Product Information

Caustic Soda Solution (NaOH 50%)

Sodium Hydroxide Solution

Brief Description
Caustic Soda Solution is a clear, colorless, odorless and slightly viscous liquid. It is miscible with water at any ratio. Caustic Soda Solution reacts strongly alkaline and is highly corrosive to various materials.

Raw Material Properties

Typical Value *
50 40 1,5 Approximately 79 Approximately 12

Test method Unit DIN

% g/Mol g/cm
3

Sodium Hydroxide (NaOH) Molecular Mass Density at 20 C Dynamic Viscosity at 20 C Freezing Point

51757 51562

mPas C

* The values given above are typical test results which should be used as a guide only. They do not form the whole or part of a specification or guarantee.

Processing and Applications

Caustic Soda Solution is a strongly alkaline product, which is applied as a chemical reactant or neutralization agent in various areas, e.g. in chemical, pharmaceutical, textile, pulp and paper, metal and food industries, for agriculture, soap and detergent manufacturing or waste water treatment. Caustic Soda Solution reacts strongly alkaline and is highly corrosive and aggressive to various materials such as aluminium, magnesium, zinc, glass, emaille and many plastic products.

Vinnolit = registered trademark of Vinnolit GmbH & Co. KG, Germany

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Packaging, Delivery and Storage

Caustic Soda Solution is transported via railcar or road tanker. Above 25 and for long storC age times, Caustic Soda Solution should be kept away from air. If exposed to air, Caustic Soda Solution will pick up carbon dioxide to form sodium carbonate, which may cause haze of the solution. In order to prevent carbonate formation, storage vessels should have minimized exposure to air, but a venting possibility to equilibrate pressure during unloading or transfer processes. Heatable storage containers for Caustic Soda Solution are recommended in order to prevent crystallization during the cold season. Caustic Soda Solution starts to freeze at temperatures as high as 10-12 When stored C. properly under the conditions recommended, Caustic Soda Solution has a virtually unlimited shelf life.

General Information
Safety data, transport information and toxicological data are provided in the current EU safety data sheet. Some applications for this product can be subject to national and / or international standards (food additives, wastewater treatment, in the Pharmaceutical Industry,..). The customer is solely liable for ensuring that all existing patents and regulations are respected applicable to our products and their applications. We assume that NaOH 50% is free from organic traces/impurities. Caustic soda is produced in a complete inorganic and closed process. Furthermore the rail tank waggons are used for transportation of NaOH only. For road tank cars and ship tanks we arrogate an applicable cleaning certificate before filling them with NaOH. All traces and impurities can be seen from our standard delivery specification.

Food Compliance
NaOH 50% fulfils the criteria of purity for food additives according to ZusatzstoffZulassungsverordnung (ZZulV), ZusatzstoffVerkehrs-Verordnung (ZVerkV), Food Chemicals Codex (FCC) and of products for water treatment concerning to human applications referred to DIN EN 896. NaOH is registered within the EU as a food additive E 524. Diluting NaOH 50% you strictly have to aviod procedures where microorganisms could be transported into the product (e.g. using cleaned and sterile containers/vessels, sterile pure VE-water, short time storages, convenient temperature etc.).

For requests please contact our marketing and sales contacts.

The data and recommendations contained in this product information represent the current state of our knowledge and serve as a guide only to our products and their potential applications. Therefore, no warranty of specific properties o f the products mentioned herein nor of their suitability or fitness for a particular purpose is implied. The information given in this leaflet should be checked by preliminary trials because of conditions during processing over which we have no control, especially where other companies' raw materials are also used. Patent or other proprietary rights of third parties must be observed. The quality of our products is warranted under the terms of our General Conditions of Sale

Ismaning, 10. January 2011 Vinnolit GmbH & Co. KG Carl-Zeiss-Ring 25 D-85737 Ismaning Tel. : +49 89 9 61 03-0 Fax: +49 89 9 61 03-103 www.vinnolit.com

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Dynamic viscosity of various Caustic Soda Solutions as a function of temperature [mPas] NaOH % (m/m) 10 20 30 33 40 45 50 20 C 1,7 4,5 13,0 19,0 39,0 57,0 79,0 30 C 1,45 3,2 8,5 12,0 22,0 29,0 44,0 40 C 1,2 2,5 6,0 7,5 14,0 18,5 25,0 50 C 0,95 1,9 4,5 5,4 9,0 11,5 16,0 60 C 0,78 1,6 3,3 3,9 6,4 7,9 10,0 70 C 0,66 1,3 2,5 3,1 4,8 5,9 7,5 80 C 0,55 1,1 2,0 2,4 3,7 4,5 5,5 90 C 0,47 0,85 1,6 1,9 2,9 3,5 4,4 100 C 0,40 0,7 1,3 1,5 2,4 2,8 3,4

Dynamic viscosity of various Caustic Soda Solutions as a function of temperature

90 80 70 60 50 40 30 20 10 0 20 C 30 C 40 C 50C 60C 70C 80 C 90 C 100 C Temperature at ( C) NaOH % (m/m) 10 20 30 33 40 45 50 dyn. viscosity at (mPas)

The data and recommendations contained in this product information represent the current state of our knowledge and serve as a guide only to our products and their potential applications. Therefore, no warranty of specific properties o f the products mentioned herein nor of their suitability or fitness for a particular purpose is implied. The information given in this leaflet should be checked by preliminary trials because of conditions during processing over which we have no control, especially where other companies' raw materials are also used. Patent or other proprietary rights of third parties must be observed. The quality of our products is warranted under the terms of our General Conditions of Sale

Ismaning, 10. January 2011 Vinnolit GmbH & Co. KG Carl-Zeiss-Ring 25 D-85737 Ismaning Tel. : +49 89 9 61 03-0 Fax: +49 89 9 61 03-103 www.vinnolit.com

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Density of various Caustic Soda Solutions as a function of temperature

NaOH %(m/m) 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 50 52 54 56 58 60

0 C 1,024 1,048 1,071 1,094 1,117 1,140 1,162 1,185 1,207 1,230 1,252 1,274 1,296 1,318

10 C 1,023 1,046 1,068 1,091 1,113 1,136 1,158 1,180 1,202 1,224 1,247 1,269 1,291 1,312 1,334 1,355

20 C 1,021 1,043 1,065 1,087 1,109 1,131 1,153 1,175 1,197 1,219 1,241 1,263 1,285 1,306 1,328 1,349 1,370 1,390 1,410 1,430 1,449 1,468 1,487 1,506 1,525

30 C 1,018 1,039 1,061 1,083 1,104 1,126 1,148 1,170 1,192 1,214 1,235 1,257 1,279 1,300 1,322 1,343 1,363 1,384 1,404 1,423 1,443 1,462 1,481 1,500 1,518 1,534

40 C 1,014 1,035 1,056 1,078 1,100 1,121 1,143 1,165 1,186 1,208 1,230 1,251 1,273 1,294 1,315 1,336 1,357 1,377 1,397 1,416 1,436 1,455 1,473 1,492 1,511 1,530 1,549 1,568

50 C 1,010 1,031 1,052 1,073 1,094 1,116 1,137 1,159 1,181 1,202 1,224 1,245 1,267 1,288 1,309 1,330 1,350 1,370 1,390 1,410 1,429 1,448 1,466 1,485 1,504 1,524 1,543 1,562 1,581

60 C 1,005 1,026 1,047 1,068 1,089 1,110 1,132 1,153 1,175 1,196 1,218 1,239 1,261 1,281 1,302 1,324 1,343 1,363 1,383 1,403 1,422 1,441 1,459 1,478 1,497 1,517 1,536 1,556 1,576

70 C 0,999 1,020 1,041 1,062 1,083 1,104 1,126 1,147 1,169 1,190 1,211 1,232 1,254 1,275 1,296 1,317 1,337 1,357 1,376 1,396 1,415 1,434 1,452 1,471 1,490 1,510 1,530 1,550 1,570 1,590

80 C 0,993 1,014 1,035 1,056 1,077 1,098 1,120 1,141 1,162 1,183 1,205 1,226 1,247 1,268 1,289 1,310 1,330 1,350 1,370 1,389 1,408 1,427 1,445 1,464 1,483 1,503 1,523 1,543 1,563 1,583

90 C 0,987 1,008 1,028 1,050 1,071 1,092 1,113 1,134 1,156 1,177 1,198 1,219 1,241 1,262 1,282 1,303 1,323 1,343 1,363 1,382 1,401 1,420 1,438 1,457 1,476 1,496 1,516 1,536 1,556 1,576

100C 0,980 1,001 1,022 1,043 1,064 1,086 1,107 1,128 1,149 1,170 1,191 1,212 1,234 1,255 1,276 1,296 1,316 1,336 1,356 1,375 1,394 1,413 1,432 1,450 1,470 1,490 1,510 1,530 1,550 1,570

Values of solutions below 50% (w/w) taken from Int. Crit. Tables, 3rd edition, page 79; values of solutions above 50% (w/w) were determined by extrapolation.

Vinnolit = registered trademark of Vinnolit GmbH & Co. KG, Germany

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Freezing points of Caustic Soda Solutions at various concentrations.

Temperature at ( C)

Boiling points of Caustic Soda Solutions at various concentrations.

Temperature at ( C)

NaOH-Content at % (m/m)

Vinnolit = registered trademark of Vinnolit GmbH & Co. KG, Germany

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