1,5 im) 1. Hon thnh cc phng trnh phn ng iu ch etyl axetat t tinh bt theo s phn ng sau ( ghi r iu kin phn ng): Tinh bt A B C etyl axetat 2. Cho cc kh sau y cha trong cc bnh mt nhn : propan( C3H8), propen(C3H6), propin(C3H4), cacbonic. Bng phng php ha hc hy nhn bit cc kh trn. Cu 3(1,5 im) 1. Hn hp A gm C3H4, C3H6, C3H8 c t khi hi i vi H2 bng 21. t chy hon ton 1,12 lt A (ktc), cho ton b sn phm chy vo bnh cha dung dch nc vi trong d. Hi khi lng bnh nc vi trong tng bao nhiu gam ? 2. t chy hon ton mt hirocacbon X, cho ton b sn phm chy li qua dung dch Ba(OH) 2 d thu c 118,2 gam kt ta, ng thi khi lng dung dch trong bnh gim i 77,4 gam. Xc nh cng thc phn t ca hirocacbon X. Cu 4(1,5 im) 1. Mt dung dch cha 5,35 gam mt mui MCl, cho tc dng vi dung dch AgNO 3 d. Sau phn ng thu c a gam mt cht kt ta v dung dch X. Cho X tc dng ht vi dung dch CuCl 2 ta li thu c 2a gam mt cht kt ta, bit tng khi lng 2 ln kt ta l 43,05 gam. Vit phng trnh phn ng. Xc nh cng thc ha hc ca mui MCl. 2. Cho m (gam) mt oxit st tc dng va vi dung dch HCl thu c dung dch A. Cho dung dch NaOH d vo A th thu c mt kt ta B. Nung B trong khng kh n khi lng khng i, thu c m ( gam) cht rn. Vit cc phng trnh phn ng v xc nh cng thc ca oxit st. Cu 5(2 im) Mt hn hp X gm 2 hirocacbon mch h ( trong phn t mi cht cha 1 lin kt i ). 9,1 gam X lm mt mu va 40 gam brom trong dung dch. Bit rng trong hn hp X thnh phn th tch ca hirocacbon c khi lng phn t nh nm trong khong t 65% n 75%. 1.Xc nh cng thc phn t, cng thc cu to c th c ca 2 hirocacbon. 2. Vit phng trnh phn ng trng hp mi hirocacbon trn thnh polime. Cu 6 (2 im) Sau khi thc hin phn ng nhit nhm trong chn khng hn hp A gm nhm v mt oxit st ( dng bt) thu c 5,09 gam cht rn B. Ha tan B vo NaOH d un nng thu c 1,008 lt kh (ktc), phn cht rn C cn li cho tan ht vo dung dch HNO3 long gii phng 0,896 lt kh (ktc) khng mu ha nu trong khng kh. 1. Vit phng trnh phn ng. Tnh khi lng Al2O3 to thnh sau phn ng nhit nhm. 2. Xc nh cng thc ha hc ca oxit st. Bit cc phn ng xy ra hon ton. ---------Ht----------

Nguyn nh Hnh THCS Chu Vn An, ak P, Gia Lai

S GIO DC V O TO GIA LAI ------------------- CHNH THC

K THI TUYN SINH VO LP 10 CHUYN Nm hc: 2009 - 2010 -------------------------------

Mn thi: Ha hc Thi gian lm bi: 120 pht (khng k thi gian pht ) -------------------------------------Cu 1 (1,0 im): Hp cht M c to bi 2 nguyn t A v B c cng thc l A2B. Tng s proton trong phn t M l 54. S ht mang in trong nguyn t A gp 1,1875 ln s ht mang in trong nguyn t B. Xc nh cng thc phn t ca M? Cu 2 (1,5 im): Vit cc phng trnh ha hc thc hin dy chuyn ha sau (ghi r iu kin phn ng, nu c): (1) (2) (3) (4) (5) MX2 oxit axit(1) oxit axit(2) axit mui axit (6) mui trung ha kim loi Cu 3 (1,0 im): Bng phng php ha hc, hy nhn bit cc cht kh sau (ng trong cc l ring bit, mt nhn): kh cacbonic, lu hunh ioxit, metan, etilen, axetilen. Cu 4 (1,0 im): Dng mt lng dung dch H2SO4 10%, un nng ha tan va 0,4 mol CuO. Sau phn ng, lm ngui dung dch. Khi lng CuSO4.5H2O tch ra khi dung dch l 30 gam. Tnh tan ca CuSO4 trong iu kin th nghim trn. Cu 5 (2,0 im): Khi kh hon ton 38,4 gam mt oxit kim loi bng 32,256 lt CO ( nhit cao trong iu kin khng c oxi) thu c hn hp kh X c t khi so vi H 2 l 18 v cht rn Y. Cho ton b Y tc dng vi dung dch HCl d thu c 10,752 lt kh H2. Xc nh cng thc ca oxit. (Cc th tch kh u c o iu kin tiu chun) Cu 6 (1,5 im): 1) Cht A c cng thc phn t l C7H8. Cho A tc dng vi Ag2O(d) trong dung dch amoniac c cht B kt ta. Phn t khi ca B ln hn ca A l 214 vC. Vit cng thc cu to ca A. Bit A c cu to mch h, khng phn nhnh. 2) Ba cht hu c A, B, C cha cng nhm chc c cng thc phn t tng ng l CH2O2, C2H4O2, C3H4O2. a. Vit cng thc cu to v gi tn cc cht A, B, C. b. Tnh khi lng cht B trong dung dch thu c khi ln men 1 lt ru etylic 9,20. Bit hiu sut phn ng qu trnh ln men l 80% v khi lng ring ca ru etylic nguyn cht l 0,8g/ml. Cu 7 (2,0 im): Cho 3 cht hu c n chc: axit X (RCOOH); ru Y (ROH); este Z to bi axit X v ru Y (RCOOR). Nu ly mt lng hn hp gm X v Z tc dng va vi 150 ml dung dch NaOH 2M (un nng) th thu c 24,6 gam mui Natri. Nu ly 13,8 gam Y tc dng ht vi 11,5 gam Natri th thu c 25 gam b rn khan. Xc nh cng thc cu to ca X, Y, Z. ---------Ht------------

Nguyn nh Hnh THCS Chu Vn An, ak P, Gia Lai