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    Scandium triflate was used to catalyze condensation reactions between various aromatic compounds containing halogen or alkyl substituents (R groups) and an amine, producing products coded as GS-149 through GS-155. For each product, the 1H and 13C NMR spectra were identical, indicating the core structure was the same and only the R groups differed between products.

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    Scandium triflate was used to catalyze condensation reactions between various aromatic compounds containing halogen or alkyl substituents (R groups) and an amine, producing products coded as GS-149 through GS-155. For each product, the 1H and 13C NMR spectra were identical, indicating the core structure was the same and only the R groups differed between products.

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    4 views2 pages

    Code R Product

    Uploaded by

    kanilkadian
    Scandium triflate was used to catalyze condensation reactions between various aromatic compounds containing halogen or alkyl substituents (R groups) and an amine, producing products coded as GS-149 through GS-155. For each product, the 1H and 13C NMR spectra were identical, indicating the core structure was the same and only the R groups differed between products.

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    of 2

    R OH H3CO N H

    Sc(OTf)3, 10 mole% DCM , 40 C , 24h

    H3CO N H N H

    OCH3

    CODE

    PRODUCT

    GS-149

    Cl

    Cl

    H3CO N H N H

    OCH3

    GS-150

    Br

    Br

    H3CO N H N H
    S H3CO N H N H

    OCH3

    GS-151
    S OH

    OCH3

    GS-152

    H
    H3CO N H N H OCH3

    GS-153

    CH3

    CH3

    H3CO N H N H

    OCH3

    GS-154

    H3CO N H N H OCH3

    OCH3

    GS-155

    OCH3

    H3CO N H N H

    OCH3

    For all these compounds, NMR spectras are same .


    1

    H NMR:

    13 aromatic protons (except cdcl3 proton at 7.26/7.24) 12 aliphatic protons.


    13

    C NMR:

    14 aromatic carbons 4 aliphatic carbons

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