Nghin cu ch to vt liu Nitinol xp ng dng lm vt liu y sinh

SINH VIN THC HIN: NGUYN VN CNG NGUYN NGC TRUNG MSE - ATP - K52 PHNG VN HIU NGUYN HUY HONG MSE-ATP-K53 GIO VIN HNG DN: TS. NGUYN NG THY PGS.TS. TRN VN DNG NCS. H K THANH

Ni dung
1.

t vn

2.
3.

Mc tiu ti
C s l thuyt
1.

Tnh ton nhit ng hc nhit chy on nhit ca phn ng SHS. C ch khuch tn ca Ni v Ti trong qu trnh thiu kt.

2.

4. 5. 6.

K thut thc nghim Kt qu v tho lun Kt lun v kin ngh

I. t vn

Nitinol

Ngun vt liu trin vng ch to vt liu chc nng ng dng trong k thut v y sinh

c bit, NiTi xp c dng nh m cng trong cy ghp.

a m nhn to

Cc phng php ch to Nitnol xp

p nng ng tnh ( Hot Isostatic Pressing) Phn ng nhit t lan truyn - SHS (Self-Propagating High-

temperature Synthesis)
Thiu kt trong chn khng-VS (Vacuum Sintering)

II. Mc tiu ca ti

Nghin cu cc thng s nh hng

n phn ng SHS.

Nghin cu ch to NiTi xp bng

phng php thiu kt trong chn

khng.

III. C s l thuyt

Phn ng SHS

phn ng ta

nhit khi b nh la v t duy tr phn ng (dng sng chy)

Tig : nhit nh la Tc : nhit chy

Tnh ton nhit ng hc nhit chy on nhit ca phn ng SHS

Phn ng SHS gia Ni v Ti: Enthalpy ca phn ng: Phn ng xy ra rt nhanh qu trnh on nhit:

Ni + Ti =NiTi
(1)

H vs T for the Ni/Ti system

Tad vs TP

C ch khuch tn ca Ni v Ti trong qu trnh thiu kt

Khuch tn trng thi rn

Cc phn ng xy ra:

Tc khuch tn: D(Ti) = 2D(Ni) Th t hnh thnh pha: Ni3Ti, NiTi2, NiTi

IV. K thut thc nghim

K thut thc nghim

Bt Ni (>99.9%,10m) v Ti (>99.9%,100m T l Ni :Ti = 1 :1 Thiu kt trong chn khng Trn 24h

P nhit t lan truyn Nghin 0 2h p s b 40 120MPa Nung s b 250 6000C

p s b 40 120MPa

nh la Tig =

20000C

Thiu kt T = 10000C, t = 4 6h

Sn Phm

X-Ray

SEM

o xp

Dng c th nghim
1. Cn in t

2. My nghin v trn

3. My p thy lc

Dng c th nghim
4. L SHS

6. L chn khng

5. B phn nh la

V. Kt qu v tho lun

Kt qu nghin cu ti trc
Hp kim NiTi xp c tng hp thnh cng bng

phng php SHS (Tp=600oC).

S hnh thnh pha

Mu SHS

TP = 3000C

TP = 5000C

S hnh thnh pha

Mu thiu kt trong chn khng

tm = 24h, TS = 10000C, tS = 4h

tm = 24h, TS = 10000C, tS = 6h

S hnh thnh pha

Mu thiu kt trong chn khng

tm = 24h, TS = 10000C, tS = 6h, VNH4HCO3 = 50%

 xp
Mu SHS
Thi gian nghin (h)
1.5 1.5

Nhit nung s b ( 0C)

400 500

p lc p s b (MPa)

xp (%)

120 120

48.3 47.2

2
2 2 2

300
250 300 400

120
40 40 40

53.6
55.7 55.4 49.0

2
2

500
600

40
40

48.5
44.7

xp ca m cy ghp: 40 80 (%)

 xp
Mu thiu kt trong chn khng
Thi gian thiu kt (h) % V NH4HCO3 (%) xp (%)

11.1

6 6

0 50

13,2 53.2

Hnh thi hc ca l xp
Mu SHS

Kch thc l xp: 100 300 (m) Kch thc l xp ca vt liu cy ghp: 100 - 500 (m)

nh hng ca tm v TP n phn ng SHS

Tig = 20000 C
Thi gian nghin ( h)
0 0.5 1 1.5 1.5 1.5 2 2 2 2 2 Nhit nung s b (C) 600 600 600 400 500 600 300 400 450 500 600 Xy ra phn ng SHS Xy ra phn ng SHS

Pcom = 120MPa
Ghi ch (Sau khi nh la) Khng xy ra phn ng SHS Khng xy ra phn ng SHS Khng xy ra phn ng SHS

nh hng ca tm v TP n phn ng SHS

Phn b nng chy

2500C

3000C

4000C

5000C

6000C

 xut qui trnh ch to a m nhn to bng phng php SHS

VI. Kt lun v kin ngh

Kt lun
Phng php SHS:
Tng thi gian nghin gim nhit nung s b

Nhit nung s b nh hng ln n tnh cht ca mu

SHS.

Mu sn phm c xp cao (40% 60%).

Kch thc l xp 100 - 300m

Kt lun
Phng php thiu kt trong chn khng:

NiTi xp c iu ch thnh cng bng phng php VS. Mu sn phm c xp cao. xp c th c khng ch.

Kin ngh
Phng php SHS:

Kim tra tnh cht c hc.

Kim sot s phn b ca l xp.

Phng php VS:

Kim sot kch thc l xp, s phn b l xp. a ra qui trnh th nghim hp l.

Kim tra tnh cht c hc

Ti liu tham kho

[1]. H.P.Li, A numerical study of the heterogeneous porosity effect on SHS, Materials
Research Bulletin 39 (2004) 18811894.
[2]. B.Y.Li, L.J.Rong, Y.Y.Li, Synthesis of porous Ni-Ti shape-memory alloys by SHS: reaction mechanism and anisotropy pore structure, Acta mater. 48 (2000) 38953904. [3]. S.Wisutmethangoon, N. Denmud, Influence of compaction pressure on the morphology

and phase evolution of porous NiTi alloy prepared by SHS technique, Songklanakarin
J. Sci. Technol.30 (6), 761-765, Nov. - Dec. 2008. [4]. J.Y.Xiong,Y.C.Li,X.J.Wang, Titaniumnickel shape memory alloy foams for bone tissue Engineering, JOURNAL OF THE MECHANICAL BEHAVIOR OF BIOMEDICAL MATERIALS 1(2008)269273. [5]. J.Laeng, Z.Xiu, Phase formation of NiTi via solid state reaction, Phys.Scr. T129 (2007)250254

Em xin chn thnh cm n!