Azeotropic dataII

AZEOTROPIC
DATAII
Compiled by LEE H. HORSLEY

The Dow Chemical Co.
Midland, Mich.
With the cooperation of WILLIAM S. TAMPLIN

Union Carbide Chemicals Co.
South Charleston, W. Va.
Number 35
ADVANCES IN CHEMISTRY SERIES
American Chemical Society
Washington, D. C.
1962
Copy r igh t
1962
AMERICAN CHEMICAL SOCIETY
All Rights Reserved
L i b r a r y of Congress Catalog C a r d 52-3085

PRINTED IN THE UNITED STATES OF AMERICA

Robert F. Gould, Editor
AMERICAN CHEMICAL SOCIETY APPLIED PUBLICATIONS
ADVISORY BOARD
Allen L. Alexander
John H . Fletcher
Wayne W. Hilty
Walter C. Saeman
William J. Sparks
Calvin L . Stevens
Glenn E. Ullyot
Calvin A. VanderWerf
George W. Watt
INTRODUCTION
This volume is a supplement to "Azeotropic Data" published as A D V A N C E S I N
6, American Chemical Society (1952).
It includes revised data on systems in the original table plus new data on
azeotropes, nonazeotropes, and vapor-liquid equilibria collected since 1952. No
attempt has been made to evaluate the data. Where appreciable differences occur
in data from different sources, more than one set of data is recorded. Where
minor differences occur, only one set of data is recorded, but all references are
cited.
A brief description is included for calculating azeotropic data for immiscible
systems from vapor pressure data.
In general data have been obtained from the original literature. Where the
original literature was not available, data have been taken from Chemical
Abstracts. In a few instances, data have been taken from collections of azeotropic
data in handbooks, review articles, and so forth.
Acknowledgment is made to Commercial Solvents Corp., The Dow Chemical
Co., Eastman Chemical Products Inc., Farbenwerke Hoechst, Imperial Chemical
Industries Limited, Minnesota Mining and Manufacturing Co., and Union Carbide
Chemicals Co. for supplying unpublished data for inclusion in the tables.
The tables are arranged in the same manner as the previous volume. This is
based on empirical formula as in Chemical Abstracts except that all inorganic
compounds are listed first, alphabetically by empirical formula.
For a given binary system the lower order component according to empirical
formula is chosen as the -component and under each -component the B-components are also arranged according to empirical formula. For ternary and
quarternary systems the same arrangement is used, using the lowest order formula
as -component, the next lowest order as B-component, and so on.
With a few exceptions for common chemical names, nomenclature in the
tables follows the Chemical Abstracts nomenclature system.
C H E M I S T R Y SERIES N O .
Abbreviations
max. b.p.
min. b.p.
atm.
mm.
p.s.i.a.
p.s.i.g.
v-1.
v.p.
vol. %
r^>
>, <
Maximum boiling point azeotrope (negative azeotrope)

Minimum boiling point azeotrope (positive azeotrope)
Pressure in standard atmospheres
Pressure in millimeters of Hg
Pressure in pounds per square inch absolute
Pressure in pounds per square inch gage
Vapor-liquid equilibrium data are given in the original reference
Vapor pressure
Azeotropic concentration is given in volume per cent. Unless so
indicated, all concentration data are in weight %
Approximate
Greater than, less than
1
ADVANCES
IN
CHEMISTRY
SERIES
Corrections for Azeotropic DataI

The following errors appeared in "Azeotropic Data,"
ADVANCES IN CHEMI ST R Y
S E R I E S N O . 6.
Page
4
6
System
65
131
7
8
9
10
13
19
23
176
240
281
306
482
834-835
1059-1060
28
33
83
114
123
1389
1696
4708-4709
6546
149
154
8651
8920
Replace -component, thionyl chloride, with sulfuryl chloride.

Azeotropic composition is 7.9 wt. % . This is an error in the
original reference.
Formula should be C H N 0 .
Replace 57% with 43% for azeotropic composition.
This system should follow system 277.
Replace "cyclohexane" with "cyclohexene."
Replace 6.32 by 6.32 for b.p. of methylamine.
-component formula is C H B r .
Between systems 1059 and 1060 insert:
A = C H I Diiodomethane b. 181 C.
Replace 59.05 with 49.05 for azeotropic b.p.
-component formula is C H B r C l .
Replace 43.6 with 38 for -component b.p.
Replace 11 with 154.5 for azeotropic b.p.
Between system 7090 and 7091, omit:
A = C4H9I l-Iodo-2-methyl propane.
Replace reference 244 with 243.
Replace C H 0 , 2-[2- (2-methoxyethoxy ) ethoxy]-ethanol,
with C H 0 , 2-(2-ethoxyethoxy)ethanol, and insert after
system 8909.
% B-component should be 93.4%.
% -component should be 8.5%.
Formula C 1 0 S .
Replace thionyl chloride with sulfuryl
chloride.
Under C H 0 , pyrocatechol, replace system 3510 with 3570.
Formula C H .
Replace 3-ethylheptane with 3-methylheptane.
3
284
296
251 14519
257 14658
267
1 6
1 4
1 8
INTRODUCTION
Calculation of Azeotropic Data for Immiscible Systems

There are many binary heterogeneous azeotropes which are not listed in the
literature because the azeotropic data can readily be calculated from the vapor
pressure data of the components.
For a mixture of two completely immiscible liquids the total vapor pressure
is equal to the sum of the vapor pressures of the two components at a given temperature. Therefore, from a plot of the vapor pressures of the two components,
it is possible to determine the temperature at which the sum of the vapor pressures is equal to 760 mm. This temperature is the azeotropic boiling point of the
system at 760 mm. The boiling point at any other pressure can be obtained in a
similar manner.
Further, the azeotropic composition can be calculated from the expression
Mole % A
V
V
100
= vapor pressure of component A

= vapor pressure of component
Table I.
Binary Systems
B-Component
No.
Formula
A
1 o
BeF
Germanium
Ethyl
chloride
ether,
25-100
p.s.i.g.
Bromine T r ifluo r ide
Bromine
Bromine,
"
Hydrogen
Uranium
8 F H
9 F U
6
BrF
pentafluoride
1760 m m .
3800 m m .
fluoride
hexafluoride
Hydrogen fluoride
4 atm.
Uranium hexafluoride
"
3 atm.
.1
o
"
90
"
100 p . s . i . a .
F U
6
7 0
Br
F H
F U
CC1
15
C C1 F
16
C C1 F
17
C HC1 F
18
C H C1 F 2
19
20
^7^5F
21
Cn
Br P
2
86.5
Nonazeotrope
v-1
298
v-1
299
...
Nonazeotrope
v-1
206
Nonazeotrope
75
84.4
100
81.5
Azeotropic
Nonazeotrope
v-1
v-1
v-1
200
101
101
91
91
135
...
...
19.4
56
19.4
56
...
. .
...
20
56
79
M i n . b.p.
82
Nonazeotrope
Nonazeotrope
Nonazeotrope
62.5
v-1
v-1
v-1
4,91
91
91
203
203
203
91
Hydrogen fluoride
Carbon tetrachloride,
736 m m .
l,l,2-Trichloro-l,2,
2 -1 r i f l u o r o e t h a n e
1,1,1,2- Te trachl or 0 2,2 - d i f l u o r o e t h a n e
l,2,2-Trichloro-l,ldifluoroethane,
736 m m .
l,l-Dichloro-2,2difluoroethane,
735 m m .
l,2,2-Trichloro-l,l,
3,3,3-pentafluoropropane
a, a, a - T r i f l u o r o t o l u e n e
19.4
56
91
91
Azeotropic
Azeotropic
76
57.7
89.1
v-1
311
47.6
41
40.8
v-1
312
91.6
57.8
89.5
v-1
312
71.1
54.1
73.5
v-1
313
59
49.6
62
v-1
313
72.5
103.9
49.1
58.1
60.5
97
v-1
v-1
312
312
Phosphorus T r i b r om i d e 175.3
71
232
340
237
58.9
Bromine
12
13
14
v-1
v-1
v-1
v-1
Bromine Pentafluoride
F H
11
11
...
...
...
...
Nonazeotrope
Nonazeotrope
Diborane
10
...
...
Sodium fluoride,
509-1061C.
2_ 6
BrF
Ref.
Be r yllium Fluor ide
FN a
6 BrF
7 B r
Wt.%A
130
A r senic Chloride
3
4
B.P.,C.
Data
-186
-183
1-15 a t m .
90-96K.
Perfluoropentane, 25C.
AsCl
B.P.,C.
Oxygen
C 5 F 1 2
Name
Argon
3 GeCl
Azeotropic
Paraffin
hydrocarbons
Min.
b.p.
234
ADVANCES
IN
Azeotropic
B-Ccmponent
No.
A=
Formula
Name
Ca r bon Dioxide
Hydrogen sulfide,
20-80 a t m .
CO 2
22 H S
2
23 N 0
24 C H
N i t r o u s oxide
Acetylene
'
Crit. press.
E t h y l e n e , <4 a t m .
12 a t m .
"
Crit. press.
Ethane
"
Crit. press.
25
C H
2
26
C H
A =
C1F
11
Chlor ine T r i f l u o r i d e
Hydrogen chloride
Hydrogen fluoride
"
1183 m m .
90 p . s . i . g .
"
125 p . s . i . g .
143 p . s . i . g .
"
148 p . s . i . g .
27 c m
28 F H
B.P.,C.
-59.6
-90.7
-84
.. .
.. .
-88.6
...
A =
A =
Cl
33 F H
C1 S0
2
34 CCI4
35 C C 1
36 C H C 1
2
37 C H C12
2
A =
CI3HS1
38
A =
C H
6
C H
C H
C H
cWie
C Hi
C H
6
1 2
1 4
1 6
1 6
Cl Si
4
45 CH3S1CI3
46 C H S i C l
4
A =
Cl Sn
47 C C I .
4
Nonazeotrope
v-1
Min. b.p.
Nonazeotrope
Nonazeotrope
Nonazeotrope
28.9
51
59.5
77.5
v-1
v-1
v-1
v-1
v-1
v-1
v-1
v-1
16,
17
293
293
293
293
293
293
293
293
4
91
90
91
91
91
91
89,
91
Hydrogen Chlo r ide

C h l o r i n e , 350 m m .
W a t e r , 100 p . s . i . g .
"
520 p . s . i . g .
860 p . s . i . g .
"
1360 p . s . i . g .
"
1815 p . s . i . g .
Methanol
-85
-44
169
244
275
306
328
64.7
Nonazeotrope
177
85.2
250
93.5
280
97.2
310
99.4
330
99.9
Max. b.p.
Chlor ine
Hydrogen fluoride,
350 m m .
-34.6
Sulfuryl Chlor ide

Carbon tetrachloride
Hexachloroethane
1,1,2,2,-Tetrachloroethane
1,2- D i c h l o r o e t h a n e
69.1
76.75
184.8
Nonazeotrope
Nonazeotrope
v-1
v-1
338
338
146.2
83.45
Nonazeotrope
Nonazeotrope
v-1
v-1
338
338
3.0
19.4
Trichlorosilane
Benzene, 30-40C.
CI3P
39
40
41
42
43
44
A =
Ref.
B.P.,C. W t . % A
56*
11
32 C H . O
Data
Reacts
Azeotropic
20
93
94.5
94
93.8
93.7
Nonazeotrope
-85
19.4
11
SERIES
-78.5
11
C1H
30 C l
31 H 0
CHEMISTRY
Phosphorus T r i c h l o r i d e
Cyclohexane
Hexane
2.2- Dimethylpentane
2,2,3 - T r i m e t h y l b u t a n e
76
80.75
68.8
79.1
89.8
80.5
80.9
Silicon T e t r achlo r ide

Methyl trichlorosilane, 20-66
Methyl dichlorosilane, 20-66
57.6
T i n Chlor ide
Il-Octane
.
114.1
76.8
125.7
-47
-35
v-1
v-1
4
334
334
334
334
334
76
4
4
92
Nonazeotrope,
v.p. curve
302
Nonazeotrope
68.7
8 v o l .%
234,
M i n . b.p.
74.5
98.8 v o l . %
74.2
73
74.5
77
236
234
236
234
234
234
Nonazeotrope,
v.p. curve
Nonazeotrope,
v.p. curve
Nonazeotrope
Nonazeotrope
179
179
v-1
v-1
34
34
TABLE
BINARY
SYSTEMS
Azeotropic Data
-Component
No.
Formula
CI4T1
4 9 2CI4O
50 C2H2CI2O
51 C2H2CI4
A=
DH
52 D
53 H
D
54 H
A =
B.P.,C.
Titanium T e t r achlo r ide

146.2
Trichloroacetyl
chloride
118
Chloroacetyl chloride
105
1,1,2,2- Tetrachlor
ethane, 740 m m .
136.6
Deuterium Hydride
Deuterium, 18-28K.
H y d r o g e n , 18 - 2 8 K .
-249.7
-252.7
Deuterium
-249.7
A =
Name
Hydrogen, 18-28 K .
FH
55 F S b
56 F U
5
-252.7
Hydrogen F l u o r i d e
19.
Antimony pentafluoride 142.
"
85 p.s.i.g.
110 p . s . i . g .
"
132 p . s . i . g .
145 p . s . i . g .
Dichlorodifluoromethane,
150 p . s . i . g .
48
Chlorodifluoromethane
7
70 p . s . i . g .
150 p . s . i . g .
29
"
230 p.s.i.g.
45
Trifluoroacetic acid
Nonazeotrope
Nonazeotrope
135.4
Nonazeotrope
Nonazeotrope
58 CHC1F
11
11
5 9 C2HF3O2
A=
60
F S
C F
61
F W
CjFxo
A=
6 2 C5F
A =
12
HNO3
63
H2O
Sulfur Hexafluoride
Perflnoropentane, 25C,
Tungsten Hexafluoride
Perfluorocyclopentane
Perfluoropentane,
1140 m m .
Nitric Ac i d
Water,
50m
100 m
200 m
400 m
760 m
11
11
11
11
6 4 CHCI3
H 0
H 0
2
65
66 H2SO4
H4N2
Water
Hydrogen peroxide
Hydrogen sulfate
200 m m .
Hydrazine,
124.8 m m .
281.8 m m .
"
411.2 m m .
"
560.4 m m .
700.6 m m .
760 m m .
Nitrogen pentoxide
11
11
11
68 N2O5
M
II
69 C S
70 CHCI3
71 CH2O2
.
.
.
.
.
Chloroform
11
67
m
m
m
m
m
v-1
v-1
300
300
v-1
32
v-1
v-1
238
238
v-1
238
v-1
301
91
91
91
91
22
18
15
14
11
CC1 F
91.7
Nonazeotrope
Nonazeotrope
11
57
Ref.
B.P.,C. W t . % A
7.5
334
3
<7
2.7
24
2.8
36
Nonazeotrope
v-1
334
334
334
222
Nonazeotrope
v-1
237
39
25/1019; 45/1982 m m .
25/833
45/1642
40.86
86
37
51.6
66.5
83.0
100
See a l s o
61
25/1035
45/2010
85.4
83.4
v-1
v-1
288
288
28.11
93.2
v-1
13
13.7
13.8
14.0
14.2
14.4
v-1
v-1
v-1
v-1
v-1
19
19
19
19
19
57.8
72.4
86.4
103.2
120.7
H2O-N2O5
47.5
below
15
258
100
. . . 330
..
...
...
66.8
86.5
96.8
105.2
111.7
113.8
...
.. .
4...
6.5
Carbon disulfide
Chloroform
61
F o r m i c a c i d , 40-760 m m . . . .
II
100.75
74.2
93.3
103.6
111.3
117.6
120
Max. b.p.
Min. b.p.
Max. b.p.
43.6
56.1
...
107.65
v-1
1.7
1.6
33.2
32.3
31.0
31.4
32.6
32.3
40
14.3
12.5
2
2.8
...
25.5
104
334
334
30
30
30
30
30
30
199
199
199
334
56
v-1
42
v-1
56,
217, 360
v-1
v-1
v-1
v-1
v-1
v-1
v-1
ADVANCES
IN
B-Component
No.
Formula
H2O
Azeotropic
B.P.,C.
Water (continued)
72
73
CH N0
CH 0
74
C j C L j F a
75
C 2 C 1
76
C 2 H F 3 O 2
7 7
C j H g c y s r O a
Nitromethane
Methanol
1,1,2 - T r i c h l o r o t r i fluoroethane
Tetrachloroethylene
78
C2H3CI3
79
C H N
80
C 2 H
Name
C 1
Methyl N,N-dichlorocarbamate
1,1,2-Trichloroethane
A c e t o n i t r i l e , 10 m m .
"
50 m m .
"
760 m m .
1,2 - D i c h l o r o e t h a n e
M
150 m m .
"
75 m m .
Acetic acid
2 -Bromoethanol,
150 m m .
2-Chloroethanol,
50 m m .
"
100 m m .
Nitroethane
Ethyl alcohol,
150-350 C .
250-2500 m m .
Ethylene glycol,
76-760 m m .
2 - Aminoethanol
"
100 m m .
1,1 - D i m e t h y l h y d r a zine,
102 m m .
11
81
82
83
84
85
4
C HsBrO
2
C 1 0
C H5N0
C H60
2
11
86
C He0
87
C H NO
88
C H N
II
89
90
C HF 0
91
C 3 H 3 N
1,2 - E t h y l e n e d i a m i n e
"
>3400 m m .
H e N 2
II
92
93
94
95
96
97
98
99
C3H3NS
C3H 0
C H 0
C H 0
C H 0
CjEUCl
4
C 1
C H NO
3
100
C g H g C i p
101
C H 0
3
11
102
103
C H 0
C HÔ
3
II
104 C H p
105 C ^ Q ,
106 C a H O a
3
Propylene oxide
1,3-Dioxolane
Ethyl formate
B.P.,C.
SERIES
Data
Wt.%A
Ref.
100
101.2
64.7
83.59
23.6
Nonazeotrope
54, 55
v - -1
68
47.5
121
121
...
44.5
88.5
87.7
105
1.0
17.2
15.8
21
334
334
17d
222
...
93
113.8
-15
13
80.1
83.5
...
...
...
118.1
86.0
16.4
2.6
<-16
<12
5.8
16.3
76.5
8.2
71.6
8.2
75.5
4.9
33.5
19.0
4.9
Nonazeotrope
100
58
60
75
114.07
37.1
51.1
87.22
60.2
59.3
28.5
...
.. .
. ..
...
...
...
.. .
Nonazeotrope
Nonazeotrope
Nonazeotrope
.. .
82.5
Max. b.p.
Nonazeotrope
18.0
Nonazeotrope
119
18.4
170.5
112
116
...
77.2
.. .
111.5
52.8
115
141.2
...
44.9
.. .
229.7
183.8
56.1
.. .
...
...
...
...
96.90
47.9
...
35
75.6
54.2
109
10
14.3
70.6
90
34.8
92.1
35.3
52.4
2.6
97
54.5
Nonazeotrope
Nonazeotrope
2.2
43.0
0.9
33
Nonazeotrope
99.4
87
Nonazeotrope
Nonazeotrope
5.2
125.4
7.2
157.6
9.4
168.4
206.0
14.3
...
39
50 v o l . %
55.7
116.9
Pentafluoropropionic
acid
Acrylonitrile
T h i a z o l e , 695.5 m m .
"
750 m m .
Acrolein
2-Propyn-l-ol
Acrylic acid
Ethylene carbonate
3 -Chloropropene
M ethylvinyl chloride
Hydr acrylonitrile
2,3-Dichloro-lpropanol
Acetone
"
50 p . s . i . a .
"
100 p . s . i . a .
"
200 p . s . i . a .
250 p . s . i . a .
500 p . s . i . a .
A l l y l a l c o h o l , 752 m m .
Propionaldehyde
11
CHEMISTRY
...
2
47.5
2.5
47.5
Nonazeotrope
7
71.9
5
52.6
v - -1
334
336
336
336
334
55
55
55
56
76
334
334
54, 55
v --1
v --1
14
251
v --1
60
334
334
v - -1
v - 1
v - -1
v --1
V " -1
v --1
V -1
v --1
V -1
v --1
v --1
37
37
76
76
334
222
334
219
219
334
95
334
334
334
334
334
334
254
254
254
254
254
254
130
334
84
60
334
334
TABLE
BINARY
SYSTEMS
-Component
No.
Formula
H 0
Name
B . P . / C .
Water (continued)
107
108
Azeotropic
C H 0
3
92
109
110
111
C H C1
C H C1
C H NO
3
56^
"
265 m m .
30
1 -Chloropropane
46.6
2 -Chloropropane
36.5
Dimethylf or mamide,
500 m m .
138
200-760 m m .
>
1 -Nitropropane
131.18
2 -Nitropropane
120.25
P r o p y l a l c o h o l , 47 m m . .. .
"
200 m m .
11
112
113
114
C H N0
C H N0
C H O
3
11
"
400
600
Wt.%A
88.5
12.8
77
Nonazeotrope
56.1
5
30
1.5
44
2.2
35.0
1
131
334
334
334
334
Nonazeotrope
Nonazeotrope
91.63
36.5
88.55
29.4
31.8
56.68
29.6
334
319
54, 55
54, 55
117
v-1 228,
306
v-1
306
v-1
306
v-1
306
72
v-1
71.92
29.0
81.68
28.5
87.65
28.3
In 1.5M C a C l Solution
mm.
mm.
II
II
115
C3H O
Isopropyl alcohol,
95 m m .
"
190 m m .
"
380 m m .
760 m m .
3087 m m .
150-300
...

82.5
11
11
11
C.
II
II
116
C He0
3
2-Methoxyethanol,
100 m m .
752 m m .
"
150 m m .
"
760 m m .
"
100 p . s . i . g .
1,2 - P r o p a n e d i o l
1,3- P r o p a n e d i o l
Propylamine
Trimethylamine
11
117
118
119
120
C H 0
C H 0
C ^ N
CaHN
3
" o-ioo c.
121
122
123
124
125
C
C
C
C
C
126
C H 0
H9NO
HF 0
H5N
HjN
H C1N
7
1 -Amino - 2 -propanol
Perfluorobutyric acid
3-Butenenitrile
Methac rylonitrile
2 - C h l o r o -2 - m e t h y l propionitrile
C rotonaldehy de,
111 m m .
273 m m .
412 m m .
11
II
127
128
129
130
131
132
133
134
135
136
cfto
C H N
C H NO
4
M ethac r ylaldehyde
3-Butenoic acid
trans-Crotonic acid
Crotonic acid
Butyrolactone
V i n y l acetate
Propylene carbonate
2-Chloroethyl vinyl
ether
Butyronitrile
2-Hydroxyisobutyron i t r i l e , 30 m m .
50 m m .
11
Ref.
100
2 -Methoxyacetalde h y d e , 770 m m .
Methyl acetate,
<10 p . s . i . a .
B.P.,C.
Data
36
49.33
63.90
80.10
120.45
13
12.8
12.6
12.0
11.7
Evaporation data
.. .
E f f e c t of d i s s o l v e d s a l t
.
...
79.2
124.6
212
188
214.8
47.8
3.2
...
159.9
122.0
118.9
.. .
51.5
80.5
99.2
81
Nonazeotrope
99.9
84.7
169
73.3
Nonazeotrope
Nonazeotrope
Nonazeotrope
75.5
10
Nonazeotrope
97
71
89.4
34
76.5
16
116
87
22
84.9
112.3
126.4
102.4
40
60
70
84
19
22
23
24.8
68.0
185
...
204.3
72.7
242.1
109.1
117.6
...
63.6
7.7
Nonazeotrope
Nonazeotrope
99.9
97.8
Nonazeotrope
66
7.3
Nonazeotrope
84
88.7
17
32.5
Nonazeotrope
Nonazeotrope
v-1
v-1
v-1
v-1
v-1
v-1
v-1
v-1
v-1
v-1
v-1
v-1
v-1
v-1
347
347
347
347
347
14
196
265
152
152
334
334
334
60
334
334
148
148
334
222
334
269
269
334
334
334
96,
142, 334
269, 334
334
334
84
334
334
334
334
334
334
334
ADVANCES
IN
B-Component
Formula
H 0
B . P . / C .
Water (continued)
137
C H C1 0
138
C H 0
Name
Azeotropic
Bis(2-chloroethyl)
ether
2 -Butanone
"
3.5 p . s . i . g .
9.2 p . s . i . g .
30 p . s . i . g .
"
60 p . s . i . g .
14.7 p . s . i . a .
"
50 p . s . i . a .
"
100 p . s . i . a .
250 p . s . i . a .
500 p . s . i . a .
179.2
79.6
11
11
11
t!
C H30
Butyraldehyde
II
140
141
142
143
C f t O
c ^ o
C HeOS
4
Ethyl vinyl ether

I sobuty raldehyde
Methyl propenyl ether
2 -Methylthiopropionaldehyde, 85 m m .
"
412 m m .
753 m m .
759 m m .
1,4-Oxathiane
p-Dioxane
~
"
260 m m .
Ethoxyacetaldehyde
2 - Hydr oxybutyr a l d e h y d e , 80 m m .
Isobutyric acid
3 -Methoxypropional d e h y d e , 100 m m .
2 - M e t h y l-1,3 -dioxolane
Methyl propionate
2-Vinyloxyethanol
Morpholine
N-(2-Hydroxyethyl)
acetamide
Butyl alcohol
250-2500 m m .
"
30 m m .
sec-Butyl alcohol
11
11
144
145
C HeOS
C He0
146
147
C He0
148
149
C Hg02
C
150
151
152
153
154
C H 0
CÔ?.
CêOz
C H NO
C H N0
155
C H
J>2
4
1 0
11
156
C H
4
1 0
II
20 m m .
E t h y l e t h e r , 20 p . s . i . g .
Isobutyl alcohol,
745 m m .
1,2 - D i m e t h o x y e t h a n e ,
100 m m .
11
157
158
159
CîoO
C H O
4
1 0
4 102
H
II
II
160
C H
4
1 0
2 -Ethoxyethanol,
<100 m m .
200 m m .
400 m m .
11
11
II
11
11
200
400
mm.
mm.
II
161
C H
4
1 (
P3
Diethylene glycol,
10 m m .
B u t y l a m i n e , 575 m m .
"
20 p . s . i . g .
11
162
74.8
...
35.5
63.5
46.3
Wt.%A
Ref.
98
65.5
11.0
73.4
79.3
12.1
88.0
12.5
15.8
111
18.3
125
v-1
73.3
11.6
15.9
112.2
139.0
19.3
23.4
180.7
26.4
216.1
Evaporation behavior
68.0
9.7
6.7
67.8
1.5
34.6
6.7
64.3
46.3
0.5
...
48
82
97.5
97.5
14^2
95.6
E f f e c t of d i s s o l v e d
60
...
90
105
64
60
68
63
48
salt
15.4
21.8
v-1
334
78
78
78
78
78
254
254
254
254
254
196
334
84
334
84
334
76
76
76
76
334
265
60
77
.. .
Nonazeotrope
98.8
71.8
334
84
.. .
45
30
75
8
71.0
8.2
98
65
Nonazeotrope
334
76
84
94
334
Nonazeotrope
v-1
...
...
52.4
28
87.0
v-1
26.8
32
88.5
16.0
32.2
60
2.0
334
196
251
335
352
196
334
147
334
154.5
82.5
79.7
143
128.3
...
48
99.5
.. .
II
Data
100
11
139
B.P.,C.
SERIES
99.5
27.3
62
...
35
85.2
85
...
...
134
96.5
115.6
135.6
.. .
69
106
...
...
6
10.4
10.1
Nonazeotrope
70
66.4
79
82.4
87
98.2
66.4
85
82.4
76
71.2
99.4
Nonazeotrope
Nonazeotrope
1.3
69
6.5
v-1
335
CO CO
No.
CHEMISTRY
76
v-1
v-1
v-1
v-1
v-1
18
18
18
18
334
334
334
60
60
334
334
TABLE
BINARY
SYSTEMS
11
B-Component
No.
Formula
Name
Water
163
(continued)
N O
2-Dimethylaminoethanol, 27 p . s . i . g .
"
744 m m .
540 m m .
250 m m .
2,2' -Iminodiethanol
2-Furaldehyde,
1-18 a t m .
Pyridine
120 m m .
758 m m .
"
>760 m m .
"
>760 m m .
"
>760 m m .
11
11
165
166
167
N 0
C H0
5
B.P.,C.
CsHgN
11
11
168
55.5
174
133.9
123.4
100.7
.. .
161.7
115.3
...
.
...
...
...
Effect
2 -Methylpyrazine,
737 m m .
133
130
2 - M e t h y l f u r a n , 740 m m . 62.7
3 - M e t h y l - 3-butene nitrile
137.0
A l l y l vinyl ether
67.4
Cyclopentanone
130.8
"
740 m m .
130
1 -Methoxy-1,3-butadiene
90.7
3-Penten-2-one
123.5
3 - M e t h y l - 3-butene 2-one
97.9
4-Pentenal
106
A l l y l acetate
104.1
Ethyl acrylate
99.5
195 m m .
61
Isopropenyl acetate,
"
200 m m .
60.2
It
97.4
Methyl methacrylate
100.8
2,4 - P e n t a n e d i o n e
140.6
-Valerolactone
V i n y l propionate
95.0
B i s (2 - c h l o r o e t h o x y )
methane
218.1
3-Dimethylaminopropionitrile
174.5
cis-l-Butenyl methyl
ether
72.0
trans-1-Butenyl
methyl ether
76.7
Isopropenyl ethyl ether
61.9
Isopropyl vinyl ether
55.7
P r o p y l vinyl ether
65.1
Tetrahydropyran
88
Vale raldehyde
103.3
Vale raldehyde s
(isomers)
98.6
Ethyl propionate,
350 m m .
76.0
3-Methoxybutyral dehyde, 100 m m .
200 m m .
II
131
II
169
170
CjHgO
C H7N
171
172
C HeO
CgHeO
173
S**
174
175
C HeO
CsHgO
176
177
178
C HeO
CjHeOj
179
C He0
A l
11
180
181
182
183
184
185
C5He0
CgH
05
05
C H
5
g^
0
0
Cl O
5 10 2
H
C H
187
C H
1 0
O
p
C 5 H 1 0 O
C5H10O
C H
5
1 0
<^5 1
C H
C H
5
1 0
1 0
O
O
194
5 102
195
5 102
1 0
186
188
189
190
191
192
193
11
B.P.,C.
Wt.%A
Ref.
100
Diethylamine
It
164
Azeotropic Data
.. .
...
E f f e c t of N a O H o n v -1
Nonazeotrope
v- 1
334
334
334
334
334
90.2
99
92.6
91
95.2
71
98.2
Nonazeotrope
3 0-
93.6
41.3
46.2
40.5
40.7
50
40.7
80
of d i s s o l v e d s a l t
150
149,
334
v- 1
216
147
117
117
v- 1
146
v- 1
146
146, 360
v- 1
265
97
92.6
57.3
55
36 v o l . %
3.4
v - 1
351
279
310
93.0
60
94.6
92.6
43.2
5.4
42.4
v - 1
36 v o l . %
334
334
334
279
76.2
92
12.7
28.6
334
334
81.5
84.3
83
81.1
48
18.4
21
16.7
15
12
334
334
334
283
334
11
48
13.4
79.3
83
14
41
94.4
Nonazeotrope
13
79
334
334
283
334
334
334
99.4
86.8
334
99.6
84
334
64
6.1
334
67
58
51.8
59
71
83
7.2
2
2.7
5
8.5
19
334
334
334
334
82
334
80
17
334
61
13.3
334
37
37
35
334
334
334
50
64
>92
ADVANCES
12
IN
-Component
No.
Formula
H 0
^5
Name
10
C5H10P2
C5H10P2
acetate,
200-700 m m .
Valeric acid
Valeric acid (isomers)
1 -Vinyloxy-2 -propanol
3 -Vinyl oxy-1 -propanol
3-Ethoxypropionic acid
3-Methoxybutyric acid
Methoxymethyl propionate
4 -Methylmorpholine
Pentane
1-Methylpiperazine
1,2 - D i m e t h o x y p r o p a n e
1-Ethoxy-2-propanol
3 -Methoxy-1 -butanol
1,5-Pentanediol
2 -Propoxyethanol
N-Methylbutylamine
1-Ethylamino-2propanol
N,N-Dimethyl-1,3propanediamine
A n i l i n e , 742 m m .
6 atm.
11 a t m .
16.4 a t m .
3-Picoline
4-Picoline
204
205
206
207
208
209
210
211
212
213
214
C H
215
C ^ N
C H O2
10
C5H10O2
C5HKJO3
C H
1 0
C H
P3
p
N O
5^12
C H
5 122
H
C5H12P2
C
5 122
H
C H
5
1 2
5 122
C H N
C H NO
C
1 3
B.P.,C.
11
11
C H N
C H N
218
219
220
221
222
223
C H N
CgHgO
C H O
...
185.5
183.2
219.2
224
225
2,5-Dimethylpyrazine
2,5-Dimethylfuran
2,4-Hexadienal
1,3-Butadienyl acetate
V i n y l crotonate
3,3'-Iminodipropionitrile
2 - E t h y l - 1 , 3 - butadiene
Cyclohexanone,
< 760 m m .
2
2
6 82
6 82
H
6 10
C H O
1 0
M
It
226
C H
6
1 0
227
228
229
230
231
232
233
C H
1 0
234
235
236
237
238
239
6 10
C H O
C
1 0
6 102
H
C6HS02
C
6 1<P
H
6 llN
C ^ J N O
H
C
C
N 0
6 12
H
C H
6
240
C6H
241
C H
6
1 2
1 2
C1 0
2
CLj0
Q
Ref.
2 -Ethylcrotonalde hyde
2-Hexenal
5-Penten-2-one
2 -Methyl - 2 -pentenal
Ethyl crotonate
V i n y l but y r a t e
Vinyl isobutyrate
Ethylene glycol
diacetate
Diallylamine
6 -Caprolactam,
50-760 m m .
2 -Methyl -2-nit ropropyl
v i n y l e t h e r , 10 m m .
Cyclohexane
4-Methyl-2-pentene
Bis(chloroisopropyl)
ether
l,2-Bis(2-chloroethoxy) ethane
Butyl vinyl ether
v - -1
89
99.8
85
99.6
~100
75
~100
75
Nonazeotrope
Nonazeotrope
307
334
334
94
94
334
334
36.1
138.0
92
132.2
161.1
242.5
151.5
91.1
95
56
24
94.2
1.4
34.6
Nonazeotrope
80
11
97.3
50.1
98.5
80
Nonazeotrope
70
98.8
82.7
15
334
334
334
334
334
334
334
334
334
334
159.4
Nonazeotrope
334
134.9
154*
93.3
171
138.5
133.9
Nonazeotrope
80.8
98.6
76.6
155
76.2
182
77.4
200
60
97
62.8
97.35
63.5
97.4
65
98.5
77.0
11.7
70
98.
35.6
93
31
92
66.9
Nonazeotrope
5.3
60.2
...
...
...
144.1
144.3
M
6
Wt.%A
100
11
216
217
B.P.,C.
Propyl
197
198
199
200
201
202
203
SERIES
Azeotropic Data
Water (continued)
196
CHEMISTRY
. ..
v --1
v --1
v --1
v --1
v --1
v --1
334
143
143
143
143
365
365
334
351
334
334
334
334
334
334
155.6
155.4
...
90
96.3
95
55
61.6
135.3
149
128.9
138.2
137.8
116.7
105.4
92.7
95.1
92.1
93.5
93.5
87.2
83.5
38
48.6
35.3
40
38
20.4
17
334
334
334
334
334
334
334
190.8
110.5
99.7
87.2
84.6
24
334
334
...
.. .
. ..
77-78
80.8
56.7
69.5
53.5
8.6
8.4
3.5
341
147
334
187.0
98.5
62.6
334
240.9
94.2
99.7
77.5
94.0
11.6
334
334
-1
v --1
V -1
121
121
334
333
TABLE
BINARY
SYSTEMS
13
Azeotropic
-Component
No.
Formula
H 0
A =
C H
6
B.P.,C.
Water (continued)
242
Name
C y c l o h e x a n o l , 42 m m .
"
57 m m .
95 m m .
158 m m .
252 m m .
385 m m .
"
570 m m .
"
684 m m .
11
.. .
.. .
160.65
160.65
116.7
83.4
128.3
118.3
35
40
50
60
70
80
90
95
97.8
90
87.5
70.5
91.0
88.5
86
84.8
82.5
80.2
77.8
75.2
72.6
70.7
69.5
74
23.7
7.8
31.3
23
169.7
194.2
205.7
97.8
99.7
99.8
61
87
92.1
11
11
243
244
245
246
247
C
C
C
C
H
H
H
H
248
249
250
C H
C H
C H
"
<760 m m .
2 -Ethylbutyraldehyde
Isobutyl vinyl ether
Hexaldehyde
2 -Methylpentanal
2-Ethylthioethyl vinyl
ether
2-Ethylbutyric acid
Hexanoic acid
4 - Hydroxy - 4 - methyl 2-pentanone
100 m m .
"
200 m m .
"
400 m m .
"
760 m m .
O
0
0
0
^12', O S
0
0
0
t !
It
251
252
253
254
255
256
257
C H
6
2-Ethyl-2-methyl1,3-dioxolane
2-Methylpentanoic acid
4 -Vinyloxy-1 -butanol
Tetrahydropyran2-methanol
2-Ethoxyethyl acetate
Methyl 3-ethoxyp r o p i o n a t e , 50 m m .
2 - (2- V inyloxyethoxy)
ethanol
6 122
6 122
C H 0
C
6 123
6 123
6 123
It
258
259
C H C1
C H >
6
1 3
1 -Chlorohexane
Cyclohexylamine,
40 m m .
70 m m .
100 m m .
200 m m .
"
300 m m .
500 m m .
"
760 m m .
Hexamethyleneimine
2,6-Dimethyl morpholine
4 -Ethylmorpholine
4 -Morpholineethanol
Hexane
2,5- Dime thylpipe r a zine
4-(2-Aminoethyl)
morpholine
1 - Pipe razine ethanol
Butyl ethyl ether
2-Ethyl-1-butanol
Hexyl alcohol
Isopropyl ether,
131 m m .
297 m m .
481 m m .
"
1520 m m .
11
11
11
11
260
261
C H
C H
262
263
264
265
C
C
C
C
266
C H
1 3
N
NO
H NO
H
N0
H
H lSr
1 3
1 4
N 0
267
C H
268
CHUO
269
270
271
C H 0
C Hi40
C , H O
1 4
N20
4
11
11
Ref.
Wt.%A
100
11
it
B.P.,C.
Data
...
.. .
.. .
123.5
143
161
169.2
117.6
196.4
187.2
156.2
Nonazeotrope
Nonazeotrope
97
66.4
90
82,6
99.5
85
87
99.6
...
334
334
334
V
V
V
V
V
-1
-1
-1
-1
-1
125
125
125
125
125
335
20
87.9
334
334
94
Nonazeotrope
97.5
55.6
334
334
88.5
99.4
M i n . b.p.
37
207.6
134.5
v - -1
374
374
374
374
374
374
374
374
374
122
334
334
334
334
50
~100
97-8
Nonazeotrope
29.7
91.8
334
94
334
334
69.0
66.0
64.1
60.7
59.1
57.0
55.8
49.5
38
38
38
38
38
38
38
81
146.6
138.3
225.5
68.7
70
99.6
96.7
46.2
Nonazeotrope
5.6
61.6
334
334
334
334
164
Nonazeotrope
334
204.7
246.3
92.2
147.0
157.1
Nonazeotrope
Nonazeotrope
11.9
76.6
96.7
58
67.2
97.8
334
334
334
335
335
51.4
72
90.9
102.5
118.9
134.5
138
22.47
41.82
54.75
92
31.7
41.9
49.0
63.6
72.7
85.3
96.4
95.5
20.0
38.0
50.0
88
2.6
3.4
4.0
7.6
334
334
334
334
ADVANCES
IN
B-Component
No. ,
Formula
H 0
2
272
273
274
275
276
277
278
279
280
QH14O
QH14O2
C6H14O2
C6H14O2
C
6 142
6 142
C H
6
6 143
H
Azeotropic
Name
B.P.,C.
W a t e r (continued)
2 - M e t h y l -1 -pentanol
4 - M e t h y l - 2 - pentanol
1,1 - D i e t h o x y e t h a n e
1,1 - D i m e t h o x y b u t a n e
1,1 - D i m e t h o x y - 2 methylpropane
2-Methyl-l,5pentanediol
3-Methyl -1,5pentanediol
B i s (2 - m e t h o x y e t h y l )
ether, 100 m m .
"
760 m m .
800 m m .
760 m m .
2 -(2 -Ethoxyethoxy)
ethanol
Diisopropylamine
1,3- D i m e t h y l b u t y l amine
Dipropylamine
-Ethylbutylamine
Hexylamine
Triethylamine
11
11
281
282
283
C H
Q>H
284
285
286
287
C
Q
C
C
288
289
290
C H
C H
QH
291
QH
292
C H
293
QH
294
C H
295
296
C7H 0
C H C10
297
298
299
C7H9N
C7H9N
300
301
C7H10O4
302
303
6 143
H
H
H
H
H
1 5
N
N
N
N
1 5
1 5
1 5
1 5
1 5
1 6
NO
NO
NO
N
N
1 5
C H
7
l 0
^7^12
C Hi20
7
7 122
H
304
7 122
305
306
C Hi204
C H 0
307
308
309
C H
C H
C H
310
1 4
2 -Butylaminoethanol
2 -Diethylaminoethanol
1 -Isopropylamino2-propanol
4-(2 - A m i n o e t h y l )
piperazine
N,N-Diethylethylenediamine
, , ', '-Tetramethylethylene diamine
Toluene
II
0
0
0
40
Guaiacol
2 -Chloroallylidene
diacetate
2,6-Lutidine
Tetrahydrobenzonitrile
1,2,3,6 - T e t r a h y d r 0 benzaldehyde
Allylidene diacetate
2,4-Dimethyl-1,3-pen t a d i e n e , 750.6 m m .
3-Hepten-2-one
Butyl acrylate
II
A m y l acetate
B.P.,C.
SERIES
Data
Wt.%A
Ref.
100
148
131.8
102.1
114
120.3
97.2
94.3
82.6
87.3
89.6
60
43.3
14.3
20.3
30
334
334
334
334
334
104.7
83.9
14.3
334
242.4
Nonazeotrope
334
248.4
Nonazeotrope
334
103
162
164
164
99.55
89.5
80.2
80
78
v-1
9
9
9
76
202.8
84.1
Nonazeotrope
9
74.1
334
334
108.5
109
111.2
132.7
89.4
89.5
28.6
86.7
87.5
43.6
95.5
49
Compound forma- v-1
tion
Nonazeotrope
98.9
74.4
334
41
334
334
315
199.3
162.1
164.5
222.0
144.9
119-22
110.7
110.6
205.0
99.8
334
86
Nonazeotrope
99.8
334
334
334
79.5
334
30
95.6
20.2
85
87.5
99.5
287
196
334
96
212.1
142
195.1
99.7
96.02
98.8
85
51.8
78.3
164.2
96.9
98.7
60
71
334
334
76.8
96
94.5
94.3
47.8
13
55.7
40
38
41
334
334
76
334
334
93.6
34.9
Nonazeotrope
334
334
93.3
162.9
147
...
...
"
100 m m .
2-Ethoxy-3,4142.9
dihydro-1,2 -pyran
P i m e l i c a c i d , 100 m m . 272
Butyl isopropenyl
ether
114.8
147.6
3-Heptanone
143.7
4-Heptanone
5 - M e t h y l - 2 -hexanone
144
II
CHEMISTRY
( i s o m e r s ) 146
86.3
94.6
94.3
94.7
93.0
94
18.8
42.2
40.5
44
75
36.2
v-1
334
365
334
334
334
334
334
84
334
TABLE
BINARY
SYSTEMS
15
-Component
No.
Formula
Name
Water (continued)
311
C H
7
1 4
Ethyl 3-ethoxypropionate
100 m m .
3-Methoxybutyl acetate
2 -(2 -Methoxyethoxy)
ethyl acetate
Heptane
5 -Methyl - 2 -hexanol
1 -Butoxy- 2-r
thoxyethane
1 -Butoxy-2-propanol
2 - E t h y l -1,5 -pentane diol
1 -(2 -Ethoxyethoxy) 2-propanol
2-Ethoxyethyl
2-methoxyethyl ether
2 -(2 - P r o p o x y e t h o x y )
ethanol
1 -Diethylamino -2 propanol
3-Diethylamino propylamine
Styrene
2-(2,4-Dichlorophenoxy) ethanol
Acetophenone
(Epoxyethyl)benzene
Ethylbenzene
11
312
313
C H
C H
314
315
316
C7Hi
C H 0
C H 0
317
318
C H
C H
319
320
321
0
0
C H
0
0
Aez
322
C H
7
1 7
NO
323
C H
1 8
324
325
CgHgCLjOj,
326
327
328
QHeO
C H
329
330
331
332
333
CeHio
334
8 10
H
N
N
N
335
C H
336
340
341
342
343
344
C
C
C
H K P
8 122
H
8 124
8 14
C H 0
C H 0
C Hi 0
C Hi 0
8
8 14 - 2
8 142
H
<
>
345
8 142
346
8 143
347
348
349
350
C H
^8^
8
0
0
8 15
8 16
B.P.,C.
m-Xylene
-Methylbenzyl alcohol
-Ethylaniline
-Methylbenzylamine
2-Methyl ^5-ethylpyridine
ar-Methyl-1,2,3,6tetrahydrobenzonitrile
2-Methyl-l,2,3,6tetrahydrobenzaldehyde
3,4-Dihydro-2,5dimethyl-2H-pyran2 - carboxaldehyde
Diethyl fumarate
Diisobutylene
Bicyclo[2.2.1]
heptane - 2 - methanol
Diisobutylene oxide
2-Ethyl-2-hexenal
2-Octenal
1,1 - D i a l l y l o x y e t h a n e
2 -Ethyl - 3 -hexenoic
acid
Vinyl 2-methylvalerate
B i s (2 - v i n y l o x y e t h y l )
ether
Butyl acetoacetate
Diethyl succinate
2 - (Aminomethyl)
bicyclo[2.2.1]
heptane
2 -Ethylhexaldehyde
B.P.,C.
Wt.%A
Data
Ref.
100
170.1
107.8
171.3
208.9
98.4
. . .
149.9
170.1
97
50.5
96.5
63
71
65.4
334
334
334
Nonazeotrope
12.9
79.2
96.5
59.1
334
334
84
95.6
98.6
42
72
334
334
253.3
Nonazeotrope
334
198.1
Nonazeotrope
334
215.8
99.5
82
Nonazeotrope
334
334
159.5
97.2
55
334
169.4
145.1
99.8
93.9
93
40.9
334
334
139.1
203.4
204.8
188.6
~100
99.1
99.2
92
91
94.5
99.7
99.2
99.4
~99.6
81.5
77.6
33.0
30.6
40
89
83.9
83.8
334
334
334
334
84
334
335
334
334
178.3
98.4
72
334
205.4
99.1
82.6
334
176.4
97.7
92.2
334
170.9
218.1
102.3
97.4
99.5
82
56
87.5
12
334
334
334
203.9
150.9
99.7
94
97.6
99.2
95.3
91
37
60.9
76.2
41
334
334
334
334
334
231.8
99.9
97.4
334
148.8
95
38
334
198.7
213.9
216.2
99.4
99.4
99.9
82
84.1
91
334
334
334
185.9
163.6
99
96.4
82
51.6
334
334
.. .
201.6
194.2
136.2
It
H
H
H
337
338
339
Azeotropic
.. .
176
...
ADVANCES
IN
-Component
No.
Formula
Water (continued)
H 2 O
351
C H
1 6
352
C H
8
353
C H
8
354
C H
355
356
357
358
359
360
361
362
363
8
8
8
8
II
l P 2
l c P 2
l t P 2
l P 2
l P 2
l P 3
l P 3
l A
364
C H
8
365
C H
1 7
366
CgHnN
36 7
Q H n N
368
CeH
1 7
369
CeH
1 7
NO
C1
370
371
372
CeHieO
373
374
8 18^2
375
376
CeH
C H
8
0
0
377
C H
378
379
2,4,4-Trimethyl1,2-epoxypentane
2,4,4-Trimethyl2,3 - e p o x y p e n t a n e
2-Butylthioethyl vinyl
ether
2-Butoxyethyl vinyl
ether
2,3-Epoxy-2-ethylhexanol
2-Ethylbutyl acetate
2-Ethylhexanoic acid
l t P 2
C H
8
182
1 8
182
C H
8
380
381
C H
382
C H
383
384
385
C H
C H
C H
386
C H
8
N0
387
C H
N0
388
C ^ O ,
8 iaP3
H
03
1 8
1 9
1 9
1 9
Name
N
N
NO
Hexyl acetate
Iso-octanoic acid
(isomers)
4 - Methyl - 2 -pentyl
acetate
2-Butoxyethyl acetate
2,5-Diethoxytetrahydrofuran
2-Ethoxyethyl 2vinyloxyethyl ether
2 - (2 - E t h o x y e t h o x y )
ethyl acetate
l-Chloro-2-ethylhe x a n e
N - E t h y l c y clone x y l amine
5-Ethyl-2-methylpipe ridine
ar-Methylcyclohexylmethylamine
4-Ethyl-2,6-dimethylmorpholine
Octane
2 - E t h y l -1 - h e x a n o l
Iso-octyl alcohol
(isomers)
2 - E t h y l -1,3 -hexanediol
1-Butoxy-2-ethoxyethane
1,1 - D i e t h o x y b u t a n e
5 -Ethoxy- 3-methyl pentanol
2-Ethyl-3-methyl1,5-pentanediol
2 -Hexyloxyethanol
2 - (2 - M e t h y l p e n t y l o x y )
ethanol
2 - (2 - B u t o x y e t h o x y )
ethanol
B i s (2 - e t h o x y e t h y l )
ether
l,2-Bis(2-methoxyethoxy) ethane
Dibutylamine
2 -Ethylhexylamine
2 -Diisopropylaminoethanol
2,2'- Butyliminodi ethanol
1,1' - E t h y l i m i n o d i 2-propanol
V i n y l benzoate
CHEMISTRY
Azeotropic
B.P.,C.
B.P.,C.
Wt.%A
SERIES
Data
Ref.
100
140.9
93.4
33
334
127.3
91
25
334
210.5
99.3
80
334
.. .
..
162.3
97.0
52.8
334
100
97.0
99.9
99.5
97.4
99.5
52.4
96.4
97.6
61
334
334
334
84
334
227.6
...
171.0
220
99.9
96
334
146.1
192.2
94.8
98.8
36.7
71.9
334
334
173.0
98
60
334
194.0
99.3
82.3
334
217.4
Nonazeotrope
334
173
97.3
55
334
164.9
97.1
58
334
163.4
97.1
57.0
334
.. .
99.0
79
334
158.1
125.7
184.8
97.5
89.6
99.1
49
25.5
80
334
334
335
186.5
243.1
82
99.8
Nonazeotrope
334
334
164.2
146.3
96.8
94.2
50
34.5
334
334
211.7
99.9
97
334
Nonazeotrope
99.7
91
334
334
265.5
208.1
197.1
230.6
188.4
...
159.6
169.1
190.9
.. .
238.9
99.6
86
Nonazeotrope
99.4
69
Nonazeotrope
97
50.5
98.2
64
99.2
85
334
334
334
9
334
334
334
Nonazeotrope
334
Nonazeotrope
99.3
82.6
334
334
TABLE
BINARY
SYSTEMS
17
Azeotropic
-Component
No.
Formula
H 0
Water (continued)
389
390
CHuN
l,2-Epoxy-3phenoxyp ropane
5-Ethyl-2-vinylpyridine
Cumene
Bicyclo[2.2.1]hept5-ene-2-ol acetate
5-Ethyl-2-pyridine ethanol
Isophorone
"
25 p . s . i . g .
l-Methyl-2,5endomethylene cyclohexane -1 methanol
Triallylamine
5-Ethyl-3-hepten2-one
Dimethyl pimelate
2,6-Dimethyl-4heptanone
2-Heptyl acetate
3-Heptyl acetate
3-(2-Ethylbutoxy)
propionic acid
Nonane
1 0 P 2
391
392
393
C H
394
CHiP
395
C H
396
397
CoHiijsr
398
399
CcHi 0
C H O
400
401
402
NO
1 3
CoH
1 6
i e
^-9
C H
C H
1 8
0
O
2
2
403
C 9 H 2 0
404
C9H20O
405
C9H20O2
406
C9H20O3
II
407
408
C9H20P3
409
410
411
C H
C H
C H
9
2 1
2 1
412
C H
413
414
C
C
415
416
C
C
1 0
1 0
Name
H
H
H
H
N
N
N0
N0
O
O
1 0
1 2
2,6-Dimethyl-4heptanol
2 -Ethyl-2-butyl 1,3-propanediol
1 - (2 - B u t o x y e t h o x y ) 2-propanol
2-Methoxymethyl2,4-dimethyl1,5-pentanediol
1,1,3-Triethoxypropane
-Methyldibutylamine
Tripropylamine
1,1' - I s o p r o p y l i m i n o di-2-propanol
2-(2-[2-(3-Aminopropoxy) ethoxy] ethoxy)ethanol
Dimethyl phthalate
2-Phenoxyethyl acetate
Dicyclopentadiene
N i c o t i n e , 110 m m .
478 m m .
572 m m .
624 m m .
760 m m .
Ethyl bicyclo[2.2.1]
hept-5-ene-2carboxylate
2 - (2 - P h e n o x y e t h o x y )
ethanol
N-Butylaniline
N-Ethyl - a-methylbenzylamine
N,N, a-Trimethylbenzylamine
11
B.P.,C.
99.8
96.1
334
15^4
99.4
95
85
43.8
334
334
188.6
98.6
70
334
.. .
215.2
251
418
419
420
C10H5N
Ci H
1 5
421
Ci H
1 5
142
Nonazeotrope
83.9
99.5
130
86.5
334
334
334
211.1
151.1
99.7
95
90.6
38
334
334
193.5
248.9
98.7
99.9
73.4
96.8
334
334
169.4
176.4
173.8
97.0
97.8
97.5
51.9
58.9
57.6
334
334
334
15 !7
150.8
100
94.8
95
> 99
82
39.8
334
332
334
178.1
98.5
70.4
335
Nonazeotrope
230.3
...
163.1
156
248.6
...
282.9
260.6
172
...
...
11
10
Ref.
244.4
11
Wt.%A
100
11
417
B.P.,C.
Data
198
297.9
240.4
99.9
334
95
334
Nonazeotrope
334
334
334
41
Nonazeotrope
334
Nonazeotrope
98.9
100
334
334
99.9
97.4
67.7
98
Nonazeotrope
99.70
...
99.02
.. .
98.50
...
99.85
97.48
334
334
106
106
106
106
106
99
96.5
94.3
99.2
70
48.0
80
Nonazeotrope
94.4
99.8
-1
-1
-1
-1
-1
334
334
334
201.2
99.2
80
334
195.8
98.6
74.8
334
ADVANCES
IN
B-Component
No.
Formula
Name
Water (continued)
422
423
424
CIOHHP
425
426
427
CioHi 0
428
1 0
1 5
NO
10 ltP
1 0
l P 2
10 182
l<f*2<P
429
430
431
C10P2 0O2
432
433
^10^21^1
434
P 1 A 1 N
435
C 1 0 H 2 2 O
436
437
438
439
440
C 1 0 H 2 0 O 2
C 1 0 H 2 0 O 2
H2o0
1 0
C 1 0 H 2 2 O
C 1 0 H 2 2 O
H 2O2
1 0
C 1 0 H 2 2 O 2
H 2O
441
1 0
442
443
444
CioH
445
446
447
448
1 0
2 3
H 2O4
2
2 3
C10H23N
NO
11 1403
11 1403
H
449
450
CiiH
451
452
453
454
C11H20O4
ll
lP3
H 2
C H220
n
C11H22O2
455
456
457
458
459
460
11 24
H
C11H24O
C11H24O2
C H2402
n
2-(a - M e t h y l b e n z y l amino) ethanol

Dicyclopentenol
Trimethyltetrahydrobenzaldehyde
Diisopropyl maleate
V i n y l 2-ethylhexanoate
V i n y l octanoate
(isomers)
2-Ethylhexyl vinyl
ether
2-Ethylbutyl butyrate
2 - E t h y l h e x y l acetate
4 - M e t h y l- 2 - p e n t y l
butyrate
2-Butoxyethyl 2vinyloxyethyl ether
C h l o r ode c a n e
(isomers)
- Butylcyclohexylamine
Decyl alcohol
(isomers)
2 -Ethyloctanol
2 -Propylheptanol
1,2- Dibut oxyethane
1,1 - D i i s o b u t o x y e t h a n e
2 -(2 -Hexyloxyethoxy)
ethanol
l,2-Bis(2-ethoxyethoxy) ethane
Bis[2-(2-methoxyethoxy)ethyl] ether
Decylamine (isomers)
Diamylamine
(isomers)
N,N-Dimethyl-2-ethylhexylamine
2 -Dibutylaminoethanol
Butyl salicylate
Ethyl 6 -formylbicyclo
[2.2.1]hept-5-en-2carboxylate
Allyl 6-methyl-3,4epoxycyclohexane carboxylate
Isopropyl 6-methyl3-cyclohexenecarboxylate
5 - E t h y l - 3 - nonen 2-one
Diethyl pimelate
5 - E t h y l - 2 - nonanone
2,6- Dimethyl- 4 -heptyl
acetate
4-Methoxy-2,6dipropyl-1,3dioxane
Undecane
5 - Ethyl - 2 -nonanol
2,2-Dibutoxypropane
2,6-Dimethyl-4heptyloxyethanol
1,1,3,3 - T e t r a e t h o x y propane
CHEMISTRY
Azeotropic
B.P.,C.
B.P.,C.
Wt.%A
SERIES
Data
Ref.
100
.. .
.. .
Nonazeotrope
100
96.6
334
334
204.5
228.7
185.2
99.0
99.9
98.6
77.0
93
68
334
334
334
.. .
99.1
74
334
177.7
199.6
198.4
97.8
98.6
99.0
59.1
74.9
73.5
334
334
334
182.6
98.2
60.8
334
226.7
99.8
90
334
210.6
99.7
84
334
209.5
99.5
81
334
217.3
220.5
217.9
203.6
160.5
100
99.9
99.8
99.1
97.4
94.8
94.0
92
76.8
52.5
335
334
334
334
334
259.1
100
98.1
334
246.9
Nonazeotrope
.. .
Nonazeotrope
82
99.5
203.7
334
9, 3 3 4
334
190
99.3
76
334
176.1
228.7
268.2
98.2
99.9
99.9
58
91.0
95.8
334
334
334
.. .
100
97
334
251.4
100
98.1
334
84
334
99.6
100
99.6
92
98.3
87.1
334
334
334
192.2
98.7
67.6
334
223.6
194.5
225.4
99.6
98.85
99.7
98.9
88.1
96
89.1
69.6
334
332
334
334
225.5
99.9
91
334
220.1
99.8
87.4
334
215.2
226.4
268.1
222.9
.. .
99.7
TABLE
BINARY
SYSTEMS
19
Azeotropic
-Component
No.
Formula
Name
Water (continued)
461
462
463
464
C
C
C
465
Ci H o0
466
467
468
469
Ci H
C H
470
471
472
473
Ci H
474
475
476
477
478
479
C
C
480
H
H
H
1 2
P4
P
2 f l
1 2
2 2 2
1 2
2 2 2
H
H
1 2
H
H
p
0
C
H p
Ci H
Ci H >
1
12
2 P
262
Ci H
Ci H
483
484
485
46
487
488
492
493
04
0
N
481
482
489
490
491
1 4
N O
0
0
Ci H
C i 2 H
C i 2 H
Ci H
Ci3H
2
Ci H
C H
4
0 P
0
2 4
0
N
14 24
H
14 2tt4
H
CuHÔ
494
495
496
14 282
497
14 282
498
499
500
501
502
0
p
H
H
N
P
14 3P2
H
Cl5 284
H
C 1 5 H 3 2 O
1 -Dibutylamino-2propanol
Diethyl phthalate
Triisobutylene oxide
- B u t y l - a- m e t h y l benzylamine
sec-Butyl - 6- methyl 3-cyclohexenecarboxylate
Dibutyl fumarate
D i b u t y l m a l e ate
2-Ethylhexyl crotonate
V i n y l decanoate
(isomers)
Diethyl 2-ethyl3 -methylglutarate
Dicyclohexylamine
2,6,8-Trimethyl4-nonanone
2-Ethylbutyl 2ethylbutyrate
2-Ethylbutyl hexanoate
Hexyl 2-ethylbutyrate
Hexyl hexanoate
Dodecane
2-Butyl-l-octanol
2,6,8-Trimethyl4-nonanol
1,1-Diethoxy2-ethylhexane
1,1 - D i i s o p e n t o x y e t h a n e
3-Ethoxy-4-ethyloctanol
Bis(2-butoxyethyl)
ether
1,1,3 - T r i e t h o x y h e x a n e
Dihexylamine
Tributylamine
T r i b u t y l phosphate
Decyl acrylate
(isomers)
2 -(Ethylhexyl)phenol
-(Ethylhexyl) aniline
1,3,6,8 - T e t r a m e t h y l 1,6 - c y c l o d e c a d i e n e
Dibutyl adipate
Trimethylnonyl vinyl
ether
2-Ethylbutyl 2-ethylhe x a n o a te
2-Ethylhexyl 2-ethylbutyrate
2-Ethylhexyl
hexanoate
Hexyl 2-ethylhexanoate
-(2-Ethylhexyl)
cyclohexylamine
7-Ethyl-2-methyl4-undecanol
2-(2,6,8-Trimethyl4 - n o n y l oxy) e t h a n o l
Dibutyl pimelate
2,8-Dimethyl-6isobutyl - 4 -nonanol
B.P.,C.
B.P.,C.
Data
Wt.%A
Ref.
100
229.1
294.3
.. .
239.3
99.8
99.9
99.3
88.4
98.4
72
334
334
334
99.8
92
334
92
98.5
98.4
93.4
334
334
334
334
88
334
.. .
100
99.9
99.9
99.9
.. .
99.9
285.2
280.6
241.2
255.8
255.8
100
97.1
Nonazeotrope
334
38
218.2
99
84
334
222.6
236.2
230.3
245.2
214.5
253.4
99.6
99.7
99.7
99.8
99.45
99.9
85.6
91.2
88.8
93.3
98
97.5
334
334
334
334
332
334
225.5
99.6
89.7
335
207.8
213.6
99.3
99.3
78.6
78.8
334
334
249.2
100
98
334
254.6
99.8
99.6
99.8
99.8
100
94.7
85
92.8
82
99.4
334
334
334
334
334
99.9
100
100
94.9
> 99
99.3
334
334
334
99.5
100
82.3
>99
334
334
223.4
99.6
84.3
334
261.5
99.9
95.8
334
252.8
99.9
94.8
334
267.2
99.9
96.4
334
254.3
99.9
94.6
334
99.7
334
96.3
334
99.0
> 99.5
334
334
.. .
239.8
213.9
.. .
...
297.0
.. .
220.5
.. .
.. .
264.3
.. .
.. .
265.4
100
99.9
100
100
99.9
97.2
334
ADVANCES
IN
CHEMISTRY
Azeotropic
-Component
No.
Formula
Water (continued)
H 0
2
503
504
1 8
505
Ci$H
3 0
506
Ci6H
3 1
507
Ci6H
508
1 6
3 4
509
1 6
3 5
510
Ci H
511
512
CieH
3 8
513
CieH
3 9
NO
514
3 6
1 6
1 8
2 0
3 2
0
N
0
3 6
2 4
5 1 5 C20H36O4
516
517
518
519
520
521
C H
C oH4
C H
C iH
C H
522
2 0
4 0
2 0
2 0
4 3
3 8
2 4
5 2
H5 0
8
B.P.,C.
11
11
524
C H
3
Ammonia
H N
3
525
526
C ^ N
C
527
C ^ g F
528
C HJQ
4
11
11
529
C H^
8
Wt.%A
100
98.7
334
100
100
99
98.8
334
334
100
99.45
334
99.9
97.9
334
99.8
96.4
334
97.6
334
100
100
>99
334
100
>99.9
334
.99.9
334
100
>99.5
334
100
>99.9
334
100
>99.9
334
>99.5
100
100
99.6
99.8
100
100
99.6
Nonazeotrope
334
334
334
334
334
100
99.9
334
100
99.8
334
-21.6
-6.5
5
15
23.5
7.8
37.1
56
72
84.2
95
7.9
11.6
14.5
17.1
19.6
75.2
82
83.7
87.2
89.9
92.7
99.0
v-1
v-1
v-1
v-1
v-1
v-1
v-1
v-1
v-1
v-1
v-1
159
159
159
159
159
161
161
161
161
161
161
Nonazeotrope
-45
44.3
34
-40.5
56.8
43
59.0
66
60.9
81
62.1
94
63.4
104
v-1
v-1
v-1
v-1
v-1
334
127
127
160
160
160
160
160
M i n . b.p. 98-100%
v-1
v-1
162
162
-33.4
Ethylamine, 0-30 C.
-32
Propadiene
2-Fluoropropene
-24
B u t a n e , 300 p . s . i . g .
500 p . s . i . g .
700 p . s . i . g .
900 p . s . i . g .
1100 p . s . i . g .
I so-octane,
200-1600 p.s.i.g.
"
> 1400 p . s . i . g .
11
Ref.
B.P.,C.
-59.6
E t h a n e , 200 p . s . i . g .
"
300 p . s . i . g .
400 p . s . i . g .
"
500 p . s . i . g .
600 p . s . i . g .
P r o p a n e , 200 p . s . i . g .
"
400 p . s . i . g .
"
600 p . s . i . g .
"
800 p . s . i . g .
"
1000 p . s . i . g .
"
1200 p . s . i . g .
CjHg
Data
100
Bis( - methylbenzyl)
ether
286.7
Bis(4-methyl-2pentyl) maleate
Tridecyl acrylate
Bis(methylcyclohexylme thyl) a m i n e
...
2-Ethylhexyl 2ethylhexanoate
280.4
B i s (2 - e t h y l h e x y l )
ether
269.8
Bis(2-ethylhexyl)
amine
280.7
3,9-Diethyl-6tridecanol
309
Bis(a - methylbenzyl)
ethylenediamine
1,1 - B i s ( 2 - e t h y l h e x y l o x y )
ethane
2-[Bis(2-ethylhexyl)
a m i n o ]ethanol
Bis(2-ethylhexyl)
fumarate
Bis(2-ethylhexyl)
maleate
2-Ethylhexyl 3(2 - e t h y l h e x y l o x y )
butyrate
Decyl ether (isomers)
Eicosanol (isomers)
Didecylamine (isomers)
...
A l l y l 9,10-epoxystearate
...
Tetra(2 -ethylbutoxy)
silane
Tri(2-ethylhexyl)
1,2,4-butane tricarboxylate
Hydrogen Sulfide
HS
523
O
0
N
03
0 Si
4 2
3 1
Name
SERIES
TABLE
BINARY
SYSTEMS
21
Azeotropic
-Component
No.
A =
Formula
He
Sulfur Dioxide
0 S
2
Methyl
532
A
Selenium
CHC1F
Chlorodif luor 0 methane

"
4.93 a t m .
2059 m m .
Chloromethane,
5380 m m .
1,1 - D i f l u o r o e t h a n e
11
534
535
C H 3 C I
C 2 H 4 F 2
II
...
Nonazeotrope
-23.6
688
60 p . s . i . a .
"
112 p . s . i . a .
M e t h y l e t h e r , 2340 m m .
Hexafluor opr opene,
2059 m m .
Heptafluoropropane,
2328 m m .
Perfluorocyclobutane,
2059 m m .
536 CziÔ
538
C HF
539
C F
A =
25.0
-30.5
0.00
24.90
40.08
4.44
25
0
282
260
260
260
260
281
281
282
-6.1
-7.1
.. .
33.5
...
A=
...
17
21
T r i ch l o r of l u o r om ethane
24.9
Acetaldehyde
Methyl formate
20.2
32
CC1
C H 4 O
543
544
C HC1
C H N
545
546
C H Q
Carbon Tetrachloride
542
C l 2
11
11
CjjHgO
548
CsHp
11
11
11
11
549
550
551
C H<p
C H80
3
Cftf)
552 C ^ g C ^
553
C H O
554
C H 0
555 CgHg
556
1 0
C 7 H 8
E t h y l acetate
-Butyl alcohol
2"-Furaldehyde
Benzene
"
40 C .
"
760 m m .
"
>1800 m m .
Toluene
0.00
78
77.55
73.80
71.22
69.31
76.2
74
90
46.3
v - -1
86.5
261
Nonazeotrope
15.6
20
346
346
102
102
55
82
76.74
64.7
Methanol
Trichloroethylene
86.2
A c e t o n i t r i l e , 371.2 m m . ...
83.45
A c e t i c a c i d , < 50 m m .
...
90 m m .
...
340 m m .
"
530 m m .
...
760 m m .
118.1
"
1080 m m .
"
1400 m m .
...
Ethyl alcohol
78.3
Acetone, 513.2m m .
...
31.29
300 m m .
450 m m .
41.56
600 m m .
49.36
760 m m .
56.08
Allyl alcohol
97.1
97.2
Propyl alcohol
2 - B u t a n o n e , 342 m m .
...
It
79.6
11
547
86
261
346
C H 0
C2H 0
2
v- 1
25
-41.4
0.00
2.1
Nonazeotrope
-40.8
0.04
CC1 F
3
540
541
165
102
65
Compound formation
11
v- 1
444.6
II
C F
Ref.
-10
II
537
Wt.%A
Dichlorodifluoromethane -29.8
C C I 2 F 2
533
ether
Sulfur
S
Se
B.P.,C.
268.9
Methane, 5-170 a t m .
531 C Hf>
A=
B.P.,C.
Helium
530 C H
A=
Name
Data
76.7
117.75
162
80.1
...
80.1
...
110.7
Ideal system
84.5
45
80
75.5
Nonazeotrope
18.7
99.28
99.42
51.5
99
64.6
98.46
76
97.7
90
97.0
...
84
65
9
45
9.03
31.22
11.80
41.47
12.48
49.26
12.6'
55.98
88.5
72.3
88.5
72.8
84.3
50.0
73.7
81.6
57
74.8
97.6
76.55
Nonazeotrope
M i n . b.p.
98
Nonazeotrope
Nonazeotrope
M i n . b.p.
. ..
Nonazeotrope
v --1
V " -1
v --1
V
V
V
V
V
V
V
V
-1
-1
-1
-1
-1
-1
-1
-1
-1
-1
-1
-1
-1
-1
V
V
V
V
245
184
22
197
132
132
132
132
132
132
132
136
23
10
10
10
10
334
334
108
108,
184
334
136
349
245
107
107
107
245,
309
22
ADVANCES
IN C H E M I S T R Y
-Component
No.
Formula
CS
CH I
Carbon Disulfide
Iodometfrane
1-Chloropropane
E t h y l acetate
Ethyl ether
557
558
559
560
561
C 2 H 4 C I 2
C H CI
3
C H 0
C HidO
8
C H C 1 F
562
563
C 2 H 2 C I 2 F 2
564
C F
565
566
C 1 F
Name
Chlo r odifluo r omethane

Chloropentafluor 0 ethane
l,2-Dichloro-l,2difluoroethane,
755 m m .
Hexafluor opropene,
2059 m m .
Perfluoropropane,
6.064 a t m .
P r o p a n e , 86.2p . s . i . a .
6.002 a t m .
Perfluorocyclobutane,
2059 m m .
t !
567
C H C 1
568
569
570
C l 2 F
C H C 1
CH 0
Chlo r ofo r m
Formic acid
Methanol
400 m m .
500 m m .
600 m m .
Tetrachloroethylene
Acetonitrile
Acetic acid
Ethyl alcohol,
20 p . s . i . g .
A c e t o n e , 101 m m .
"
129 m m .
202 m m .
250 m m .
308 m m .
"
455 m m .
"
546 m m .
Methyl acetate
CH 0
4
11
11
11
571
572
573
5-74
575
C 2 C I 4
C H N
2
C H 02
4
C H 0
6
Azeotropic Data
B.P.,C.
46.2
42.55
57.2
46.6
76.7
34.6
11
fl
C H<0
577
578
579
C Hg02
41.2
46
45.2
46.1
34.4
Wt.%A
18.6
94
55
97
1
Ref.
v - -1
116
334
334
334
334
- 4 0 . 8 (-17.1V2059 mm.)
-38.5
-45.6
48.7
15
29.8
-41.4
87.6
96
-6.1
-17.3
69.7
346
12.5
0
0
0
46
68
68.3
261
280
261
.. .
8.6
21.0
61.2
100.75
64.7
...
...
...
121.1
81.6
118.1
101.7
...
...
11
576
B.P.,C.
Nonazeotrope
Dichlo r ofluo r o7.63/723 m m .

methane
1,2-Dichloro-l,1,2,2tetrafluoroe thane,
0.00
2.22
723 m m .
SERIES
...
...
.. .
57.1
...
25
. ..
. ..
88.9
36.3
88.4
41.6
46.2
87.9
Nonazeotrope
Nonazeotrope
Nonazeotrope
82
15
20
30
35
40
50
55
64.74
346
89
74.3
75.0
76.1
76.3
76.7
77.1
77.3
64.35
261
-1
-1
-1
-1
-1
-1
-1
56
31
233
233
233
64
334
56
-1
335
286
286
286
286
286
286
286
31,
V
V
V
V
V
Ethyl formate
2 -Bromopropane
2-Butanone
C H Br
C HeO
3
C HeO
4
580
581
582
583
584
C 4 H 8 O 2
C H
4
C H
6
1 0
1 2
1 2 2
C9H O
10
C H 2 C l B r
585
CH2CI2
C H 2 C I 2
586
14
2-Butanone
Isopropyl formate
Ethyl ether
4 - M e t h y l - 2 -pentanone
Butyl acetate
Ethyl benzoate
54.1
59.35
79.6
79.6
68.8
34.5
115.9
126.2
213.3
Bromochloromethane
Dichloromethane
69
40.7
Dichloromethane
2,2- D i m e thylbutane,
742 m m .
40.0
49.74
87
62.7
62.2
65
Nonazeotrope
17
79.9
70
13
Nonazeotrope
Nonazeotrope
Nonazeotrope
Nonazeotrope
Nonazeotrope
35.6
53 v o l .
qc;
195, 252
195, 252
V -1
183,
184
334
195
177
V -1
V -1
157
V -1
63
334
96
235
TABLE
BINARY
SYSTEMS
23
Azeotropic Data
B-Component
No.
A =
587
588
Formula
CH2O2
C2H4O2
C H NO
3
Name
Formic Acid
Acetic acid
N,N -Dimethylf
amide
11
11
589
"
Pyridine
C 5 H 5 N
CH Cl Si
3
590
C H SiCl
3
CH3NO2
B.P.,C.
100 m m .
200 m m .
760 m m .
Nitromethane
C
C
C
C
C
Butyl alcohol
sec-Butyl alcohol
tert-Butyl alcohol
Isobutyl alcohol
Benzene
Cyclohexane
A =
H
H
H
H
H6
1 0
1 0
1 0
l 0
C6 !2
H
CH
603
604
A =
O
O
O
O
153.0
153.2
158.8
98.5
117.0
158.8
107.43
90'
107.9
153
115.5
Chlorotrimethylsilane
597
598
599
600
601
602
Nonazeotrope
CH 0
C C1 F
607
C2H2CI2
608
C2H2CI2
609
610
611
C2HCl2
612
613
614
615
C
C
C
C
616
C H 0
C H 0
179
64.51
.. .
78.32
.. .
82.40
97.25
97.15
117.73
99.53
82.41
107.89
80.1
80.75
64.33
12.2
Nonazeotrope
76.05
29.0
Nonazeotrope
79.33
27.6
Nonazeotrope
89.09
48.4
97.99
71.4
91.14
45.8
80.04
21.2
94.46
57.6
12.7
69.5
26.5
v-1
v-1
55
22
55
22
55
135
55
55
55
55
55
343
343
v-1
v-1
268
268
v-1
v-1
v-1
H60
H60
H N
H 0
3
3 62
H
C H NO
C H NO
3
Nonazeotrope
Nonazeotrope
V.p. curve,
azeotrope
302
non-
64.7
1,1,2 - T r i c h l o r o t r i fluoroethane
cis-l,2-Dichloroethylene
trans -1,2 - D i c h l o r o ethylene
Acetaldehyde
Acetic acid
47.5
39.9
60.3
51.5
15.1
48.3
83.5
20.2
118.1
9.02
41.9
35
59.5
Nonazeotrope
Nonazeotrope
-1
-1
V
V
-1
-1
47
14.8
-1
56.1
108
132
150
57.1
Nonazeotrope
32
102
124
46
140
56
17.7
53.9
-1
107
132
149
131.18
120.25
29
99
34.6
120
40.4
135
Nonazeotrope
Nonazeotrope
it
"
"
"
Methyl
4.4 a t m .
"
7.8 a t m .
"
11.2 a t m .
1 -Nitropropane
2 -Nitropropane
-1
-1
Nonazeotrope
4.56 a t m .
7.82 a t m .
11.6 a t m .
acetate
335
Ethyl alcohol
78.3
Methyl ether
-23.65
A c r y l o n i t r i l e , 1 7 5 m m . 37
A c e t o n e , 752 m m .
...
11
617
618
non-
Dichloromethylsilane
Methanol
606
61.4
101.2
Chlorotrimethyl silane, 30-40
v-1
v-1
v-1
v-1
295
210
210
210
210
360
1.2
V.p. curves,
azeotrope
...
Ethane
Propane
56
Methane
C2H.6
C H8
CH^ljSi
A =
v-1
Trichloromethylsilane
Methanol
Acetonitrile, 60 C .
Ethyl alcohol
Acetone, 45 C .
Isopropyl alcohol
Propyl alcohol
178.1
orm-
CH 0
C H N
CaHgO
CaHgO
C H O
C H O
2
Ref.
100.75
591
592
593
594
595
596
B.P.,C. W t . % A
.. .
29
55.07
5
5
335
171
205,
285
7, 6 8
130
335
7,
130
192
335
335
335
31,
58
335
335
335
55
55
ADVANCES
IN
B-Component
No.
Formula
CH 0
Name
B.P.,C.
2 -Methoxyethanol
752 m m .
800 m m .
T r i m e t h y l borate
60 p . s . i . g .
"
30 p . s . i . g .
200 m m .
V i n y l acetate
C3H9BO3
11
11
621
622
623
624
C H60
4
C H80
2 -Butanone
Butyraldehyde
e t r a h yd r o fu r a n ,
740 m m .
E t h y l acetate, 40-60
C4H8O
C HeO
4
625
626
627
11
C H
4
1 0
628
629
630
631
632
633
C HeO
Methyl propionate
Butyl alcohol, crit.
region
D i e t h y l a m i n e , 740 m m .
Isoprene
3 - M e t h y l -1,2 -butadiene
is -1,3 -Pentadiene
trans -1.3- Pentadiene
^ H g
C5H3
...
6 !
.. .
...
...
72.7
72.6
79.6
74.8
65
76.7
79.7
117.75
54.7
34.3
40.8
44.0
42.0
634
635
636
637
1,3-Butadienyl methyl
ether
3-Methyl-1-butene
2 - M e t h y l -1 -butene
2 - M e t h y l - 2 - butene
1 -Pentene
^5 10
5 10
5 10
H
638
639
640
641
CsH
C H
C H
642
643
644
645
^ - 5 12
C H 0
C H 0
C H
1 0
1 0
1 0
O
O
5 12
H
is-2 -Pentene
2-Pentanone
Isopropyl acetate
2 -Methylbutane
Pentane
A m y l alcohol
Benzene
11
11
646
647
648
649
QHgO
650
C6 12
651
652
653
654
655
656
^6^12
CH
1 0
^6 10
6 10
C
Q H 1 2 O
C H
6
l z
C6H14
CeHi4
90.7
21.2
32
37.7
29.92
30.1
37.1
102.2
88.7
27.6
...
36.15
137.8
80
80.1
108
64.7 p.s.i.a.
128
112.7 p.s.i.a.
141
159.7 p.s.i.a.
152
"
209.7 p . s . i . a .
161
259.7 p . s . i . a .
93.3
2,5 - D i m e t h y l f u r a n
72.9
1,3-Hexadiene
82
2,4-Hexadiene
3-Methyl-l,377
pentadiene
C y c l o h e x a n e , <760 m m .
"
<760 m m .
...
"
<760 m m .
...
"
<760 m m .
...
66.4
cis-3-Hexene
94.2
Butyl vinyl ether
116.2
4 - M e t h y l - 2 -pentanone
49.74
2,2 - D i m e t h y l b u t a n e
60.27
2 -Methylpentane
3 -Methylpentane
63.28
"
"
B.P.,C.
Wt.%A
Ref.
64.7
11
620
SERIES
Azeotropic Data
Methanol (continued)
619
CHEMISTRY
Nonazeotrope
Nonazeotrope
54.0
27
100
33
84
29
22
25
58.8
36.6
59.05
36.6
70
64.5
Nonazeotrope
v-1
335
v-1
335
115, 335
335
335
335
335
96
135
v-1
37
59.1
31.1
% alcohol i n creases with
pressure
62.1
48.6
62.0
50
v-1
v-1
Nonazeotrope
v-1
66.2
29.57
34.7
38.1
36.5
36.5
335
84
40
5.2
8.5
16 v o l . %
15 v o l . %
12.9
v-1
62
57.5
v-1
17.9
4.28
v-1
27.4
8.1
11.2
33.1
v-1
13 v o l . %
26.4
8.92
v-1
26.3
31.8
7 vol. %
Nonazeotrope
v-1
70.2
64.0
24.62
4
24.2
6.98
v-1
7
30.85
v-1
Nonazeotrope
61-62
45
58
38
v-1
1
102
123
138
148
159
61.5
<58
-58
49
54
58
62
65
51
-40
-40
115
228
v-1
v-1
v-1
v-1
v-1
-58
-40
27.5
34
30
32.6
31.6
38
42
26.8
26 v o l . %
49.6
52
62
Nonazeotrope
v-1
17 v o l . %
39.6
21 v o l . %
45.6
47.1
20 v o l . %
75,
135
335
324
324
291
291
249
335
249
249
249
291
249
291
135
335
324
249
324
135
201
182,
9 7^
2
27
75
5
275
275
275
335
80
80
80
317
317
317
317
291
335
135
291
291
291
TABLE
BINARY
SYSTEMS
25
B-Component
Formula
No.
CH 0
Methanol (continued)
Hexane
657
6 14
658
659
660
661
662
C H
663
7 16
1 4
It
Butyl ethyl ether

2,2- Dimethoxybutane
Toluene
trans -1,3 -Dimethyl cyclopentane
Heptane
406 m m .
2-Methylhexane
3-Methylhexane
-Xylene
2"-Ethyl-2-hexenal
Octane
406 m m .
N o n a n e , 406 m m .
6 142
6 142
Name
7 14
Azeotropic
B.P.,C.
7
7
7
Q
Ce
16
16
16
10
H 0
1 4
8 18
H
11
670
671
C H
9
C9H20
672
673
674
C H
675
C4H10
676
CH N
C H
4
677
C H
II
D e c a n e , 406 m m .
10 22
H
II
U n d e c a n e , 406 m m .
CH S
Methanethiol
2-Methylpropene,
95 p . s . i . a .
2-Methylpropane
Methylamine
Butadiene
"
5 atm.
20 a t m .
1 - Butene
"
5 atm.
"
20 a t m .
90.77
98.4
9 ! 5
91.85
80.88
138.35
176
125.75
...
169.4
...
150.7
...
171.8
...
26.4
49.5
50.57
28
56
62.6
Nonazeotrope
64.5
81.5
70.8
63.6
57.3
45 v o l .
58.8
46.1
43.83
44 v o l .
57.1
44 v o l .
57.6
38 v o l .
54.1
64.0
5
Nonazeotrope
67.5
62.75
47.65
C C1F
Chloropentafluoroethane
1,1 - D i f l u o r o e t h a n e
678
C2H4F2
C2Cl2F
679
C4H10
C2G13F3
680
C2C14F2
681
C2C1
682
683
684
685
686
687
688
689
690
C2H3CI3
CaHgO
C3H3O
C4H10O
C2HCI3
C2H4CI2
C2H4O2
C3H6CI2
C.HgO
C He0
4
Ref.
v-1
%
175
324
335
334
201
202
291
174
366
291
291
291
84
334
174
366
%
%
%
Nonazeotrope
48.93
83.4
64.1
Nonazeotrope
Nonazeotrope
Nonazeotrope
v-1
334
366
174
366
249
366
6.00
...
-11.70
53
-13.00
19.5
4.9
145
21
-6
.. .
20
20
20
20
20
20
58
74
96
50
64
74
11
Wt.%A
64.7
68.95
68.95
92.2
114
106-7
110.7
11
664
665
666
667
668
669
B.P.,C.
Data
...
-38.5
-24.7
-41.3
1, 2 - Di ch l o r o t e t r a fluoroethane
Butane
-0.5
-2.2
1,1,2-Trichlorotri-
47.5
fluoroethane
1,1,2,2 - T e t r a c h l o r o difluoroethane
Ethyl alcohol
92.4
78.3
83.8
198
59
102
Nonazeotrope
96.2
43.8
Tetrachloroethylene
1,1,2 - T r i c h l o r o e t h a n e
Acetone
Isopropyl alcohol
Butyl alcohol
121.1
113.65
56.1
82.3
117.7
112.9
26
Nonazeotrope
19
81.7
110
68
T r ichlor oethylene
Acetic acid
1,2 - D i c h l o r o p r o p a n e
2-Butanone
Ethyl acetate,
700-760 m m .
86.2
83.45
117.9
96.3
79.6
39
82.2
Nonazeotrope
Nonazeotrope
Nonazeotrope
Nonazeotrope
96, 334
335
v-1
197
64
334
334
197
334
334
184
v-1
274
26
ADVANCES
IN
B-Component
Formula
No.
C H
C H
2
691
Name
11
692
C H
2
"
Ethane
B.P.,C.
-84
103.7
Crit. press.
- 3 5 , 0 , 40 F .
.. .
-88.3
Crit. press
-35, 0, 4 0 F .
Propyne, -50 to 35 C .
C H
3
C ^ C l ,
694
695
696
697
698
699
700
701
i s - 1 , 2 - Di c h l o r 0 ethylene
Ethyl alcohol
Acetone
Ethyl formate
M e t h y l acetate
Methylal
2 -Butanone
Tetrahydrofuran
Isopropyl ether
CaHgO
CaHgO
C3I5O2
^3
0
C HeO
C H2C1
2
702
703
704
705
706
707
708
709
CsHgO
C 3 H 6 O
H g 0
C HeO
C HeO
4
C H C1
C H C1
2
710
711
C H C1
C H C1
.. .
Nonazeotrope
v-1
v-1
293
293
137
293
293
137
28
Calculated
61.9
73
Nonazeotrope
61.7
73
Nonazeotrope
Nonazeotrope
69.8
44.5
Nonazeotrope
v-1
v-1
v-1
v-1
v-1
v-1
v-1
v-1
5
5
5
5
103
5
103
103
Calculated
Nonazeotrope
Nonazeotrope
Nonazeotrope
48.6
79.3
Nonazeotrope
Nonazeotrope
Nonazeotrope
v-1
v-1
v-1
v-1
v-1
v-1
v-1
v-1
5
5
5
5
103
5
103
103
18
19
v-1
'. ! !
78.3
56.4
54.0
57.2
42.6
79.6
66.1
68.0
trans - 1 , 2 - Di ch l o r 0 ethylene
Ethyl alcohol
Acetone
Ethyl formate
M e t h y l acetate
Methylal
2-Butanone
Tetrahydrofuran
Isopropyl ether
78.3
56.4
54.0
57.2
42.6
79.6
66.1
68.0
V i n y l Ch l o r i d e
Acetone
83.5
56.1
Nonazeotrope
Nonazeotrope
334
334
74.1
113.9
57.4
Nonazeotrope
Nonazeotrope
96
96
48.35
13.4
C 2 H 4 C I 2
C H F 0
CgHgO
2,2,2-T r ifluor oethanol

Ethyl alcohol
...
714
Acetonit r ile
715
716
717
718
C^H^Cla
C H3N
CaHgO
C H NO
81.55
83.15
77.1
719
720
721
722
723
724
725
726
5 12
C6H
C H N
7 16
Q 18
CHJJO
C
Qo 22
C H
H
C H
2
8 10
CeHio
C
Ethylene
78 .*3
...
153
.. .
65
...
134
98.4
125.75
150.7
173.3
195.4
1,2 -Dibromoethane
m-Xylene
-Xylene
81.75
226
57.65
-79.1
49
Nonazeotrope
Nonazeotrope
Nonazeotrope
Nonazeotrope
58
13
45
30.7
Nonazeotrope
69.55
76.7
79.82
81.45
Nonazeotrope
v-1
v-1
v-1
v-1
267
334
25
334
334
334
22
247
368
368
368
368
368
103.7
Ethane, -35, 0, 40 F . -88.3

" 0, -40, -100 F . ...
C H Br
728
729
Acrylonitrile
Acetone, 45 C .
,
-Dimethylformamide
"
100-500 m m .
Pentane, 24 p . s . i . g .
Benzene, 278 m m .
2-Picoline
Heptane
Octane
Nonane
Decane
Undecane
C H
72 7
39*
44
60.3
1,1,1-T richloroethane
1,1,2 - T r i c h l o r o e t h a n e
712
713
Ref.
B.P.,C. W t . % A
11
693
SERIES
Azeotropic Data
Acetylene
Ethylene
CHEMISTRY
131.5
139
138.4
...
...
Nonazeotrope
Nonazeotrope
131.0
94
v-1
v-1
137
129
113
113
TABLE
BINARY
SYSTEMS
27
Azeotropic
B-Component
Formula
No.
730
731
732
733
734
735
C2H4CI2
C3I6CI2
CaHeO
C4H8CI2O
C H
C6H
C H
6
1 2
C2I4O
736
737
C H C1
C H<p
738
739
740
741
742
C^HgOz
743
C4H8O
C4H
1 0
C H
Name
1,2-Dichloroethane
Acetaldehyde
Chloroethane
Propylene oxide,
35 p . s . i . g .
V i n y l acetate
Ethyl vinyl ether
Butane
Ethyl ether
Isopropyl ether
Ethylene Oxide
C2H4O2
Acetic A c i d
C H Q
745
746
C H<p
C H O
747
748
749
750
C H60
751
C H
752
C H N
C4H3O2
C4H3O2
C H9NO
4
757
758
7 16
H
760
761
C H
762
763
764
765
10.5
139.9
Nonazeotrope
119.4
79.5
Nonazeotrope
Pyridine
115.5
345
88.7
36.15
134
68.7
68.60
68.3
143.41
144
II
76.7
165
117.1
98.25
Heptane
143.6
125.75
CHi 2
Cumene
Nonane
152.8
150.2
150.2
^10 16
C a m p h e n e , 100 m m .
Decane
8 18
H
C9H20
H
C H 2
1 0
II
II
.. .
173.3
173.3
II
766
767
768
769
CiiH
2 4
C 1 2 H 2 0 O 2
C12H26
C2H5CI
C4H10
334
22
Acetic anhydride
-Dioxane
Ethyl acetate
N,N-Dimethylacetamide
Butyl alcohol
o-Xylene
Octane
-6.5
v-1
v-1
II
C
334
96
334
334
243
334
Ideal s y s t e m
Nonazeotrope
II
759
Nonazeotrope
Nonazeotrope
Nonazeotrope
-7
16
18.9
76.5
Nonazeotrope
140.7
97.25
Isopropyl ether
2,6-Lutidine
96
Propionic acid
Propyl alcohol
C Hi 0
^
C H N
73
72.5
35.5
-0.5
34.5
68.3
9.5
11
v-1
C Hu
C5H12
12.3
Nonazeotrope
Crit. press.
Isopropyl acetate
Pentane
2-Picoline
Hexane
C 5 H 1 0 O 2
Undecane
II
Isobornyl
Dodecane
334
334
334
235
235
235
118.1
alcohol
11
753
754
755
756
Nonazeotrope
72.7
60.8
Nonazeotrope
80.1
15 v o l . %
74.7
38 v o l . %
73.7
35 v o l . %
78.3
Ethyl
Ref.
Wt.%A
20.2
-0.5
Butane
B.P.,C.
83.65
96.3
1,2 - D i c h l o r o p r o p a n e
82.3
Isopropyl alcohol
B i s (2 - c h l o r o e thyl) e ther 1 7 9 . 2
80.1
Benzene
Cyclohexane
80.75
80.8
2,4- Dimethylpentane
C2H4O
C4H10
744
B.P.,C.
Data
acetate
Chloroethane
-Butane
"
738.6 m m .
194*5
194.5
225.8
216
205,
285
48
205,
285
334
180
334
295
205,
285
373
138.1
51.1
323
348
20.2
Nonazeotrope
334
Nonazeotrope
187
144.12
40.4
369
334
Nonazeotrope
187, 189
68.25
6.0
334
Nonazeotrope
v-1
358
147.28
24
364
148.1
22.9
370
162.3
19.5
187, 189,
91.7233
355, 373
372
116.6
78
105.7
53.7
v-1 189,
355, 359
76
116
84
112.8
69 187, 189, 355
324
113.25
69.6
v-1
294
60.6
90
116.75
79.5
187,
189, 355
324
117.2
79
v-1
358
116.10
87
117.72
95 187, 189, 355
324
117.17
78
v-1
294
Ideal system
Nonazeotrope
187
170.8
120.3
21.1
43
v-1
12.4
-0.5
-0.5
-1.4
15.6
20.2
v-1
255
263
ADVANCES
28
IN
Azeotropic
B-Component
No.
A =
Formula
C H C10
2
770
C ^ C I O
7 7 1 C4H8CI2O
Name
B.P.,C.
2-Chloroethanol
7 7 2 C4H8O2
773
2-Chloroethyl vinyl
ether, 120 m m .
Bis(2 -chloroethyDether,
50 m m .
96
179.2
-Dioxane
101.3
A =
C2H5NO
11 10
Acetamide
C2H5N02
Nitroethane
774
775
776
777
778
779
780
C HeO
C HeO
C4H10C
C H p
C H p
C H O
781
C Fi
782
C HeO
CaHgO
A =
1 (
1 (
l 0
Ethyl alcohol
Isopropyl alcohol
Propyl alcohol
Butyl alcohol
sec-Butyl alcohol
tert-Butyl alcohol
Isobutyl alcohol
Ethyl Alcohol
C3H7NO2
C3H7NO2
CsHeO
C H O
1-Nitropropane
2-Nitropropane
Isopropyl alcohol
2 -Butanone
787
788
789
C H 0
C H 0
C H 0
Butyraldehyde
Ethyl vinyl ether
-Dioxane, 200 m m .
400 m m ,
600 m m .
760 m m .
E t h y l acetate, 40-60 C.
It
11
11
11
790
C H 0
4
"
"
791
792
793
794
795
796
797
798
799
800
801
802
803
804
QHKP
C4HKP
C4H10O2
C4H11N
Q H 1 1 N
C5HA
C5H10
CSHKP
C5H10O
C5H10O
CAP
Cs H 0
C Hi 02
12
241.1
114.07
78.32
82.40
97.15
117.75
99.53
82.41
107.89
55.62
14
341
334
334
334
Nonazeotrope
Nonazeotrope
Nonazeotrope
...
78.03
81.82
94.49
107.94
97.16
82.22
102.68
55
98
12.6
10.6
31.8
58.6
27.6
4.5
40.8
55
55
55
55
55
55
55
77.4 m m .
760 m m .
131.18
120.25
82.3
79.6
79.6
75.7
35.5
.. .
...
...
...
...
...
II
77.05
117.75
Butyl alcohol
sec-Butyl alcohol
99.4
134
2-Ethoxyethanol
Butylamine
77.8
Diethylamine
55.5
E t h y l a c r y l a t e , 1 0 0 m m .4 4 . 9
31.10
2-Methyl-1-butene
Isopropyl vinyl ether,
737 m m .
54.8
102.35
2-Pentanone
Propyl vinyl ether
65.1
A m y l alcohol
137.8
Butyl methyl ether
70.3
80
Benzene, 310 m m .
...
180 m m .
400 m m .
...
168.4 m m .
...
233.5 m m .
"
336.4 m m .
...
"
584 m m .
...
209 m m .
80.1
760 m m .
11
11
11
11
11
11
Nonazeotrope
v-1
155
Nonazeotrope
v-1
7,
134
55
55
116
134
334
335
334
124
124
124
124
228
78.3
56.4
Acetone
783
784
785
786
Ref.
B.P.,C. W t . % A
222
P e rfluo roheptane,
crit. region
Data
Ethane
C H6
7
2 -Methylnaphthalene
SERIES
128.7
11
A =
CHEMISTRY
Nonazeotrope
78.28
93.6
v-1
Nonazeotrope
v-1
74.0
39
74.8
34
70.7
60.6
Nonazeotrope
v-1
46.4
68
62.4
82
72.19
88
78.25
>98
% A l e . increases v-1
with press.
15.95
...
30.97
72.18
25.8
Nonazeotrope
v-1
Nonazeotrope
v-1
v-1
Nonazeotrope
82.2
49 .
Nonazeotrope
32
54.4
30.1
22 v o l . %
52.6
78
93.3
60
18.4
Nonazeotrope
65.5
20
Min. b.p.
45
26.2
32.5
23.2
51.2
28.1
29.97
21.33
38.37
23.72
47.15
26.32
61.06
30.35
35.0
24.3
67.9
31.7
v-1
v-1
v-1
v-1
v-1
v-1
v-1
117
117
228
134
134
335
335
334
335
291
334
134
334
134
334
201
22
240
240
328
328
328
328
256
191,
344
TABLE
BINARY
SYSTEMS
29
Azeotropic
B-Component
Formula
No.
C H 0
2
804
805
806
807
808
809
810
C H6
6
C H N
C Hio
6
CHIO
C Hio
QHio
6
1 2
Name
B.P.,C.
Ethyl Alcohol
(continued)
B e n z e n e (continued)
"
5570 m m .
"
11,720 m m .
"
19,160 m m .
Aniline
1,3-Hexadiene
2,4-Hexadiene
3 -Methylcyclopentene
3-Methyl-l,3pentadiene
C y c l o h e x a n e , 296 m m .
420 m m .
643 m m .
"
760 m m .
"
760 m m .
2-Ethyl-1-butene
1 -Hexene
cis-2-Hexene
cis- 3-Hexene
Methylcyclopentane
cis-3-Methyl-2-pentene
trans-3-Methyl-2pentene
trans-4-Methyl-2pentene
Butyl vinyl ether
Paraldehyde
Hexane
"
1545 m m .
2 - Methylpentane
Ethyl butyl ether
Isopropyl ether
1,2- D i e t h o x y e t h a n e
Triethylamine
Toluene
11
C H
818
C H
819
820
821
822
C H 0
C H 0
823
824
825
826
827
828
C H
H i 2
H i 2
H i 2
C
C
1 2
H i 2
1 2
1 2
1 2
l P 3
C Hi
C
QH140
c ^ p
C
C H
C H
l P 2
1 5
...
...
184.35
72.9
82
64.9
77
.. .
..
64.95
63.49
68.8
66.4
72.0
70.52
67.6
58.4
94.2
83.4
124.5
68.95
...
60.27
92.2
68.3
121.1
89.7
110.7
327 m m .
800 m m .
1,3-Heptadiene
2,4-Heptadiene
1,1-Dimethylcyclo87.85
pentane
cis-1,2 -Dimethyl 99.53
cyclopentane
trans -1,2 - D i m e t h y l 91.87
cyclopentane
cis -1,3-Dimethyl91.73
cyclopentane
trans -1,3 -Dimethyl 90.77
cyclopentane
2 , 3 - D i m e t h y l - 1 - pe nte ne 84.2
103.47
Ethylcyclopentane
1,1,2,2- Te tr amethyl 75.9
cyclopropane
79.20
2,2 - D i m e t h y l p e n t a n e
89.78
80.50
2,4-Dimethylpentane
86.07
93.47
3 -Ethylpentane
98.4
Heptane
11
...
.. .
.. .
11
829
830
831
7 1 2
C H i 2
832
833
7 14
834
C H
7
835
C H
836
837
838
C H
C H u
C H
839
840
841
842
843
844
C H
7
H u
7 16
C H
C
7
7
7
C
16
16
16
H
11
180
Wt.%A
Ref.
56
69.5
81
256
256
256
138
80
80
291
78.3
11
811
812
813
814
815
816
817
B.P.,C.
Data
mm.
...
132.9
166.9
191.1
.. .
v-1
...
M i n . b.p.
M i n . b.p.
57.2
20 v o l . %
M i n . b.p.
41.2
49.3
60.8
64.8
64.9
57.0
56.1
59.5
49.6
60.05
60.4
25.5
27.3
29.8
31.3
40
23 v o l .
22 v o l .
22 v o l .
26 v o l .
22.7
24 v o l .
58.8
%
%
%
%
v-1
%
20 v o l . %
80
316
316
316
316
147
291
291
291
291
304
291
291
15 v o l . %
291
52.6
335
48
73
33
335
69.2
Nonazeotrope
334
20.8
v-1
304
58
26.3 v o l . % 251
2
91
12 v o l . %
53.1
73.8
49.3
335
17.1
335
64
Nonazeotrope
334
76.9
51
335
66.7
v - 1 138,
76.5
191
117
76.2
117
81.6
80
M i n . b.p.
M i n . b.p.
80
. .
.. .
68.0
3 7 vol. %
291
72.1
46 v o l . %
291
69.6
39 v o l . %
2-91
69.5
38 v o l . %
291
69.1
67.1
73.1
37 v o l . %
35 v o l . %
48 v o l . %
291
291
291
62.6
63.9
68.6
64.6
67.1
70
72
30
25
34
29
38
38
48
37.5
43
vol.
vol.
vol.
vol.
vol.
vol.
%
%
%
%
%
%
v-1
239,
v-1
291
291
291
291
291
291
138,
335
158
ADVANCES
30
IN
B-Component
No.
Formula
Name
Ethyl Alcohol
(continued)
844
7 16
11
11
845
846
847
^7 16
7 16
C8 16
H
848
8 16
849
8 16
850
C8 16
H
851
8 16
852
8 16
853
8 16
854
8 16
855
856
857
858
859
860
861
C
C
C
C
C
C
C
862
C Hi
863
864
C Hi
865
866
CeHieO
8
8
H
H
H
Hi
H
H
H
1 8
1
8 18
H
8 182
H
C H60S
2
867
C H6
C H 0
C H 0
869
Dimethylsulf oxide
Benzene,
868
C ^ C i p
25-70
Ethylene G l ycol
872
C He02
C H30
4
carbonate,
10 m m .
"
25 m m .
"
50 m m .
"
72 m m .
Bis(2-chloroethyl)
ether, 50 m m .
C5H12O3
2 -Vinyloxyethanol
Ethylene glycol
monoacetate
"
150 m m .
2 -(2 -Methoxyethoxy)
ethanol
50 m m .
"
200 m m .
Aniline, 37.1 m m .
"
104.7 m m .
"
257.9 m m .
11
873
C H N
6
B.P.,C.
B.P.,C.
Data
Wt.%A
Ref.
78.3
. .
...
90.05
91.85
54.5
71.0
68.7
69.3
43
45
36 v o l .
36 v o l .
119.54
76.2
65 v o l . %
291
124.32
76.9
70 v o l . %
291
124.45
76.9
70 v o l . %
291
119.35
76.2
64 v o l . %
291
121.52
76.5
66 v o l . %
291
117.5
75.9
62 v o l . %
291
109.29
74.3
52 v o l . %
291
104.91
106.84
115.61
117.73
117.65
118.93
117.71
73.9
73.6
75.5
75.8
75.8
76.0
75.8
50
46
57
60
59
61
61
%
%
%
%
%
%
%
291
291
291
291
291
291
291
109.84
74.3
53 v o l . %
291
99.24
71.8
40 v o l . %
291
114.76
75.3
56 v o l . %
291
113.47
142.1
57 v o l . %
75.1
Nonazeotrope
291
334
243.1
Nonazeotrope
334
V.p.
164
...
...
vol.
vol.
vol.
vol.
vol.
vol.
vol.
curve
v-1
v-1
%
%
158
158
291
291
197.4
Ethylene
It
870
871
Azeotropic
SERIES
Heptane
(continued)
400 m m .
750 m m .
2 -Methylhexane
3 -Methylhexane
1,1 - D i m e t h y l c y c l o hexane
cis -1,4 - D i m e t h y l cyclohexane
trans -1,3 - D i m e t h y l cyclohexane
1-Ethyl-l-methylcyclopentane
l,cis-2,trans-3Trimethylcyclopentane
l,trans-2,cis-4Trimethylcyclopentane
2,4,4-Trimethyl2-pentene
2,2- Dimethylhexane
2,3- Dimethylhexane
3,4- D i m e thylhexane
2 -Methylheptane
3 - Methylheptane
4 -Methylheptane
2,2,3-Trimethylpentane
Butyl ether
2-Ethyl-l,3hexanediol
CHEMISTRY
...
...
96
178.6
143
..
...
194
115
151
...
...
...
88
107
122
163
13.9
7.5
2.6
0
262
262
262
262
92.7
164
...
17.8
13
335
60
94
Nonazeotrope
Nonazeotrope
147
147
...
...
114
149
95
120
145
30
4
12
8.75
12.7
16.8
284, 335
335
335
59
v-1
59
v-1
59
v-1
TABLE
BINARY
SYSTEMS
31
Azeotropic
B-Component
No.
Name
Formula
C2H5O2
874
CgHiP
875
C H
6
1 4
Ethylene G l ycol
(continued)
Hexyl alcohol
2 -(2 -Ethoxyethoxy)
ethanol
197.4
CgHô
C H N
8
Nonazeotrope
202.8
137.3
45.5
33
26.6
2.3
56
26
284, 3 3 5
335
243
335
60
188
110.6
205.2
191
22.9
26.6
30.0
6.9
v-1
v-1
v-1
144*4
95
120
145
135.7
17.6
21.8
26.5
9.7
6.4
v-1
v-1
v-1
171.3
142.1
95
120
145
170.5
139.5
230.6
M i n . b.p.
79
111
127
197.8
217.9
74
104
121
184.5
183.6
Phenyl ether, 50 m m .
i'o
259.3
137.0
340
100 m m .
36 m m .
11
11
882
883
884
C H
CeH
C H
885
C H
1 8
N
0
0
NO
1 9
11
11
A =
886
887
888
CoH 0
CioH
Cj()H oOS
889
CXQH220
890
Ci2H
891
892
893
Ci H 0
Ci Hio
C H Q
2 6
1 6
3 4
CgH^S
8 9 4 C5H10
895
A =
1 4
C H
5
896
C 5 H 1 0
897
C 5 H 1 2
898
899
C H
C H
5
C2H6S2
900 C s H ^
9 0 1 C5H12S
902
C H
903
C H
904
C H
905
CeH
7
1 6
906
C8H
907 Q H
A =
1 8
C H N
2
Hexyl ether, 50 m m .
Anthracene
2-Ethylhexyl ether,
10 m m .
Methyl Sulfide
Cyclopentane
2 - M e t h y l - 2 -butene
2 -Methyl -1 -butene
2 -Methylbutane
Pentane
2,2- Dimethylbutane
908 C ^ ^ N O
334
157.1
11
880
881
Ref.
Wt.%A
Toluene
Benzyl alcohol
o-Cresol
-Methylaniline,
31.8 m m .
"
95.3 m m .
244 m m .
-Xylene
,N -Dimethylaniline,
39.3 m m .
115 m m .
293 m m .
s-Collidine
B u t y l ether
2 - (2 - B u t o x y e thoxy)
ethanol
2 -Diisopropylaminoethanol, 10 m m .
50 m m .
100 m m .
Phorone
Naphthalene
2 -Hexylthioethyl
vinyl ether
Tripropylene glycol
methyl ether
11
Q H e
C HaO
C HeO
C HoN
B.P.,C.
192
134
108.5
110.1
193.1
189.52
"
876
877
878
879
B.P.,C.
Data
Methyl Disulfide
2 -Methylthiophene
Ethyl isopropyl sulfide
Toluene
Methylcyclohexane
Heptane
trans-1,3 -Dimethyl cyclohexane
2,3 - Dimethylhexane
2 -Methylheptane
Dimethy lamine
2 - (Dimethylamino)
ethanol
59
59
59
188
334, 335
284
335
335
335
59
147
10
15
18
42
46
329
M i n . b.p.
243
135
192
138.5
111.5
120.4
192.3
112.8
197
59
59
59
335
82
77.2
75.1
62.3
64.5
35.6
98.3
v-1
76
76
76
335
59
335
305
335
87
37.32
87.5
53.6
17.0
25.0
46.6
79.8
70
70
70
70
70
70
111.92
107.22
110.85
101.05
98.40
Nonazeotrope
106.37
108.93
98.92
28.6
26.3
96.44
. ..
...
70
70
70
70
70
120.30
109.15
117.70
107.22
102.84
106.22
73.3
48.2
69.5
70
70
70
49.35
38.60
31.25
27.90
36.15
49.70
37.09
34.83
30.64
26.62
31.80
36.50
109.44
7.4
134.6
Nonazeotrope
334
32
ADVANCES
IN
B-Component
No.
A=
Formula
C H N
2
909
910
A=
C 4 H 1 1 N
C4H11NO2
C2H7NO
911
912
A=
CÔ
C H
4
A =
N 0
C H N
C4H8
C HKP
2
913
914
915
916
917
Diethylamine
2,2'-Iminodiethanol
2-Aminoethanol
2
Acetone
2,2-Iminodiethanol,
10 m m .
Ethylenediamine
p-Dioxane
Butyl alcohol
Isobutyl alcohol
Benzene
Toluene
C 4 H K P
CH
C H
7
Name
Ethylamine
C3UF 0
5
CHEMISTRY
Azeotropic
B.P.,C
B.P.,C.
SERIES
Data
Wt.%A
Ref.
16.6
55.5
Nonazeotrope
Nonazeotrope
334
334
Nonazeotrope
334
Nonazeotrope
334
Nonazeotrope
124.7
35.7
120.5
50
Nonazeotrope
104
30.8
103
30
334
335
335
334
76
334
171.0
56.1
150
116.9
101.3
117.7
107.9
80.1
110.7
Pentaf luoropropionic
Acid
918
A=
C6F14
P e r f l u o r o h e x a n e , 25 C .
CsHaClFaOj^
919
A=
C H NO
3
C H F 0
3
920
A =
C3H NO
7
. . .
3-Chloro-2,2,3t rifluoropropionic A c i d
N,N, -Dimethylforma m i d e , 20 m m .
Nonazeotrope
115-120
2,2,3,3-Tetrafluoropropionic A c i d
N,N-Dimethylforma m i d e , 20 m m .
v-1
237
...
93
67
93
101-106
...
93
91-4
187
66
...
93
93
40
C3H3CIF3NO 3-Chloro-2,2,3921
A=
trifluoropropionamide
, -Dimethylf o r m a m i d e , 20 m m .
C3H NO
7
C3H3F4NO
922
A=
CjHyNO
C3H3N
923
A =
C H5N
A =
C 3 H 6
C 3 H 8
4
C H
C H
C3H
C H
928
929
930
A =
C3H4CI4
931
A =
C H C1
5
A =
C H 0
C H
3
932
0 3 ^ 0 2
933
C H 0
s
.. .
153
Acrylonit rile
77.2
Propadiene
C 3 H 4
C H
propionamide
,N - Dimethylf or m a m i d e , 20 m m .
"
Propionitrile
C3H4
924
925
926
927
2,2,3,3-Tetrafluoro-
97.4
Nonazeotrope
334
-32
Propyne
Propene
Propane
1,3-Butadiene
-23.2
-47.7
-42.1
-4.5
Nonazeotrope
Nonazeotrope
-42
11.6 v o l . %
Nonazeotrope
334
334
334
334
Propyne
Propene
Propane
1,3-Butadiene
-23.2
-47.7
-42.1
-4.5
Nonazeotrope
-42
11.7 v o l . %
Nonazeotrope
334
334
334
Nonazeotrope
250
Tetrachloropropane
Tetrachloropentane,
12-150 m m .
2-Propyn-l-ol
Benzene
115
80.1
Acrylic Acid
Ethyl acrylate
141.2
99.3
78
v-1
Nonazeotrope
95
334
TABLE
BINARY
33
SYSTEMS
Azeotropic Data
B-Component
No.
A =
Formula
C3H5CI
934
A =
3-Chloropropene
2 -Chloropropane
C^Cl
C H C10
3
9 3 5 C5H7CIO
A =
936
A =
. . .
10
341
Propene
Propane, 10--190F.
-48
. . .
Nonazeotrope
v - 1 128
Nonazeotrope
Nonazeotrope
334
334
939
C H 0
940
CaHgO
C H80
1.2- Dichlo r opropane

Propylene oxide,
20 p . s . i . g .
1.2- P r o p a n e d i o l
96.3
60
187.3
Acetone
Isopropyl alcohol
56.5
82.3
Nonazeotrope
Nonazeotrope
Nonazeotrope
v-1
941
C H 0
942
C H 0
943 C ^ C l
4
Diketene
V i n y l acetate
1 - Chlor - 2- methyl propene
2 -Butanone,
15-500 p.s.i.a.
C HgO
4
CgHgOjj
946 C5H10
947
948
C H
C H
949
1 0
C H
C H
951
952
C H
C H
953
954
955
956
957
C
C
C
C
C
958
959
C H60
0
C HaO
960
961
962
963
CsHeOi
C H
C H
C H 0
H
H
H
H
H
Isopropenyl acetate
1 - Pentene
Isopropyl acetate
Pentane
"
<100 m m .
Benzene, 45 C .
it
950
1 2
1 2
Cyclohexane
0
0
Methylcyclopentane
1,1,2-Trimethylcyclopropane
4-Methyl-2-pentanone
B u t y l acetate
2.3- Dimethylbutane
Hexane
Heptane
A l l y l Al coh ol
Isopropyl alcohol
72.7
68
1 2
1 4
1 4
CsHgO
964
C H50
965
CsHgO
966
C H60
C H O
967
968
C H 0
C H
C7H
A l l y l acetate
Cyclohexane
Hexane
Isopropyl ether
55.6
96.5
29.97
88.7
36.15
...
.. .
80.1
80.75
80.75
72.0
52.6
1 11155 . 99
126.2
58.0
68.95
98.4
96.6
82.3
8.*8
68.8
68.3
Propionaldehyde
Propylene oxide,
30 p . s . i . g .
2-Methylfuran
48.7
Propylene Oxide
Ethyl ether
35
34.5
69
63.7
45,
46
334
334
241
81
Nonazeotrope
67*4
A=
83
C H
CÔ
A =
v-1
v - 1 337
938
A=
Nonazeotrope
Ref.
Nonazeotrope
C&Cl
A =
W t . % A
116.45
156.85
A=
945
45.15
34.9
B.P.,C.
Epichlor ohyd r in
1,2,3-Trichloropropane
944
2-Chloro-2-propen-l-ol
2-Chloroallyl vinyl
ether
B.P.,C.
CsHgClO
C H C1
9 3 7 C3H8
A =
Name
v-1
Nonazeotrope
28.9
19 v o l . %
Nonazeotrope
32.5
20
Nonazeotrope
Nonazeotrope
v-1
Nonazeotrope
v-1
v-1
53.0
67.5
67
57
42.3
32 v o l . %
v-1
Nonazeotrope
Nonazeotrope
v-1
46.5
256,
49.8
59
89.5
254,
334
147
291
334
131
131
23
36
186
256
256
291
157
63
256
334
256
5
63
58
12.5
Nonazeotrope
172
341
334
1
147
176
334
Nonazeotrope
Nonazeotrope
334
270
Nonazeotrope
66.6
95.1
74.0
32.6
10
49.6
v-1
243
1 0
1 6
1.3- Dioxolane
Toluene
Heptane
75.6
110.6
98.4
Nonazeotrope
72.3
81
334
334
ADVANCES
34
IN
Azeotropic
B-Component
No.
Name
Formula
1,3-Dioxolane
(continued)
=
969
970
CgHxgO
C H o
Butyl ether
Nonane
C H 0
Ethyl Formate
971
C H Br
972
973
974
975
976
977
978
979
980
981
982
983
984
985
986
987
988
989
990
C H Br
CsHejO
C H
C H
C H
C H
CeHg
C H
C H
C H 0
3
991
992
993
994
995
996
997
998
999
1000
1001
=
2 -Bromopropane
Methyl Acetate
2 -Bromopropane
2-Methylfuran
Cyclopentene
Cyclopentane
1 -Pentene
Pentane
Benzene
1,3-Cyclohexadiene
Cyclohexene
Cyclohexane
2,3-Dimethyl-1-butene
2,3- D i m e t h y l - 2 - butene
3,3-Dimethyl -1 -butene
2-Ethyl-1-butene
1 -Hexene
cis-2-Hexene
3 - M e t h y l - 2 -pentene
4 - M e t h y l -1 -pentene
trans-4-Methyl 2-pentene
Methylcyclopentane
2.3- Dimethylbutane
Hexane
2-Methylpentane
3 -Methylpentane
Heptane
2-Methylhexane
3 - Methylhexane
2,2,3 - T r i m e thylbutane
Q 12
C Hi
Q H
CeHi
CHi
Q H
C6H
Q H
Q H i
Q H
H
1 2
C H
Q>H
C6H
6
1 4
1 4
Q>H
Q
Q H
Q H
C Hi
C H
C H
H
1 4
C H 0
3
1002
1003
1004
C H60
CgHgN
1005
1006
1007
Q H u
Q H
C5H11NO
1
8 18
H
Propionic A c i d
Acetic anhydride
Pyridine
N,N-Dimethylpropionamide
Hexane
Heptane
Octane
M
"
1008
1009
C9H20
1010
C n H
=
1011
1012
CioH
C H<s0
3
C H
8
Nonane
Decane
Undecane
2 2
8 10
6 12
=
1013
A =
1014
Satd. with N a
propionate
Methyl Glycolate
Ethylbenzene
m-Xylene
s - T r i ox a n e
H
C H C10
3
CgH^CÔ
Cyclohexane
Propylene Chlorohydrin
Bisfchloroisopropyl)
e t h e r , 100 m m .
CHEMISTRY
] .P.,C.
B.P.,C.
SERIES
Data
Wt.%A
Ref.
75.6
.42.1
.50.8
334
334
Nonazeotrope
Nonazeotrope
54.1
59.35
53.0
59.4
195,
252
56.95
59.35
.. .
44.4
49.3
30.1
36.08
80.1
80.25
83.1
80.6
55.62
73.38
41.4
64.8
63.58
68.55
70.64
54.0
58.45
71.8
49.65
58.05
68.85
60.2
63.25
80.7
98.45
90.0
91.85
80.9
14.5
55.6
Nonazeotrope
27.7
41.7
37.9
43.2
30.0
3.3
22
34.05
99.7
56.7
98.0
56.7
90.2
56.5
83.0
54.9
42.8
48.95
71.8
55.1
39.9
8.8
60.1
52.8
63.6
52.5
69.8
53.7
73.7
54.45
36.7
48.3
50.0
53.0
43.7
48.0
51.75
49.25
50.05
54.7
56.65
56.0
56.3
55.1
195
270
126
126
126
126
126
126
126
126
126
126
126
126
126
126
126
126
51.3
68.0
38.2
48.25
60.7
51.6
57.4
72.4
96.45
88.6
84.9
74.2
126
126
126
126
126
126
126
126
126
126
126
126
140.7
138
115.5
Nonazeotrope
67.2
148.6
175.5
68.85
98.15
125.12
125.12
...
179.3
23.6
Nonazeotrope
2.0
97.82
24
120.89
24.2
...
6
.. .
150.67
174.06
193.85
134.27
54
80.5
139.76
Nonazeotrope
151.2
136.15
139
M i n . b.p.
M i n . b.p.
...
v-1
v-1
v-1
250
370
295
189
189
189
154
154
189
189
189
52
52
114.5
80.75
M i n . b.p.
52
73/100
121.9
Nonazeotrope
334
TABLE
BINARY
SYSTEMS
35
Azeotropic Data
B-Component
No.
=
1015
Formula
1017
Nonazeotrope
CjH NO
Propionamide
D e c a n e , 50 m m .
"
100 m m .
"
200 m m .
"
760 m m .
U n d e c a n e , 50 m m .
100 m m .
"
200 m m .
"
760 m m .
D o d e c a n e , 50 m m .
100 m m .
"
200 m m .
760 m m .
CloH22
11
24
1 2
2 6
C H N0
3
=
1025
1026
1027
1028
1029
1030
=
1031
1032
1033
CaHeO
C H p
C H p
C H p
C H p
4
1 (
1 (
1 (
1 (
C H N0
C H 0
CsHeO
C H O
CiHidO
C H O
C H p
3
l d
l d
1 {
C H O
C Hs0
3
CAO2
C H30
4
1034
1035
C He0
QEfeCl
1036
1037
1038
1039
1040
C ^ X Q O
C H N
CsH O
C Hi O
4
10
216
26
26
26
26
26
26
26
26
26
26
26
26
1- Nitropropane
Isopropyl alcohol
Propyl alcohol
Butyl alcohol
sec-Butyl alcohol
tert-Butyl alcohol
Isobutyl alcohol
131.18
82.40
97.15
117.73
99.53
82.41
107.89
Nonazeotrope
8.8
96.95
32.2
115.30
4.1
99.40
Nonazeotrope
15.2
105.28
55
55
55
55
55
55
2- Nitropropane
Isopropyl alcohol
Propyl alcohol
Butyl alcohol
sec-Butyl alcohol
tert-Butyl alcohol
Isobutyl alcohol
120.25
82.40
97.15
117.73
99.53
82.41
107.89
4.2
82.24
24.9
95.97
52.4
111.61
18.0
98.70
Nonazeotrope
33.1
105.28
55
55
55
55
55
55
11
11
11
11
11
C
C
C
C
C
H
Hio
Hio
H O
H
1 0
1 0
1 2
11
11
1046
1047
C H 0
C HisN
6
1 2
...
173*3
...
.
194.5
...
Isopropyl Alcohol
82.3
72.7
V i n y l acetate
p-Dioxane
E t h y l acetate
77*05
"
40-60 C .
Methyl propionate
*79*6
1- C h l o r o - 2 - m e t h y l propane
68.9
Ethyl ether
34.6
Butylamine
77.8
2- Pentanone
102.35
B e n z e n e , 155 m m .
"
243 m m .
509 m m .
607 m m .
"
760 m m .
"
196 m m .
512 m m .
4920 m m .
10,180 m m .
15,380 m m .
1.3- Hexadiene
72.9
2.4- Hexadiene
82
3 - M e t h y l - 1 , 3 - p e n t a d i e n e 77
M e s i t y l oxide
128
C y c l o h e x a n e , 129 m m .
270 m m .
"
434 m m .
549 m m .
"
760 m m .
4- Methyl-2-pentanone 115.9
Diisopropylamine
84.1
11
1041
1042
1043
1044
1045
222
3
5
7.5
11.8
15
16
17.3
21
26
26
26
31.6
11
C 3 H 8 O
52
88
106
126
168
105
123
142
183
115
132
152
193
11
1019
1020
1021
1022
1023
1024
Ref.
B.P.,C. W t . % A
N,N-Dimethylfor mamide 153

Benzene
80.1
11
1018
B.P.,C.
CjHyNO
C H
7
1016
Name
70.8
22.4
...
75.9
2. 5.
77"
28
63.8
19
Nonazeotrope
84.7
60
16.5
Nonazeotrope
31.8
20.6
41.8
23.6
60.4
29.9
65.3
31.4
71.74
33.7
37.2
22.4
60.3
30
134.7
62
166.3
79
186.1
91
Min. b.p.
Min. b.p.
Min. b.p.
Nonazeotrope
26.3
18.3
42.5
23.3
54.1
27.1
60.2
29.2
69.4
32
Nonazeotrope
79.7
40
v-1
v-1
v-1
v-1
335
47
228
228
335
335
334
335
341
11
316
316
316
316
316
256
256
256
256
256
80
80
80
334
316
316
316
316
316
11
335
36
ADVANCES
IN
A -
Formula
C H O
3
Isopropyl Alcohol
(continued)
Hexylamine
Toluene
1 0 4 8 C6H15N
1049
C H
1050
CeHu
1051
C H
1 6
1052
CgH
1 6
1 6
1053
C H
1054
C H
1055
C H
8
1 6
1056
C H
8
1 6
1057
C H
8
1 6
1058
C H
8
1 6
1059
C H
1 8
A =
II
Diisobutylene
cis-1 -Ethyl - 2-methyl cyclopentane
trans-1-Ethyl-2methylcyclopentane
trans-l-Ethyl-3methylcyclopentane
1,1,2-Trimethylcyclopentane
1,1,3-Trimethylcyclopentan
1 6
C HeO
3
1060
1061
1062
1063
C
C
C
C
H S
H 0
H O
H O
8
Name
1 0
1 0
B.P.,C.
CgHgCl
CgHg
132.7
110.7
110.6
102.3
79 v o l .
291
128.05
82.2
83 v o l .
291
121.2
81.6
76 v o l .
291
120.8
81.4
75 v o l .
291
113.73
80.4
66 v o l .
291
104.89
78.5
53 v o l .
291
117.5
81.1
71 v o l .
291
116.73
80.9
71 v o l .
291
99.3
77.3
48.5
66.4
8.65
P r op y l Alcohol
97.25
1 - P r o p a n e t h i o l , 7 6 6 m m. 6 7 . 8
Ethyl acetate,
40-60 C.
77.05
3-Pentanone
101.8
P r o p y l acetate
101.6
200 m m .
"
400 m m .
"
600 m m .
"
760 m m .
132
Chlorobenzene
B e n z e n e , 239 m m .
" 44.7-309.7 p.s.i.g.
"
123 m m .
"
289 m m .
423 m m .
"
610 m m .
"
760 m m .
342 m m .
"
573 m m .
"
2420 m m .
5020 m m .
10,050 m m .
18,200 m m .
C y c l o h e x a n e , 161 m m .
"
250 m m .
"
429 m m .
560 m m .
760 m m .
4-15 atm.
8*3
2 -Methylpentanal
(Trimethylsiloxy)
p r o p a n e , 735 m m .
100.3
110.7
Toluene
110.6
II
110.7
II
S t y r e n e , 50 m m .
11
11
11
11
11
11
1067
1068
C H 0
C H OSi
1069
C H
7
1070
CeH
1 2
1 6
334
327
335
335
Nonazeotrope
52
69
80.6
54.5
77.8
81.4
11
C H
Ref.
Wt.%A
123.42
11
1066
B.P.,C.
82.3
1064
1065
SERIES
Azeotropic Data
B-Component
No.
CHEMISTRY
...
.. .
Nonazeotrope
57
94.9
94.7
49
31.4
59.96
39.2
77.06
88.04
44.8
94.7
48.9
80
96.5
10.5
45
E f f e c t of p r e s s .
8.0
28.0
49.8
11.6
59.9
13.6
15.7
70.1
77.10
17.1
53.7
12.3
15.3
68.6
27.5
117.6
37
147.5
50.5
183.8
218.3
66.1
9.9
33.8
44.3
11.8
15.0
58.0
16.5
65.4
18.5
74.69
E f f e c t of p r e s s .
95
86
v-1
181
v-1
v-1
v-1
v-1
v-1
v-1
v-1
v-1
316,
316,
316,
316,
316,
87.5
50.5
49
v-1
51.5
92.6
v-1
84
38.5
% P r O H increases
with press.
9...
2.6
29
228
334
264
306
306
306
306
334
24
277
344
344
344
344
344
256
256
256
256
256
256
316
316
316
316
316
278
334
193
327
334
202
211
211
TABLE
BINARY
SYSTEMS
37
B-Component
No.
Formula
C HeO
8 10
1072
8 10
E t h y l b e n z e n e , 50 m m .
-Xylene
2-Methylthioethyl
v i n y l e t h e r , 22 m m .
1073
^
0
C H
3
1074
1075
2 -Methoxy ethanol
Benzene
Cyclohexane
Q H 1 2
1076
1077
C H
1078
C H
1079
1080
1081
Ce io
C H
1082
CeHi
1083
^8^16
H i 2
1084
8 16
1085
8 16
1086
^8^16
1087
^8^16
1088
1089
1090
1091
C H
C Hi
C H
1092
9K20
1093
1094
C H o
8 16
H
C H 0
3
1095
1096
1097
C H
6 14
C
C
1 0
H 6
C
C
C
C
C
1104
1105
1106
^12^26
Ci H
H8
H60
H
H 0
H
1 8
16
2 O
C H 0
3
1,2 -Propanediol
1098
1099
1100
1101
1102
1103
1107
trans-2 -Heptene
1- tert-Butoxy-2methoxyethane
S t y r e n e , 57 m m .
"
62 m m .
-Xylene
?-Vinylcyclohexene,
57 m m .
cis-1,3-Dimethyl cyclohexane
l,cis-2,cis-3-Trimethylcyclopentane
l,trans-2,cis-3-Trimethylcyclopentane
2,4,4-Trimethyl1-pentene
2,4- Dimethylhexane
1,1,3-Trimethylcyclohexane
2,2,3,4 - T e t r a m e t h y l pentane
2,3,4 - T r i m e t h y l h e x a n e
2,3,5 - r i m e thylhexane
7 16C>2
5 102
H
...
138.4
3-Vinyloxy-lpropanol
Wt.%A
Ref.
% P r O H increases
with press.
92
...
211
327
...
...
75
20
329
124.5
80.1
80.7
...
98.0
67.9
...
138.35
Nonazeotrope
v-1
Nonazeotrope
15
v-1
77.5
19 v o l . %
92.9
331
334
331
291
119
54.8
56.8
51.9
119.3
76
291
152
152
291
45
62 v o l .
50.1
34.3
54 v o l .
%
v-1
v-1
%
.. .
44.4
30 v o l . %
291
120.9
105.6
36 v o l . %
291
121.2
106.3
32 v o l . %
291
120.8
106.0
35 v o l . %
291
96.7
20 v o l . %
291
123.0
107.4
35 v o l . %
291
110.2
100.2
20 v o l . %
291
95.5
99.3
99.7
20 v o l . %
26 v o l . %
25 v o l . %
291
291
291
136.6
113.1
41 v o l . %
291
133.02
139.0
131.34
111.4
113.5
110.6
39 v o l . %
39 v o l . %
40 v o l . %
291
291
291
104.89
101.44
109.43
109.84
187.8
3 - V inyloxypropanol
...
Benzene
80.1
Dipropylene glycol,
10 m m .
.. .
Toluene
110.6
Coumarone
173
0-Xylene
144.4
142.1
Butyl ether
Naphthalene
218.1
Tripropylene glycol
m e t h y l e t h e r , 50 m m .
.. .
Dodecane
216
252.5
Tetradecane
Bis( 2-ethylhexyl)
e t h e r , 10 m m .
135
1,3-Propanediol
B.P.,C.
97.25
2-(Methylthio)ethanol
C H OS
B.P.,C.
P r op yl Alcohol
(continued)
1071
Name
Azeotropic Data
M i n . b.p.
Nonazeotrope
94
334
Nonazeotrope
v-1
1.5
110.5
Azeo. distillation
10
135.8
334,
136
Azeo. distillation
60
335
120
335
335
120
Nonazeotrope
67
175
179
76
84
76
60
60
335
214
10-15
94
38
ADVANCES
1108
1109
1110
1111
1112
1113
Formula
CaHgS
C H
6
1 2
12
12
C H
6
6 14
CTH
C
C3H9BO3
CHEMISTRY
Azeotropic
B-Component
No.
IN
B.P.,C.
SERIES
Data
Wt.%A
Ref.
Name
l.P.,C.
E t h y l Methyl Sulfide
Cyclohexane
1 -Hexene
Methylcyclopentane
2,3- Dimethylbutane
Hexane
66.61
80.35
63.50
71.85
58.10
68.75
79.20
Nonazeotrope
29.4
62.71
65.59
64.1
18.7
57.41
63.94
56.6
88.2
66.37
T r i m e t h y l Borate
Tetrahydrofuran
68.7
65
Nonazeotrope
32.4
68.7
Nonazeotrope
334
70
70
70
70
70
70
v - -1
115
1114
C ^ g O
A =
1115
C H N
C H
Isopropy lamine
Hexane
A =
1116
1117
CjHNO
CgHgCl
C H N0
1- Ami n o- 2 - p r op a n ol
Chlorobenzene
l,l'-Iminodi-2p r o p a n o l , 100 m m .
Toluene
Heptane
159.9
131
128.30
13
259
185
110.7
98.4
Nonazeotrope
110
5
6
96.6
334
259
334
1,2 - P r opanediamine
Butyl alcohol
Isobutyl alcohol
Toluene
120.9
117.7
107.9
110.6
126.5
123
105
49
65
32
335
335
334
1 4
1118
1119
C H
0,
1120
1121
1122
C
C
C
C
A =
H
H
H
H
1 6
N
O
O
1 0
1 0
1 0
C C1 F
1123
C C1 F
1124
1125
C H
CeF
1126
1127
1128
C
C
C
C
1129
1130
C H20
C H
C H 0
A =
A =
1 6
HF 0
H
H
H
7
A =
1 6
2 2
C H
C H C1
4
1131
C4HA
A =
1132
A =
C H
7
C H S
4
1133
1134
C^ I Q S
1136
1137
1138
1139
QsHi
C H
C H
C H
1140
1141
1142
C H
C H
97.4
2,2,3-Trichloroheptafluorobutane
1,2 - D i c h l o r o h e x a fluorocyclopentene
Heptane
P e r f l u o r o c y c l i c oxide
90.6
98.53
102.6
Nonazeotrope
92.3
76
67
96.35
Perfluorobutyric A c i d
Ethylbenzene
m-Xylene
-Xylene
122.0
136.15
139
138.4
115.4
117.5
117.6
M a l e i c Anhydride
m - X y l e n e , 150 m m .
Uibutyl phthalate,
50 m m .
238
Vinylacetylene
2-Chloro-l,3b u t a d i e n e , 740 m m .
Thiophene
2-Butanethiol
Isopropyl methyl
sulfide
Benzene
Cyclohexane
Methylcyclppentane
Hexane
trans -1,3 - Dimethyl cyclopentane
Heptane
83.97
85.15
84.76
80.10
80.85
71.85
68.75
90.80
89.90
80.55
98.40
V
V
-1
-1
-1
354
354
354
52
52
52
80
83
82
Nonazeotrope
334
Nonazeotrope
334
Nonazeotrope
Diketene
T o l u e n e , 60 m m .
v-1
151
41
10
84
82.27
. ..
70
83.42
. ..
Nonazeotrope
77.90
41.2
71.47
14.0
68.46
11.2
82.00
80.90
76.58
83.09
67.7
64
42.7
83.2
70
70
70
70
70
70
70
70
70
TABLE
BINARY
SYSTEMS
39
Azeotropic Data
B-Component
No.
A =
Formula
^HgCl
1143
1144
C H C1
4
C H<p
4
Name
2-Chloro-l,3butadiene
1,3- D i c h l oro - 2 100 m m
"
340 m m
3-Butene-2-one,
100 m m
"
340 m m
B.P.,C.
butene,
.
.
Nonazeotrope
Nonazeotrope
v-1
v-1
151
151
.
.
Nonazeotrope
Nonazeotrope
v-1
v-1
151
151
A =
1145
A =
1146
1147
1148
1149
QHgOa
C H O
C6H
C7H
C H 0
V i n y l Acetate
Butyl alcohol
Cyclohexane
Heptane
Butyl ether
A =
1150
QHgOa
C H80
Ace t ic Anhydride
Isopropenyl acetate
Isopropyl acetate
Isopropyl ether
139.9
97.4
88.7
68.3
2-Chlor oe t hyl V i n y l
E t he r
Isoamyl alcohol
50 m m .
109.1
Cfifi
1 0
1 2
1 6
1 8
1151
1152
C6H
A =
2,3-Butanedione
2- Butanone
O 2
1 4
C H C10
4
1153
C Hi 0
5
11
C H Cl20
4
1154
1155
1156
C H
4
1 0
GiH O
u
C H
8
1 8
A =
C H O
1157 C ^ g C ^
4
1158
C H C1
4
1159
C Hi O
1160
C H<jO
Bis(2-chlor oethyl
Ether)
Diethylene glycol
3- Heptanol
2 - E t h y l -1 -hexanol,
50 m m .
2-Butanone
Isopropyl formate
1 - C h l o r o -2-methyl propane
sec-Butyl alcohol
374 m m .
2-Methylfuran
Benzene
14.7 p . s . i . a .
"
66.7 p.s.i.a.
118.0 p . s . i . a .
"
125.0 p . s . i . a .
Phenol, 200-760 m m .
2,5- Dimethylf ur an
Cyclohexane,
14.7 p . s . i . a .
"
66.7 p . s . i . a .
118.0 p . s . i . a .
"
125.0 p . s . i . a .
11
90.7
79.6
72.7
117.7
80.7
98.4
142.1
131.8
67
11
CgHgO
C HaO
C H
6
1 2
245.5
156.4
109
79.6
68.8
68.8
99.5
.. .
8.
0 . 1.
...
.. .
..3 ..3
9
11
1 1 6 5 QH14
1166
C6Hi
1167
C Hi
1168
C Hi
1169 q , H
Hexane
Methyl cyclohexane
Heptane
2,5- Dimethylhexane
A =
1170
1171
C HeO
C H 0
C H 0
4
Butyraldehyde
Isobutyraldehyde
Butyric acid
Nonazeotrope
334
Nonazeotrope
67.4
61.3
72
83.5
Nonazeotrope
334
334
334
334
Nonazeotrope
Nonazeotrope
Nonazeotrope
334
334
334
109
39
99
99
335
335
174.6
141.2
92
28
60
334
96
90
335
178.65
11
1162
1163
1164
Ref.
B.P.,C. W t . % A
80.85
80.85
80.85
58
68.95
101.15
98.4
109.4
74.8
69.5
163.3
310
Nonazeotrope
Nonazeotrope
Nonazeotrope
Nonazeotrope
Nonazeotrope
47
78.1
45
78.2
133.0
67.6
90.0
160.7
Nonazeotrope
Nonazeotrope
Nonazeotrope
71.0
128.7
156.4
182.5
71.6
71.5
...
52.5
61.0
64.0
69.0
45.5
44
42
15.1
29.6
80
73
95
Nonazeotrope
Nonazeotrope
V
V
V
V
V
V
V
V
V
-1
-1
-1
-1
-1
-1
-1
-1
-1
310
8
8
310
74
321
321
321
321
33
334
321
321
321
321
186
73
256
256
256
256
256
256
96
334
ADVANCES
40
IN
B-Component
No.
A
Formula
C H O
1172
1173
1174
1175
1176
A =
1177
1178
1179
C H
1 0
C H O
C H O
CeHi
C H 0
4
1 0
1 0
C 5 H 5 N
QH
NO
CllH
C H 0
C H O
Q H
O
Q H
C H 0
A =
C Hg0
1 0
C 7 H 8
1186
1187
1188
1189
CUHeQi
A =
1180
1181
1182
1183
1184
1185
Q H
C H40
C H
5
CHI
B.P.,C.
Butyraldehyde
(continued)
Isobutyl alcohol
1,1 - D i m e t h o x y e t h a n e
M e s i t y l oxide
Hexane
74.8
Nonazeotrope
Nonazeotrope
Nonazeotrope
60
26
Nonazeotrope
334
334
334
334
334
Bu t y r ic A c i d
Pyridine
,N -Dimethylbutyr a m i d e , 100 m m .
Undecane
162.45
115.5
163.2
370
124.5
194.5
130
162.4
p-Dioxane
Butyl alcohol
Isobutyl alcohol
Benzene, 200-760 m m .
Isopropyl ether
Toluene, 200-760 m m .
101.3
117.75
108
Cyclohexane
233 m m .
"
301 m m .
"
415 m m .
"
581 m m .
"
756 m m .
Butyl acetate
2-Butoxyethanol
.. .
68.3
...
A =
1192
1193
C Hi20
C H 0
6
C He0
C5Hg0
4
8 10
Isobutyric A c i d
Methyl acetoacetate
Ethylbenzene
30 m m .
Mixed xylenes
"
56 m m .
1 0
...
135.1
161.45
80.1
80.75
...
...
...
...
126.1
171.1
154.7
171.7
136.15
11
1194
C4H 0
1195
A
1196
1197
1198
1199
1200
1201
1202
A =
P r o p y l F o r ma t e
Hexane
6 14
H
C^gS
C6H14S
C H
7
8 16
H
8 16
CgHig
C Hig
8 18
H
1203
C ^ C l
C H O
1204
C H9Cl Sn
CgH Cl Sn
1205
Ci H
A =
1 0
1 8
2 7
ClSn
92
32.6
84.5
Nonazeotrope
101.3
Nonazeotrope
Nonazeotrope
Nonazeotrope
295
370
v - -1
v - -1
V-
-1
V
V
-1
-1
-1
-1
215
208
124
334
124
77.05
11
1190
1191
Ref.
B.P.,C. W t . % A
107.9
64.5
128.3
68.7
114
Isobutyl alcohol,
100-760 m m .
2 -Ethoxyethanol
2-Furaldehyde
Benzene
Q H 1 0 O 2
SERIES
Azeotropic Data
Name
E t h y l Acetate
CHEMISTRY
.. .
...
...
38.7
50.1
45.1
51
53.6
52.3
63.0
54.1
71.1
55.3
Nonazeotrope
Nonazeotrope
316
220
350
43,
44
43,
44
316
316
316
316
316
334
334
Nonazeotrope
133.0
8.8
48.0
0.8
133.0
10.0
62
1.0
334
84
84
84
84
Nonazeotrope
Nonazeotrope
Nonazeotrope
71.6
56
80.9
68.95
63.6
324
29.5
Tetrahydrothiophene
Isopropyl sulfide
Toluene
trans -1,3 -Dimethyl cyclohexane
Ethylcyclohexane
2,5 - D i m e t h y l h e x a n e
2 - Methylheptane
Octane
120.79
119.25
110.85
118.40
Nonazeotrope
70
70
120.30
131.85
109.15
117.70
125.70
115.90
120.46
107.95
113.96
117.79
70
70
70
70
70
1-Chlorobutane
Butyl alcohol
77.9
117.75
Nonazeotrope
Butyltin T r i c h l o r i d e
Dibutyltin dichloride,
17 m m .
Tributyltin chloride,
17 m m .
113/17
43.1
80.7
16.8
38.2
60.3
-1
335
157
Nonazeotrope
334
166
Nonazeotrope
334
TABLE
BINARY
SYSTEMS
41
Azeotropic
B-Component
No
=
1206
1207
=
1208
=
1209
1210
Formula
C4H9NO
C H
C H
8
l g
0
O
N 0
2-Methyl-2-nitropropyl vinyl ether,

10 m m .
B u t y l Alcohol
sec-Butyl alcohol
Isobutyl alcohol,
to c r i t . r e g i o n
1 (
C A P
C H p
4
1212
1213
1214
1215
1216
1217
1218
1219
1220
1221
1222
1223
C H!iN
4
C 5 H 5 N
5
- C
H i 2
C 6 H 1 2 O
C 6 H 1 2 O
C H
6
C 6 H 1 4
C H
C H
6
126.7
73
334
169.4
128
98
334
...
99.5
7 122
H
1226
C H
7
1 8
1227
C H
7 16
H
SiO
0
Nonazeotrope
v-1
Nonazeotrope
97.8
14.84
Nonazeotrope
118.6
69
Nonazeotrope
Nonazeotrope
Nonazeotrope
v-1
Cyclohexane
Butyl vinyl ether
Hexaldehyde
B u t y l a c e t a t e , 50 m m .
79.8
93.3
116.8
80.8
94.2
128.3
.. .
126.2
11
Hexane
68.95
171.1
2-Butoxyethanol
Toluene
110.7
"
200 m m .
.. .
"
400 m m .
...
600 m m .
...
760 m m .
...
B u t y l a c r y l a t e , 100 m m . 6 9 . 7 7
20 m m .
...
"
150 m m .
...
II
147
Heptane
98.4
II
98.4
(Trimethylsiloxy)
butane
.. .
...
"
100 m m .
...
300 m m .
...
500 m m .
...
"
760 m m .
136.15
Octane
125.75
Butyl ether
142.1
Dibutylamine
159.6
Nonane
150.7
11
A =
1232
1233
1234
1235
1236
1237
C H
C H 0
Q ^ N
8
C9HJJ0
C H O
4
s e c - B u t y l Alcohol
1 0
C H 0
Q>Hi 0
C H
C H
C Hj
C H
4
75,
334
335
11
1228
1229
1230
1231
334
Nonazeotrope
750 m m .
.. .
ether
to c r i t . r e g i o n
34.5
1 - B u t a n e t h i o l , 7 7 0 m m . 98
Butylamine
77.1
Pyridine
115.5
Methyl methacrylate
99.8
Benzene, 45
8u!l
1!
11
1225
341
8.6
v-1
107
11
71-81
117.75
11
1224
Ref.
Nonazeotrope
Ethyl
C A P
C H80
Wt.%A
142.1
11
1211
B.P.,C.
2-Methyl-2-nitro1-Propanol
C H p
4
B.P.,C.
128.3
Butyl ether
2,6 - D i m e t h y l - 4 heptanone
C4H9N03
Q H
Name
Morpholine
Data
Butyl acetate
s e c - B u t y l acetate
Methylcyclohexane
Heptane
Diisobutylene
Iso-octane
9.5
7.8
77.1
27.3
117.6
67.2
68.2
3.2
Nonazeotrope
105.5
27.5
66.8
17.7
85.45
22.9
97.7
26.5
105.3
29.7
69
75
39
87.7
77
92.2
117
98.2
93.85
18
-94
-16
Azeotropic
36.3
63.65
42.1
51.0
59.7
115.85
65.1
108.45
43.2
117.6
82.5
Nonazeotrope
115.9
71.5
75
181
334
v-1
141
147
v-1
24
v-1 344,
362
147, 335
335
335
117
117, 335
174, 335
v-1
335
v-1
377
v-1
124
124
v-1
124
v-1
124
v-1
334
76
76
76
174, 175
141
v-1
193
92
92
92
92
92
175
335
334
174, 175
v-1
v-1
v-1
v-1
v-1
174,
99.5
126.1
112.2
101.5
98.4
102.3
99.3
Nonazeotrope
Nonazeotrope
89.7
38.2
88.1
36.7
91
35
88.0
33.8
334
334
352
352
37
352
ADVANCES
42
IN
B-Component
No.
1238
Formula
C4H10O
C H
6
Name
Isobutyl Alcohol
Benzene
"
"
"
"
"
11
"
"
"
C H O
1239
1 0
C H
1 8
Ethyl Ether
Butyl ether, 600 m m .
C4H10O2
1240
C H O
6
C Hio0
4
1241
1242
1243
1244
1245
1246
1247
1248
6 122
4 102
C 5 H 8 O 2
C5H10O2
C 6 H 1 2 O 2
C H
6
N2
1 4
C 6 H 1 4 O 3
C H
C H
8
1249
1250
1251
1252
C H
1253
1254
1255
1256
1257
8 16
C H
1258
1259
1260
1261
1262
1263
1264
1265
1266
1267
1268
^8^18
Q i o
C H
H
e 16
H
8 18
8 18
8 18
H
C9H12
C
9 12
H
C)H
C9Hi
18
C 9 H
C 9 H
C 9 H 2 0
C 9 H 2 0
C 9 H 2 0
1269
C 9 H 2 0
1270
C 9 H
1271
1272
1273
1274
1275
1276
C9H20
C 9 H 2 0
C9H20
C9H20
C9H20
C
9 20
H
1,2-Dimethoxy ethane
Isopropyl ether
1,4-Butanediol
$.P.,C.
Methyl methacrylate
P r o p y l acetate
B u t y l acetate
2,5-Dimethylpiperazine
2 - (2 - E t h o x y e t h o x y )
ethanol
S t y r e n e , 50 m m .
"
57 m m .
"
735 m m .
it
m - X y l e n e , 735 m m .
0-Xylene, 735 m m .
- X y l e n e , 735 m m .
trans -1,2- Dimethyl cyclohexane
Ethylcyclohexane
cis-2-Octene
3,3-Dimethylhexane
3-Ethyl-3-methylpentane
Octane
o-Ethyltoluene
M e s i t y l e n e , 735 m m .
Butylcyclopentane
Isobutylcyclopentane
Isopropylcyclohexane
1 -Nonene
Propylcyclohexane
3,3 - D i e t h y l p e n t a n e
-Nonane
, 2,3,3 - T e t r a m e t h y l pentane
2,2,4,4 - T e t r a m e t h y l pentane
2,3,3,4-Tetramethylpentane
2,2,3-Trimethylhexane
2,2,4 rimethylhexane
2,4,4 - r i m e thylhe xane
3,3,4 - r i m e t h y l h e x a n e
B.P.,C.
Wt.%A
Ref.
12
2.7
4.2
6.4
7.4
4.2
6.0
7.9
21.0
33
Ill
316
316
316
316
256
256
256
256
256
107
80*1
80*1
78.36
28.4
45.0
67.4
79.3
43.0
59.5
79.4
159.9
207.5
34.5
142.4
Ideal system
v-1
257
85.2
68.3
334
Nonazeotrope
230
94
Min. b.p.
4 -Vinyloxybutanol
2 -Ethoxy ethanol
SERIES
Azeotropic Data
80.1
111 m m .
240 m m .
525 m m .
760 m m .
206 m m .
394 m m .
759 m m .
5420 m m .
12,930 m m .
CHEMISTRY
134.0
99.8
101.6
126.2
164
Nonazeotrope
Nonazeotrope
125.7
13
Nonazeotrope
v-1
v-1
147
220
221
334
202.8
60*62
134.9
136.15
137.9
143.1
137.4
Nonazeotrope
42.5
v-1
59.8
27.6
v-1
53.9
42 v o l . %
50.0
43.3
v-1
126.2
45
v-1
128
48.9
v-1
127.7
57.2
v-1
129.6
47.9
v-1
127.3
334
110
110
291
167
227
167
167
167
123.42
131.78
125.6
109.10
111.97
115.6
120.2
117.9
105.1
107.1
27
33
28
16
17
118.26
125.75
165.15
163.4
156.56
147.6
154.5
146.87
156.72
146.17
150.8
111.7
122.5
135.0
133.7
130.2
127.4
129.6
128.1
130.2
126.4
128.0
23 v o l . %
33.6
v-1
91 v o l . %
85.7
v-1
61 v o l . %
49 v o l . %
56 v o l . %
48 v o l . %
59 v o l . %
45 v o l . %
50 v o l . %
291
227
291
167
291
291
291
291
291
291
291
140.27
124.1
40 v o l . %
291
122.28
114.3
26 v o l . %
291
141.55
133.60
126.54
137.68
131.34
130.65
140.46
124.6
120.8
116.8
122.8
119.5
119.1
124.0
41
34
26
41
32
34
40
291
291
291
291
291
291
291
...
vol.
vol.
vol.
vol.
vol.
vol.
vol.
vol.
vol.
vol.
vol.
vol.
%
%
%
%
%
%
%
%
%
%
%
%
291
291
291
291
291
TABLE
BINARY
SYSTEMS
43
Azeotropic
B-Component
Formula
No
C4H10O2
1277
C4H10O3
=
1278
C H
1 2
1279
1280
G H
1281
C HiP
1282
C H
1283
1284
1285
1286
C H N
1287
6 123
C8H
10
CeHio
C8Hi 0
8
8 184
1288
1289
CioHe
C H OS
1290
1291
1292
1293
1294
1295
1296
C
H
Gi H
H9N
1 2
C12H10
12So
C
H p S
C
2-Ethoxyethanol
(continued)
tert-Butylcyclohexane
10 20
Name
C14H10
Diethylene G lycol
2 -(2 - M e t h o x y e t h o x y )
ethanol
Benzene
2 -(2 - V i n y l oxyethoxy)
ethanol
2 - (2 - E thoxye thoxy)
ethanol
Triethylene glycol,
3 m m .
Indole
Ethylbenzene
-Xylene
2 - (2 - B u t o x y e t h o x y )
e t h a n o l , 10 m m .
2 - [2 - (2 - E t h o x y e thoxy)
ethoxy]ethanol, 2 m m .
"
3m m .
Naphthalene
2 -(Benzylmrcapto)
ethyl vinyl ether
C a r b a z o l e , >10 m m .
Biphenyl
2-(2-Ethylhexylthio)
ethyl vinyl ether
H e x y l e t h e r , 50 m m .
Fluorene, 10-760 m m .
P h e n a n t h r e n e , 20 m m .
"
100 m m .
"
200 m m .
300 m m .
"
400 m m .
Benzyl ether, 5 m m .
Bis(2 -ethylhexyl) ether,
10 m m .
11
1297
1298
1299
C4H10S
C4H10S
2-Butanethiol
C H
Ethyl Sulfide
1 0
1300
1301
1302
C H
7
1303
C H
1304
1305
1306
1307
1308
C1A4O
6 12
C H
C
7 14
C Hi
C Hi
C
7 16
8 18
H
C4H10S
1309
1310
1311
C H
7
1312
C H
1313
6 12
C H
7 16
H
Isopropyl methyl
sulfide
B.P.,C.
Cyclohexane
Methylcyclopentane
trans -1,3 - Dimethyl cyclopentane
1,1- D i m e t h y l c y c l o pentane
3 - Methylhexane
Wt.%A
Ref.
134.0
171.5
133.3
73 v o l . %
291
245.5
193.6
80.1
.. .
Nonazeotrope
Nonazeotrope
Min. b.p.
334
334
94
Nonazeotrope
334
253
136.15
138.2
Nonazeotrope
v-1
Azeo. distillation
Azeo. distillation
Azeo. distillation
60
120
120
120
109
Nonazeotrope
334
87
135
Azeo.
43
83.4
distillation
335
60
120
M i n . b.p.
Nonazeotrope
Azeo. distillation
23
329
100
120
335
M i n . b.p.
129.9
Min. b.p.
146
180
203
217
226
329
335
100
100
100
100
100
100
335
202.8
.. .
98
.. .
218.1
.. .
294
355.9
100
137*
294
...
...
...
135
15.5
93
96.2
98.5
99.5
99.9
40
114
335
85.15
84.76
Nonazeotrope
70
Nonazeotrope
Nonazeotrope
70
70
92.07
80.10
Benzene
80.85
Cyclohexane
trans -1,3 -Dimethyl cyclopentane
90.80
1,1 - D i m e t h y l c y c l o 87.90
pentane
M e t h y l c y c l ohe x a n e
101.05
91.60
3-Methylhexane
89.90
80.55
2,2,4 - T r i m e t h y l p e n t a n e 99.30
Isopropyl Methyl Sulfide
B.P.,C.
Data
88.89
41.0
70
86.98
92.10
89.19
87.93
80.53
91.44
26.1
94.5
48.3
38.6
2.26
77.0
70
70
70
70
70
70
84.76
80.85
71.85
79.76
30
Nonazeotrope
70
70
90.80
84.38
80.4
70
87.90
91.60
83.62
84.38
64.9
82.4
70
70
44
ADVANCES
B-Component
No, .
Formula
C4H10S
1314
1315
1316
C H
C H
C H
7
1 6
1 6
1 6
Isopropyl Methyl Sulfide

(continued)
C4H10S
=
1317
1318
1319
C H
C H
C H
1320
C H
7
1 4
1321
1322
1323
1324
C H
1 6
=
1325
1326
=
1327
1328
1 4
1 4
^8 18
C9H20
C10H22
E t hyl Disulfide
Nonane
3-Ethyl-3-methylheptane
C4H11N
Diethylamine
C H
4
C H
C H
1 0
1 5
330
O
NO
C H N0
CjF
1 6
N0
1332
C F
Perfluoropentane,
9.6-25 C .
Perfluorohexane,
15-25 C .
5 12
F
C H4F 0
8
CgHiP
C H 0
5
1 2
1335
C H40
C H 0
1336
C H
1337
1338
1339
=
1340
1341
1342
1343
1344
1345
C5H5N
5
1 2
2 - F u r aldehyde
Furfuryl alcohol,
25 m m .
Benzene
Methylcyclohexane
Heptane
7 16
C H
C H
C H
2,2,3,3,4,4,5,5Octaf l u o r o- 1 -pentanol
Active amyl alcohol
Isoamyl alcohol
Cyclohexane
6 12
C H
2,2 -Iminodiethanol
2,2',2"-Nitrilotriethanol, 2 mm
1
1,2 - D i c h l o r ohexafluorocyclopentene
C5F10
C
1333
1334
Isopropyl ether
2 -(Diethylamino)
ethanol
C H
1331
N
0
Py r idine
Piperidine
3-Pentanol
Toluene
7 16
Heptane
8 10
8 10
Ethylbenzene
o-Xylene
Azeotropic Data
B.P.,C.
II
B.P.,C.
Wt.%A
Ref.
84.76
89.90
80.55
79.20
Methyl P r o p y l Sulfide
95.47
t h y l c y c l ope ntane
103.45
Methylcyclohexane
101.05
trans -1,3 - Dimethyl 90.80
cyclopentane
1,1- D i m e t h y l c y c l o 87.90
pentane
91.60
3-Methylhexane
89.90
106.85
2,2-Dimethylhexane
2,2,4 - T r i m e t h y l p e n t a n e 99.30
1329
Name
SERIES
83.83
79.39
78.40
72.8
29.7
23.3
70
70
70
95.41
95.06
90.7
78.0
70
70
90.11
24.3
70
87.66
90.53
89.10
95.42
94.00
9.7
32.95
22.75
94.4
62.2
70
70
70
70
70
154.11
150.65
148.62
41.2
70
163.00
153.02
80.2
70
55.5
68.3
162.1
Nonazeotrope
334
Nonazeotrope
334
126/2 m m .
195
Nonazeotrope
334
90.6
102.6
v- -1
354
Nonazeotrope
v- -1
237
Nonazeotrope
V ' -1
237
90.4
80
...
.. .
128.5
132.0
330
330
Nonazeotrope
Nonazeotrope
161.45
80.1
Nonazeotrope
Nonazeotrope
-1
-1
80.75
Nonazeotrope
V" -1
101.05
98.40
100.8
98.3
4.1
5.3
115.5
106
115.6
110.8
105.8
117.4
110.1
3.4
45
22.2
98.40
98.40
136.15
143.6
95.60
25.3
13.3
95
Nonazeotrope
Nonazeotrope
v - -1
v - -1
348
52,
331
52,
331
114
114
- -1
147
334
141,
355, 373
--1
141
363
372
TABLE
BINARY
SYSTEMS
45
B-Component
No. ,
A
1346
1347
1348
1349
A =
1350
1351
1352
1353
A
=
1354
1355
1356
Formula
C H N
C H
5
C9H20
C10H3N2
C
C H S
5
^7 16
C H
8
1 8
8 18
CePie
C
CsHeS
C H
7
7 16
8 16
H
1357
1358
1359
1360
A =
1361
1362
1363
1364
1365
A =
1366
A
1367
1368
C H
C H
Q H
8
1 8
1 8
C H
C H
5
1 0
C5H10
C H
5
C5H12
CsH Cl
C7Hi2Cl
8
C H 0
CsHiaO
C H 0
5
1 2
Name
109.5
56.1
115.1
89.9
Nonazeotrope
Nonazeotrope
2 -Methy lthiophene
Heptane
2 - Methylheptane
2,5-Dimethylhexane
2,2- Dimethylhexane
111.92
98.40
117.70
109.15
106.85
97.77
109.97
106.12
104.62
2.2
67.8
39.6
33.2
70
70
70
70
3 -Methy lthiophene
Ethylcyclopentane
Heptane
trans -1,3 - Dimethyl cyclohexane
1,1,2 - T r i m e t h y l c y c l o pentane
Octane
2 - Methylheptane
2,5- Dimethylhexane
114.96
103.45
98.40
102.82
3.9
Nonazeotrope
70
70
120.3
113.17
66
70
113.75
125.70
117.70
109.15
110.47
114.15
111.86
107.12
43.2
82
58.8
31.7
70
70
70
70
Nonazeotrope
Nonazeotrope
Nonazeotrope
Nonazeotrope
33.6
72.5
v - -1
248
248
248
248
248
Nonazeotrope
v - -1
250
129.5
128.5
131.85
Nonazeotrope
127.8
60
v - -1
131.85
131.85
128.9
128.9
129.4
Nonazeotrope
127
124.6
330
87,
88
314
2
87, 88
314
99.3
68.3
Nonazeotrope
334
61.8/200 m m .
Methyl Methacrylate
Butyl methacrylate,
200 m m .
117.7
Nonazeotrope
2-Ethoxyethyl
Nonazeotrope
m e t h a c r y l a t e , 200 m m . 134.3
147
Isoprene
2 - M e t h y l -1 -butene
2-Methyl-2-butene
2 -Methylbutane
P e n t a n e , 758 m m .
34.3
21.2
32
37.7
27.6
36
Tetrachloropentane
...
Tetrachloroheptane,
12-150 m m .
II
5
2 - M e t h y l -1- butanol
It
C5H4O2
1370
Q H
1371
1372
C H
1373
C5H8O2
C5H8O2
C5H10
CsH 0
A =
1374
1375
A =
1376
A =
1377
8 142
H
C6H
1 4
Ref.
B.P.,C. W t . % A
115.5
125.75
150.7
274
173.3
Cyclopentanone
Active amyl alcohol
Isoamyl alcohol
C Hi 0
B.P.,C.
Py r idine (continued)
Octane
Nonane
2,2'-Dipyridyl
Decane
II
1369
Azeotropic Data
E t h y l Ac r y l a t e
Isopropyl ether
2,4- Pentanedione
Isopropenyl acetate
140.2
96.5
Nonazeotrope
Cyclopentane
Benzene
49.4
80.1
49.7
Nonazeotrope
49.1
82.3
C5H10
C5H12
C5H10
C5H12
2 -Methy 1- 2 -butene
2-Methylbutane
Pentane
355
355
147
355
147
147
-1
230
214
22.5
27.6
Nonazeotrope
248
37.7
36.15
Nonazeotrope
248
46
ADVANCES
IN
B-Component
No.
A =
Formula
C H O
5
C Hi
1380
C Hi2
1381
1382
1383
C7H
C Hi
CeHi6
1384
C H
A=
C HidO
2-Pentanone
A=
Cyclohexane
C H O
5
A =
1385
A =
1386
A=
3-Pentanone
1 0
Methylcyclohexane
Heptane
1,3-Dimethylcyclohexane
2,5-Dimethylhexane
1 4
1 8
C5Hio0
CHSO
5
NO
1 5
C H
5
Isopropyl Acetate
2,5-Dimethylfuran
C HioQ2
C7H
B.P.,C.
Cyclohexane
Heptane
Valeric Acid
N,N-Dimethylvalera m i d e , 100 m m .
Pentane
1 2
B.P.,C.
Wt.%A
80.75
98.4
. . .
. . .
14.8
48
256
256
. . .
5.0
256
102.35
80.75
102
101.15
98.4
...
...
40
35
256
256
120.7
109.4
...
...
83
60
256
256
88.7
93.3
Nonazeotrope
334
145.8
295
186.35
141
30.8
36.15
Q H 6
Benzene
80.2
Nonazeotrope
1388
1389
C6H12
C6Hi
Cyclohexane
Methylcyclopntane
80.75
72.0
Nonazeotrope
Nonazeotrope
1390
O7F16
1391
C H
82.5
101.15
Azeotrope
Nonazeotrope
A=
Perfluoroheptane,
crit. region
Methylcyclohexane
C H 0
5
A m y l Alcohol
1 2
1392
1393
1394
1395
1396
1397
Q H O
C H O
C H N
QHie
CeH
C H2 02
1398
1399
1400
1401
1402
1403
1404
1405
1406
C H 0
C H C1
C H FO
05
QHioO
C7H F
Q H
1407
1408
1409
1410
1411
C
C
C
q
1412
1413
1414
1415
1416
1417
1418
1419
C5H
A=
1 4
1 8
C5H12O
A=
1 2
QH9N
Q H
7
Hi5N
H N
H
j H ^
1 5
C9H20
C5H12O
1 2
QH5CI
QH5FO
Q H N
Q H
p
C H
C H F
C H
7
Benzene
Methylcyclopentanone
C paraffins
Octane
Diamyloxymethane
8
Active A m y l Alcohol
Isoamyl alcohol
Chlorobenzene
o-Fluorophenol
2-Picoline
M e sityl oxide
o-Fluorotoluene
Toluene
2,6-Lutidine
2,4-Dimethyl3-pentanone
1,2-Dimethylpiperidine
Ethylbenzene
n-Octane
Isoamyl Alcohol
3-Methyl-1-butanethiol
Chlorobenzene
o-Fluorophenol
1-Picoline
M e sityl oxide
C hydrocarbons
o-Fluorotoluene
Toluene
7
Ref.
95.4
1387
SERIES
Azeotropic Data
3-Methyl-2-butanone
1 0
Q5H12
1378
1379
Name
CHEMISTRY
v-1
52,
229
v - 1 231
v - 1 52,
231
v-1
v-1
155
52,
231
137.8
80.2
138
164
120-130
125.75
. . .
Nonazeotrope
M i n . b.p.
Nonazeotrope
M i n . b.p.
121.8
. . .
Nonazeotrope
v - 1 344
87, 88, 314
334
314
314
334
128.5
131
132
.. .
129
129.5
114
111
144
Nonazeotrope
124.4
43
Nonazeotrope
132.8
49
Nonazeotrope
112.0
16
109.9
12
Nonazeotrope
125
128
128
136
126.0
124
124.1
130.3
130.7
125.0
117.0
115.5
21
...
54
53
34
29
v - 1 246
330
330
330
330
330
330
330
330
330
330
330
330
330
131
116
132
...
129
129.5
95-120
114
111
115.6
22.89
123.9
38
Nonazeotrope
132.8
61
Nonazeotrope
M i n . b.p.
112.1
14
109.7
10
181
330
330
330
330
314
330
330, 371
TABLE
BINARY
SYSTEMS
47
Azeotropic
B-Component
No.
Formula
C H
5
1420
1 2
G7H9N
1421
C H
1422
C7H15N
1423
C7H15N
1424
1425
1426
^ 10
8 18
C9H20
C5H12O
1427
1428
C H
C H
1429
C6H
Isoamyl Alcohol
(continued)
2 , 6 - L u t i d i n e , 70 m m .
It
2,4-Dimethyl3-pentanone
Ethylbenzene
-Octane
^, 2,5- r i m e thylhe xane
2-Me t hyl-1-Bu t anol

7
C H
1 2
2 - M e t h y l - 2 -butanol
Benzene
11
1430
C H
7
C5H12O3
1432
1433
1434
1435
1436
1437
1438
1439
1440
1441
1442
1443
1444
1445
1446
1447
1448
1449
1450
1451
1452
1453
1454
C8H5CI2
C9 12
C Hi
H
C9H12
C H
9
9 12
H
9Hl2
CIOHH
C
CIOH
C
C
C
C
C
H
H
H
H
1 4
10 14
10 14
10 14
H
11 10
Ql 16
C H
C
C11H24
C
C
1 2
H 6
2
12 26
H
Q2 26
H
13 26
H
C F
6
1455
C F
1456
C Fi4
Q H
B.P.,C.
Max. b.p.
Nonazeotrope
330
330
125
124.5
330
128
132.5
81
330
128
136
126
124
132.6
125.7
117.0
116.0
76
49
30
26
330
330
330
330
128.9
95-120
110.7
Pe r fluor ocyclic Ether
314
314
M i n . b.p.
M i n . b.p.
101.7
...
110.7
ar-Dichlorostyrene,
15 m m .
"
29 m m .
-Ethyltoluene
m - E thyltoluene
o-Ethyltoluene
1,2,3-Trimethylbenzene
Mesitylene
Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Isobutylbenzene
m -Diethylbenzene
-Diethylbenzene
5-Ethyl-m-xylene
-Cymene
1,2,3,5 - T e t r a m e t h y l benzene
t e r t - A m y l benzene
tert-Amylcyclohexane
n-Undecane
n - D o d e c a n e , 217 m m .
2,2,4,4,6-Pentamethylheptane
2,2,4,6,6- Pentamethyl heptane
1-Tridecene
Ref.
144*
80.0
l'.
715 m m .
2 - (2-Methoxy ethoxy )
ethanol
Wt.%A
131
80.2
715 m m .
Toluene
11
1431
B.P.,C.
C
hydrocarbons
Toluene
Name
Data
15
4.95
56
32.5
v-1
52
272
52
272
v-1
192.95
...
...
. ..
161.99
161.31
165.15
86-90
100-101
161.4
160.9
164.3
9 vol.
13 v o l .
16 v o l .
%
%
%
49
49
291
291
291
176.08
173.4
26 v o l .
291
169.35
164.72
183.27
173.30
169.11
172.76
181.13
183.78
183.75
177.10
167.9
163.8
177.9
170.7
167.6
170.3
176.3
177.9
177.9
173.3
21
12
32
16
13
24
29
31
30
22
vol.
vol.
vol.
vol.
vol.
vol.
vol.
vol.
vol.
vol.
%
%
%
%
%
%
%
%
%
%
291
291
291
291
291
291
291
291
291
291
197.93
241.1
198.1
198.1
195.88
169.79
185.9
48
Nonazeotrope
40
182.8
40
180.6
178.7
40
52
144.2
vol.
vol.
vol.
vol.
vol.
%
%
%
%
291
98
291
291
291
291
185.6
173.6
30 v o l .
291
177.9
232.78
168.9
191.6
23 v o l .
70 v o l .
%
%
291
291
v-1
237
v-1
v-1
v-1
79
79
79
...
Nonazeotrope
Perfluorohexane, 25
Perfluorohexane
Hexane, 325 m m .
"
479 m m .
689 m m .
11
...
...
.. .
25
35
45
83.4
83.7
80.0
ADVANCES
48
IN
Azeotropic
B-Component
No.
A
C F
6
1457
A =
1 4
C H C1
C H ^ O j
6
1458
A =
Formula
C6H4CI2
1 4 5 9 C9H6O2N2
1 4 6 0 C15H10O2N2
A =
1461
C H Br
C H 0
6
Name
C H C1
C H
CHÔ*
6
A =
1464
C H F
C H
A =
1465
C H N0
C H
1466
6 12
H
237
1,2,4-T r ichlor obenzene

2,4-Tolylene
diisocyanate, 40 m m .
Nonazeotrope
v-1
119
67.0/15
o-Dichlorobenzene
2,4-Tolylene
Nonazeotrope
d i i s o c y a n a t e , 15 m m . 128.7
Di-p -isocyanatodi phenylmethane,
192.0
Nonazeotrope
5 m m .
Bromobenzene
Cyclone xanol,
250 m m .
"
500 m m .
730 m m .
156.1
127.0
144.4
158.6
113.6
136.8
150.6
Chlorobenzene
n-Hexane
^",4-Tolylene d i i s o cyanate, 40 m m .
131.8
68.95
Nonazeotrope
1469
CH
1 4
1470
C Fi
1471
1472
1473
1474
1475
C F
1 2
C Hi6
C H
C H
7
...
84.9
80.1
Nitrobenzene
Cyclohexane
210.85
80.75
Benzene
Cyclohexane
80.1
80.75
II
80.75
II
...
...
...
...
...
128 m m .
155 m m .
II
287 m m .
II
307 m m .
II
495 m m .
It
602 m m .
II
760 m m .
M
14.7 p . s . i . a .
It
66.7 p . s . i . a .
II
118.0 p . s . i . a .
186.8 p . s . i . a .
It
66.7 p . s . i . a .
It
116.5 p . s . i . a .
II
165.9 p . s . i . a .
II
217.0 p . s . i . a .
II
268.7 p . s . i . a .
Methylcyclopentane
4 - M e t h y l - 2- pentanone,
450-760 m m .
Hexane
It
4-18 a t m .
Perfluor ometh^lcyclo hexane
Perfluoroheptane
Methylcyclohexane
2,3-Dimethylpentane
Heptane, 180-450 m m .
"
6 12
0$
Ref.
B.P.,C. W t . % A
v-1
II
1467
1468
Data
Nonazeotrope
Fluorobenzene
Benzene
B.P.,C.
SERIES
Perfluorohexane
(continued)
Tris(perfluorobutyl)
amine, 25
11
A =
1462
1463
CHEMISTRY
It
...
...
...
...
.. .
...
...
71.85
.. .
68.95
.. .
73-78
83
101.05
89.79
81
.. .
98.4
85.5
81.5
74.8
147
147
-1
v - -1
v - -1
V"
318
318
318
52
Nonazeotrope
-1
119
Ideal
-1
12
system
52
Nonazeotrope
77.6
51.2
77.4
28.4
33.1
48.3
50.4
63.7
69.8
77.56
77.4
137.1
165.8
193.0
52.5
47.6
48.0
49.3
49.4
50.8
51.3
51.9
50.2
61.5
67.0
71.5
59.7
64.9
67.6
71
74
16
...
...
.. .
71.7
Nonazeotrope
Nonazeotrope
Nonazeotrope
59
61
Nonazeotrope
78.8
79.4
48.4
>75
Nonazeotrope
Nonazeotrope
44,
v-1
191, 3 4 3
74, 111
316
316
316
316
316
316
316
321
v-1
321
v-1
321
v-1
321
v-1
v-1
276
v-1
2 76
v-1
276
v-1
276
v-1
276
230
v-1
v-1
v-1
v-1
v-1
v-1
v-1
v-1
66
229
276
51
51
230
190
51
240
229
TABLE
BINARY
49
SYSTEMS
Azeotropic Data
B-Component
Formula
No.
C H
CeFieO
CeHie
6
1476
1477
1478
1479
Ceie
C Hi 0
8
C6H 0
C Hi O
6
1480
Name
B.P.,C.
Benzene (continued)
Perfluorobutyl ether
Octane
2,2,4-Trimethylpentane, 35-75 C .
2 - (2 - B u t o x y e t h o x y )
ethanol
80.1
100
125.75
CeHioCU
C H 0
6
1 2
11
1483
1484
1485
1486
1487
1488
A =
1489
A =
1490
1491
1492
1493
1494
1495
1496
C Hg0
C Hi 0
8
C H
C H
C H
9
0
C
1 2
1 2
1 4
1 2
SiO
6
H
Pyrocatechol
1,3,5-Triethylbenzene
1 8
C 6 H 1 2 O
C H
6
1 3
Q H 1 4
C H
C H N
7
7 16
C H N
.. .
.. .
...
245.9
215.5
184.35
Aniline
Cyclohexanol
134
Cyclohexylamine
Hexane, 556-731 m m .
110.7
Toluene
- M ethylaniline,
95-145
98.4
Heptane
N,N -Dimethylaniline,
36.7 m m .
101.4 m m .
243.1 m m .
Iso-octane, 86-741 m m .
- C v m e n e , 50 m m .
"
100 m m .
300 m m .
"
500 m m .
760 m m .
C H N
6
230.6
..
.. .
C 9 H 1 0
11
e 18
10 14
H
11
11
71.5
Azeotropic
Max. b.p.
195.53
111
111
120
140
180
195.89
75.8
39.2
70
73
70
71
87
8.9
95.6
162
149
158.5
95
7
2
14
214.7
Nonazeotrope
Nonazeotrope
Nonazeotrope
242
242
356
138
...
Nonazeotrope
v-1
v-1
59
138
...
95
74.5
120
76.1
77.5
145
Nonazeotrope
21.3
1()6!3
23
v-1
v-1
v-1
v-1
v-1
v-1
v-1
v-1
v-1
59
59
59
356
92
92
92
92
92
.. .
.
..
.. .
...
...
172.80
. ..
...
31.3
C H,C1N
Aniline H y d r o chloride
Diphenylamine,
100 m m .
250 m m .
"
350 m m .
"
740 m m .
"
2500 m m .
...
.. .
215
45.8
48
50
65
1 8
11
324
v-1
147,
v-1
v-1
27.3
34, 335
303
76
324
8.9
143.5
1 2
76
57
334
253
76
57
57
76
76
253
193
144
144.06
v-1
175.5
3 - P i col i n e
2,6-Lutidine
H N
H 0
H
H o
1503
.. .
345
334
C H N
C H N
Nonazeotrope
Nonazeotrope
121.12
42
84.1
129.2
1502
v-1
128.8
124.5
125.75
150.7
C
C
C
C
51
52
2 - P i col i n e
Paraldehyde
Octane
Nonane
A =
1499
1500
1501
Ref.
68
Nonazeotrope
...
.. .
11
1497
1498
Wt.%A
Nonazeotrope
181.42
Phenol
C y c l o h e x a n o n e , 5 0 m m . 73
If
155.6
50 m m .
Ethylene diacetate
189.86
Cyclohexanol, 60 m m .
"
70 m m .
90 m m .
"
200 m m .
160.65
11
195.14
Phenyl acetate
2-Ethyl-l-hexanol,
25 m m .
-Methylstyrene
152.8
Cumene
158.9
Propylbenzene
(Trimethylsiloxy)
181.9
benzene
11
1481
1482
B.P.,C.
334
369
369
v-1
27
...
...
...
265
.. .
233
270
153
153
153
153
153
ADVANCES
50
IN
B-Component
No.
Formula
C H N
6
1504
1 1
1 0
Azeotropic
Name
B.P.,C.
2 - Amino-3-methylpyridine
1 -Methylnaphthalene,
20 m m .
"
50 m m .
"
150 m m .
"
290 m m .
400 m m .
"
760 m m .
2 -Methylnaphthalene,
16 m m .
"
50 m m .
"
150 m m .
"
400 m m .
550 m m .
"
760 m m .
221
155.6
...
11
1505
244.8
...
...
11
CAoO
C H 0
Cyclohexanone
150 6
1507
150 8
C H O
C H 0
CgHÔjj
M e s i t y l Oxide
4 - M ethyl - 2 - pentanone
4 - H y d r o x y- 4- m e t h y l 2-pentanone
3-Hepten-2-one
4-Methyl - 2-pentyl
acetate
1 0
1 2
1509
1510
C H
1 2
1511
CgHigO
Cyclohexanol,
1 2
C6H12
C H
C H
1514
1515
15 16
1517
1*518
C6H13N
1519
=
15 2 0
1521
^6
C
C H
7
1523
=
15 2 4
l P 2
q,H
C H
6
Toluene
Methylcyclopentane
H e x a n e , 200-760 m m .
12
6 14
1 4
1 2
8 162
H
1525
=
1526
1527
1528
COH
Q H
C H
1 2
1 4
O
0
8 18
H
Butyl Acetate
2 -Butoxyethanol
Butyl ether
9 8,
98,
9 8,
9 8,
9 8,
9 8,
99
99
99
99
99
99
109
57.5
13 7
69.5
16 5
76.8
196
92
209
96
Nonazeotrope
98,
98,
98,
98,
98,
98,
99
99
99
99
99
99
Nonazeotrope
-1
57
334
334
14 6 . 1
Nonazeotrope
334
169.4
Nonazeotrope
334
Nonazeotrope
334
80.85
.. .
.. .
68.95
110.7
80.5
98.4
71.72
68.95
110.7
. .
4-Methyl-2-pentyl
acetate
115
68.2
136
75.2
166
89.7
187
96.4
198
98.7
Nonazeotrope
Nonazeotrope
Nonazeotrope
Cyclohexanol
16 1
Cyclohexyl formate,
50 m m .
Cyclohexyl vinyl ether,
45 m m .
4-Methyl-2pentanone
Ref.
16 9 . 2
162.9
80.8
Wt.%A
334
Data
Nonazeotrope
7 16
1 2
B.P.,C.
SERIES
128.3
116 . 2
7 16
7 16
6 14
C H
C
...
16 1. 1
1 2
C H
1522
0
0
241.1
Cyclohexanol
4-Methyl-2-pentanone,
450-760 m m .
Cyclohexylamine
Hexane
Toluene
Heptane
100 m m .
Cyclohexane
15 12
1513
CHEMISTRY
-1
-1
-1
-1
-1
Nonazeotrope
-1
Nonazeotrope
-1
Nonazeotrope
Nonazeotrope
Nonazeotrope
Nonazeotrope
80.2
48.6
80.0
V
V
V
46.6
66
242
231
230
214
52,
231
214
85,
231
230
79.4
50
147
71-80
21
341
116.2
14 6 . 1
Nonazeotrope
334
169.4
Nonazeotrope
334
Nonazeotrope
Nonazeotrope
125.9
95
334
334
334
126.1
112 . 2
171. 1
14 2 . 1
TABLE
BINARY
51
SYSTEMS
Azeotropic
B-Component
No.
Formula
A =
1529
C H
C H
1530
C H
1 7
1531
NO
C H
9
0
O
1 2
S 0
1532
C
15 18
16 34
1533
1534
A =
C H
151
142
75
75
225
225
Perfluoroheptane,
crit. region
Toluene
150-760 m m .
Methylcyclohexane
1 7
C H
8
Nonazeotrope
Nonazeotrope
113
113
77
92
Hexyl Al c oh ol
157.1
162.3
154.4
A =
CA4O
Isopropyl E t h e r
1,2- D i e t h o x y e t h a n e
68.3
121.1
Nonazeotrope
334
C H
8
4-Methy 1-2 -pentanol

4 -Methyl - 2- pentyl
acetate
131.8
Nonazeotrope
334
C H
8
Min. b.p.
329
02
1 6
O S
1 6
OS
C H 0
C H
C Hi6
Ci Hi
CioHu
Ci H
Ci H
CioH o
C H
CioH
CioH o
6
1 4
1 2
1 4
1 4
1 0
2 0
2 0
CIQH O
2
2 -Bu t y lthioethanol
ether
2-Butoxyethanol
Cumene
cis -Hexahydroindan
Butylbenzene
sec-Butylbenzene
tert- Butylbenzene
p-Cymene
n- Butylcyclohexane
sec-Butylcyclohexane
Isobutylcyclohexane
cis-1 -Methyl -4 isopropylcyclohexane
trans-1 -methyl - 4 isopropylcyclohexane
!7
...
146.1
...
171.2
152.4
167.7
183.4
173.3
169.1
177.2
180.95
179.3
171.3
151.7
159.9
169.6
166.0
164.4
167.4
165.6
165.1
161.5
172.7
170.5
v-1
155
52
229
52,
231
89
106.9
1 4
68.95
Nonazeotrope
C6H 0
C Hi 0
1556
124
139
138.4
147.0
163.6
A =
1543
A =
1546
1547
1548
1549
1550
1551
1552
1553
1554
1555
334
2-Ethyl-l-butanol
2-Ethylhexaldehyde
3-(Chloromethyl)
heptane, 50m m .
100 m m .
1 4
11
1545
Nonazeotrope
101.15
C H 0
C H
0
C H C1
6
A =
156.2
110.6
Azeotropic
Nonazeotrope
Nonazeotrope
Nonazeotrope
1539
1544
b.p.
2,4-Dimethylsulfolane
A m y l naphthalene,
20 m m .
H e x a d e c a n e , 20m m .
Hexane
1538
1542
Max.
v - 1 289
353
m-Xylene
p-Xylene
C7F16
A =
Nonazeotrope
25
Paraldehyde
8 10
8 10
1537
1540
1541
205.15
Ref.
<80
Toluene
C . B.P., C. Wt.%A
4-Hydroxy-4-methyl
166
2-Pentanone
x - E t h y l t o l u e n e , 20m m .
2-Ethoxyethyl Acetate
CHI 03
7
1535
1536
Hexanoic A c i d
Octanoic acid,
20-100 m m .
N,N-Dimethylhexana m i d e , 100 m m .
B.P.,
C H
C6Hi 03
A =
Name
Data
v-1
v-1
334
335
335
61
68
335
72.5
%
%
%
168
291
168
168
168
168
291
291
291
162.0
45 v o l . %
291
160.9
41 v o l . %
291
10.3
38 v o l .
73.4
47.9
39.1
56.6
56 v o l .
53 v o l .
40 v o l .
52
ADVANCES
IN
Azeotropic
B-Component
No.
A =
Formula
C H
6
1557
A =
1 4
C HH0
6
C 3 H 1 0
1559
C H
A =
1560
1561
A =
1562
C H
6
Naphthalene
2 - Methylnaphthalene
CJ JH^Q
6
C H
A =
1564
C H O
C H N
6
155.5
1567
1568
A =
1569
A =
1570
1571
1572
1573
A =
1574
A =
1575
1576
C
C
H
H
1 0
Cj Hio
4
C H
6
C H
C F
7
N0
N0
CVH
C F
C H
C H
C H60
1 2
1 0
v-1
271
218.1
142.9
v-1
204
241.1
Nonazeotrope
98
Nonazeotrope
Nonazeotrope
Nonazeotrope
334
Nonazeotrope
Min. b.p.
Nonazeotrope
Nonazeotrope
Min. b.p.
100
334
Min.
100
288.7
l,l',l"-Nitrilotri-2propanol, 10m m .

Toluene
p-Cresol
ethylcyclohexane
l,l -Iminodi-2-propanol
Benzoic A c i d
C H
C H 0
C H
7
291
Nonazeotrope
T r iethylene G l y c o l
Perfluoroheptane
Heptane, crit. region
Perfluorocyclic oxide
Octane, crit. region
Nonane, crit. region
1 6
23 v o l . %
151.6
271
202.8
Carbazole
L o w press.
Fluorene
"
High press.
Phenanthrene,
Low
press.
Glycol decreases with
Benzyl ether, 5 m m .
1 2
Ref.
v-1
188.4
72
241.1
294
11
1565
1566
B . P . , C . Wt.%A
Nonazeotrope
2 - (2 -Ethoxyethoxy )
ethanol
Bis (2- ethoxyethyl)
ether
10 m m .
2- M e t h y l n a p h t h a l e n e
M
1563
Data
Dipropylene G l y c o l
C H
SERIES
171.2
Hexylene G l y c o l
Ethylbenzene, 400 m m .
Ethylcyclohexane,
400 m m .
CioH
B.P.,C.
2 -Butoxy ethanol
(continued)
3,3,5-Trimethylheptane
C10H22
1558
Name
CHEMISTRY
102
294
340
12.4
334
98
100
100
100
b.p.
decreasing pressure
145.5
. . .
28
335
133/10
1
1 77
77
Nonazeotrope
334
82.5
102!6
Azeotropic
Nonazeotrope
Azeotropic
Nonazeotrope
v-1
v-1
v-1
v-1
155
354
155
155
189/100 m m .
181
176.5
27
76
110.7
201.7
101.1
Nonazeotrope
Nonazeotrope
v-1
v-1
213
114,
309
60-100 C .
1577
1578
C H
C HnN
1579
1580
1581
1582
C Hie
C Hi8
C H O
Ci H 0
A =
1583
A =
1584
1 0
2 2
C H O
7
1 0
C H 0
C H O
7
B e n z y l Al coh ol
C H
m - C resol
2
Ethyl
benzoate
Nonazeotrope
Nonazeotrope
Nonazeotrope
Nonazeotrope
297
114
334
v-1
v-1
266
52
334
Nonazeotrope
334
103
341
205.2
Benzyl vinyl ether,

25 m m .
Heptane
98
2-Methyl-5-ethylpyridine
178.3
Iso- octane
2,2,4-Trimethylpentane 99.3
Decyl alcohol (isomers) 217.3
2,6,8-Trimethyl225.5
4-nonanol
Evaporation data
Evaporation data v - 1
202.2
212.4
26.6
112
TABLE
BINARY
SYSTEMS
53
B-Component
No.
A
Formula
Name
B.P.,C.
B.P.,C. W t . % A
o-Cresol
s-Collidine
191
171.30
197.20
C H 0
C H N
202
163
157
142-5
204.9
204.4
202.5
202
71.8
Nonazeotrope
212
98
24.5
112
1586
1587
1588
C H N
x-Cresol
Pyridine
Pyridine
Pyridine
1589
1590
C H 0
CioH
CnHio
m,p-Cresols
Naphthalene
2- Methylnaphthalene
202
218.1
241.15
1591
C HeO
C H O
D-Cresol
Ethyl benzoate
201.7
212.4
CjHN
C HnN
N-Methylaniline
N,N-Dimethylaniline, 95 - 1 4 5
196.25
1592
2,6-Lutidine
Decane
143.41
174.0
o-Toluidine
D i e t h y l - 0- toluidine,
20 m m .
200.7
Methylcyclohexane
100.93
98
O 7 H 9 N
7
1 0
C7H9N
A
1593
1594
C H9N
C H
N
10 22
H
C Hi4
7
1595
C F
1597
C Hi 0
C H NO
C H
C F
H
1600
C H
1 6
11 10
1 6
C F
1602
1603
1604
C H
1601
1 9
1598
1599
Perfluorocyclic
1 6
C H C1
8
1605
C ^ Q O S
C H
C H
8
1606
1607
C Hio
8
A
1608
11 10
H
oxide
Heptanoic A c i d
N,N-Dimethylheptanamide
102.5
188
63.0
367
367
367
78
80
90
Nonazeotrope
v-1
59
Nonazeotrope
v-1
358
95.8
Nonazeotrope
85
173
48
40 v o l .
v-1
114,
309
207
222.0
Max. b.p.
295
Heptane
98
P e r fluor obutyl ether
100
136.15
Ethylbenzene
"
100-760 m m .
2,2,4- T r imethylpentane 9S
Min. b.p.
Nonazeotrope
Nonazeotrope
Nonazeotrope
50
52
229
52
Dipropylene G l y c o l
Methyl Ether
Nonazeotrope
241.15
P e r f l u o r ocycl i c Oxide
102.5
131.78
Ethylcyclohexane
2,2,4- T r i m e t h y l p e n t a n e 99.24
2,3,4- T r i m e t h y l h e x a n e 131.34
e 16
H i
C H o
C
bases
bases
bases
Heptane
7 16
1596
A
Ref.
C H 0
QHiiN
7
1585
Azeotropic Data
ar-Trichlorostyrene
2 - (2-Isoamyloxyethoxy )
ethanol, 6.7m m .
Styrene
Ethylbenzene,
10-100 m m .
"
30-120 C .
X y l e n e , 20 m m .
Methyl Salicylate
96.3
87.5
98.4
v-1
98
80 v o l . %
60 v o l . %
80 v o l . %
207
207
207
49
101
145
50'
222.3
241.15
Nonazeotrope
v-1
Nonazeotrope
Nonazeotrope
v-1
Nonazeotrope
40,
110
156
334
98
54
ADVANCES
Azeotropic Data
B-Component
No.
Formula
A =
1609
CeHio
C Hi6
1610
1611
C Hi6
C Hi
1612
C 9 H 1 2
1613
C 9 H 2 0
1614
C 9 H 2 0
Name
B.P./C.
B . P . / C .
Nonazeotrope
Nonazeotrope
Nonazeotrope
Nonazeotrope
Nonazeotrope
Nonazeotrope
Nonazeotrope
139.0
96.1
CgH
C Hi 0
C Hi 0
m-Xylene
2-Ethyl-1 -hexanol
2-Ethylheptanal
139
184.8
A =
C H
C 9 H 2 0
o-Xylene
Nonane
143.6
150.7
C Hio
C H
p-Xylene
Octane
138.4
125.75
B i s (2 - vi n y loxy ethyl)
Ethe r
B i s (2-ethoxyethyl )
e t h e r , 10 m m .
196.5/10 m m .
10
A=
1617
A =
1618
1 0
1 8
QH14O3
1619
A =
C H
8
C H
8
1620
A =
1 6
C9H
A =
2- Ethylhexanoic A c i d
2-Methylnaphthalene
C Hi 0
Octanoic A c i d
N , N - Dimethyloctana m i d e , 100 m m .
C 1 0 H 2 1 N O
CeHieOs
1623
A =
llHio
C H C1
8
1624
A =
A =
1627
1628
1629
A =
1 8
Cl2Sn
C H ClSn
1 2
2 7
C10H20O2
C 1 1 H 2 5 N
C 1 0 H 2 0 O
C 1 0 H 2 0 O S
O ct yl Al coh ol
Octyl vinyl ether,
5 mm.
2-Hexylthioethanol
2-Hexylthioethyl vinyl
ether
v-1
v-1
v-1
372
81
Nonazeotrope
271
342
52
334
363
342
334
52
52
Nonazeotrope
v-1
Nonazeotrope
334
<50
98
241.15
238.5
187
241.15
190
26.0
Nonazeotrope
295
98
106.9/100 m m .
124.8
106
98
335
157/17
166
2-Ethyl-l-hexanol
184.8
Nonane
150.8
2-Ethylhexyl acetate
198.4
(2-Ethylhexyl)
p r o p y l a m i n e , 50 m m . 147
C 9 H 2 0
CJHIJOS
1631
Dibutyltin
Dichlor ide
Tributyltin chloride,
17 m m .
169.4
CeHieO
A =
3- (Chloromethyl)
heptane
2-Ethyl-1 -hexanol,
100 m m .
144.25
Ref.
146.1
Butyl Ethe r
2-Ethyl-1 -hexanol
C Hi 0
1630
2 -(2 -Ethoxyethoxy )
E t h y l Acetate
187.8
C Hi 0
C ^ O
8
1626
1 7
C Hi 0
C H
1625
1,3-Dimethylbutyl
Acetate
C Hi 02
C H
1622
A =
1 8
1621
Wt.%A
Ethylbenzene
136.15
Ethylcyclohexane,
400 m m .
121.6
1-Octene
125.75
Octane
152.4
Cumene
150.7
Nonane
2,2,5-Trimethylhexane 120.1
A =
1615
1616
SERIES
142.1
184.8
Nonazeotrope
334
Nonazeotrope
334
Nonazeotrope
Nonazeotrope
334
334
Nonazeotrope
334
195.15
64
64
Min. b.p.
17
341
329
TABLE
BINARY
55
SYSTEMS
Azeotropic Data
B-Component
No.
A=
Formula
C8H
1632
A =
1 8
1 6
CeHie03
1633
1634
CôHg
C H
n
2-(2-Butoxyethoxy)
ethanol
Naphthalene, 100 m m .
1 - Methylnaphthal e n e , 20 m m .
"
100 m m .
"
200 m m .
2- Methylnaphthalene, 20 m m .
"
100 m m .
1635
CnHio
1636
Ci H g
B.P.,C.
2-Ethyl-l,3243.1
hexanediol
Bis(2-ethylhexyl)ether,
10 m m .
135
269.8
3 4
Name
M
2
Dodecane, 100 m m .
1-Pentadecene,
217 m m .
1 6 3 7 C15H30
A=
Cc,F N
T r i s (per fluor opropyl)

amine
Cumene
2 1
1 6 3 8 C9H12
A=
C9H N 0
2
1639
A =
09
C9H7N
Ref.
B.P.,C. W t . % A
123
241
40
335
335
231.2
144.35
Nonazeotrope
v-1
144
46.8
64.3
74
98
98
98
98
98
98
144
241.15
146.2
142.6
38
53.5
82
34
183.7
185.16
87 v o l . %
v-1
291
130
152
2,4 -Tolylene
Diisocyanate
2,6-Tolylene diisocyanate, 5-60 m m .
51
116
Nonazeotrope
v-1
53
Isoquinoline
1640
CnHio
2 - M e t h y l n a p h t h a l ene
241.15
<50
98
A =
1641
C H N
C H
Quinoline
237.3
241.15
>50
98
E t h y l Salicylate
"
50 m m .
"
180 m m .
233.7
A =
C9HK1O3
1S42
A -
1 2
1 0
C9H12
1643
A =
1644
A =
1645
A =
C9H
C H
9
Mesitylene
12
1 2
C H OS
C H OS
9
1 2
1 4
C9H 0
14
1646
A =
1647
A =
1648
C H
C F
9
1 8
C9H20
C
Cumene
T r i s (per fluorobutyl )
amine
Nonazeotrope
Nonazeotrope
Nonazeotrope
177
118
118
118
138
51
Nonazeotrope
96
164.7
169.2
2-Benzylthio ethanol
2 -Benzylthioethyl
vinyl ether
Isophorone
v-1
v-1
v-1
329
Min. b.p.
241.15
Propycyclohexane
Per fluor otributyl amine
156.72
Nonane
Perfluorotributylamine
151
178.4
177
Nonazeotrope
145.4
Min. b.p.
55 v o l . %
98
207
50
56
ADVANCES
IN
Azeotropic
B-Component
No.
A =
1649
Formula
C9H20O
C
Name
2 , 6 - Di m e t h y l 4-heptanol
2,6,8-Trimethylnonene, 8 m m .
52 m m .
B.P.,C.
C9H20O4
1650
1 2
H N
1651
T r ip r opylene G l y c o l
Carbazole
L o w press.
Fluorene, high press.
"
L o w press.
Phenanthrene
1 6 5 2 C14H10
294
A =
1653
CioH
Ci H g
Naphthalene
Dodecane, 100 m m .
A =
1654
CioHie
C H
Decahydronaphthalene
D e c a n e , 10 m m .
"
20 m m .
"
50 m m .
A =
1655
C H O
Ci H O
Menthone
Menthol, 5m m .
"
50 m m .
"
180 m m .
209.5
A =
CioH
3,3,5-Trimethylheptane
Perfluorotributyl amine
155.68
De c y l Al coh ol
Dodecyl alcohol, 20,
50, 100, 300 m m .
232.9
1656
1 0
1 8
2 0
2 2
C^()H 0
22
1657
A =
1658
A =
1659
A =
1660
1 2
Q H
0
1 2
2 6
2 2
OS
H2 OS
4
C i oH 0 4
22
CnHio
CnHio
C
218.1
178.4
241.15
1-Methylnaphthalene
5 - Ethyl - 2- nonanol,
19 m m .
50 m m .
150 m m .
"
200 m m .
"
400 m m .
244.8
5- Ethyl - 2- nonanol,
20 m m .
"
50 m m .
"
90 m m .
"
200 m m .
"
300 m m .
400 m m .
241.1
CnH
C H
u
, f
Ref.
334
334
100
100
100
100
100
100
59.2
140.2
v-1
144,
204
Nonazeotrope
Nonazeotrope
Nonazeotrope
v-1
v-1
v-1
309
309
309
Nonazeotrope
Nonazeotrope
Nonazeotrope
v-1
v-1
v-1
118
118
118
55 v o l . %
147.3
system
v-1
207
290
329
Min. b.p.
11
A =
1661
Wt.%A
Nonazeotrope
Min. b.p.
Min. b.p.
Nonazeotrope
Min. b.p.
% glycol decreases
with decreasing
pressure
Ideal
ethanol
ethyl vinyl ether
T r i p r op y l e n e G l y c o l
Methyl E t h e r
Data
18
32
56
95
11
B.P.,C.
SERIES
104/52
11
A =
CHEMISTRY
98
<50
41.4
121
25.2
143
5.25
173
2
179.5
Nonazeotrope
98,
98,
98,
98,
98,
99
99
99
99
99
49.8
120
36.0
140.5
24.5
157
9.0
181.5
3.5
193.5
Nonazeotrope
98,
98,
98,
98,
98,
98,
99
99
99
99
99
99
TABLE
BINARY
57
SYSTEMS
Azeotropic
B-Component
No.
A =
Formula
C12H9N
1662
1 4
3 0
Name
B.P.,C.
Carbazole
Tetradecanol
Low press.
Heptadecanol
"
Low press.
355
1664
Ci H
C H
A -
A =
1665
=
1666
A =
1667
1 0
2 4
C
C
i 2
1 2
3 8
H
H
Biphenyl
Dioctyl phthalate,
10 m m .
255.9
2 4
2,6,8-Trimethylnonene
2,6,8-Trimethyl4 - n o n a n o l , 50 m m .
"
10 m m .
Dodecane
Hexadecane,
10-760
2 6
C 1 6 H 3 4
C13H10
q H
4
A =
1669
C
C
1 4
1670
A =
1671
C
C
A =
1672
Ci H3 0
C H 03
1 4
1 6
1 8
H
H
3 0
H
H
3 6
1 0
248
Nonazeotrope
334
137
103
Nonazeotrope
Nonazeotrope
334
334
216
Nonazeotrope
mm.
Fluorene
Tetradecanol,
Low press.
High press.
Heptadecanol,
Low press.
"
High press.
294
Phenanthrene
340
3 2
Tetradecanol
Heptadecanol
0
0
3 4
1673
Ci H3^D
1674
C 2 0 H 3 0 Q 2
Oleic A c i d
Ricinoleic acid,
5 mm.
Stearic acid,
5 mm.
Abietic acid,
1-10 m m .
v-1
163
Nonazeotrope
M i n . b.p.
100
100
Nonazeotrope
M i n . b.p.
100
100
% Phenanthrene i n creases with pressure; m i n . b.p.

% Phenanthrene i n creases with pressure; m i n . b.p.
100
Palmi t ic A c i d
Stearic acid, 5 m m .
1 8
Ref.
100
100
100
100
11
1668
Wt.%A
Nonazeotrope
M i n . b.p.
Nonazeotrope
M i n . b.p.
11
1663
B.P.,C.
Data
Nonazeotrope
100
v-1
139
v-1
139
v-1
139
v - 1 166
58
ADVANCES
IN
CHEMISTRY
SERIES
T a b l e II.
A-Component
Formula
No.
1675
1676
A
CO
1677
C 1 F
1678
c m
1679
HF
1680
1681
H N 0 3
1682
1683
1684
1685
1686
1687
1688
1689
1690
H o O
Name
Argon
Carbon
monoxide
Chlorine
trifLuoride
1694
1695
19.4
Water
100
...
Water
Sulfur
dioxide
Chloroform
Chloroform
Chloroform
Chloroform
Chloroform
Chloroform
F o r m i c acid
F o r m i c acid
Nit ro methane
Methanol
100
CHCl 3
- 1 0
C H 0
100
100
C H C I 3
C H
100
C H
100
CH N0
Water
100
C H
Water
Water
100
C H
100
C H
Water
Water
100
C H
100
C H
61
61
61
61
61
61
10 8
H
H F
C H
C H
C H N
2
C H 0
2
CaÔ
C ^ O
100.75
100.75
C H N
CaHgO
101
64.3
Methanol
Methanol
64.7
64.7
CJHJO
C H 0
Methanol
Methanol
64.7
64.7
C HeO
C l 3 F
Azeotropic
Composition, Wt. %
A
B
C
B.P.,
C.
Oxygen
Nitrogen
-183
-195.8
Nonazeotrope
v-1
v-1
97,194
2
56
Nonazeotrope
v-1
91,292
218.1
Chloroform
61
Acetalde20.2
hyde
F o r m i c acid
100.75
Methanol
64.7
81.6
Acetonitrile
Acetic acid
118.1
78.3
Ethyl alcohol
79.6
2-Butanone
Acetic acid
118.1
Pyridine
115.5
Isopropyl
82.3
alcohol
47.5
1,1,2-Trichlorotrifluoroethane
Ethyl alcohol
78.3
Propionalde47.9
hyde
M e t h y l a c e t a t e 57.1
Isopropyl
82.3
B.P.,
C.
Data
Name
Uranium
hexafluoride
Naphthalene
F U
100
20 atm. to critical point.

20 p.s.i.g.
A
B
Hydrogen
fluoride
o
N
CHCI3
CHCI3
1692
1693
-195.8
-252.7
19.5
C H C I 3
H 2 O
Nitrogen
Hydrogen
Formula
100
B.P.,
C.
115.5
100
Name
Pyridine
C H C I 3
1691
C-Component
C H N
CHCl,
FH
100
100
so
N
H
100
-185.7
-192
Formula
-85
B.P.,
C
Hydrogen
chloride
Hydrogen
fluoride
Nitric acid
Water
Water
Water
Water
Water
Water
Water
Water
Water
Water
Ternary Systems
B-Component
Ref.
322
189.6
108
12
28
92
60
222
5
v-1
52.6
78.0
39.4
Nonazeotrope
81
15
Nonazeotrope
Nonazeotrope
3.9
91.2
4.9
Nonazeotrope
Nonazeotrope
Nonazeotrope
11.7
36.8
51.5
v-1
0.6
3.0
v-1
v-1
v-1
96.4
258
273
56
335
334
56
335
334
56
360
176
335
Nonazeotrope
Nonazeotrope
v-1
68
334
Nonazeotrope
Nonazeotrope
v-1
58
334
Azeotropic
C-Component
B-Component
A-Component
B.P.,
C.
No.
Formula
Name
B.P.,
C.
1696
HzO
Water
100
CH 0
Methanol
64.7
C H 0
1697
H 0
Water
100
CH 0
Methanol
64.7
C H 0
1698
H 0
Water
100
CH 0
Methanol
64.7
1699
H 0
2
Water
100
C C1 F
47.5
C H 0
1700
H 0
2
Water
100
C HC1
86.2
C H 0
Allyl
1701
H 0
2
Water
100
C HC1
86.2
3^0
H 0
Water
.00
C HC1
86.2
C H 0
1703
1704
1705
H 0
H 0
H 0
100
100
100
C H N
C H N
C H N
81.6
81.6
81.6
C H 0
Water
Water
Water
1706
1707
H 0
H 0
2
Water
Water
100
100
C H N
C H C1
1708
H 0
2
Water
100
C H C1
1709
H 0
2
Water
100
C H 0
Isopropyl
alcohol
Ethyl alcohol
1710
H 0
2
Water
100
C H 0
1711
H 0
Water
100
C H C10
1712
H 0
100
C H 0
1713
1714
1715
H 0
H 0
H 0
Water
Water
Water
Water
Water
Acetonitrile
1,2-Dichloroethane
1,2-Dichloroethane
Acetaldehyde
Acetaldehyde
2-Chloroethanol
Ethyl alcohol
Ethyl alcohol
Propyl
alcohol
Isopropyl
alcohol
Ethyl alcohol
Diethylamine
Isopropyl
ether
Triethylamine
Ethyl alcohol
97.3
1702
1,1,2-Trichlorotrifluoroethane
Trichloroethylene
Trichloroethylene
Trichloroethylene
Acetonitrile
Acetonitrile
Acetonitrile
Methyl
acrylate
Methyl
propionate
2-Methylpropane
Ethyl alcohol
100
100
100
CzHgO
C H G
2
2
Name
B.P.,
C.
Formula
4
C H 0
2
Ethyl alcohol
Ethyl alcohol
Ethyl alcohol
Formula
4
4 10
H
C H N
C H O
A
81.6
83.5
C H
1 5
83.5
C H 0
20.2
C H 0
20.2
128.7
C H 0
2
6 123
H
C H
6
78.3
C H N
78.3
78.3
78.3
C H 0
Name
alcohol
Paraldehyde
B.P.,
C.
Data
Composition, Wt. %
A
C
Ref.
80.9
Nonazeotrope
334
79.85
Nonazeotrope
84
Nonazeotrope
334
-11.7
78.3
42.6
0.6
97.1
71.4
7.5
80
7.1
84.8
73
82.3
69.4
78.3
55.5
68.3
72.9
3.9
95.5
335
12.5
334
8.1
176
20
335
59
44
55
Nonazeotrope
5
13
82
335
334
334
89.7
78.3
68.6
67.8
6
7.2
31
77.1
63
15.7
334
335
82.3
69.7
7.7
73.3
19.0
335
78.3
...
124
Benzene
80.1
Acrylonitrile
Acrylonitrile
"
100
Acetone
Ethyl formate
Crotonaldehyde
77.2
mm.
56.1
54.2
102.4
69.5
<30
78.0
v-1
133
Nonazeotrope
334
Nonazeotrope
334
8.7
20.3
71.0
335
6.6
9.0
84.4
Nonazeotrope
Nonazeotrope
4.8
87.9
7.3
335
334
334
335
m
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SERIES
-Component
Name
B-Component
B.P.,
C.
Formula
No.
Formula
1756
H 0
Water
100
1757
H 0
Water
100
C H 0
1758
H 0
Water
100
C H 0
1759
H 0
Water
100
C H 0
1760
H 0
Water
100
C,H 0
1761
H 0
Water
100
C H 0
1762
H 0
Water
100
C H 0
Water
100
C H 0
H 0
1763
II
II
1764
H 0
2
Water
100
C H O
1765
H 0
Water
100
C H O
H 0
Water
100
C H 0
H 0
2
Water
100
C H O
1768
H 0
Water
100
C H O
1769
H 0
Water
100
C H O
17.66
1767
II
II
Propionic
acid
Isopropyl
alcohol
Isopropyl
alcohol
Isopropyl
alcohol
Isopropyl
alcohol
Isopropyl
alcohol
Isopropyl
alcohol
Isopropyl
alcohol
140.7
C H 0
82.3
C H 0
82.3
C H N
Isopropyl
alcohol
Isopropyl
alcohol
Isopropyl
alcohol
Propyl
alcohol
Propyl
alcohol
Propyl
alcohol
82.3
10
82.3
C H
82.3
C H
82.3
C H O
82.3
C H O
6
82.3
C H
1 5
82.3
1 2
97.3
C H S
97.3
C H
97.3
8 14
H
1 0
H 0
Water
100
C H 0
1771
H 0
Water
100
C H Q
Propyl
alcohol
Propyl
alcohol
102
It
1770
82.3
It
fl
Formula
It
II
B.P.,
C.
II
II
Name
C-Component
Name
Azeotropic
B.P.,
C.
B.P.,
C.
Data
Composition, Wt. %
A
C
Ref.
84
Nonazeotrope
Methyl
propionate
2-Butanone
79.85
79.6
73.4
11
Butylamine
77.8
83
75.5
65.7
90
8.2
19.8
72.
10
18
72
Nonazeotrope
335
335
334
335
88.7
Isopropyl
acetate
80.1
Benzene
"
20 p . s . i . g .
4-Methyl116.2
2-pentanone
Butyl ethyl
92.2
ether
68.3
Isopropyl
ether
30 p . s . i . g .
15 p . s . i . g .
84.1
Diisopropylamine
110.6
Toluene
Diisobutylene
1-Propanediol
3-Pentanone
Propyl
acetate
"
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11
97.3
Benzene
97.3
12
Cyclohexane
88
335
12.5
40.5
47
335
11
13
76
335
73.4
10.4
61.8
95
81
5
6
6
21.9
67.7
4
91
9
85
7
87
Nonazeotrope
335
335
335
334
76.3
13.1
38.2
48.7
335
102.3
72.3
9.3
31.6
59.1
335
67.5
60.8
101.8
81.2
20
50.23
66.07
76.26
82.45
68.5
Nonazeotrope
13.3
4.7
82.0
15.0
78.5
6.5
75.5
16.0
8.5
73.0
17.0
10.0
82.4
9.0
8.6
101.6
200 m m .
400 m m .
600 m m .
760 m m .
80.1
80.7
66.6
181
8.5
20
10.0
60
81.5
334
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V " -1
v --1
v --1
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264
308
308
308
308
334
334
B.P.,
C.
Formu
No.
Formula
1772
H 0
Water
100
C H O
1773
H 2 O
Water
100
C H 0
1774
H 0
Water
100
C H O
1775
H 0
Water
100
1776
H 0
Water
100
C H 0
1777
H 0
Water
100
C H 0
1778
H 0
Water
100
C H 0
1779
H 0
Water
100
C H 0
1780
1781
1782
1783
H
H
H
H
Water
Water
Water
Water
oooo
Name
C H 0
2
2
2
2
0
0
0
0
8 2
C
C
C
C
4
4
4
4
H
H
H
H
8
8
a
8
0
0
O
0
1784
H 0
Water
100
1785
H 0
2
Water
100
C H 0
1786
H 0
2
Water
100
C H O
1787
H O
z
Water
100
C H
4
1 0
1788
H 0
2
Water
100
C H
4
1 0
1789
H 0
Water
100
C H
4
1 0
1790
H 0
Water
100
C H
4
1 0
1791
H 0
Water
100
C H
1 0
1792
H 0
Water
100
C-Component
B-Component
A-Component
1 0
Name
Propyl
alcohol
Propyl
alcohol
Propyl
alcohol
2-Methoxyethanol
2-Methoxyethanol
2-Me thoxyethanol
1 , 2 - P r o p a n e -diol
Crotonaldehyde
2-Butanone
2-Butanone
2-Butanone
Butyr aldehyde
Butyr aldehyde
Butyr aldehyde
Butyraldehyde
Butyl
alcohol
Butyl
alcohol
Butyl
alcohol
Butyl
alcohol
Butyl
alcohol
Butyl
alcohol
B.P.,
C.
B.P.,
C.
2-Hexanone
127.2
87
27
63
10
123
118.3
86
28
58
14
334
146.6
87.6
27.4
51.6
21.0
334
2-Methylpentanal
Dipropoxyethane
Benzene
12
Cyclohexane
97.3
C H
97.3
C Hi20
97.3
l z
124.6
162
124.6
187.8
C H
102.4
C H
79.6
79.6
79.6
74.8
1 0
6 6
6 12
H
C H
C H
6
1 0
74.8
4 102
74.8
6 122
74.8
6 14
117.7
C H
117.7
C4H10 s
117.7
C H N
4
117.75
C H
l z
117.75
C H
1 2
117.75
1 0
6 14
H
B.P.,
C.
Data
Name
Formula
124.6
Azeotropic
O
0
Composition, Wt. %
A
B
C
Ref.
80.1
Nonazeotrope
334
80.7
Nonazeotrope
334
Toluene
110.6
Nonazeotrope
334
Toluene
110.6
Nonazeotrope
334
2-Ethylcrotonaldehyde
Benzene
Cyclohexane
Hexane
Isobutyl
alcohol
1,1-Dimethoxyethane
Butyl
acetate
Hexane
135.3
Nonazeotrope
334
80.1
80.7
68.7
107.9
68.2
63.6
55
8.8
26.1
65.1
5
35
60
1
22
77
Nonazeotrope
334
334
334
334
64.5
Nonazeotrope
334
126.1
Nonazeotrope
334
68.7
55
sec-Butyl
alcohol
1-Butanethiol
Butylamine
99.5
Butyl vinyl
ether
Butyl
acetate
Hexane
94.2
77.4
126.1
97.5
75
Nonazeotrope
334
m
</
334
181
78.6
Nonazeotrope
334
10
88
335
90.7
29
63
335
61.5
19.2
2.9
77.9
174
77.8
68.95
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Name
B.P.,
C
Formula
Name
No.
Formula
1811
H 0
Water
100
C HN
Butyl amine
1812
H 0
Water
100
C H N
Diethyl amine
Pyridine
Pyridine
Pyridine
Pyridine
Pyridine
Pyridine
Ethyl
acrylate
2-Pentanone
A m y l alcohol
1813
1814
1815
1816
1817
1818
1819
H
H
H
H
H
H
H
0
0
0
0
0
0
0
Water
Water
Water
Water
Water
Water
Water
100
100
100
100
100
100
100
C H N
1820
1821
H 0
H 0
Water
Water
100
100
C H
C H
H 0
Water
100
C H
1823
H 0
2
Water
100
1824
1825
H 0
H 0
2
Water
Water
100
100
C H N
C H O
1826
H O
z
Water
100
6 122
1827
H 0
Water
100
6 122
1822
2
2
2
2
2
2
C 5 H 5 N
C5H5N
C H N
5
C 5 H 5 N
C H N
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5
1 0
l z
1 2
O
O
0
Benzene
6 6
H
1 0
1828
H 0
2
Water
100
6 122
1829
H 0
2
Water
100
6 12 3
1830
H 0
Water
100
C H O
1831
H 0
Water
100
C H
765.4 mm.
Isoamyl
alcohol
2-Picoline
Cyclohexanone
Butyl
acetate
Butyl
acetate
sec-Butyl
acetate
2-Ethoxyethyl
acetate
Isopropyl
ether
Toluene
Azeotropic
C-Component
B-Component
A-Component
B.P.,
C.
Formula
77.8
C H
55.5
C H
7 16
8 18
C9H o
102.3
138.0
C H
C H
132
C H
80.1
128.8
155.6
1 4
115.5
115.5
115.5
115.5
115.5
115.5
99.3
1 9
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1 2
C H O
6
6 123
H
126.1
126.1
112.2
C H
156.2
C7H0
8 18
H
1 8
68.3
110.6
C*10^22^
Name
Dibutylamine
Isopropyl
ether
Heptane
Octane
Nonane
Decane
Undecane
Dodecane
Isopropyl
ether
Benzene
Diamyloxymethane
3-Methyl1-butanethiol
Hexyl
alcohol
Paraldehyde
Cyclohexanol
B.P.,
C.
B.P.,
C.
68.3
Nonazeotrope
78.6
86.7
90.5
92.3
93.1
93.5
14
13.5
70.5
22.5
25.5
52
30.5
37
32.5
35.5
45.5
19
38.5
51
10.5
40.5
54.5
5
Nonazeotrope
Nonazeotrope
Nonazeotrope
80.1
120
Composition Wt. %
A
B
C
Nonazeotrope
159.6
98.4
125.75
150.7
173.3
194.5
216
68.3
86.6
157.85
Nonazeotrope
124.5
160.65
Nonazeotrope
Nonazeotrope
112.2
Nonazeotrope
142.1
Nonazeotrope
142.1
Nonazeotrope
110.6
Nonazeotrope
89.7
Triethylamine
2
1
7.3
Decyl alcohol
(isomers)
Nonazeotrope
sec-Butyl
acetate
Butyl
ether
Butyl
ether
Toluene
Data
Nonazeotrope
A-Component
No.
Formula
B.P.,
C.
Formula
1832
H 0
Water
1833
CCI4
C a r b o n t e t r a - 7 6 . 7
chloride
Chloroform
61
Chloroform
61
Chloroform
61
CH 0
CH 0
CH 0
C H C I 3
Chloroform
Chloroform
Chloroform
Chloroform
61
61
61
61
C H C I 3
Chloroform
C H C I 3
1834
1835
1836
C H C I 3
CHCl 3
C H C I 3
1837
1838
1839
1840
C H C I 3
C H C I 3
C H C I 3
1841
1842
1843
100
Name
Trichloroethylene
Formic acid
Methanol
Methanol
86.2
C H 0
100.75
64.7
64.7
C H 0
C H 0
3 62
CH 0
CzHeO
C H O
C H 0
Methanol
Ethyl alcohol
Acetone
Acetone
64.7
78.3
56.4
56.4
C
C
C
C
61
C H 0
Acetone
56.4
C H O
Chloroform
Chloroform
61
61
C H 0
*3 0
56.4
54.1
C H
C H Br
57.1
C H Br
59.4
C H 0
82.3
C H 0
64.7
8 183
80.1
6 12
CHCI3
Chloroform
61
C H 0
C H C I 3
Chloroform
61
C H Br
Chloroform
61
C H O
Dichloromethane
40.0
CH Q
C H
Benzene
C H C I 3
1847
CH C1
18 48
CH N0
1852
1853
CH
C H 4 O
CH 0
4
C H 4 O
CH Q
4
-200 to 50 F.
Formula
C2HCI3
1844
1846
B.P.,
C.
C He
1845
CHCI3
G-Component
Toluene
Acetone
Ethyl
formate
Methyl
acetate
2-Bromopropane
Isopropyl
alcohol
Methanol
1849
1850
1851
Name
B-Component
Nitromethane
Methane
Methanol
Methanol
Methanol
Methanol
101.2
-161.5
64.7
64.5
64.5
64.5
C H
C H 0
C H 0
Ethane
Ethyl alcohol
Acetone
C H 0
3 62
Acetone
Methyl
acetate
110.6
-88.6
78.3
56.1
56.1
56.3
1 2
H 0
H 0
^ O
H O
8
l z
C H
C H 0
3 62
3
C Hi
6 u
6
2 6
Name
2,6,8-Trimethyl-4nonanol
2-Butanone
Acetic acid
Acetone
Methyl
acetate
2-Butanone
Acetone
2-Butanone
4-Methyl-2pentanone *
Isopropyl
ether
Toluene
2-Bromopropane
2-Bromopropane
Isopropyl
formate
2-Butanone
Azeotropic Data
B.P.,
C.
B.P.,
C.
Composition, Wt. %
A
B
C
225.5
Nonazeotrope
79.6
118.1
56.1
57.1
79.6
56.1
79.6
115.9
Ref.
Nonazeotrope
57.5
56.42
63.2
334
v-1
184
Nonazeotrope
v-1
46.7
23.4
29.9 v-1
51.4
21.6
27
v-1
56
335
31,143
Nonazeotrope
65.3
10.4
24.3 v-1
Nonazeotrope
v-1
Nonazeotrope
v-1
334
224
62
157
68.3
Nonazeotrope
334
Nonazeotrope
v-1
5.3
15.7
296
195
59.4
Nonazeotrope
195
68.8
Nonazeotrope
195
79.6
Nonazeotrope
334
2-(2-Butoxyethoxy)
ethanol
Cyclohexane
230.6
Nonazeotrope
334
Propane
Acetone
Methyl
acetate
Hexane
Hexane
-44
56.1
56.3
110.7
59.4
61.97
80.75
68.95
68.7
79
Nonazeotrope
v-1
343
v-1
v-1
53.7
Nonazeotrope
Nonazeotrope
17.4
5.8
76.8
268
7
335
47
45
14.6
14
30.8
27
59.6
59
105
335
B.P.
C.
Name
B.P.,
C
Formul
Name
CH4O
Methanol
64. 7
C3H9BO3
Methanol
Acetylene
Acetonitrile
64
1857
CH4O
C2H2
C H N
C6H*
C H
C H60
Trimethyl
borate
Benzene
Ethylene
Ethyl alcohol
1858
C2H4CI2
C H 0
Acetone
1859
C2H4O2
1,2-Dichloro83 45
ethane
118 1
Acetic acid
C H N
Pyridine
C2H4O2
Acetic acid
118
C H N
Pyridine
115.5
C2H4O2
C2H4O2
C H 0
Acetic acid
Acetic acid
Acetic acid
118
C H N
C5H5N
C H N
Pyridine
Pyridine
Pyridine
115.5
115.5
115.5
C H N
C H N
C H N
C H N
C H N
C H N
CjHN
C7H9N
Pyridine
Pyridine
2-Picoline
2-Picoline
2-Picoline
2-Picoline
2,6-Lutidine
2,6-Lutidine
115,
115,
134
134
134
134
144
144
Formula
No.
1854
1855
1856
1860
1861
1862
1863
-84
81
68.7
80.1
-104
78.3
Formula
C H 0
4
6 12
2 6
C H N
C
1 5
56.4
C H
115.5
C H
118. 1
118. 1
1866
C2H4O2
C H 0
C2H4O2
1867
1865
1868
1869
1870
1871
Acetic
Acetic
Acetic
Acetic
Acetic
Acetic
Acetic
Acetic
2H4O2
C2H4O2
C2H4O2
C H 0
C2H4O2
2
acid
acid
acid
acid
acid
acid
acid
acid
118. 1
118. 1
118
118
118. 1
118
1
118. 1
118. 1
Ethylbenzene
-Xylene
Octane
Nonane
CpH,,
C
8 10
H
CoHno
Acetic acid
Acetic acid
118
CyHgN
118
Nitroethane
114
C H 0
1874
C H N0
1875
C H 0
Ethyl alcohol
78. 3
1876
C H 0
Ethyl alcohol
Ethyl alcohol
Ethyl alcohol
78
78
78
1877
1878
C H Q
2
C9H00
C
10H22
ll?24
0H1
II
C H 0
C H 0
1872
Decane
Undecane
Octane
Nonane
Decane
Undecane
Octane
Decane
10H22
11 24
C o_ H 18
i,
C
8 10
H
6 6
H
2,6-Lutidine
Ethylbenzene
p-Dioxane
II
144
136.15
C H
C H
9
2 0
101.3
C H
1 0
Benzene
Benzene
Benzene
Benzene
80.1
80.1
C H
C H
6
1 4
1 4
Undecane
Nonane
Isobutyl
alcohol
Methylcyclopentane
Cyclohexane
Hexane
Methylcyclohexane
B.P.,
C.
80.75
-88
89.7
70.1
80.1
98.4
136.15
143.6
125.75
150.7
173.3
194.5
125.75
150.7
173.3
194.5
125.75
173.3
34
Ref.
Nonazeotrope
v-1
115
Nonazeotrope
Nonazeotrope
8
58
v-1
v-1
223,362
137
335
Nonazeotrope
v-1
35
96.2
96.5
129.08
2
3.4
13.5
91.5
86.0
61.3
373
355
363
132.2
115.7
128.0
128.0
134.1
137.1
121.3
135.0
141.3
143.4
17.7
30.5
51.8
20.1
10.4
69.5
20.7
29.4
49.9
29.3
49.8
20.9
31.4
38.2
30.4
19.0
43.5
37.5
3.6
24.8
71.6
38.4
48.8
12.8
33.3
19.9
46.8
55.2
14.3
30.5
Nonazeotrope
12.6
74.3
13.1
...
7 !
11.3
13!
Nonazeotrope
372
355
372
355
355
370
369
369
369
369
364
323,364
358
370
363
147.0
194.5
150.7
162!
108
102.87
72
80.75
68.95
100.88
Data
Composition, Wt. %
A
B
C
65
11
II
1873
Tetrahydrofuran
Cyclohexane
Ethane
Triethylamine
Benzene
B.P.,
C.
II
II
1864
Name
Heptane
1 (
11
II
Azeotropic
C - Component
B-Component
A-Component
65.05
31.7
6.5
10.6
25.2
17.7
50.6
v-1
>
208
Nonazeotrope
304
30.4
58.8
10.8
Nonazeotrope
Nonazeotrope
362
326
326
s
79
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331
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C H
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1908
C H
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1907
C H
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1906
C H
4
1905
C H
4
1904
C H
1903
C H Cl Sn
1902
C H 0
C H 0
1900
1901
Formula
No.
1 0
1 0
1 0
1 0
1 0
1 0
O
O
O
O
O
O
A-Component
Name
Butyric acid
Ethyl
acetate
Butyltin
trichloride
Isobutyl
alcohol
Butyl
alcohol
Butyl
alcohol
Butyl
alcohol
Butyl
alcohol
2-Ethoxyethanol
B.P.,
C.
162.45
77.05
113/17
107.0
117.7
117.75
117.75
117.7
135.1
Formula
C5H5N
C H
6
B-Component
Name
Pyridine
Benzene
CoHigClzSn
C H
6
Dibutyltin
dichloride
Benzene
Butylamine
C H N
n
Pyridine
C H N
C H
C
Benzene
Butyl
acetate
Styrene
6 122
H
C He
8
B.P.,
C.
115.5
80.1
157/17
80.1
77.8
115.5
80.1
126.1
145
Formula
Cll 24
6 12
C
Cj H
2
2 7
ClSn
6 12
H
8 19
H
C H
7
1 8
C-Component
Name
Undecane
Cyclohexane
Tributyltin
chloride
Cyclohexane
Dibutylamine
Toluene
Cyclohexane
6 12
C H
C
II
Butyl
ether
Ethylbenzene
8 10
H
It
2-Ethoxyethanol
2-Furalde-
1909
1916
C5H5N
1915
C H N
1914
C H 0
1913
C H 0
1912
C H 0
1911
C H 0
1910
1917
hyde
2-Fur aldehyde
2-Fur alde-
hyde
2-Fur aldehyde
Pyridine
Pyridine
Benzene
6 6
H
C H
6
Benzene
135.1
161.7
Ethylbenzene
Benzene
8 10
H
C H
6
Toluene
161.7
161.7
161.7
115.5
115.5
80.1
80.1
Toluene
C H8
7
7 14
H
C H
5
Methylcyclohexane
Isoamyl
alcohol
Ethylbenzene
Cyclohexane
1 2
8 10
H
^6 12
H
2 , 3 - D i m e t h y l -pentane
7 16
H
136.15
80.1
110.7
110.7
101.1
131
136.15
80.75
89.8
Octane
8 18
H
Cyclohexane
6 12
H
Methylcyclohexane
Heptane
7 14
H
7 16
H
Heptane
7 16
Toluene
2 0
C H
C H
7
C H
6
Nonane
0
1 2
1 2
2 7
4-Methyl-2pentanone
Perfluorotributylamine
B.P.,
C.
B.P.,
C.
80.75
Azeotropic Data
Composition, Wt. %
A
C
Nonazeotrope
Nonazeotrope
194.5
80.75
166/17
80.75
v-1
Nonazeotrope
76.73
159.6
110.7
42
11.9
4
20.7
48
8.6
4.1
Ref.
153,362
67.4
140
48
362
Nonazeotrope
Nonazeotrope
334
v-1
Nonazeotrope
Nonazeotrope
v-1
v-1
Nonazeotrope
v-1
Nonazeotrope
v-1
v-1
Nonazeotrope
98.4
110.19
370
43,44
334
50
334
Nonazeotrope
108.7
77.42
142.1
136.15,
5 mm.
62 m m .
125.75
80.75
v-1
Nonazeotrope
101.1
98.4
110.7
150.7
110
152
227
331
114
114
114
371
87.3
363
Nonazeotrope
115.9
Nonazeotrope
65
v-1
Nonazeotrope
v-1
190
-Component
Formula
No.
Formula
C H 0
Phenol
182
C H
1919
C H 0
Phenol
182
^6
1920
C H N
Aniline
184.35
C H
1 2
C H N
Aniline
184.35
C H
1924
C H 0
Aniline
Hexylene
glycol
x-Cresol
1925
C H 0
2-Cresol
1922
1923
1926
C H N
C Hi 02
6
C H 0
7
90 nm.
J 80 to 100 C.
400 ran.
B.P.,
C.
1918*
1921
Name
2-Cresol
C-Component
B-Component
1 0
1 0
184.35
C H
CeHio
202
C H N
202
C H N
202
C H N
7
Name
B.P.,
C.
Formula
Cyclohexanone
Ethylene
diacetate
Cyclohexanol
155.6
C H
186
C H 0
8
160.65
C H
6
1 3
Toluene
110.7
C H
1 4
Toluene
Ethylbenzene
Pyridine
bases
Pyridine
bases
Pyridine
bases
110.7
136.15
143
157
163
l z
Name
.202.48
218.1
202.03
65.5
202.39
62
10 8
Naphthalene
Cl0 8
H
Nonazeotrope
218.1
Composition, Wt. %
A
B
C
195.7
10 8
C Hi
CeHi6
B.P.,
C.
160.65
B.P.,
C.
Cyclohexanol
Phenyl
acetate
Cyclohexylamine
Methylcyclohexane
Heptane
Ethylcyclohexane
Naphthalene
Azeotropic Data
Naphthalene
194.45
26.4
34.4
Evaporation
218.1
81
v - -1
data
Nonazeotrope
Nonazeotrope
98.4
131.8
57
253
39.2
Nonazeotrope
101.1
Ref.
v - -1
242
297
v - -1
v - -1
138
271
10
367
16.5
18
367
17
21
367
Table III. Quaternary Systems

Azeotropic
Azeotropic
No.
1927
Formula
A
C
D
1928
H
C
C
C
0
H N
H 0
H N
1929
A
C
D
1930
11.1
0.1
80.1
84
H 0
CzHO
C H
Q H
Water
Ethyl alcohol
Benzene
Cyclohexane
100
78.3
80.1
80.75
62.19
62.14
7.1
6.1
17.4
19.2
21.5
20.4
54.0
54.3
357
322,361
Water
Ethyl alcohol
Benzene
Hexane
100
78.3
80.1
68.95
Nonazeotrope
326
Water
Ethyl alcohol
Benzene
Methylcyclohexane
100
78.3
80.1
100.88
Nonazeotrope
326
H 0
C H 0
Q H
QrHi
Water
Ethyl alcohol
Benzene
Heptane
100
78.3
80.1
98.4
64.79
6.8
18.7
62.4
12.1
325
H 0
C H 0
C H
Water
Ethyl alcohol
Benzene
Iso-octane
100
78.3
80.1
64.69
6.7
17.7
61.4
14.1
325
H 0
C H 0
H H
C H
7
1 4
C
D
Ref.
8.7
1933
70
C
D
100
78.3
102.2
77.1
Composition
Water
Ethyl alcohol
Crotonaldehyde
E t h y l acetate
1 5
1932
H 0
C H 0
C H60
C4H8O2
2
6
H 0
C H 0
Q H
C
D
B.P./C.
100
81.6
78.3
89.7
1931
B.P.,C.
Water
Acetonitrile
Ethyl alcohol
Triethylamine
2
2
Name
Data
8 18
H
Nonazeotrope
334
TABLE
II
eu
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SYSTEMS
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<PQUQ
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TERNARY
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PQ
Pu
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55
cd
fi
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ci
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H m CD >
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cd
vo
00
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U
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VO t
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rfi
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. <U
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rfi
CM
HIffi
CM vo VO
u u u u
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00 ^ O CO
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CM
fi
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cd
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tO
m co
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73
Formula Index
T h i s index l i s t s a l l c o m p o u n d s a p p e a r i n g i n the a z e o t r o p i c t a b l e s .
Included are
f o r m u l a , n a m e , s t a n d a r d b o i l i n g point, a n d n u m b e r s of the s y s t e m s i n w h i c h the
compound appears as a component. The inorganic substances are indexed f i r s t .
Formula
A
AsCl
BeF
BrF
BrF
Br
B r
CO
CO
C1F
C1H
Cl
ci o s
2
CI3HS1
CI3P
Cl Ge
4
Cl Si
4
Cl Sn
4
Cl Ti
4
DH
D
FH
FNa
F Sb
5
N a m e and System
Formula
Nos.
Argon
B.p., -186
1, 2 , 1 6 7 5
Arsenic chloride
3
B . p . , 130
Diborane
B.p., -87.5
5
B e r y l l i u m fluoride
4
Bromine trifluoride
6-9
B . p . , 135
B r o m i n e pentafluoride
6 , 1 0 , 11
Bromine
B . p . , 58.9
7, 1 2 - 2 0
Phosphorus tribromide
21
B . p . , 175.3
Carbon monoxide
1676
B.p., -192
C a r b o n dioxide
22-26
B.p., -78.5
Chlorine trifluoride
2 7 - 2 9 , 1677
Hydrogen chloride
B.p.,
-85
27, 3 0 - 3 2 , 1678
Chlorine
B.p., -34.6
3 0 , 33
Sulfuryl chloride
34-37
B . p . , 69.1
Trichlorosilane
38
Phosphorus trichloride
39-44
B . p . , 76
Germanium chloride
3
B . p . , 86.5
Silicon tetrachloride
4 5 , 46
B . p . , 57.6
Tin chloride
B . p . , 114.1
47, 48
Titanium tetrachloride
49-51
B . p . , 146.2
Deuterium hydride
5 2 , 53
Deuterium
B.p., -249.7
5 2 , 54
Hydrogen fluoride
B.p.,
19.4
8, 1 0 , 1 2 , 2 8 , 3 3 , 5 5 - 5 9 ,
1677, 1679
Sodium fluoride
4
Antimony pentafluoride
55
B . p . , 142.7
U r a n i u m hexafluoride
B . p . , 56
9, 1 1 , 1 3 , 2 9 , 5 6 , 1 6 7 7
F W
6
HNO3
H
H 0
2
22
H S
2
H S0
2
H N
3
He
N
N 0
2
25
o s
2
S
Se
CCI
CCI3F
CCI.
cs
CHC1F
CHC1F
74
N a m e and S y s t e m
Nos.
Sulfur hexafluoride
60
Tungsten hexafluoride
61, 62
B . p . , 19.5
Nitric acid
B . p . , 86
6 3 , 64, 1680
Hydrogen
B.p., -252.7
5 3 , 54, 1676
Water
B . p . , 100
31, 63, 6 5 - 5 2 2 ,
16791832, 1927-1935
Hydrogen peroxide
65
B . p . , 151.4
Hydrogen sulfide
B.p.,
-59.6
22, 523, 524
Hydrogen sulfate
66
Ammonia
B.p., -33.4
525-529
Hydrazine
B . p . , 113.8
67
Helium
B.p., -268.9
530
Nitrogen
B.p., -195.8
1675, 1676
N i t r o u s oxide
23
B.p., -90.7
N i t r o g e n pentoxide
68
Oxygen
B.p., -183
1, 1 6 7 5
Sulfur dioxide
B.p., -10
5 3 1 , 1681
Sulfur
B . p . , 444.6
532
Selenium
B . p . , 688
532
Dichlorodifluoromethane
B.p.,
-29.8
57, 533-539
richlorofluoro methane
B.p.,
24.9
5 4 0 , 541
B.p.,
76.8
14, 34, 4 7 ,
542-556,
1833
Carbon disulfide
B.p.,
46.2
69, 557-561
Chlorodifluoromethane
B.p.,
-40.8
58, 533, 5 6 2 - 5 6 7
Dichlorofluoromethane
B.p., 7.63/723 m m .
568
FORMULA
Formula
CH9CI2
CHoO,
Chloromethane
CH3CI
CHoCloSi
CH3l
CH Cl Si
2
CH 0
4
CH S
4
CH N
5
C C1 F
2
1,1,2-Trichlorotrifluoro-
C2CI3F3
C C1
2
C C1 F
ethane
B . p . , 47.6
15, 74, 6 8 0 , 6 8 1 ,
1691, 1699
Tetrachloroethylene
B . p . , 121
75, 5 7 1 , 6 8 2 - 6 8 5
1,1,1,2-Tetrachlorodifluoroethane
B . p . , 91.6
16
1,1,2,2-Tetrachlorodifluoroethane
B . p . , 92.4
680
Trichloroacetyl chloride
49
B . p . , 118
C C1 F
2
C C1 0
2
C HC1
2
C HC1 F
2
C HF 0
C H
2
C H C1 F
2
C2H2CI2F2
C H C1 0
2
C H C1
2
C H C1
2
C H C1 N02
2
C H C1
2
CH C1
3
C H F 0
2
C H N
2
C H
C H Br
2
C H C1
C H C1
C H F
2
C H 0
2
C H 0
2
C H 0
C H 0
Hexachloroethane
C2CI6
72, 5 9 1 - 6 0 2 , 1690, 1848

Methane
B . p . , -161.5
530, 6 0 3 , 604, 1849
Dichloromethylsilane
46, 605
Methanol
B . p . , 64.7
32, 7 3 , 542, 570, 5 9 1 ,
606-673, 1683, 16911698, 1835-1837, 1847,
1849-1855
Methanethiol
B . p . ,6.00
674, 675
Methylamine
B.p., -6
676, 677
562, 678
B.p., -38.5
1,2-Dichlorotetrafluoroethane
B.p., 2.22/723 m m .
568, 606, 679
C H C1
B . p . , 101.2
Chloropentafluoroethane
C2CIF5
Name and System Nos.
B.p., -24
534
Trichloromethylsilane
45, 590
Iodomethane
B . p . , 42.55
557
Nitromethane
CH3NO2
Formula
B . p . , 61.2 C ^ ^ l o ,
64, 70, 5 6 9 - 5 8 4 , 1 6 8 0 ,
1682-1687,
1834-1846
Bromochloromethane
585
B . p . , 69
Dichloromethane
B.p., 40.7
585, 586, 1847
F o r m i c acid
B . p . , 100.75
71, 5 6 9 , 5 8 7 - 5 8 9 ,
1682, 1688, 1689, 1834
CH BrCl
75
Chloroform
CHCI3
C H
INDEX
35
B . p . , 184.8
Trichloroethylene
B.p., 86.2
543, 686-690,
1700-1702, 1833
1,2,2- T r i c h l o r o - 1 , 1 - d i fluoroethane
B.p., 71.1/736 m m .
17
5 9 , 76
Acetylene
B.p.,-84
24, 6 9 1 - 6 9 3 , 1856
C H BrO
2
C H C1
2
C H C10
2
CoHrNO
is-l,2-Dichloroethylene
B.p., 60.3
607, 694-701
trans-1,2- Dichloro ethylene
B . p . , 48.3
608, 702-709
1,1-Dichloro-2,2-difluoroethane
18
B . p . , 59/735 m m .
l,2-Dichloro-l,2-difluoroethane
B . p . , 30
563
Chloroacetyl chloride
50
B . p . , 105
1,1,2,2-Tetrachloroethane
3 6 , 51
B . p . , 146.2
Vinyl chloride
7 1 0 , 711
B . p . , 13.4
Methyl dichlorocarbamate
77
712, 713
B . p . , 74.1
B.p.,
113.65
68, 6 8 2 , 712
2,2,2-Trifluoroethanol
714
Acetonitrile
B . p . , 80.1
79, 544, 572, 592,
715-726, 1684,1 7 0 3 1706, 1857, 1927
Ethylene
B . p . , -103.7
25, 6 9 1 , 727, 1856
1,2-D i b r omoethane
728, 729
B . p . , 131.5
1,1-Dichloroethane
558, 713
B . p . , 57.2
1 , 2 - D i c h l o r o ethane
B.p., 83.16
37, 80, 545, 6 0 9 ,
686, 710, 715, 7 3 0 735, 1707, 1708, 1858
1,1-Difluoroethane
535, 678
B.p., -24.7
Acetaldehyde
B . p . , 20.2
540, 610, 736-742,
1681, 1709, 1710
Ethylene oxide
743
B . p . , 10.5
Acetic acid
B . p . , 118.1
81, 546, 573, 587, 6 1 1 ,
687, 744-768, 1685,
1688, 1834, 1 8 5 9 1873, 1936, 1937
Methyl formate
B . p . , 32
541
2 - B r o m o ethanol
B.p., 100/150 m m .
82
Chloroethane
B . p . ,12.4
736, 769
2-Chloroethanol
B.p., 128.7
83, 7 7 0 - 7 7 2 , 1711
Acetamide
B . p . ,222
773
ADVANCES
Formula
C H N0
2
C H
CzHgO
C H 0
2
C H OS
2
C H 0
2
C H S
2
C H S
2
C H N
2
C ^ N
C H NO
2
C H N2
2
C H N
2
C3CI3F5
C F
3
C F
C 3 H F 5 O 2
C HF
3
C H C1F C>2
3
C H F 0
3
C H ClF NO
3
C H F NO
3
C H N
3
C H NS
3
C H

Nitroethane
P . p . , 114.0
84, 7 7 4 - 7 8 0 , 1874
Ethane
B.p., -88.6
26, 523, 6 0 3 , 6 9 2 ,
727, 7 8 1 , 1849, 1856
Ethyl alcohol
B . p . , 78.3
85, 547, 574, 593, 612,
681, 694, 702, 714, 744,
774, 782-866, 1686,
1692, 1699, 1703, 1707,
1709, 1712-1738, 1838,
1850,
1857,1875-1882,
1927-1933, 1938, 1939
Methyl ether
B.p., -23.7
531, 536, 612
Dimethyl sulfoxide
867
Ethylene glycol
B . p . , 197
86, 8 6 8 - 8 9 3 , 1883
Methyl sulfide
B . p . , 37.32
894-899
Methyl disulfide
900-907
B . p . , 109.44
Dimethylamine
B . p . , 7.4
908, 1739
Ethylamine
B . p . , 16.6
525, 909, 910
2- A m i n o ethanol
B.p., 170.5
87, 9 1 1 , 912
1,1-Dimethylhydrazine
88
E t h y l e n e d i a m i n e B . p . , 116
89, 913, 917, 1740
1,2,2-Trichloropentafluoropropane
B . p . , 72.5
19
Hexafluoropropene
B.p., -6.1/2059 m m .
537, 564
Perfluoropropane
B.p., 12.5/6.064 a t m .
565
Pentafluoropropionic acid
90, 918
Heptafluoropropane
B.p., 17/2328 m m .
538
3-Chloro-2,2,3-trifluoropropionic acid
919
2,2,3,3-Tetrafluoropropionic acid
920
3-Chloro-2,2,3-trifluoropropionamide
921
2,2,3,3-Tetrafluoropropionamide
922
Acrylonitrile
B . p . , 77.2
91, 614, 716, 923, 1712,
1741
Thiazole
B . p . , 116.8
92
Propadiene
B.p., -32
526, 924-927, 1 8 8 4 1886
Formula
C 3 H 4
C3H4C14
C 3 H 4 0
C 3 H 4 0
C H C1
3
C H C1
3
C 3 H 5 C I O
C 3 H 5 C I O
C 3 H 5 C I 3
C 3 H 5 F
C H N
3
C 3 H 5 N O
C H C1 0
3
^3H 0
IN
CHEMISTRY
SERIES
Name andSystem Nos.

Propyne
B.p., -23.2
693, 924, 928-930,
1884-1886
Tetrachloropropane
931
Acrolein
B . p . , 52.8
93
2-Propyn-l-ol
B . p . , 115
94, 932, 1742, 1743
Acrylic acid
B . p . , 141.2
95, 933, 1744
Ethylene carbonate
96, 868
3-Chloro propene
97, 934
B.p., 45.15
x-Methylvinyl chloride
98
2-Chloro-2-propen-l-ol
935
Epichlorohydrin
936
B . p . , 116.45
1,2,3- Trichloropropane
936
B . p . , 156.85
2- F l u o r o p r o p e n e
527
B.p., -23
Propionitrile
B . p . , 97.4
923, 1741
Hydracrylonitrile
99
B . p . , 229.7
Propene
B.p., -48
925, 928, 937, 1884
1,2- Dichloropropane
B.p., 96.3
688, 730, 938,
939, 1745
2,3 - D i c h l o r o - l - p r o p a n o l
100
B . p . , 183.8
Acetone
B . p . , 56.1
101,
548, 575, 594,
615, 683, 695, 703,
711, 717, 782, 9 1 1 ,
940-957, 1713, 17461752, 1835, 1 8 3 8 1842, 1850, 1 8 5 1 ,
1852, 1858, 1887-1890
Allyl alcohol
B . p . , 96.90
102, 549, 9 5 8 - 9 6 3 ,
1700, 1753-1755, 1891
Propionaldehyde
B.p., 47.9
103, 964, 965, 1693
Propylene oxide
B . p . , 38
104, 737, 9 3 8 , 964, 966
1,3-Dioxolane
B . p . , 75.6
105, 967-970
Ethyl formate
B.p., 54.0
106, 577, 696, 704,
971, 1714, 1843
Methoxyacetaldehyde
B.p., 92/770 m m .
107
M e t h y l acetate
B . p . , 57.2
108, 576, 6 1 6 , 6 9 7 ,
705,
972-1001,
1694,
1836, 1844, 1 8 5 1 ,
1853, 1887
FORMULA
Formula
C H 0
3
C H 0
3
C H C1
3
C H 7Cl
,
C H C10
3
C H NO
3
C H NO
3
C H N0
3
C H N0
3
C H
3
C H 0
3
C H 0
3
C H OS
3
C H 0
3
3 82
C H 0
8
3 82
H
C3HgS
C3H S
8
C H BO
3
N a m e and System
Nos.
Propionic acid B.p.,

745,
1002-1010,
1756, 1892
C H Br
3
77
INDEX
140.7
Methyl glycolate
1011, 1012
B . p . , 151.2
s-Trioxane
B . p . , 114.5
1013
2- Bromopropane
B . p . , 59.35
578, 971, 972,
1843-1845
1 - Chloropropane
1 0 9 , 559
B . p . , 46.6
2- Chloropropane
110, 934
B . p . , 34.9
Propylene chlorohydrin
B.p., 73/100 m m .
1014, 1745
, -Dimethylf ormamide
B . p . , 153.0
111, 588, 718,
919-922,
1015
Propionamide
B . p . , 222.1
1016-1018
1 - Nitropropane
B . p . , 131.6
112, 617, 783,
1019-1024
2-Nitropropane
B . p . , 120.3
113, 618, 784,
1025-1030
Propane
B . p . , -42.1
524, 566, 604, 926,
929, 937, 1849, 1885
Isopropyl alcohol
B . p . , 82.5
115, 595, 684, 731, 775,
785, 940, 958, 1019,
1025, 1031-1059,
1690,
1695, 1702, 1708, 1746,
1757-1766, 1846, 1888,
1893-1895,
1934
P r o p y l alcohol B . p . , 97.25
114, 550, 596, 746, 776,
1020, 1026,
1060-1072,
1701, 1 7 6 7 - 1 7 7 4 , 1896
2- ( M e t h y l t h i o ) e t h a n o l
1073
2 - Methoxyethanol
B . p . , 124.5
116, 619, 1 0 7 4 - 1 0 9 4 ,
1 7 7 5 - 1 7 7 7 , 1897, 1898
Methylal
B . p . , 42.6
6 9 8 , 706
1,2-Propanediol
B . p . , 188
117, 939, 10951106, 1778
1,3-Propanediol
B . p . , 214
118, 1107
Ethyl methyl sulfide
1108-1113
B . p . , 66.61
1-Propanediol
B . p . , 67
1060, 1767
T r i m e t h y l borate
B . p . , 68.7
620, 1114, 1854
Formula
C H ClSi
3
C H N
3
C H N
3
C H N
3
C H NO
3
C H
3
1 0
C C1 F
4
C F
4
C HF 0
4
C H 0
4
C H
C H 0
4
C H S
4
C^sCl
C H N
4
C ^ N
C Hg
4
C H C1N
4
C H C1
4
C H 0
4
C H 0
4
C H 0
4
C H 0
C H 0
C H 0
C H 0
C H 0
C H 0
C H 0
C H 0
N a m e and System
Nos.
Chlorotrimethylsilane
590, 605
Isopropylamine
1115
B . p . , 32.4
Propylamine
B . p . , 48.5
119
Trimethylamine
120
B . p . , 3.2
1 - A m i n o - 2-propanol
B . p . , 159.9
121, 1116-1119
1,2-Propanediamine
1 1 2 0 - 1 1 2 2 B . p . , 120.9
2,2,3- Trichloroheptafluorobutane
B . p . , 97.4
1123-1125
Perfluorocyclobutane
539, 567
B . p . , 122.0
122, 1126-1128,
1679
Maleic anhydride
1129, 1130
Vinylacetylene
1131
Diketene
941, 1132
Thiophene
B . p . , 83.97
1133-1142
2 - C h l o r o -1,3 -butadiene
1131, 1143, 1144
3-Butenenitrile
123
B . p . , 118.9
Methacrylonitrile
124
1,3-Butadiene
B.p., -4.5
676, 927, 930, 1886
2-Chloro - 2- methylpropionitrile
B . p . , 116
125
1,3-Dichloro-2-butene
1143
Crotonaldehyde
B . p . , 101.5
126, 1715, 1779, 1928
Methacrylaldehyde
127
B . p . , 68.0
3-Butene-2-one
1144
2,3-Butanedione
1145
B . p . , 90.7
3-Butenoic acid
128
Butyrolactone
131
B . p . , 204.3
Crotonic acid
B . p . , 185
129, 130
Methyl acrylate
1696
B . p . , 80.9
V i n y l acetate
B . p . , 72.7
132, 621, 738, 942,
1031, 1146-1149,
1747
Acetic anhydride
B . p . , 138
747, 1002, 1 1 5 0 - 1 1 5 2
Propylene carbonate
133
B . p . , 242.1
78
ADVANCES
Formula
C H C1
4
Formula
Name andSystem Nos.
1 - Chloro-2-methylpropene
C H 0
943
B . p . , 68
2-Chloroethyl vinyl ether
B . p . , 109.1
134, 7 7 0 , 1153
C He0
Butyronitrile
B . p . , 117.6
135
C H 0
2- H y d r o x y i s o b u t y r o n i t r i l e
136
C H 0
1-Butene
B . p . ,-6
677
2-Methylpropene
B . p . ,-6
C H S
674
Bis(2-chloroethyl) ether
C H C1
B.p., 178.6
137, 732, 7 7 1 , 8 6 9 ,
C H C1
1154-1156
2-Butanone
B . p . , 79.6 C H C l S n
138, 5 5 1 , 579, 622, 689,
699, 707, 786, 944,
C H NO
1145, 1157-1169, 1687,
1716, 1748, 1757, 1 7 8 0 1782, 1833, 1837, 1839,
C H NO
1846, 1899
Butyraldehyde
B . p . , 75.7
C H N02
139, 6 2 3 , 787, 1 1 7 0 1176, 1717, 1749,
1783-1786
C H N0
Ethyl vinyl ether
B.p., 35.5
140, 739, 788, 1718
C Hio
Isobutyr aldehyde
141, 1170
B.p., 63.5
C H
Methyl propenyl ether
142
B.p., 46.3
C HioO
Tetrahydrofuran
B . p . , 66.1
624, 700, 708,
1114, 1854
2-(Methylthio)propionaldehyde
143
C Hi O
1,4-Oxathiane
B . p . , 149.2
144
Butyric acid
B . p . , 162.45
1171, 1177-1179, 1900
p-Dioxane
B . p . , 101
145, 748, 772, 789, 9 1 3 ,
C H O
1032, 1180-1184, 1874
Ethoxyacetaldehyde
146
B . p . , 105
C H O
E t h y l acetate
B . p . , 77.05
552, 560, 6 2 5 , 690, 749,
790, 1033, 1061, 1 1 8 5 1191, 1893, 1901, 1928
C HioO
2 - Hydroxybutyr aldehyde
147
Isobutyric acid
B.p., 154.5
148, 1192-1194
C H O
Isopropyl formate
C H O
B.p., 68.8
580, 1157, 1845
3- M e t h o x y p r o p i o n a l d e h y d e
4 102
149
2 - Methyl - 1 , 3 - dioxolane
150
B.p., 82.5
4
C 4 H 7 C I O
C 4 H 7 N
C H NO
4
C48
C HeCl 0
4
C H 0
4
C H 0
4
C4H 0
8
C4H 0
8
C H O
4
1 0
C H 0
4
C H OS
4
C H OS
4
C H 0
C H 0
C H 0
4
4 82
H
1 0
1 0
C H 0
4
82
C H 0
4
C H 0
4
4 82
H
1 0
1 0
IN
CHEMISTRY
SERIES
Name andSystem Nos.

Methyl
propionate
B . p . , 79.7
151, 626, 1034,
1697, 1756
Propyl formate
B . p . , 80.9
1195
2 - V i n y l o x y ethanol
152, 870
B . p . , 143
Ethylene glycol monoacetate
871
Tetrahydrothiophene
1196-1202
B . p . , 120.79
1-Chlorobutane
B . p . , 77.9
1203
1 - Chloro- 2- methylpropane
1035, 1158
B . p . , 68.9
Butyltin trichloride
B.p., 113/17 m m .
1204, 1902
N,N-Dimethylacetamide
750
B . p . , 165
Morpholine
B . p . , 128.3
153, 1206, 1207
N-(2-Hydroxyethyl)
acetamide
154
2- M e t h y l - 2 - n i t r o - 1 propanol
1208
Butane
B.p., -0.5
528, 679, 740, 7 4 3 , 769
2- Methylpropane
675, 1698
B . p . , -11.70
Butyl alcohol
B . p . , 117.75
155, 553, 597, 627, 685,
751, 777, 791, 914,
1021, 1027, 1120, 1146,
1180, 1203, 1209-1231,
1787-1799,
1904-1907,
1935
sec-Butyl alcohol
B.p., 99.5
156, 598, 778, 792,
1022, 1028, 1159, 1209,
1232-1237, 1787, 18001807
tert-Butyl alcohol
B . p . , 82.41
599, 779, 1 0 2 3 ,
1029, 1800
Ethyl ether
B . p . , 34.5
5, 1 5 7 , 5 6 1 , 5 8 1 , 7 4 1 ,
966, 1036, 1211, 1239
Isobutyl alcohol
B . p . , 107
158, 6 0 0 , 780, 9 1 5 ,
1024, 1030, 1121, 1172,
1181, 1185, 1210, 1238,
1783, 1808, 1874, 1903
1,4-Butanediol
B . p . , 230
1241
1,1 - D i m e t h o x y e t h a n e
1173, 1784
B.p., 64.5
1,2-Dimethoxyethane
159, 1240
B . p . , 85.2
FORMULA
Formula
C H
4
C H
4
C H
4
1 0
2-Butanethiol
C4H10S
4
C H
4
1 0
C H
4
1 0
C4H10S2
Butylamine
C4H11N
C H
4
1 1
NO
N 0
C C1 F
5
C F
5
1 0
C F
C H F 0
5
C H 0
5
C5H5N
C H N
5
C H 0
5
C H 0
5
C H S
5
C H S
5
B . p . , 77.8
B . p . , 115.5
167, 589, 752, 1003,

1177, 1214, 1340-1349,
1678, 1689, 1813-1818,
1859-1865, 1892, 1900,
1905, 1914, 1915, 1936,
1937
2-Methyl pyrazine
168
B . p . , 133/737 m m .
2-Methylfuran
B . p . , 63
169, 965, 973, 1160
Furfuryl alcohol
1335
2-Methylthiophene
B . p . , 111.92
900, 1350-1353
3-Methylthiophene
1354-1360
B . p . , 114.96
C H N
5
C H
CsH
5 8
5 8
B . p . , 85.15
162, 794, 1037, 1213,

1719, 1758, 1789, 1811,
1904
Diethylamine
B . p . , 55.5
163, 628, 795, 909,
1327, 1328, 1704, 1812
2-Dimethylaminoethanol
B.p., 134.6
164, 9 0 8 , 1739
2,2'-Iminodiethanol
165, 910, 912, 1329
1,2-D i c h l o r o h e x a f l u o r o cyclopentene
B . p . , 90.6
1123, 1330
B.p., 25/833 m m .
61, 1331, 1332
Perfluoropentane
B.p., 40.86/1140 m m .
2, 6 0 , 6 2 , 1331
2,2,3,3,4,4,5,5-Octafluoro1-pentanol
1333, 1334
2-Furaldehyde
B . p . , 162
166, 554, 1187,
1335-1339,
1910-1913
Pyridine
C H C10
1133, 1299
Ethyl sulfide
B . p . , 92.07
1300-1308
Isopropyl methyl sulfide
B . p . , 84.76
1134, 1299, 1309-1316
Methyl propyl sulfide
1317-1324
B . p . , 95.47
Ethyl disulfide
B . p . , 154.11
1325, 1326
C Hi S
Formula
Name and System N o s .
B.p., 134.0
160, 7 9 3 , 1186,
1242-1277, 1809,1810,
1908, 1909
Diethylene glycol
B . p . , 245.5
161, 1154, 1278-1298
1- Butane thiol
B.p., 98/770 m m .
1212, 1788
1 0
79
2-Ethoxyethanol
O3
1 0
INDEX
C H
5
C5H8CI4
CsH 0
8
C H 0
5
C H 0
5
C H 0
5
C HeO
5
c iô
5
C He0
5
2
CsH 0
8
^5 8 - 2
H
C H 0
5
5 82
H
CsH 0
8
^5^8^ 3
C
5 10
5 10
5 10
'5 10
^5
2- C h l o r o a l l y l v i n y l ether
935
3- M e t h y l - 3 - b u t e n e n i t r i l e
170
B . p . , 137
Cyclopentene
B . p . , 44.4
974
Isoprene
B . p . , 34.3
629, 1361-1365
3- Methyl -1,2-butadiene
630
B.p., 40.8
cis-1,3- Pentadiene
631
B . p . , 44
trans-1,3- Pentadiene
632
B.p., 42.0
Tetrachloropentane
931, 1366
171, 959
B . p . , 67.4
Cyclopentanone
B . p . ,130
172, 1367-1369
1- M e t h o x y - 1 , 3 - b u t a d i e n e
173, 633
B . p . , 90.7
3- Penten-2-one
174
B.p., 123.5
3 - M e t h y l - 3-buten-2 - one
175
B . p . , 97.9
4- P e n t e n a l
B . p . ,106
176
A l l y l acetate
B . p . , 104.1
177, 960
3.3- D i m e t hoxypropyne
1742
B.p., I l l
Ethyl acrylate
B . p . , 99.5
178, 796, 933, 1370,
1720, 1744, 1819
Isopropenyl acetate
B.p., 97.4
179, 945, 1150, 1373
Methyl methacrylate
B.p., 100.8
180, 1215, 1242,
1371, 1372
2.4- Pentanedione (acetyl
acetone)
B . p . , 140.6
181, 1373
- Valerolactone
182
V i n y l propionate
183
B . p . , 95.0
Methyl acetoacetate
1192
B . p . , 171.7
Cyclopentane
B . p . , 49.35
894, 975, 1374, 1375
2- M e t h y l -1 - butene
B.p., 31.10
635, 797, 896, 1362
3- M e t h y l -1 - butene
B.p., 21.2
634, 1 3 6 1 , 1376
2-Methyl-2-butene
B . p . , 38.60
636, 895, 1363, 1377
1-Pentene
B . p . , 29.92
637, 946, 976
cis-2-Pentene
B . p . , 37.1
638
Bis( 2- chloroethoxy )
methane
B . p . , 218.1
184
ADVANCES
80
Formula
C H
5
1 0
3-Dimethylaminopropionitrile
B . p . , 174.5
185
c i s - l - B u t e n y l methyl
ether
B . p . , 72.0
186, 1721
trans-1-Butenyl methyl
ether
B . p . , 76.7
187
Ethyl isopropenyl ether
188
B . p . , 61.9
B . p . , 55.7
189, 798, 1038
3-Methyl-2-butanone
1378, 1379
B . p . , 95.4
2-Pentanone
B . p . , 102.2
639, 799, 1039,
1380, 1820
3-Pentanone
B . p . , 102
1062, 1381-1384, 1768
P r o p y l vinyl ether
B . p . , 65.1
190, 800, 1722
Tetrahydropyran
B . p . , 88
191
C 5 H 1 0 O
C 5 H 1 0 O
^ 5 ^ 1 0 ^
C H
5
1 0
C H
5
1 0
C H
5
1 0
C H
1 0
C 5 H 1 0 O
C H
5
1 0
Valeraldehyde
C5H10O
C 5 H 1 0 O S
C H
5
1 0
C H
1 0
C H
1 0
C H
C5Hio0
C5Hio0
C H
5
C 5 H 1 0 O 3
C H
5
C H
C 5 H 1 1 N
C H
5
N O
C 5 H 1 1 N O
C H
5
C H
5
1 2
Formula
B.p.,
103.3
192, 193
2-Methylthioethyl vinyl
ether
1073
Ethyl propionate
194
B . p . , 99.1
Isopropyl acetate
B . p . , 88.7
640, 753, 947,
1151, 1385, 1723, 1750,
1759, 1888, 1894
3-Methoxybutyraldehyde
195
B . p . , 131
P r o p y l acetate B . p . , 101.6
196, 1063, 1243, 1769
Valeric acid
B . p . ,187
197, 198, 1386
3-Vinyloxy-l-propanol
200, 1095, 1107
1-Vinyloxy-2-propanol
199
3-Ethoxypropionic acid
201
B . p . , 219.2
3-Methoxybutyric acid
202
Methoxymethyl propionate
203
Piperidine
B . p . , 106
1340
N,N-Dimethylpropionamide
B . p . , 175.5
1004
4-Methylmorpholine
204
B . p . , 115.6
2-Methylbutane
B . p . , 27.90
641, 897, 1364, 1376
Pentane
B . p . , 36.15
205, 642, 719, 754,
898, 948, 977, 1365,
1377, 1387-1391
C Hi N
5
C 5 H 1 2 O
C H
5
C H
5
C H
5
C H
5
C H
5
C H
CsHi 0
2
5 122
5 122
^5
1 2
5 122
5 122
5 123
^5H
1 2
CsH
1 2
C H
1 3
C Hi NO
5
C H
5
CgFizO
C F
6
1 4
6 3
H
C 1
C6H C1
4
C H Br
6
C H C1
6
C H F
6
C H FO
6
C H N0
6
IN
CHEMISTRY
SERIES

1 - Methylpiperazine
206
B . p . , 138.0
Active amyl alcohol
B.p., 128.5
1333, 1367, 1398-1411
A m y l alcohol
B . p . , 137.9
643, 801, 1 3 9 2 1397, 1821
Butyl methyl ether
802, 1724
B . p . , 70.3
Isoamyl alcohol
B . p . , 131.85
1153, 1334, 1368,
1398, 1412-1426,
1725, 1822, 1914
2- M e t h y l - 1 -butanol
B . p . , 128.9
1369, 1427, 1428
2 - M e t h y l - 2- butanol
1429,1430
B . p . , 101.7
3- P e n t a n o l
B . p . , 115.6
1341
207
B . p . , 92
2,2- Dimethoxypropane
644, 803
B . p . , 80
1 -Ethoxy-2-propanol
208
B . p . , 132.2
3-Methoxy-1 - butanol
209
B . p . , 161.1
1,5-Pentanediol
210
B . p . , 242.5
2 - Propoxyethanol
211
B . p . , 151.5
2- (2- M e t h o x y ethoxy)
ethanol
B . p . , 194.2
872, 1278, 1431-1454
E t h y l isopropyl sulfide
901
B . p . , 107.22
3 - M e t h y l -1 - but anet h i o l
1412, 1822
B . p . , 116
N - Methylbutylamine
212
B . p . , 91.1
1-Ethylamino-2-propanol
213
B . p . , 159.4
N,N-Dimethyl-1,3-propanediamine
B . p . , 1349
214
Perfluorocyclic ether
1455
Perfluorohexane
918, 1332, 1455, 1456,
1457
1,2,4-Trichlorobenzene
1458
B . p . , 213
o-Dichlorobenzene
1459, 1460
B . p . , 179
Bromobenzene
B . p . , 156.1
1461
Chlorobenzene
B . p . , 131
1064, 1116, 1399,
1413, 1462, 1463, 1889
Fluorobenzene
B . p . , 84.9
1464
o-Fluorophenol
1400, 1414
Nitrobenzene
1465
B . p . , 210.85
INDEX
81
Formula
N a m e and System Nos.

Benzene
3 . p . , 80.1
38, 555, 601, 645, 720,
733, 804, 867, 916, 932,
949, 978, 1015, 1040,
1065, 1074, 1096, 1135,
1161, 1182, 1188, 1216,
1238, 1279, 1300, 1336,
1374, 1387, 1392, 1429,
1464, 1466-1479,
1711,
1740, 1743, 1760, 1770,
1775, 1780, 1801, 1820,
1823, 1848, 1855, 1858,
1875-1879, 1889,
1890,
1895-1897, 1899, 1901,
1903, 1906, 1910, 1916,
1917, 1929-1933,
1938
Phenol
B . p . , 182
1162,
1480-1488,
1918, 1919
Pyrocatechol
B . p . , 245.9
1489
Aniline
B . p . , 184.35
215, 805, 873,
1490-1498, 1880, 1881,
1920-1922,
1939
2- P i c o l i n e
B . p . , 134
721, 755, 1401, 1415,
1499-1501,
1824,
1966-1869
3- P i c o l i n e
B . p . , 144.1
216, 1502
4- P i c o l i n e
B . p . , 144.3
217
1.3- C y c l o h e x a d i e n e
979
B . p . , 80.25
Aniline hydrochloride
1503
2-Amino-3-methyl pyridine
1504, 1505
B . p . , 221
2,5-Dimethylpyrazine
B.p., 154/742 m m .
218
2,5- D i m e t h y l f u r a n
B . p . , 93.3
219, 646, 1163, 1385
2.4- Hexadienal
B . p . , 171
220
1,3-Butadienyl acetate
221
B . p . , 138.5
V i n y l crotonate
222
B . p . , 133.9
3,3'-Iminodipropionitrile
223
Cyclohexene
B . p . , 83.1
980
2- E t h y l - 1 , 3 - b u t a d i e n e
224
B . p . , 66.9
1.3- H e x a d i e n e
B . p . , 72.9
6 4 7 , 806, 1041
2.4- Hexadiene
B . p . , 82
648, 807, 1042
3- M e t h y l c y c l o p e n t e n e
808
B . p . , 64.9
3 - Methyl - 1 , 3 - pentadiene
B . p . , 77
649, 809, 1043
Cyclohexanone
B . p . , 155.6
225, 1480, 1506,
1825, 1918
C H
6
1 0
C Hi O
6
CHIOO
C HioO
6
C HioO
6
C HioO
6
6 102
6 102
^6
^6
C H N
6
C H NO
6
C H N0
6
C Hi
6
6 12
6 12
6 12
6 12
6 12
C H
6
1 2
6 12
6 12
6 12
C Hi
6
N a m e and System
Nos.
2-Ethylcrotonaldehyde
226, 1779
B . p . , 135.3
2-Hexenal
B . p . , 149
227
M e s i t y l oxide
B . p . , 129.5
1044, 1174, 1402,
1416, 1507-1511
2-Methylcyclopentanone
1393
B . p . , 138
2 - Methyl - 2- pentenal
229
B . p . , 138.7
5- P e n t e n - 2 - o n e
228
B . p . , 128.9
Ethyl crotonate
230
B . p . , 137.8
Vinyl butyrate
231
B . p . , 116.7
Vinyl isobutyrate
232
B . p . , 105.4
Ethylene, diacetate
B . p . , 186
233, 1481, 1919
Diallylamine
B . p . , 110.5
234
6- C a p r o l a c t a m
235
2-Methyl-2-nitropropyl
vinyl ether
236, 1208
Cyclohexane
B . p . , 80.6
39, 237, 602, 650, 734,
810, 950, 961, 981,
1013, 1045, 1066, 1075,
1108, 1136, 1147, 1164,
1189, 1217, 1301, 1309,
1337, 1378, 1380, 1388,
1465, 1466,
1512-1519,
1726, 1771, 1776, 1781,
1848, 1855, 1876, 1890,
1893, 1895-1897,
1899,
1901, 1903, 1906, 1910,
1916, 1929
2,3-Dimethyl-1 -butene
982
B . p . , 55.62
2,3-Dimethyl-2-butene
983
B . p . , 73.38
3,3-Dimethyl-1 -butene
984
B . p . , 41.4
2-Ethyl-1-butene
811, 985
B . p . , 64.95
1-Hexene
B . p . , 63.49
812, 986, 1109
cis-2-Hexene
B . p . , 68.8
813, 987
cis-3-Hexene
B . p . , 66.4
6 5 1 , 814
Methylcyclopentane
B . p . , 71.8
815, 951, 991, 1110,
1137, 1310, 1389, 1467,
1520, 1521, 1875, 1938
c i s - 3- M e t h y l - 2 - pentene
816, 988
B . p . , 70.52
t r a n s - 3 - M e t h y l - 2 - pentene
817
B . p . , 67.6
4 - M e t h y l -1 - pentene
989
B . p . , 54.0
4-Methyl-2-pentene
238, 818
B . p . , 56.7
ADVANCES
82
Formula
C Hi2
6
6 12
C Hi Cl 0
6
6 12
H
C 1
22
C Hi 0
2
C Hi 0
2
C Hi 0
2
C Hi 0
2
C H
6
C H
C H
6
C H
C Hi OS
6
C Hi 0
2
C i22
H
C Hi 0
2
C Hi 0
C6Hi Q
C Hi 0
2
C Hi 0
2
6 122
H
QH12O2
C6Hi 0 S
2
Name andSystem Nos.

t r a n s - 4- M e t h y l - 2 - pentene
990
B . p . , 58.4
1,1,2- T r i m e t h y l c y c l o p r o pane
B . p . , 52.6
952
Bis(chloroisopropyl)ether
239, 1014
B . p . , 187.0
1,2 - B i s ( 2 - c h l o r o e t h o x y )
ethane
B . p . , 240.9
240
Butyl vinyl ether
B.p., 94.2
241, 652, 819,
1218, 1790
Cyclohexanol
B . p . , 160.55
242, 1461, 1482, 1490,
1506, 1512, 1522, 1523,
1825, 1918, 1920
2- Ethylbutyraldehyde
243
B . p . , 116.7
2-Hexanone
B . p . , 127.2
1772
Hexanal
B . p . , 128.3
245, 1219
B.p., 83.4
244, 820, 1727
2- Methylvaleraldehyde
B.p., 118.3
246, 1067, 1773
4 - M e t h y l - 2- pentanone
B.p., 116.2
582, 6 5 3 , 9 5 3 , 1046,
1468, 1513, 1524, 1525,
1761, 1840, 1916
2-Ethylthioethyl vinyl
ether
B . p . , 169.7
247
Butyl acetate
B . p . , 126.2
583, 954, 1190, 1220,
1232, 1244, 1526-1528,
1785, 1791, 1826, 1827,
1907, 1935
B.p., 112.3
1233, 1526, 1802,
1826, 1828, 1906
2-Ethylbutyric acid
248
B . p . , 194.2
2-Ethyl - 2- methyl -1,3dioxolane
B . p . , 117.6
251
Hexanoic acid
B.p.,
205.15
249, 1529, 1530
4- H y d r o x y - 4- methyl - 2 pentanone (diacetone
alcohol)
B . p . , 161
250, 1508
2-Methylpentanoic acid
252
B . p . , 196.4
Tetrahydropyran-2methanol
B . p . , 187.2
254
4-Vinyloxy-1 -butanol
253, 1241
2,4- D i m e t h y l suif olane
1532, 1533
Formula
C O H 1:203
C H
6
C H
C Hi 0
C6H13NO
C H
6
1 3
NO
C H
1 3
NO
C Hi N0
6
Co 14
H
C H
6
C H
6
C H
6
C H
C6H14N2
C H
6
N 0
2
C Hi N 0
6
C H
6
C Hi 0
4
C H
6
C H
Name andSystem Nos.
255,
Methyl
256
Paraldehyde
B . p . , 124
821, 1499, 1535,
1536, 1710, 1824
2-(2-Vinyloxyethoxy)ethanol
257, 1280
1-Chlorohexane
258
B.p., 134.5
Cyclohexylamine
B.p., 124.5
259, 1491, 1514, 1920
Hexamethyleneimine
260
B . p . , 138
C Hi N
C H
SERIES
acetate
B.p., 156.2
1534, 1829
3-ethoxypropionate
CHEMISTRY
2-Ethoxyethyl
C Hi Cl
6
IN
N,N-Dimethylbutyramide
B.p.,
124.5/100 m m .
1178
2,6-Dimethylmorpholine
261
B . p . , 146.6
4-Ethylmorpholine
262
B . p . , 138.3
4-Morpholineethanol
263
B . p . , 225.5
2,2-Dimethylbutane
B.p.,
49.74
586, 654, 8 9 9 ,
992, 1375
2,3-Dimethylbutane
B.p.,
58.05
955, 993, 1111, 1165
Hexane
B . p . , 68.60
40, 264, 657, 756, 822,
956, 962, 994, 1005,
1112, 1115, 1138, 1166,
1175, 1195, 1221, 1456,
1462, 1469, 1492, 1515,
1520, 1537-1539, 1728,
1753, 1782, 1786, 1792,
1852, 1853, 1877, 1887,
1930, 1938
2-Methylpentane
B.p.,
60.27
655, 823, 995
3-Methylpentane
565, 996
B . p . , 63.28
B.p., 164
265, 1245, 1394
4-(2-Aminoethyl)morpholine
B . p . , 204.7
266
1-Piperazineethanol
267
B . p . , 246.3
Isopropyl propyl ether
1732
Butyl ethyl ether
B.p., 92.2
268, 658, 824,
1729, 1762
2-Ethyl-1 -butanol
B.p., 147.0
269, 1 5 4 0 , 1541
Ethyl isobutyl ether
1730
B . p . , 79
FORMULA
Formula
C
C HuO
6
C Hi 0
6
C H
6
OS
l 4
COHUQS
C H
6
C H
6
C H
C Hi 0
4
0$
INDEX
83

Hexyl alcohol
B . p . , 157.85
270, 874, 1542, 1323
Isopropyl ether
B . p . , 68.0
271, 701, 709, 742, 757,
825, 963, 1152, 1183,
1327, 1370, 1543, 1705,
1731, 1751, 1763, 1812,
1819, 1830, 1841, 1891,
1894
2- M e t h y l - 1 -pentanol
272
B . p . , 148
4-Methyl-2-pentanol
273, 1544
B . p . , 131.8
2-Butylthio ethanol
1545
2-Butoxy ethanol
B.p., 171.2
1191, 1222, 1527,
1546-1557
274
B . p . , 102.1
826, 1543
B . p . , 121.1
1,1-Dimethoxybutane
B . p . , 114
275, 659, 1176
2,2-Dimethoxybutane
660
B.p., 106-7
1,3-Dimethoxybutane
276
B . p , 120.3
1,1-Dimethoxy-2-methylpropane
B . p . , 104.7
277
Hexylene glycol
1558, 1559, 1923
2-Methyl-1,5-pentane diol
278
B . p . , 242.4
3-Methyl-l,5-pentanediol
279
B . p . , 248.4
Bis(2 - methoxyethyDether
280
B . p . , 162
Dipropylene glycol
1097, 1 5 6 0 , 1561
2- (2-Ethoxyethoxy)ethanol
B.p., 202.8
281, 875, 1246, 1281,
1562, 1563
Triethylene glycol
B.p., 288.7
1282, 1564-1568
Isopropyl sulfide
1196
B . p . , 119.25
Diisopropylamine
'
B . p . , 84.1
282, 1047, 1764
1,3-Dimethylbutylamine
283
B . p . , 108.5
Dipropylamine
B . p . , 109
284
N-Ethylbutylamine
285
B . p . , 111.2
Hexylamine
B . p . , 132.7
286, 1048
Triethylamine
B . p . , 89.4
287, 827, 1706,
1830, 1857, 1927
2-Butylaminoethanol
288
B . p . , 199.3
Formula
C6H15NO
C Hi5NO
6
C H
6
C H
1 5
N0
NO 3
C6H15N3
C H
6
1 6
C H
1 6
CHioOSi
C7FH
C7F16
C H
7
C H
6
C Hi 0
CHI 0
C Hi 0
4
C Hi 0
6
C H
6
C H
C Hi S
6
C H
6
C Hi N
6
C H
6
Ce i5
H
C H
6
C H
C H
1 5
NO
C7H5F3
C7H60
C7H7F
C H
7
C H O
7
C H 0
7
C H 0
7
C H 0
7
C H O
7
C H 0
7
C7H9CIO
C7H9N
2-Diethylaminoethanol
289, 1328
B . p . , 162.1
1-Isopropylamino-2-propanol
B . p . , 164.5
290
1,1'-Iminodi-2-propanol
B.p., 185/100 m m .
1117, 1569
2,2 ' , 2 " - N i t r i l o t r i e t h a n o l
1329
4-(2-Aminoethyl)piperazine
B . p . , 222.0
291
N,N-Diethylethylenediamine
B . p . , 144.9
292
, , ', '-Tetramethylethylenediamine
293
B . p . , 119
l-(Trimethylsiloxy) propane
B.p., 100.3/735 m m .
1068
Perfluoro(methylcyclohexane)
B . p . , 73-78
1470
Perfluoroheptane
B . p . , 83
371, 1390, 1471,
1537, 1570-1573
C 7 Hydrocarbons
B.p., 95-120
1417, 1427
, a, a - T r i f l u o r o t o l u e n e
20
B . p . , 103.9
Benzoic acid
1574
o-Fluorotoluene
B . p . , 114
1403, 1418
Toluene
B . p . , 110.7
294, 556, 6 6 1 , 828, 876,
902, 917, 967, 1049,
1069, 1098, 1118, 1122,
1132, 1184, 1197, 1223,
1342, 1404, 1419, 1428,
1430, 1493, 1516, 1521,
1534, 1538, 1575-1582,
1733, 1754, 1765, 1777,
1778, 1809, 1829, 1831,
1832, 1842, 1880, 1882,
1905, 1911, 1912, 1914,
1920, 1921, 1934, 1939
B e n z y l alcohol B . p . , 205.2
877, 1583
x-Cresol
B . p . , 202
1586-1588, 1924-1926
o-Cresol
B . p . , 191
878, 1585, 1883
m - and p-Cresol
B.p., 202
1584, 1589, 1590
p-Cresol
B . p . , 201.7
1575, 1591
Guaiacol
B . p . , 205.0
295
2-Chloroallylidene d i acetate
B . p . , 212.1
296
2,6-Lutidine
B . p . , 144
297, 758, 1405, 1420,
1502, 1593, 1870-1872
ADVANCES
IN
Formula
N a m e and S y s t e m Nos.
84
Formula
C H N
7
N-
C H N
7
C H N
7
C H N
7
C Hi O
7
C H
7
1 0
C Hi
7
C H
7
^7 12
C7H
C1
1 2
C Hi20
7
C H
C Hi 0
C H
7
C H
7
C H
7
1 4
C H
7
1 4
C Hi
7
C Hi
C Hi
C H
C H
7
N a m e and System N o s .
Methylaniline
879, 1494, 1592
Pyridine bases
1586-1588,1924-1926
Tetrahydrobenzonitrile
298
B . p . , 195.1
o-Toluidine
B . p . , 200.7
1594
1,2,3,6- Tetrahydrobenzal dehyde
B . p . , 164.2
299
Allylidene diacetate
300
2,4-Dimethyl-1,3-pentadiene
B . p . , 93.3
301
1,3-Heptadiene
829
2,4-Heptadiene
830
Tetrachloroheptane
1366
3-Hepten-2-one
302, 1509
B . p . , 162.9
Butyl acrylate
B . p . , 147
303, 1224, 1793
Cyclohexyl formate
1522
2-Ethoxy- 3,4-dihydro-1,
2-pyran
B . p . , 142.9
304
Pimelic acid
305
1,1 - D i m e t h y l c y c l o p e n t a n e
B . p . , 87.85
831, 1303, 1312, 1320
cis-1,2 - Dimethylcyclopentane
B . p . , 99.53
832
trans-1,2-Dimethylcyclopentane
B . p . , 91.87
833
cis-1,3-Dimethylcyclopentane
B . p . , 91.73
834
trans-1,3-Dimethvlc vclopentane
B . p . , 90.77
662, 835, 1139,
1302, 1311, 1319
2,3- D i m e t h y l -1 - pentene
836
B . p . , 84.2
Ethyl cyclopentane
B . p . , 103.47
837, 1317, 1354
trans-2-Heptene
1076
B . p . , 98.0
Methylcyclohexane
B . p . , 101.05
903, 1167, 1234, 1304,
1318, 1338, 1381, 1391,
1472, 1539, 1576, 1595,
1734, 1803, 1878, 1911,
1913, 1 9 2 1 , 1931
1,1,2,2- T e t r a m e t h y l c y c l o propane
B . p . , 75.9
838
Butyl isopropenyl ether
306
B . p . , 114.8
C H
7
C H
C H O
7
C H
7
C H
C7H
1 4
C H
1 4
C H
7
C H
C H
1 5
C H
C H
1 5
16
C H
7
C H
C Hi
NO
7 16
C H
7 16
H
C7 16
H
7 16
H
C H
7
1 6
C H
1 6
CHEMISTRY
SERIES
2,4 - D i m e t h y l - 3 - p e n t a n o n e
1 4 0 6 , 1421
B . p . , 125
3-Heptanone
B . p . , 147.6
307
4 - D i m e t h y l - 3-pentanone
308
B . p . , 143.7
5-Methyl-2-hexanone
309
B . p . , 144
A m y l acetate
B . p . , 146
310
Heptanoic acid
1597
B . p . , 222.0
Ethyl 3-ethoxypropionate
311
B . p . , 170.1
3-Methoxybutyl acetate
312
B . p . , 171.3
2- ( 2 - M e t hoxy ethoxy) ethyl
acetate
B . p . , 208.9
313
1,2-Dimethyl piperidine
1407, 1422
B . p . , 128
2,6 - D i m e t h y l p i p e r i d i n e
B . p . , 128
1386, 1408, 1423
N,N-Dimethylvaleramide
B.p., 141/100 m m .
1386
B . p . , 79.20
41, 839, 1113, 1316
2,3-Dimethylpentane
B . p . , 89.78
42, 840, 1140, 1306,
1314, 1322, 1473, 1917
B . p . , 80.50
43, 735, 841, 997, 1141,
1307, 1315, 1474, 1517
3,3-Dimethylpentane
842
B . p . , 86.07
3 - E t h y l pentane
843
B . p . , 93.47
Heptane
B . p . , 98.25
314, 663, 722, 759, 844,
904, 957, 968, 998,
1006, 1119, 1124, 1142,
1148, 1168, 1225, 1235,
1339, 1343, 1350, 1355,
1379, 1382, 1475, 1495,
1518, 1570, 1577, 1595,
1598-1600, 1735, 1794,
1804, 1813, 1859, 1879,
1881, 1882, 1912, 1913,
1922, 1932, 1939
2-Methylhexane
B . p . , 90.05
664, 845, 999
3- Methylhexane
B . p . , 91.85
665, 846, 1000,
1305, 1313, 1321
2,2,3- T r imethylbutane
B . p . , 80.88
44, 666, 1001, 1519
3-Heptanol
B . p . , 156.4
1155
5- Methyl - 2- hexanol
315
FORMULA
INDEX
85
Formula
N a m e and System
7 162
1 - Butoxy- 2- methoxyethane
316
B . p . , 149.9
1 - t e r t - B u t o x y - 2- methoxyethane
1077
1- B u t o x y - 2 - p r o p a n o l
317
B . p . , 170.1
2 - Ethyl - 1 , 5 - pentanediol
318
B . p . , 253.3
Dipropoxymethane
1774
B . p . , 146.6
Dipropylene glycol methyl
ether
1601
1 - (2-Ethoxyethoxy) - 2-propanol
B . p . , 198.1
319
2-Ethoxyethyl 2-methoxyethyl ether
320
2 - (2- P r o p o x y ethoxy )
ethanol
B . p . , 215.8
321
1 - Diethylamino-2-propanol
B . p . , 159.5
322
3- Diethylaminopropyl amine
B . p . , 169.4
323
( T r i m e t h y l s i l o x y )butane
1226
B.p.,
102.6
1125, 1330, 1571,
1596, 1602-1604
Perfluorobutyl ether
1476, 1598
B . p . , 100
ar-Trichlorostyrene
1605
a r - D i c h l o r o styrene
1431
Coumarone
B . p . , 173
1099
Indole
B . p . , 253
1283
Styrene
B.p., 67.9/57
324, 1070, 1078, 1247,
1606, 1736, 1898, 1908
2-(2,4-Dichlorophenoxy)
ethanol
325
Acetophenone
B . p . , 201.6
326
(Epoxyethyl)benzene
327
B . p . , 194.2
P h e n y l a c e t a t e B . p . , 195.1
1483, 1919
Methyl salicylate
1608
B . p . , 222.3
Ethylbenzene
B . p . , 136.15
328, 1011, 1071, 1079,
1126, 1193, 1227, 1248,
1284, 1344, 1409, 1424,
1558, 1599, 1606, 16091614, 1860, 1873, 1898,
1908, 1915, 1923, 1936
C H
7
7 162
7 lcP2
7 163
7 lo03
7 163
C H
7
1 6
C H
7
1 7
NO
C H
7
1 8
C H
7
1 8
OSi
C F
C Fi 0
8
C H5Cl3
8
C H C1
8
C H 0
8
C H N
8
C H
8
C H C1 0
8
C H O
8
C H 0
8
C H 02
8
C H 03
8
C H
8
1 0
Formula
Nos.
C H
8
1 0
C Hio
8
C Hio
8
C HioO
8
C H N
8
C H N
8
C H N
8
C H N
8
C H N
8
C H N
8
C Hi
8
C H
8
1 2
C H
8
1 2
C H
1 2
C Hi4
8
C H!P
8
C H
8
C H
1 4
C H
O
0
O
C H O
8
8 142
H
C H
8
8 142
8 142
C Hi 0
C H
8 143
H

m-Xylene
B . p . , 139
329, 728, 1012, 1127,
1129, 1194, 1249, 1535,
1607, 1615, 1616
-Xylene
B.p., 143.1/735 m m .
760, 880, 1100, 1250,
1345, 1617, 1861, 1937
p-Xylene
B . p . , 138.35
~
667, 729, 1072, 1080,
1128, 1251, 1285, 1536,
1618
-Methylbenzyl alcohol
330
B . p . , 203.4
N,N-Dimethylaniline
B.p., 194.05
881, 1496, 1592
N-Ethylaniline
331
B . p . , 204.8
- Methylbenzylamine
332
B . p . , 188.6
2- M e t h y l - 5- ethyl p y r i d i n e
333, 1578
B . p . , 178.3
x-Methyl-1,2,3,6-tetrahydrobenzonitrile
334
B . p . , 205.4
s-Collidine
B . p . , 171.3
882, 1585, 1883
4-Vinylcyclohexene
1081
2-Methyl-l,2,3,6-tetrahydrobenzaldehyde
335
B . p . , 176.4
3,4-Dihydro- 2,5- d i m e t h y l 2H- pyran- 2- carboxaldehyde
B . p . , 170.9
336
Diethyl fumarate
337
B . p . , 218.1
Diisobutylene
B . p . , 102.3
338, 1050, 1236,
1766, 1805
Bicyclo[2.2.1 ]-heptane-2methanol
B . p . , 203.9
339
Cyclohexyl vinyl ether
1523
Diisobutylene oxide
340
2 - Ethyl - 2- hexenal
341, 668
B . p . , 176
2-Octenal
342
Butyl methacrylate
1371
1,1 - D i a l l y l o x y e t h a n e
343
B . p . , 150.9
2-Ethyl-3-hexenoic acid
344
B . p . , 231.8
Vinyl 2-methylvalerate
345
B . p . , 148.8
Bis(2-vinyloxyethyl)ether
346, 1619
B . p . , 198.7
Butyl acetoacetate
347
B . p . , 213.9
2-Ethoxyethyl methacrylate
1372
ADVANCES
86
Formula
C H
8
C H
1 5
C H
8
1 6
C H
g
1 6
CQHI
C H
8
1 6
C H
8
1 6
^8 16
H
CeHi6
C H
8
1 6
C Hi
8
Ce l6
H
CeHi6
C H
8
1 6
C Hi
8
8 16
H
C H
1 6
C H
1 6
C H
8
C H i6
8
C Hi6
8
C H i6
8
C Hi6
8
C Hi
8
N a m e and System
Formula
Nos.
Diethyl succinate
348
B . p . , 216.2
2-(Aminoethyl)bicyclo
[2.2.1 Jheptane
349
B . p . , 185.9
1,1- D i m e t h y l c y c l o h e x a n e
847
B . p . , 119.54
trans-1,2-Dimethylcyclohexane
B . p . , 123.42
1051, 1252
1,3-Dimethylcyclohexane
1383
B . p . , 120.3
cis-1,3-Dimethylcyclohexane
B . p . , 120.09
1082
B . p . , 124.45
849, 905, 1198, 1356
cis-1,4-Dimethylcyclohexane
B . p . , 124.32
848
B . p . , 119.35
850
Ethylcyclohexane
B.p., 131.85
1199, 1253, 1559,
1602, 1609, 1923
1-Ethyl-1-methylcyclopentane
B . p . , 121.52
851
c i s - 1 - E t h y l - 2- methyl cyclopentane
1052
B . p . , 128.05
trans -1 - E t h y l - 2 - methyl cyclopentane
B . p . , 121.2
1053, 1083
t r a n s - 1 - E t h y l - 3- m e t h y l cyclopentane
B . p . , 120.8
1054, 1084
1-Octene
B . p . , 121.6
1610
is-2-Octene
B . p . , 125.6
1254
B . p . , 113.73
1055, 1357
B . p . , 104.89
1056, 1085
1,cis- 2,cis- 3 - T r i m e t h y l cyclopentane
B . p . , 123.0
1086
1,cis-2, trans- 3-Trimethyl
cyclopentane
B . p . , 117.5
852, 1057
1,trans-2,cis- 3-Trimethyl cyclopentane
B . p . , 110.2
1087
1,cis-2,trans - 4-Tr imethyl cyclopentane
1058
B . p . , 116.73
1, t r a n s - 2 , c i s - 4 - T r i m e t h y l cyclopentane
853
B . p . , 109.29
2,4,4-Trimethyl-1-pentene
493, 1088
B . p . , 101.44
C Hi
8
C H
8
1 6
C Hi 0
8
C Hi 0
8
C Hi OS
8
C Hi 02
8
C Hi 0
C Hi 0
8 162
8 162
C Hi 0
C Hi 0
8 162
8 162
8 163
8 163
8 163
8 164
C H
8
C1
1 7
C Hi Cl
8
C H
8
1 7
C H
1 7
C Hi NO
8
C Hi NO
8
8 18
8 18
C Hl8
8
IN
CHEMISTRY
N a m e and S y s t e m
SERIES
Nos.
2,4,4- T r i m e t h y l - 2 - pentene
854
B . p . , 104.91
2-Ethylhexanal
350, 1540
B . p . , 163.6
2,4,4- T r imethyl -1,2epoxypentane
B . p . , 140.9
351
2,4,4-Trimethyl-2,3epoxypentane
B . p . , 127.3
352
ether
B . p . , 210.5
353, 1545
2-Butoxyethyl vinyl ether
354
1,3 - D i m e t h y l b u t y l a c e t a t e
1620
B . p . , 146.1
2,3- Epoxy- 2- ethylhexanol
355
356, 1542
B . p . , 162.3
2-Ethylhexanoic acid
3 5 7 , 1621
B . p . , 227.6
H e x y l acetate
B . p . , 171.0
358
Iso-octanoic acid (isomers)
B . p . , 220
359
4 - M e t h y l - 2 - p e n t y l acetate
B.p.,
146.1
360, 1510, 1524, 1544
Octanoic acid
B . p . , 238.5
1529, 1622
2-Butoxyethyl acetate
361
B . p . , 192.2
2,5- Diethoxytetrahydrofuran
B . p . , 173.0
362
2- Ethoxyethyl 2-vinyloxyethyl ether
B . p . , 194.0
363
2 - (2- thoxy ethoxy) ethyl
acetate
B . p . , 217.4
364, 1623
1 - C h l o r o - 2 - ethylhexane
365
B . p . , 173
3- ( C h l o r o m e t h y l ) h e p t a n e
1541, 1624
N-Ethylcyclohexylamine
366
B . p . , 164.9
5- Ethyl - 2- methyl piper i dine
B . p . , 163.4
367
ar-Methylcyclohexanemethylamine
368
N,N-Dimethylhexanamide
1530
4- E t h y l - 2 , 6 - d i m e t h y l m o r pholine
B . p . , 158.1
369
2,2- Dimethylhexane
B.p., 106.84
855, 1323, 1353
2.3 - D i m e t h y l h e x a n e
856, 906
B . p . , 115.61
2.4 - D i m e t h y l h e x a n e
1089
B . p . , 109.43
FORMULA
Formula
C H
8
1 8
C H
8
1 8
C H
1 8
C Hi
C Hi
8 18
H
C Hi
C Hi
C H
8
1 8
C^H^
C H
8
1 8
C H
8
1 8
C H
8
1 8
C H
1 8
Cl Sn
2
C Hi 0
8
C H
8
C H
8
1 8
1 8
C Hi 0
8
C Hi OS
8
C Hi 02
8
C Hi
8
C Hi 0
8
C Hi 02
8
INDEX
87
Formula

B.p.,
109.15
1169, 1200, 1255,
1352, 1360, 1384
3,3-Dimethylhexane
1256
B . p . , 111.97
3,4-Dimethylhexane
857
B . p . , 117.73
3-Ethyl-3-methylpentane
1257
B . p . , 118.26
Iso-octane
529, 1237, 1497,
1579, 1806, 1933
2-Methylheptane
B.p.,
117.65
858, 907, 1201,
1351, 1359
3-Methylheptane
859
B . p . , 118.93
4-Methylheptane
860
B . p . , 117.71
-Octane
B . p . , 125.7
48, 370, 669, 723, 761,
1007, 1202, 1228, 1258,
1346, 1358, 1396, 1410,
1425, 1477, 1500, 1572,
1611, 1618, 1795, 1814,
1862, 1866, 1870
2,2,3-Tr imethylpentane
861, 1090
B . p . , 109.84
2 , 2 , 4 - T r i m e t h y l pentane
B.p.,
99.24
862, 1059, 1308, 1324,
1478, 1580, 1600, 1603
863
B . p . , 114.76
2,3,4-Tr imethylpentane
864
B . p . , 113.47
Dibutyltin dichloride
B.p., 157/17 m m .
1204, 1 6 2 5 , 1902
Butyl ether
B . p . , 142.1
865, 883, 969, 1107,
1149, 1206, 1229, 1239,
1528, 1626, 1737, 1796,
1807, 1827, 1828, 1907,
1935
2- Ethyl-1 - hexanol
B.p.,
184.8
371, 1156, 1484, 1615,
1624,
1626-1629
Iso-octyl alcohol (isomers)
372
B . p . , 186.5
Octyl alcohol
B . p . , 195.15
1630
2- Hexylthio ethanol
1631
1-Butoxy-2-ethoxye thane
374
B . p . , 164.2
1,1- Diethoxybutane
375
B . p . , 146.3
5-Ethoxy-3-methylpentanol
B . p . , 211.7
376
2-Ethyl-1,3-hexanediol
B . p . , 243.1
373, 866, 1632, 1738
1 8
C Hi 02
8
C Hi 0
C H
QHieOs
C Hi 0
C H
8
C H
8
1 9
C H
1 9
C Hi NO
8
C H
C H
1 9
N0
NO 2
C F iN
9
C HgN202
9
C H N 0
9
C H N
9
C H N
9
C H 0
9
C H
9
1 0
^
C Hio02
9
C Hio0
C H
9
1 0
C H
9
1 1
C H
1 2
C Hi
9
C Hi2
9

2- thyl - 3- m e t h y l - 1 , 5 pentanediol
B . p . , 265.5
377
2-Hexyloxyethanol
378
B . p . , 208.1
2-(2-Methylpentoxy)
ethanol
B . p . , 197.1
379
Bis(2-ethoxyethyl) ether
B.p.,
188.4
381, 1562, 1619
2-(2-Butoxyethoxy)ethanol
B.p.,
231.2
380, 884, 1286,
1479, 1 6 3 3 - 1 6 3 7 , 1847
l,2-Bis(2-methoxyethoxy)
ethane
382
2-[2-(2-Ethoxyethoxy)
ethoxy] ethanol
1287
Dibutylamine
B . p . , 159.6
383, 1230, 1797,
1811, 1904
2-Ethylhexylamine
384
B . p . , 169.1
2-Diisopropylaminoethanol
385, 885
B . p . , 190.9
2,2' - B u t y l i m i n o d i e t h a n o l
386
1,1'- E t h y l i m i n o d i - 2 propanol
B . p . , 238.9
387
Tris(perfluoropropyl)
amine
B . p . , 130
1638
2,4-Tolylene diisocyanate
1458, 1459, 1463, 1639
2,6-Tolylene diisocyanate
1639
Isoquinoline
1640
Quinoline
B . p . , 237.3
1641
V i n y l benzoate
388
-Methyl styrene
1485
Benzyl vinyl ether
1583
l,2-Epoxy-3-phenoxypropane
B . p . , 244.4
389
Ethyl benzoate
B . p . , 213.3
584, 1 5 8 4 , 1591
Ethyl salicylate
1642
B . p . , 233.7
5-Ethyl-2-vinyl pyridine
390
Cumene
B . p . , 152.4
391, 762, 1486, 1546,
1612, 1638, 1643
m-Ethyltoluene
1433
B . p . , 161.31
o-Ethyltoluene
B.p.,
165.15
1259, 1434
Formula
p-Ethyltoluene
1432
B . p . , 161.99
x "
y
1531
Mesitylene
B . p . , 164.72
1260, 1437, 1644
Propylbenzene
1487
B . p . , 158.9
1435
B . p . , 176.08
B.p.,
169.35
1436, 1644
C9H12
C H
9
1 2
CcjHxg
C9H12
C H
9
C9H12
C9.H12OS
C H
C H
1 3
C H
9
C H
9
NO
O
1 4
C H
9
1 4
OSi
C H
9
1 5
C H
1 6
C H
C H
1 6
C H
9
C H
9
1 8
C H
9
1 8
C H
9
1 8
C H
9
1 8
C H
9
1 8
C H
1 8
C9Hi 0
8
C9H18O
C Hi80
9
Name and System N o s ,
CgHÔj
C9H18O3
CgH^NO
2-Benzylthioethanol
1645
Bicyclo[2.2.1 ]hept-5-ene2-ol acetate
B . p . , 188.6
392
5-Ethyl- 2-pyridineethanol
393
Isophorone
B . p . , 215.2
394, 1646
1-Methyl-2,5-endomethylenecyclohexane-1 - methanol
B . p . , 211.1
395
Phorone
B . p . , 197.8
886
(Tr imethyl siloxy)benzene
1488
B . p . , 181.9
Triallylamine
B . p . , 151.1
396
cis-Hexahydroindan
1547
B . p . , 167.7
5-Ethyl-3-hepten-2-one
397
B . p . , 193.5
2,2-Bis(allyloxy)propane
1755, 1891
Dimethyl pimeiate
398
B . p . , 248.9
Butylcyclopentane
1261
B . p . , 156.56
Isobutylcyclopentane
1262
B . p . , 147.6
Isopropylcyclohexane
1263
B . p . , 154.5
1-Nonene
B . p . , 146.85
1264
Propylcyclohexane
B.p.,
156.72
1265, 1647
1,1,3-Trimethylcyclohexane
B . p . , 136.6
1091
2,6-Dimethyl-4-heptanone
B.p., 169.4
399, 670, 1207,
1511, 1525, 1620
2-Ethylheptanal
1616
2-Heptyl acetate
400
B . p . , 176.4
3-Heptyl acetate
401
B . p . , 173.8
3- ( 2 - E t h y l b u t o x y ) p r o p i o n i c
acid
402
N,N-Dimethylheptanamide
1597
ADVANCES
IN
Formula
Name andSystem Nos.
C920
C H
9
CQHOQ
C o9H 2. 0
n
C 9H 2, 0
Q
Con
H o
9
C H o
9
C H o
9
C H
Q
C9H o
2
C H
9
2 0
C H
9
2 0
C H
2 0
C9H20
C9H20O
C H
9
C9H20O2
9 202
H
C9H20O3
C H
9
O3
2 0
9 203
H
C H
9
2 0
C H o0
9
C H2iN
9
C H
9
C H2iNC>2
9
CHEMISTRY
SERIES
3,3-Diethylpentane
1266
B . p . , 146.17
n-Nonane
B . p . , 150.2
403, 671, 724, 763, 970,
1008, 1231, 1267, 1325,
1347, 1501, 1573, 1613,
1617, 1627, 1648, 1798,
1815, 1863, 1867, 1873,
1936, 1937
B . p . , 140.27
1268
2,2,3,4- Tetramethylpentane
B . p . , 133.02
1092
2,2,4,4- Tetr amethylpentane
B . p . , 122.28
1269
B . p . , 141.55
1270
1271
B . p . , 133.60
1272
B . p . , 126.54
B . p . , 124
1411, 1426, 1614
1273
B . p . , 137.68
1093, 1604
B . p . , 139.0
B.p.,
131.34
1094, 1274
1275
B . p . , 130.65
1276
B . p . , 140.46
2,6-Dimethyl-4-heptanol
404, 1649
B . p . , 178.1
Dibutoxymethane
1799
B . p . , 181.8
Diisobutoxymethane
1808
B . p . , 163.8
2-Ethyl-2-butyl-l,3propanediol
405
l-(2-Butoxyethoxy)-2propanol
B . p . , 230.3
406
2-(2-Isoamyloxyethoxy)
ethanol
1605
2-Methoxymethyl-2,4dimethyl-1,5-pentanediol
407
1,1,3-Triethoxypropane
408
Tripropylene glycol
1650-1652
N-Methyldibutylamine
409
B . p . , 163.1
Tripropylamine
B . p . , 156.
410
1,1 ' - I s o p r o p y l i m i n o d i - 2 propanol
B . p . , 248.6
411
FORMULA
Formula
C H iN0
9
C9H21NO4
ClO 8
H
Ci H N
0
H o0
1 0
10 123
10 14
10 14
10 14
Hi
CioHi
10 14
10 14
C
C
10 14
H
1 0
1 4
10 143
H
Ci H
1 5
C10H15N
C10H15NO
C10H16
CioHi 0
6
CioHieO
CIQHI 0
6
INDEX
89

1,1 ' , 1 " - N i t r i l o t r i - 2 - p r o panol
1569
2-(2-[2-(3 - A m i n o p r opoxy )
ethoxy ]ethoxy)ethanol
412
Naphthalene
B . p . , 218.1
887, 1102, 1288, 1560,
1589, 1633, 1653, 1678,
1924-1926
2,2'-Dipyridyl
B . p . , 274.
1348
D i m e t h y l phthalate
413
B . p . , 282.9
2-Phenoxyethyl acetate
414
B . p . , 260.6
Butylbenzene
B . p . , 183.27
1438, 1548
sec-Butylbenzene
B . p . , 173.30
1439, 1549
t e r t - B u t yl b e n e n e
B . p . , 169.11
1440, 1550
p-Cymene
B . p . , 177.2
1445, 1 4 9 8 , 1551
Dicyclopentadiene
415
B . p . , 172
m-Diethylbenzene
1442
B . p . , 181.13
-Diethylbenzene
1443
B . p . , 183.78
5- E t h y l - m - x y l e n e
1444
B . p . , 183.75
Isobutylbenzene
1441
B . p . , 172.76
1,2,3,5-Tetramethylbenzene
B . p . , 197.93
1446
Nicotine
416
Ethyl bicyclo[2.2.1]hept5-en-2-carboxylate
417
B . p . , 198
2 - (2 - P h e n o x y e t h o x y )
ethanol
B . p . , 297.9
418
N - B u t y l a n i l i n e B . p . , 240.4
419
N-Ethyl-a-methylbenzylamine
B . p . , 201.2
420
, ,-Trimethylbenzyl- '
amine
B . p . , 195.8
421
2 - ( a-Methylbenzylamino)
ethanol
422
Camphene
764
Dicyclopentenol
423
Trimethyltetrahydrobenzaldehyde
B . p . , 204.5
424
Diisopropyl maleate
425
B . p . , 228.7
Formula
CioHie
Ci Hi O
CioHi 0
CioHi 0
8
CioH
2 0
CioH o
2
CioH
C
2 0
10 20
H
CioH o
2
CioH o
2
C 10^20
CioH oO
2
CioHÔ
Ci H
0
2 0
OS
CioH o0
CioH o0
2
H o0
1 0
C10H20O3
CioH iCl
2
C10H21N
C
1 0
2 1
NO
C10H22
CioH
2 2
CioH
2 2
C10H22
C10H22O
C10H22O
C10H22OS
^10^22^2

Decahydronaphthalene
1654
Vinyl
2-ethylhexanoate
426
B . p . , 185.2
V i n y l octanoate (isomers)
427
Menthone
B . p . , 209.5
1655
n- Butylcyclohexane
1552
B . p . , 180.95
sec- Butylcyclohexane
1553
B . p . , 179.3
tert- Butylcyclohexane
1277
B . p . , 171.5
Isobutylcyclohexane
1554
B . p . , 171.3
cis-1-Isopropyl-4-methylcyclohexane
B . p . , 172.7
1555
trans-1-Isopropyl-4methylcyclohexane
1556
B . p . , 170.5
2-Ethylhexyl vinyl ether
428, 1810
B . p . , 177.7
Menthol
1655
Octyl vinyl ether
1630
2-Hexylthioethyl vinyl
ether
888, 1631
2-Ethylbutyl butyrate
429
B . p . , 199.6
2 - E t h y l h e x y l acetate
430, 1628
B . p . , 198.4
4-Methyl-2-pentyl butyrate
B . p . , 182.6
431
2 - Butoxy ethyl 2- vinyl oxyethyl ether
B . p . , 226.7
432
Chlorodecane (isomers)
433
B . p . , 210.6
N-Butylcyclohexylamine
434
B . p . , 209.5
N,N-Dimethyloctanamide
B.p., 187/100 m m .
1622
Decane
B . p . , 173.3
672, 725, 765, 1009,
1016, 1349, 1593, 1654,
1816, 1864, 1868, 1871
3 - E t h y l - 3- methylheptane
1326
B . p . , 163
3,3,5- T r imethylheptane
1557, 1656
B . p . , 155.5
Decyl alcohol
B . p . , 232.9
1 5 8 1 , 1 6 5 7 , 1831
2-Ethyloctanol
436
B . p . , 220.5
2- Propylheptanol
437
B . p . , 217.9
2 - (2 - t h y l h e x y l t h i o )
ethanol
1658
1,2- Dibutoxyethane
438
B . p . , 203.6
ADVANCES
90
Formula
^10^22^2
C10H22O3
10 224
H
10 224
H
Cl H
0
2 3
C10H23N
^10^23^
C
C
1 0
NO
2 3
11 10
H
11 10
H
C H OS
n
1 4
C11H1403
11 143
H
11 16
H
CnH
C H
n
1 6
1 7
11 182
H
11 20
H
C11H20O4
C11H22
CllH
2 2
11 222
H
CnH 20
2
C11H24
Formula
N a m e andSystem N o s .
1,2 - D i i s o b u t o x y e t h a n e
439
B.p., 160.5
2 - (2- Hexyloxyethoxy )
ethanol
B . p . , 259.1
440
1,2 - B i s ( 2 - e t h o x y e t h o x y )
ethane
B . p . , 206.9
441
Tripropylene glycol methyl
ether
B . p . , 243
889, 1103, 1659
Bis[2-(2-methoxyethoxy)
ethyl ]ether
442
Decylamine (isomers)
443
B . p . , 203.7
Diamylamine (isomers)
444
B . p . , 190
N , N - Dimethyl - 2- ethylhexylamine
B . p . , 176.1
445
2- Dibutylaminoethanol
446
B . p . , 228.7
B.p., 244.8
1504, 1634, 1660
B . p . , 241.1
773, 1447, 1505,
1561, 1563, 1590, 1601,
1608, 1621, 1623, 1635,
1640, 1641
2- (Benzylmercapto)- ethyl
vinyl ether
1289, 1645
Butyl salicylate
447
B . p . , 268.2
Ethyl 6-formylbicyclo[2.2.1 ] h e p t - 5 - e n - 2 - c a r boxylate
448
t e r t - A m y l b enz ene
1448
B . p . , 198.1
Allyl 6-methyl-3,4-epoxycyclohexanecarboxylate
449
B . p . , 251.4
N,N-Diethyl-o-toluidine
1594
Isopropyl 6-methyl- 3cyclohexenecarboxylate
450
B . p . , 215.2
5 - E t h y l - 3- n o n e n - 2 - one
451
B . p . , 226.4
Diethyl pimelate
452
B . p . , 268.1
tert-Amylcyclohexane
1449
B . p . , 198.1
5 - E t h y l - 2 - nonanone
453
B . p . , 222.9
2,6 - D i m e t h y l - 4 - h e p t y l
acetate
B . p . , 192.2
454
4- M e t h o x y - 2,6- d i p r o p y l 1,3-dioxane
B . p . , 223.6
455
Undecane
B . p . , 195.88
456, 673, 726, 766,
1010, 1017, 1179, 1450,
CiiH
CHEMISTRY
SERIES
N a m e a n dS y s t e m N o s .
1817, 1865, 1869, 1872,
1892, 1900
5-Ethyl-2-nonanol
B.p., 225
457, 1660, 1661
2 4
IN
Diamyloxymethane
C11H24O2
1397, 1821
C11H24O2
2,2-Dibutoxypropane
C11H24O2
2- Nonyloxyethanol
458
459
C11H25N
CnH 5NO
2
C12F27N
C 1 2 H 9 N
C12H10
Ci HioO
2
HuN
1 2
Ci Hi 04
2
C12H18
Ci2Hi 0
8
C12H19N
C12H20O2
Ci H o0
H2o0
1 2
12 204
H
1 2
1 2
2 2
1 2
2 2
H2 0
2
Ci H
2 3
^1 H
2 4
2 4
1 2
B . p . , 225.5
1,1,3,3-Tetraethoxypro-
C11H24O4
pane
B . p . , 220.1
460
2-Ethyl-N-propylhexylamine
1629
1-Dibutylamino-2-propanol
B . p . , 229.1
461
Tris(perfluorobutyl)amine
B.p., 177
1457, 1643, 1647,
1648, 1656, 1917
Carbazole
B . p . , 294
1290, 1564, 1650,
1662, 1663
Biphenyl
B . p . , 355.9
1291, 1664
Phenyl ether
B . p . , 259.3
890, 1292, 1565,
1574, 1642
Diphenylamine
B.p., 265/350 m m .
1503
Diethyl phthalate
462
B . p . , 294.3
1,3,5-Triethylbenzene
1489
B . p . , 215.5
Triisobutylene oxide
463
-Butyl--methylbenzylamine
B . p . , 239.3
464
sec-Butyl 6-methyl-3cyclohexenecarboxylate
465
Isobornyl acetate
767
B . p . , 225.8
Dibutyl fumarate
466
B . p . , 285.2
Dibutyl maleate
467
B . p . , 280.6
2-Ethylhexyl crotonate
468
B . p . , 241.2
V i n y l decanoate (isomers)
469
Diethyl 2- ethyl-3-methylglutarate
B . p . , 255.8
470
Dicyclohexylamine
471
B . p . , 255.8
2,6,8-Trimethylnonene
1649, 1665
2,6,8-Trimethyl-4-nonanone
B.p., 218.2
472
FORMULA
INDEX
Formula
N a m e and System
CI2H24OS
C12H24O2
Ci2H2 C>2
4
H 40
1 2
Ci H 6
2
C12H26
C12H26
C12H26O
Hexyl ether
891, 1294
2,6,8-Trimethyl-4-nonanol
B . p . , 225.5
479, 1582, 1665, 1832
l,l-Diethoxy-2-ethylhexane
B . p . , 207.8
480
1,1-Diisopentoxyethane
481
B . p . , 213.6
3- thoxy- 4- ethyloctanol
482
B . p . , 249.2
Bis(2-butoxyethyl)ether
483
B . p . , 254.6
1,1,3-Triethoxyhexane
484
C12H26O
12 262
H
1 2
^26 O 2
12
1 2
27
H27N
12 27
12 274
13 10
C13H24O2
13 26
H
C14H10
C14H10
C14H14O
Ci H
4
0
N
Formula
Nos.
2 - (2 - t h y l h e x y l t h i o ) e t h y l
vinyl ether
1293, 1658
2-Ethylbutyl 2-ethylbutyrate
B . p . , 222.6
473
2 - E t h y l b u t y l hexanoate
474
B . p . , 236.2
Hexyl 2-ethylbutyrate
475
B . p . , 230.3
Hexyl hexanoate
476
B . p . , 245.2
Dodecane
B . p . , 216
477, 768, 1018, 1104,
1451, 1636, 1653,
1666, 1818
B . p . , 185.6
1452
B . p . , 177.9
1453
2-Butyl-l-octanol
478
B . p . , 253.4
Dodecyl alcohol
1657
C12H24O2
91
Tributyltin chloride
B.p., 116/17 m m .
1 2 0 5 , 1 6 2 5 , 1902
Dihexylamine
B . p . , 239.8
485
T r i b u t y l a m i n e B . p . , 213.9
486
T r i b u t y l phosphate
487
Fluorene
B . p . , 294
1295, 1566, 1651,
1667, 1668
Decyl acrylate (isomers)
488
1-Tridecene
B . p . , 232.78
1454
Anthracene
B . p . , 340
892
Phenanthrene
B . p . , 340
1296, 1567, 1652,
1669, 1670
B e n z y l ether
1297, 1568
o - ( E t h y l h e x y l )phenol
489
B . p . , 297.0
N-(Ethylhexyl)aniline
490
CuH
N a m e and System
C14H28O
H 282
1 4
2 8
C14H28O2
Ci4H2 C>2
8
2 9
1 4
3 0
14 30
l 4
3 0
14 302
l 5
O2N
1 0
C15H18
<
-'15 28 - 4
H
Cl5 30
H
Cl5H
3 2
16 18
Ci6H28C>4
- l6 30 :
16 322
H
î6 32 - 2
H
Ci H
6
16 34
H
^16 35^
Nos.
1,3,6,8-Tetramethyl-1,6cyclodecadiene
491
B . p . , 220.5
Dibutyl adipate
492
Trimethylnonyl vinyl ether
493
B . p . , 223.4
2-Ethylbutyl 2-ethylhexanoate
B . p . , 261.5
494
2-Ethylhexyl 2-ethylbutyrate
B . p . , 252.8
495
2 - E t h y l h e x y l hexanoate
496
B . p . , 267.2
Hexyl 2-ethylhexanoate
497
B . p . , 254.3
N-(2-Ethylhexyl)cyclohexylamine
498
Tetradecane
B . p . , 252.5
1105
7-Ethyl-2-methyl-4-undecanol
B . p . , 264.3
499
x-Tetradecyl alcohol
1662, 1667, 1669
2-(2,6,8-Trimethyl-4-nonyloxy)ethanol
500
Di-p-isocyanatodiphenylmethane
1460
B.p., 192/5 m m .
Amylnaphthalene
1532
Dibutyl pimelate
501
1-Pentadecene
B.p., 183.7/217 m m .
1637
2,8-Dimethyl-6-isobutyl 4-nonanol
B . p . , 265.4
502
Bis(a-methylbenzyl)ether
503
B . p . , 286.7
Dibutyl phthalate
B.p., 238/50 m m .
1130
Bis(4-methylbenzyl)ether
maleate
504
Tridecyl acrylate
505
l,l'-Bis(x-methylcyclohexyl )dimethylamine
506
2-Ethylhexyl 2-ethylhexanoate
B . p . , 280.4
507
Palmitic acid
1671
Hexadecane
1533, 1666
Bis(2-ethylhexyl) ether
B . p . , 269.8
508, 893, 1106,
1298, 1632
Bis( 2-ethylhexyl )amine
509
B . p . , 280.7
ADVANCES
Formula
Ci H
3,9-Diethyl-6-tridecanol
510
B . p . , 309
X "
C18H24N2
1 8
1 8
H380 2
3 9
Name andSystem Nos.
NO
C20H30O2
alcohol
1663, 1668, 1670

Bis(a-methylbenzyl)ethylenediamine
511
Oleic acid
1672
Ricinoleic acid
1672
Stearic acid
1671, 1673
1,1- B i s ( 2 - ethylhexyloxy)
ethane
512
2-[Bis( 2- ethylhexyl)amino]
ethanol
513
Abietic
1674
acid
Formula
0
2oH
20 364
20 403
3 6
C20H42O
C
2 0
4 2
C20H43N
21 383
H
24
384
^24 52^4^^
31 586
H
IN
CHEMISTRY
SERIES
Name andSystem Nos.

Bis(2-ethylhexyl)fumarate
514
Bis(2-ethylhexyl)maleate
515
2-Ethylhexyl 3-(2-ethylhexyloxy)butyrate
516
Decyl ether (isomers)
517
Eicosanol (isomers)
518
Didecylamine (isomers)
519
Allyl 9,10-epoxystearate
520
Dioctyl phthalate
1664
Tetra(2-ethylbutoxy)silane
521
Tri( 2-ethylhexyl)-1,2,4butanetricarboxylate
522
Bibliography
1. Adelson and Evans, U. S. Patent 2,605,216 (1952).
2. Akers and Eubanks, Proc. Cryogenic Eng. Conf., 2nd, Boulder, 1957, p. 275;
C.A. 52, 14267 (1958).
3. Albanesi, Pasquon, and Genoni, Chim. e ind. (Milan) 39, 814 (1957); C.A. 52,
3440 (1958).
4. Allen and Ellis, U. K. At. Energy Authority, IGR-R/CA, 216 (1957).
5. Alpert and Elving, Ind. Eng. Chem. 43, 1174, 1182 (1951).
6. Al'tshuler, Zviadadze, and Chizhikov, Zhur. Neorg. Khim. 2, 1581 (1957); C.A.
52, 7833 (1958).
7. Amer, Paxton, and Van Winkle, Ind. Eng. Chem. 48, 142 (1956).
8. Amick, Weiss, and Kirshenbaum, Ibid., 43, 969 (1951).
9. Ansul Chemical Co., Ansul Ethers, Chem. Prod. Bull.
10. Bachman and Simons, Ind. Eng. Chem. 44, 202 (1952).
11. Ballard and Van Winkle, Ibid., 45, 1803 (1953).
12. Banks and Musgrave, J . Chem. Soc. 1956, p. 4682; C.A. 51, 3216 (1957).
13. Barber and Cady, J. Am. Chem. Soc. 73, 4247 (1951).
14. Barr-David and Dodge, J. Chem. Eng. Data 4, 107 (1959).
15. Benning, U. S. Patent 2,641,579 (1953).
16. Bierlein, Univ. Microfilms (Ann Arbor, Mich.), No. 24,101; C.A. 52, 6909 (1958).
17. Bierlein and Kay, Ind. Eng. Chem. 45, 618 (1953).
18. Boublik and Kuchynka, Chem. Listy 50, 1181 (1956); C.A. 50, 16320 (1956); Collection Czechoslov. Chem. Communs. 21, 1634 (1956); C.A. 51, 11794 (1957).
19. Boublik and Kuchynka, Collection Czechoslov. Chem. Communs. 25, 579 (1960);
C.A. 54, 16068 (1960).
20. Broich and Hunsmann, Ger. Patent 1,002,321 (1957); C.A. 53, 21663 (1959).
21. Brooks and Nixon, J . Am. Chem. Soc. 75, 480 (1953).
22. Brown and Smith, Australian J. Chem. 7, 264 (1954); 8, 62 (1955).
23. Ibid., 10, 423 (1957); C.A. 52, 3441 (1958).
24. Ibid., 12, 407 (1959); C.A. 54, 1003 (1960).
25. Ibid., 13, 30 (1960); C.A. 54, 10436 (1960).
26. Bruner and Darden, U. S. Patent 2,609,336 (1952).
27. Brzostowski, Malanowski, and Zieborak, Bull. acad. polon. sci., Classe III 7,
421 (1959); C.A. 54, 19067 (1960).
28. Burch and Leeds, Ind. Eng. Chem., Chem. & Eng. Data Ser. 2, 3 (1957).
29. Bures, Cano, and Wirth, J . Chem. Eng. Data 4, 199 (1959).
30. Burtle, Ind. Eng. Chem. 44, 1675 (1952).
31. Bushmakin and Kish, Zhur. Priklad. Khim. 30, 200 (1957); C.A. 51, 10989-90
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32. Butta, Chem. Listy 50, 1646 (1956); C.A. 51, 2349 (1957); Collection Czechoslov.
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34. Campbell and Hickman, J. Am. Chem. Soc. 75, 2879 (1953).
35. Canjar, Horni, and Rothfus, Ind. Eng. Chem. 48, 427 (1956).
36. Canjar and Lonergan, A.I.Ch.E. Journal 2, 280 (1956).
37. Carleton, Ind. Eng. Chem., Chem. & Eng. Data Ser. 1, 21 (1956).
38. Carswell and Morrill, Ind. Eng. Chem. 29, 1247 (1937).
39. Chabrier de la Saulniere, Ann. chim. 17, 353 (1942); C.A. 38, 3255 (1944).
40. Chaiyavech and Van Winkle, J. Chem. Eng. Data 4, 53 (1959).
41. Challis, U. S. Patent 2,691,624 (1954).
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43. Chao, Univ. Microfilms (Ann Arbor, Mich.), No. 19076; C.A. 51, 9245 (1957).
44. Chao and Hougen, Chem. Eng. Sci. 7, 246 (1958); C.A. 52, 15219 (1958).
45. Choffe and Asselineau, Rev. inst. fran. ptrole et Ann. combustibles liquides
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46. Ibid., 12, 565 (1957); C.A. 51, 17383 (1957).
47. Choffe, Cliquet, and Meunier, Ibid., 15, 1051 (1960); C.A. 55, 8009 (1961).
48. Christian, J . Phys. Chem. 61, 1441 (1957).
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51. Ibid., 2,789,087 (1957).
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53. Cole, Ind. Eng. Chem., Chem. & Eng. Data Ser. 3, 213 (1958).
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56. Conti, Othmer, and Gilmont, J. Chem. Eng. Data 5, 301 (1960).
57. Cova, Ibid., 5, 282 (1960).
58. Crawford, Edwards, and Lindsay, J. Chem. Soc. 1949, 1054; C.A. 43, 8835
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59. Crutzen, Jost, and Sieg, Z. Elektrochem. 61, 230 (1957); C.A. 51, 10214
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60. Curme and Johnson, "Glycols," ACS Monograph 114, Reinhold, New York,
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62. Dakshinamurty and Rao, J. Sci. Ind. Research (India)15 B, 118 (1956); C.A. 50,
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63. Ibid., 17B, 105 (1958); C.A. 52, 16851 (1958).
64. Dakshinamurty and Rao, Trans. Indian Inst. Chem. Engrs. 8, 57 (1955-6); C.A.
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65. Dakshinamurty, Rao, Acharya, and Rao, Chem. Eng. Sci. 9, 69 (1958); C.A. 53,
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66. Dakshinamurty, Rao, Raghavacharya, and Rao, J. Sci. Ind. Research (India)
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67. Davis and Evans, J. Chem. Eng. Data 5, 401 (1960).
68. Delzenne, Ind. Eng. Chem., Chem. & Eng. Data Ser. 3, 224 (1958).
69. Delzenne, J. Chem. Eng. Data 5, 413 (1960).
70. Desty and Fidler, Ind. Eng. Chem. 43, 905 (1951).
71. Din, Inst. intern. froid, Commissions intern. Zurich 1953, p. 17; C.A. 49, 5910
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72. Dobroserdov and Il'ino, Zhur. Priklad. Khim. 34, 386 (1961); C.A. 55, 13023
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73. Donald and Ridgeway, Chem. Eng. Sci. 5, 188 (1956).
74. Donald and Ridgeway, J. Appl. Chem. (London) 8, 403, 408 (1958); C.A. 53,
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75. Donham, Univ. Microfilms (Ann Arbor, Mich.), Mic. 58-687; C.A. 52, 14267
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76. Dow Chemical Co., unpublished data.
77. Drake, Duvall, Jacobs, Thompson, and Sonnichsen, J. Am. Chem. Soc. 60, 73
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78. Drout, U. S. Patent 2,647,861 (1953).
79. Dunlap, Bedford, Woodbrey, and Furrow, J. Am. Chem. Soc. 81, 2927 (1959).
80. Dunn, U. S. Patent 2,524,899 (1950).
81. Du Pont, Polychemicals Dept. Sales Bull. (1959).
82. Du Pont, New Products Bull. No. 19.
83. Dykyj, Paulech, and Seprakova, Chem. Zvesti 14, 327 (1960); C.A. 54, 21908
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84. Eastman Chemical Products, Inc., unpublished data.
85. Ehrett and Weber, J. Chem. Eng. Data 4, 142 (1959).
86. Eiseman, J. Am. Chem. Soc. 79, 6087 (1957).
87. Eliot, U. S. Patent 2,635,072 (1953).
88. Eliot and Weaver, Ibid., 2,662,847 (1953).
89. Ellis, U. K. At. Energy Authority, Ind. Group Hdq. 5197 (1953); C.A. 53, 15681
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90. Ellis and Forest, Ibid., IGR-TN/CA 457 (1957); C.A. 51, 9245 (1957).
91. Ellis and Johnson, J. Inorg. & Nuclear Chem. 6, 194, 199 (1958).
92. Ellis and Razavipour, Chem. Eng. Sci. 11, 99 (1959); C.A. 54, 10436 (1960).
93. England, U. S. Patent 2,802,028 (1957).
94. Faerber, Ibid., 2,836,546 (1958).
95. Fahnoe, Ibid., 2,527,358 (1950).
96. Farbenwerke Hoechst, unpublished data.
97. Fastovskii and Petrovskii, Zhur. F i z . Khim. 31, 836 (1957); C.A. 52, 25 (1958).
98. Feldman and Orchin, Ind. Eng. Chem. 44, 2909 (1952).
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100. Ibid., 2,590,096 (1952).
101. Fischer, Bingle, and Vogel, J. Am. Chem. Soc. 78, 902 (1956).
102. Fleischer, U. S. Patent 2,191,196 (1940).
103. Flom, Alpert, and Elving, Ind. Eng. Chem. 43, 1178 (1951).
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158. Katz and Newman, Ibid., 48, 137 (1956).
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100
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Azeotropic dataII

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AZEOTROPIC

Compiled by LEE H. HORSLEY

With the cooperation of WILLIAM S. TAMPLIN

AMERICAN CHEMICAL SOCIETY

All Rights Reserved

L i b r a r y of Congress Catalog C a r d 52-3085

ADVANCES IN CHEMISTRY SERIES

Maximum boiling point azeotrope (negative azeotrope)

Corrections for Azeotropic DataI

Replace -component, thionyl chloride, with sulfuryl chloride.

Calculation of Azeotropic Data for Immiscible Systems

= vapor pressure of component A

Bromine T r ifluo r ide

Be r yllium Fluor ide

Hydrogen Chlo r ide

Sulfuryl Chlor ide

Silicon T e t r achlo r ide

Titanium T e t r achlo r ide

Ethyl vinyl ether

2-(a - M e t h y l b e n z y l amino) ethanol

Chlorodif luor 0 methane

Chlo r odifluo r omethane

Dichlo r ofluo r o7.63/723 m m .

Chlorotrimethyl silane, 30-40

Butyl ethyl ether

2,2,2-T r ifluor oethanol

Ethane, -35, 0, 40 F . -88.3

1.2- Dichlo r opropane

N,N-Dimethylfor mamide 153

2-Methyl-2-nitropropyl vinyl ether,

Isopropyl Methyl Sulfide

Isopropyl Methyl Sulfide

2-Me t hyl-1-Bu t anol

Pe r fluor ocyclic Ether

1,2,4-T r ichlor obenzene

4-Methy 1-2 -pentanol

Phenyl ether, 100 m m .

Benzyl vinyl ether,

T r i s (per fluor opropyl)

% Phenanthrene i n creases with pressure; m i n . b.p.

20 atm. to critical point.

< < << < < < <!<<

I> E> I> > "tf

.> o .> u _> o

> > > > >

co* co" CO*

te" tc^ te"

Table III. Quaternary Systems

72, 5 9 1 - 6 0 2 , 1690, 1848

Name and System Nos.

Name and System Nos.

Name and System Nos.

Name andSystem Nos.

Propionic acid B.p.,

Name andSystem Nos.

Name andSystem Nos.

167, 589, 752, 1003,

162, 794, 1037, 1213,

Name and System Nos.

Name and System N o s .

Name and System Nos.

Name and System Nos.