KIM TRA CUI CNG Cu I: (1,5 im) 1.

T vi, than v cc cht v c cn thit, hy vit cc phng trnh phn ng iu ch benzen, cao su buna (ghi r iu kin phn ng nu c). 2. t hn hp gm cacbon v lu hunh trong kh oxi d, thu c hn hp kh A. Cho kh A li qua dung dch NaOH thu c dung dch B v kh C. Cho kh C qua hn hp cha CuO v MgO nung nng thu c cht rn D v kh E. Cho kh E li qua dung dch Ca(OH)2 thu c kt ta F v dung dch G. Thm dung dch KOH vo dung dch G li thy kt ta F xut hin, un nng G cng thy xut hin kt ta F. Hy xc nh thnh phn A, B, C, D, E, G, F v vit cc phng trnh phn ng xy ra. Cu II: (0,75 im) C 3 l b mt nhn cha cc dung dch: - L X gm K2CO3 v NaHCO3 - L Y gm KHCO3 v Na2SO4 - L Z gm Na2CO3 v K2SO4 Ch c dng dung dch BaCl2 v dung dch HCl. Nu cch nhn bit cc l v vit cc phng trnh phn ng ha hc minh ha.

Cu VI (2,0 im). 1. Cho 0,01 mol mt este X phn ng va ht vi 100 ml dung dch NaOH 0,2M, sn phm to ra ch gm mt mui v mt ancol u c s mol bng s mol este, u c cu to mch cacbon khng phn nhnh. Mt khc x phng ho hon ton 2,61 gam este X bng dung dch KOH va , th va ht 200 ml KOH 0,15M v thu c 3,33 gam mui. Vit cng thc cu to ca X? 2. Trong cht bo khng tinh khit thng cn ln mt lng nh axt mncacboxylic t do. S miligam KOH cn trung ho axit t do c trong 1g cht bo gi l ch s axit ca cht bo. a) Tnh khi lng NaOH cn trung ho 1g cht bo c ch s axit bng 7. b) x phng ho 20kg cht bo ni trn ngi ta un n vi dung dch cha 71mol NaOH. Sau khi phn ng kt thc, mun trung ho hn hp cn 1lt HCl 1M. Tnh khi lng glixerin v khi lng x phng nguyn cht thu c. c) T cc d kin thu c trn, tm phn t khi trung bnh ca cc axit bo bit rng cu to ca cc axit bo t do cng ging nh axit bo trong phn t cht bo.