TRNG THPT CHUYN H LONG ------------------

THI TH I HC LN I NM HC 2011 - 2012 MN: HA HC

Thi gian lm bi: 90 pht (50 cu trc nghim)

M thi 165

H, tn th sinh:.......................................................................... S bo danh:............................................................................... I. PHN CHUNG CHO TT C TH SINH (40 cu , t cu 1 n cu 40) Cu 1: Cho hn hp X gm hai kim loi kim tan ht trong 200ml dung dch cha BaCl2 0,3M v Ba(HCO3)2 0,8M thu c 2,8 lt H2 ( ktc) v m gam kt ta. Gi tr ca m l: A. 43,34 B. 49,25 C. 31,52 D. 39,4 Cu 2: Hn hp X gm hiro, propen, propanal, ancol alylic (CH2=CH-CH2OH). t 1 mol hn hp X thu c 40,32 lt CO2 (ktc). un X vi bt Ni mt thi gian thu c hn hp Y c dY X = 1,25. Nu ly 0,1 mol hn hp Y th tc dng va vi V lt dung dch Br2 0,2M. Gi tr ca V l: A. 0,1 lt B. 0,2 lt C. 0,25 lit D. 0,3 mol Cu 3: Dy cc kim loi c cu trc mng tinh th lp phng tm khi l: A. Ca, Sr, Ba B. Na, K, Ba C. Na, K, Mg D. Mg, Ca, Ba + 2+ 2Cu 4: Dy no sau y gm cc ion X , Y ,Z ,T v nguyn t M u c cu hnh e l 1s22s22p63s23p6 ? A. K+, Ca2+, Cl-, S2-, Ar. B. K+, Ca2+, F-, O2-, Ne. C. Na+, Ca2+, Cl-, O2-, Ar. D. K+, Mg2+, Br-, S2-, Ar. Cu 5: Nhng mt l st nh vo dung dch cha lng d mt trong nhng cht sau: FeCl3, AlCl3, CuSO4, Pb(NO3)2, NaCl, HCl, HNO3 long, H2SO4 c nng, NH4NO3. S trng hp phn ng to mui Fe(II) l: A. 4 B. 3 C. 6 D. 5 Cu 6: phn ng ht a mol kim loi M cn 1,25a mol H2SO4 v sinh ra kh X (sn phm kh duy nht). Ha tan ht 19,2 gam kim loi M vo dung dch H2SO4 to ra 4,48 lt kh X (sn phm kh duy nht, ktc). Kim loi M l: A. Fe. B. Cu. C. Mg. D. Al. Cu 7: Cho 3,76 gam hn hp X gm Mg v MgO c t l mol tng ng l 14:1 tc dng ht vi dung dch HNO3 th thu c 0,448 lt mt kh duy nht (o ktc) v dung dch Y. C cn cn thn dung dch Y thu c 23 gam cht rn khan T. Xc nh s mol HNO3 phn ng. A. 0,28 B. 0,36 C. 0,32 D. 0,34 Cu 8: t chy hon ton 4,872 gam mt hirocacbon X, dn sn phm chy qua bnh ng dung dch nc vi trong. Sau phn ng thu c 27,93 gam kt ta v thy khi lng dung dch gim 5,586 gam. Cng thc phn t ca X l: A. CH4 B. C4H8 C. C4H10 D. C3H6 Cu 9: Hn hp X cha K2O, NH4Cl, KHCO3 v BaCl2 c s mol bng nhau. Cho X vo nc d, un nng, dung dch thu c cha cht tan l: A. KCl, BaCl2 B. KCl, KOH C. KCl, KHCO3, BaCl2 D. KCl Cu 10: un nng 10,71 gam hn hp X gm propyl clorua v phenyl clorua vi dung dch NaOH long, va v un nng, sau thm tip dung dch AgNO3 n d vo hn hp sau phn ng thu c 8,61 gam kt ta, cc phn ng xy ra hon ton. Khi lng phenyl clorua c trong hn hp X l: A. 4,0 gam. B. 2,71 gam. C. 4,71 gam D. 6,0 gam.
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Cu 11: Nung nng hon ton 27,3 gam hn hp NaNO3, Cu(NO3)2. Hn hp kh thot ra c dn vo nc d th thy c 1,12 lt kh (ktc) khng b hp th (lng O2 ha tan khng ng k). Khi lng Cu(NO3)2 trong hn hp ban u l: A. 4,4 gam. B. 18,8 gam. C. 28,2 gam. D. 8,6 gam. Cu 12: Trn 3 dung dch Ba(OH)2 0,1M, NaOH 0,2M, KOH 0,3 M vi nhng th tch bng nhau thu c dung dch A . Ly 300ml dung dch A cho phn ng vi V lt dung dch B gm HCl 0,2M v HNO3 0,29M, thu c dung dch C c pH =12. Gi tr ca V l: A. 0,134 lt B. 0,414 lt C. 0,424 lt D. 0,214 lt Cu 13: Ha tan mt lng ancol X vo nc thu c 6,4 gam dung dch Y, nng ca X trong Y l 71,875%. Cho 6,4 gam dung dch Y tc dng vi lng d Na thu c 2,8 lt H2 (ktc). S nguyn t H c trong cng thc phn t ancol X l: A. 10 B. 6 C. 8 D. 4 Cu 14: Dung dch X cha 14,6 gam HCl v 22,56 gam Cu(NO3)2. Thm m (gam) bt st vo dung dch X, sau khi phn ng xy ra hon ton thu c hn hp kim loi c khi lng l 0,628m (gam) v ch to kh NO (sn phm kh duy nht ca N+5). Gi tr ca m l: A. 1,92. B. 9,28. C. 14,88. D. 20,00. Cu 15: Trong t nhin clo c hai ng v c s khi l 35 v 37. Khi lng trung bnh nguyn t ca clo l 35,5. Vy % v khi lng ca 37Cl trong axit pecloric HClO4 l (Cho s khi 1H, 16O): A. 9,204 B. 9,25 C. 9,45 D. 9,404 Cu 16: Nhit si ca ancol etylic (I), anehit axetic (II), axit axetic (III) v axit propionic (IV) sp xp theo th t gim dn l: A. I > II > III > IV. B. IV > III > I > II. C. II > III > I > IV. D. IV > I > III > II. Cu 17: Xt ba nguyn t c cu hnh electron ln lt l: X: 1s22s22p63s1 ; Y: 1s22s22p63s2 ; Z: 1s22s22p63s23p1. Hiroxit ca X, Y, Z xp theo th t tng dn tnh baz l: A. XOH < Y(OH)2 < Z(OH)3 B. Z(OH)2 < Y(OH)3 < XOH C. Y(OH)2 < Z(OH)3 < XOH D. Z(OH)3 < Y(OH)2 < XOH Cu 18: Cho m gam hp cht hu c X c cng thc phn t l C3H6O2 tc dng hon ton vi 200 ml dung dch KOH 0,7M thu c dung dch Y. C cn Y thu c 12,88 gam cht rn khan. Cng thc cu to ca X v gi tr ca m l: A. C2H5COOH v 8,88 gam. B. CH3COOCH3 v 6,66 gam. C. HCOOCH2CH3 v 8,88 gam. D. C2H5COOH v 6,66 gam. Cu 19: X l tetrapeptit Ala-Gly-Val-Ala, Y l tripeptit Val-Gly-Val. un nng m (gam) hn hp cha X v Y c t l s mol ca X v Y tng ng l 1:3 vi dung dch NaOH va . Phn ng hon ton thu c dung dch T. C cn cn thn dung dch T thu c 23,745 gam cht rn khan. Gi tr ca m l: A. 19,455. B. 68,1. C. 17,025. D. 78,4 Cu 20: Hn hp X gm hai cht hu c n chc tc dng vi 500ml dung dch KOH 1M, thu c hai mui ca hai axit hu c v mt ancol. Cho lng ancol trn tc dng vi Na d th c 3,36 lt H2 (ktc). X gm : A. Hai este. B. Mt este mt ancol. C. Mt este v mt axit. D. Mt axit mt ancol. Cu 21: t chy hon ton mt hn hp X (glucoz, fructoz, metanal v etanoic) cn 3,36 lt O2 (iu kin chun). Dn sn phm chy qua bnh ng dung dch Ca(OH)2 d, sau phn ng hon ton thu c m gam kt ta. Gi tr ca m l: A. 10,0 B. 12,0 C. 15,0 D. 20,5 Cu 22: Khi nhit phn hon ton 100 gam mi cht sau: KClO3 (xc tc MnO2), KMnO4, KNO3 v AgNO3. Cht to ra lng O2 t nht l: A. KMnO4 B. KNO3 C. AgNO3 D. KClO3
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Cu 23: C bao nhiu ng phn cu to, mch h c cng thc phn t C5H8 tc dng vi H2 d (xc tc thch hp) thu c sn phm isopentan ? A. 4. B. 2. C. 6. D. 3. Cu 24: Cho cc polime sau: t nilon-6,6; poli(vinyl clorua); thy tinh plexiglas; teflon; nha novolac; t visco, t nitron, cao su buna. Trong , s polime c iu ch bng phn ng trng hp l: A. 5 B. 4 C. 6 D. 7 Cu 25: Chn cu ng trong cc cu sau: A. Ancol a chc ha tan Cu(OH)2 to thnh dung dch mu xanh. B. Phng php chung iu ch ancol no, n chc bc 1 l cho an ken cng nc. C. un nng ancol metylic vi H2SO4 c 170oC thu c ete. D. Khi oxi ha ancol no, n chc th thu c anehit. Cu 26: Nung nng m gam hn hp gm Al v CuO trong iu kin khng c khng kh. Cho cht rn sau phn ng vo dung dch NaOH (d) thu c 672 ml kh H2 v cht rn X. Ho tan ht X trong dung dch HNO3 long (d) thy c 448 ml kh NO (cc phn ng xy ra hon ton v cc th tch kh o ktc). Gi tr m l: A. 2,94 B. 3,48 C. 34,80 D. 29,40 Cu 27: Mt hp cht X c khi lng phn t bng 103. Cho 51,50 gam X phn ng ht vi 500 ml dung dch NaOH 1,20M, thu c dung dch Y trong c mui ca aminaxit v ancol (c khi lng phn t ln hn khi lng phn t O2). C cn Y thu m gam cht rn. Gi tr m l: A. 52,50 B. 24,25 C. 26,25 D. 48,50 Cu 28: Cho Ba kim loi ln lt vo cc dung dch sau: NaHCO3, CuSO4, (NH4)2CO3, NaNO3, MgCl2. S dung dch to kt ta l: A. 5 B. 4 C. 2 D. 3 Cu 29: Cho cc cht: amoniac (1); anilin (2); p-nitroanilin (3); p-metylanilin (4); metylamin (5); imetylamin (6). Th t tng dn lc baz ca cc cht l: A. (3) < (2) < (4) < (1) < (5) < (6) B. (2) > (3) > (4) > (1) > (5) > (6) C. (3) < (1) < (4) < (2) < (5) < (6) D. (2) < (3) < (4) < (1) < (5) < (6) Cu 30: Hp th hon ton 4,48 lt CO2 (ktc) vo 200ml dung dch cha Na2CO3 0,5M v NaOH 0,75M thu c dung dch X. Cho dung dch BaCl2 d vo dung dch X thu c kt ta c khi lng l: A. 29,55 gam. B. 19,7 gam. C. 9,85 gam. D. 39,4 gam. Cu 31: Cho cc cht sau: toluen, etilen, xiclopropan, stiren, vinylaxetilen, etanal, imetyl xeton, propilen. S cht lm mt mu dung dch KMnO4 nhit thng l: A. 4. B. 5. C. 7. D. 6. Cu 32: Hn hp X gm HCOOH v CH3COOH trn theo t l mol 1 : 1. Cho 10,6 gam hn hp X tc dng vi 11,5 gam C2H5OH (c H2SO4 c lm xc tc) thu c m gam este (hiu sut phn ng este ha t 80%). Gi tr ca m l: A. 16,2. B. 14,08. C. 17,6. D. 12,96. Cu 33: iu no sau y khng ng? A. Cht do l nhng vt liu b bin dng di tc dng ca nhit v p sut m vn gi nguyn bin dng khi thi tc dng. B. T visco, t axetat l t tng hp. C. Nilon-6,6 v t capron l poliamit D. T tm, bng, len l polime thin nhin. Cu 34: Tm nhn xt ng: A. Khi thay i bt k 1 trong 3 yu t: p sut, nhit hay nng ca mt h cn bng ho hc th h s chuyn dch sang mt trng thi cn bng mi.
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B. Trong bnh kn tn ti cn bng 2NO2(nu) N2O4. Nu ngm bnh trn vo nc thy mu nu trong bnh nht dn. iu chng t chiu nghch ca phn ng l chiu thu nhit. C. Trong bnh kn, phn ng 2SO2 + O2 2SO3 trng thi cn bng. Thm SO2 vo , trng thi cn bng mi, ch c SO3 l c nng cao hn so vi trng thi cn bng c. D. Khi thm cht xc tc, hiu sut phn ng tng hp NH3: N2 + 3H2 NH3 s tng. Cu 35: Cho cc nhn xt sau: 1) Sc Ozon vo dung dch KI s thu c dung dch c kh nng lm h tinh bt ho xanh. 2) Hiro peoxit v hiro sunfua c th lm mt mu dung dch thuc tm trong mi trng H2SO4 long. 3) Sc hiro sunfua vo dung dch FeCl3 s thy xut hin vn c mu vng. 4) Dung dch H2S lu trong khng kh s c vn c mu vng. 5) Hiro peoxit l cht kh mnh v khng c tnh oxi ho Cc nhn xt ng l : A. 1, 3, 4. B. 1, 2, 4, 5. C. 1, 2, 3, 4. D. 2, 4, 5. 22+ Cu 36: Cho cc cht v ion sau: Cl , Na, NH3, HCl, O , Fe , SO2, Cl2. Cc cht v ion ch th hin c tnh kh trong cc phn ng oxi ha kh l: A. Cl-, Na, O2B. Cl-, Na, O2-, NH3, Fe2+ C. Na, O2-, NH3, HCl D. Na, O2-, HCl, NH3, Fe2+ Cu 37: t chy 3,2 gam mt este E n chc, mch h c 3,584 lt CO2 (ktc) v 2,304 gam H2O. Nu cho 15 gam E tc dng vi 200 ml dung dch NaOH 1M, c cn dung dch sau phn ng thu c 14,3 gam cht rn khan. Vy cng thc ca ancol to nn este trn c th l: A. CH2=CH-OH B. CH3OH C. CH3CH2OH D. CH2=CH-CH2OH Cu 38: S nguyn t m nguyn t ca n ( trng thi c bn) c tng s electron trn cc phn lp s bng 7 l: A. 9. B. 3. C. 5. D. 1. Cu 39: Cho cc cht sau: axetilen, axit fomic, fomanehit, phenyl fomat, glucz, anehit axetic, metyl axetat, mantz, natri fomat, axeton. S cht c th tham gia phn ng trng gng l: A. 6 B. 7 C. 8 D. 5 Cu 40: Cho cc cht: FeCO3, Fe(NO3)2, Fe2(SO4)3, FeSO4, FeS, FeS2, CuS. S lng cht c th c kh thot ra khi cho vo dung dch HCl v un nng nh l: A. 7. B. 4. C. 5. D. 6. II. PHN RING [10 cu] Th sinh ch c lm mt trong hai phn (Phn A hoc B) A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50) Cu 41: Chia 38,1 gam FeCl2 thnh 2 phn, phn 2 c khi lng gp 3 ln phn 1. em phn 1 phn ng ht vi dung dch KMnO4 d, trong mi trng H2SO4 long, d, thu ly kh thot ra. em ton b kh ny phn ng ht vi phn 2, c cn dung dch sau phn ng thu c m gam cht rn. Gi tr ca m l? A. 29,640. B. 28,575. C. 24,375. D. 33,900. Cu 42: Pht biu no sau y l ng ? A. Phn t cc amino axit ch c 1 nhm amino. B. Trong peptit mch h to ra t n phn t H2NRCOOH, s lin kt peptit l (n1) C. Dung dch cc amino axit u khng lm i mu qu tm. D. Phn t ipeptit mch h c 2 lin kt peptit. Cu 43: C cc dung dch ring r sau: AlCl3, NaCl, MgCl2, H2SO4. Ch dng thm mt dung dch no sau y nhn bit c 4 dung dch trn? A. NaOH. B. qu tm. C. AgNO3. D. BaCl2.
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Cu 44: Cho 35,48 gam hn hp X gm Cu v FeCO3 vo dung dch HNO3 long, un nng v khuy u. Sau khi cc phn ng xy ra hon ton thu c NO; 0,03 mol kh CO 2; dung dch Y v 21,44 gam kim loi. C cn dung dch Y thu c khi lng cht rn khan l: A. 38,82 g B. 36,24 g C. 36,42 g D. 38,28 g Cu 45: Khi phn tch thnh phn mt ancol n chc X th thu c kt qu: tng khi lng ca cacbon v hiro gp 3,625 ln khi lng oxi. S ng phn ancol ng vi cng thc phn t ca X l: A. 1 B. 2 C. 3 D. 4 Cu 46: Ha tan hon ton 80 gam hn hp X gm CuSO4, FeSO4 v Fe2(SO4)3 trong S chim 22,5% v khi lng trong nc c dung dch X. Thm NaOH d vo X, lc kt ta em nung trong khng kh n khi lng khng i thu c cht rn Y, thi CO d qua Y thu c hn hp rn Z. Bit cc phn ng xy ra hon ton. Khi lng ca Z l: A. 30 gam B. 40 gam C. 26 gam D. 36 gam Cu 47: Cho m gam hn hp X gm hai ancol no, n chc, k tip nhau trong dy ng ng tc dng vi CuO (d) nung nng, thu c mt hn hp rn Z v mt hn hp hi Y (c t khi hi so vi H2 l 13,75). Cho ton b Y phn ng vi mt lng d AgNO3 trong dung dch NH3 un nng, sinh ra 64,8 gam Ag. (Cc phn ng u xy ra hon ton). Gi tr ca m l: A. 7,4 B. 8,8 C. 9,2 D. 7,8 Cu 48: Cho dy cc cht: C2H2, HCHO, HCOOH, CH3CHO, (CH3)2CO, C12H22O11 (mantoz). S cht trong dy tham gia c phn ng trng gng l: A. 6 B. 4 C. 5 D. 3 Cu 49: hirat ha 2-metylbutan-2-ol thu c sn phm chnh l anken no sau y? A. 3-metyl but-1-en B. Pent-1-en C. 2-metyl but-1-en D. 2-metyl but-2-en Cu 50: Nung hn hp SO2, O2 c s mol bng nhau trong mt bnh kn c th tch khng i vi cht xc tc thch hp. Sau mt thi gian, a bnh v nht ban u thy p sut trong bnh gim 10% so vi p sut ban u. Hiu sut ca phn ng xy ra bng: A. 40% B. 50% C. 20% D. 75% B. Theo chng trnh Nng cao (t cu 51 n cu 60) Cu 51: Khi nung butan vi xc tc thch hp thu c hn hp T gm CH4, C3H6, C2H4, C2H6, C4H8, H2 v C4H10 d. t chy hon ton hn hp T thu c 8,96 lt CO2 (o ktc) v 9,0 gam H2O. Mt khc, hn hp T lm mt mu va ht 12 gam Br 2 trong dung dch nc brom. Hiu sut phn ng nung butan l: A. 75%. B. 65%. C. 50%. D. 45%. Cu 52: A l hp cht hu c mch vng cha C, H, N trong N chim 15,054% theo khi lng. A tc dng vi HCl to ra mui c dng RNH3Cl. Cho 9,3g A tc dng ht vi nc brom d thu c a g kt ta. Gi tr ca a l: A. 30 gam B. 33 gam C. 44 gam D. 36 gam Cu 53: Cho 0,2 mol mt anehit n chc, mch h X phn ng va vi 300 ml dung dch cha AgNO3 2M trong NH3. Sau khi phn ng xy ra hon ton thu c 87,2 g kt ta. Cng thc phn t ca anehit l: A. C4H5CHO B. C3H5CHO C. C4H3CHO D. C3H3CHO. Cu 54: Trn 10,8g bt Al vi 34,8g bt Fe3O4 ri tin hanh phan ng nhit nhm trong iu kin khng co khng khi. Hoa tan hoan toan hn hp rn sau phan ng bng dung dich H 2SO4 loang (d) thu c 10,752 lit khi H2 (ktc). Hiu sut cua phan ng nhit nhm la: A. 70% B. 90% C. 80% D. 60% Cu 55: Th nh 6,85 gam Ba (c ct nh) vo 20 gam dung dch H2SO4 9,80%. Sau khi kt thc phn ng thu c dung dch X. Nng cht tan c trong dung dch X l: A. 23,22% B. 23,12% C. 22,16% D. 31,96%
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Cu 56: Cho dung dch NH3 d vo dung dch X cha hn hp MgCl2, ZnCl2, FeCl3, FeCl2 thu c kt ta Y. Nung kt ta Y trong khng kh ta c cht rn Z. Cho lung kh CO d i qua A nung nng (cc phn ng xy ra hon ton) thu c cht rn T. Trong T c cha: A. Fe2O3, MgO, ZnO B. Fe, Mg, Zn C. Fe, MgO D. Fe, MgO, ZnO Cu 57: Cho cc cht sau: phenol, kh sunfur, toluen, ancol benzylic, isopren, axit metacrylic, vinyl axetat, phenyl amin, axit benzoic. S cht phn ng c vi dung dch nc brom nhit thng l: A. 6. B. 5. C. 4. D. 3. Cu 58: Trong phng th nghim, kh hiro halogenua c iu ch t phn ng: 0 NaXrn + H2SO4 c t HX + NaHSO4 Phng php trn c dng iu ch hiro halogenua no? A. HBr B. HCl C. HCl v HBr D. HI Cu 59: Cho cc cht: ancol etylic, glixerol, glucoz, imetyl ete v axit fomic. S cht tc dng c vi Cu(OH)2 l: A. 4 B. 1 C. 3 D. 2 Cu 60: X v Y ln lt l cc tripeptit v hexapeptit c to thnh t cng mt amoni axit no mch h, c mt nhm COOH v mt nhm NH2. t chy hon ton 0,1 mol X bng O2 va thu c sn phm gm CO2, H2O v N2 c tng khi lng l 40,5 gam. Nu cho 0,15 mol Y tc dng hon ton vi NaOH (ly d 20% so vi lng cn thit), sau phn ng c cn dung dch th thu c bao nhiu gam cht rn? A. 87,3 gam B. 9,99 gam C. 107,1 gam D. 94,5 gam
Cho bit: Nguyn t khi: H=1; O=16; S=32; C=12; N=14; Cl=35,5; F=19; Br=80;I=127; Al=27; Fe=56; Cu=64; Ca=40; Ba=137; Mg=24; Sr=88; Mn=55; K=39; Na=23; Ag=108; Li=7; Cs=133.

Th sinh c mang my tnh vo phng thi, khng c s dng bng tnh tan v bng h thng tun hon. Ch : Cn b coi thi khng gii thch g thm. ----------- HT ----------

P N THI TH I HC LN 1 NM HC 2011 2012 Cu

1 2 3 4

M 165
A C B A

M 241
D B A C

M 302
C D A B

M 417
C B C A Trang 6/8 - M thi 165

5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

A C B C D D B A C D A B D D C C C C D A C B A B A C B D B B C A D B B B D B A C D C D B D A A B C C A C A B D D

B B C D B A C B A D D C A B B A B C B A C A C C C D A D A A D C C B B C D D A A C B A C A D C B A D D D B A C B

A C D D A A D B A C A D A B B A B C C B B B C C D C C D B C C C D B D A C D A C A D B D C B A D A A A B B C D B

A A D D A B C B D B C D D C B D A D C A B D C B D C A B D A D D B C B A C D D D A B B C B D C A C A A A D C A C

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