& S GIO DC O TO

THI BNH

THI CHN HC SINH GII LP 12 NM HC 2011-2012

Mn: HO HC Thi gian: 90 pht (Khng k thi gian giao ) gm 04 trang; Th sinh lm bi vo Phiu tr li trc nghim M : 132

Cho bit khi lng mol (vC) ca cc nguyn t: H=1; C=12; N=14; O=16; F=19; Na=23; Mg=24; Al=27; P=31; S=32; Cl=35,5; K=39; Ca=40; Cr=52; Mn=55; Fe=56; Ni=59; Cu=64; Zn=65; Br=80; Ag=108; I=127; Ba=137; Au=197; Pb=207.

Trng nhm bin son: ThS Phan Vn Dn GV trng THPT Chun Quc gia Bc ng Quan - Thi Bnh 0912.135.401 Cu 1: Gii thch no sau y l khng ng? A. Xenluloz trinitrat hnh thnh nh phn ng: H SO c, [C6H7O2(OH)3]n + 3nHNO3 t [C6H7O2(ONO2)3]n + 3nH2O B. Rt dung dch HCl vo vi si bng, vi mn dn do phn ng: dung dch HCl (C6H10O5)n + nH2O nC6H12O6 C. Rt H2SO4 c vo vi si bng, vi b en v thng ngay do phn ng: H SO c, t (C6H10O5)n 6nC + 5nH2O D. Xenluloz triaxetat hnh thnh nh phn ng: [C6H7O2(OH)3]n + 3nCH3COOH [C6H7O2(OOCCH3)3]n + 3nH2O Cu 2: Cho Cacbon (C) ln lt tc dng vi Al, H2O, CuO, HNO3 c, H2SO4 c, KClO3, CO2 iu kin thch hp. S phn ng m trong C ng vai tr l cht kh? A. 4 B. 7 C. 5 D. 6 Cu 3: Thc hin phn ng crackinh butan thu c mt hn hp X gm cc ankan v cc anken. Cho ton b hn hp X vo dung dch Br2 d thy c kh thot ra bng 60% th tch X v khi lng dung dch Br 2 tng 5,6 gam v c 25,6 gam brom tham gia phn ng. t chy hon ton kh bay ra thu c a mol CO2 v b mol H2O. Vy a v b c gi tr l: A. a = 0,9 mol v b = 1,5 molB. a = 0,56 mol v b = 0,8 mol C. a = 1,2 mol v b = 1,6 molD. a = 1,2 mol v b = 2,0 mol Cu 4: Ho tan hon ton hn hp X cha Fe3O4 v FeS2 trong 63 gam dung dch HNO3 thu c 1,568 lt NO2 duy nht (ktc). Dung dch thu c tc dng va vi 200 ml dung dch NaOH 2M, lc kt ta ri em nung n khi lng khng i th thu c 9,76 gam cht rn. Nng % ca dung dch HNO3 ban u l: A. 47,2% B. 42,6% C. 46,2% D. 46,6% Cu 5: X phng ha hon ton 100 gam cht bo X cn dng va 100 ml dung dch NaOH 0,8M, sau phn ng thu c 100,81 gam x phng. Xc nh ch s axit ca cht bo . A. 1,4 B. 5,6 C. 11,2 D. 2,8 Cu 6: Cho cc dung dch AlCl3, NaCl, NaAlO2, HCl. Dng mt ho cht trong s cc ho cht sau: Na2CO3, NaCl, NaOH, qu tm, dung dch NH3, NaNO3 th s ho cht c th phn bit c 4 dung dch trn l: A. 3 B. 4 C. 5 D. 6 Cu 7: Cho m gam Mg vo dung dch cha 0,12 mol FeCl3. Sau khi phn ng xy ra hon ton thu c 3,36 gam cht rn. Gi tr ca m l: A. 2,88 gam B. 2,16 gam C. 4,32 gam D. 5,04 gam -5 Cu 8: Cho dung dch CH3COOH 0,1M, KA = 1,8.10 . in li ca axit axetic gim mt na so vi ban u th khi lng CH3COOH cn phi cho vo 1 lt dung dch trn l: A. 6 gam B. 12 gam C. 9 gam D. 18 gam Cu 9: ipeptit mch h X v tripeptit mch h Y u c to nn t mt -aminoaxit (no, mch h, trong phn t cha mt nhm -NH2 v mt nhm -COOH). t chy hon ton 0,1 mol Y thu c tng khi lng CO2 v H2O bng 54,9 gam. t chy hon ton 0,2 mol X, sn phm thu c cho li t t qua nc vi trong d, to ra m gam kt ta. Gi tr ca m l: A. 120 gam B. 60 gam C. 30 gam D. 45 gam Cu 10: Hp cht hu c X mch h c khi lng mol l 56 vC. Khi t chy X bng oxi thu c sn phm ch gm CO2 v H2O. X lm mt mu dung dch brm. S cng thc cu to c th c ca X l:
2 4 o
2 4 o

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A. 4 B. 7 C. 6 D. 5 Cu 11: Cho dy gm cc cht: Na, Mg, Ag, O3, Cl2, HCl, Cu(OH)2, Mg(HCO3)2, CuO, NaCl, C2H5OH, C6H5OH, C6H5NH2, CH3ONa, CH3COONa. S cht tc dng c vi dung dch axt propionic (trong iu kin thch hp) l: A. 10 B. 11 C. 9 D. 8 Cu 12: Nha phenolfomanehit c iu ch bng cch un nng phenol d vi dung dch: A. CH3COOH trong mi trng axit B. CH3CHO trong mi trng axit C. HCOOH trong mi trng axit D. HCHO trong mi trng axit Cu 13: Ha tan 3,56 gam oleum X vo nc thu c dung dch Y. trung ha dung dch Y cn dng 80 ml dung dch NaOH 1,0M. Vy cng thc ca X l: A. H2SO4.2SO3 B. H2SO4.4SO3 C. H2SO4.SO3 D. H2SO4.3SO3 Cu 14: Cho m gam bt Fe vo 200 ml dung dch hn hp A cha H2SO4 1M, Fe(NO3)3 0,5M v CuSO4 0,25M. Khuy u cho n khi phn ng kt thc thu c 0,75m gam cht rn. Gi tr ca m l: A. 43,2 gam B. 56 gam C. 33,6 gam D. 32 gam Cu 15: Cho kim loi M vo dung dch mui ca kim loi X thy c kt ta v kh bay ln. Cho kim loi X vo dung dch mui ca kim loi Y thy c kt ta Y. Mt khc, cho kim loi X vo dung dch mui ca kim loi Z, khng thy c hin tng g. Cho bit s sp xp no sau y ng vi chiu tng dn tnh kim loi ca X, Y, Z, M? A. Z < X < Y < M B. Y < X < Z < M C. Z < X < M < Y D. Y < X < M < Z Cu 16: Hn hp kh X gm H2 v C2H4 c t khi so vi He l 3,75. Nung X vi Ni sau mt thi gian thu c hn hp kh Y c t khi so vi He l 5. Hiu sut phn ng hiro ha l: A. 50% B. 20% C. 40% D. 25% Cu 17: un nng cht H2N-CH2-CONH-CH(CH3)-CONH-CH2-COOH trong dung dch HCl d, sau khi cc phn ng kt thc thu c sn phm l: A. H3N+-CH2-COOHCl-, H3N+-CH2-CH2-COOHClB. H3N+-CH2-COOHCl-, H3N+-CH(CH3)-COOHClC. H2N-CH2-COOH, H2N-CH2-CH2-COOH D. H2N-CH2-COOH, H2N-CH(CH3)-COOH Cu 18: Dn hn hp M gm hai cht X v Y c cng thc phn t C 3H6 v C4H8 vo dung dch brom trong dung mi CCl4 thy dung dch brom b nht mu v khng c kh thot ra. Ta c cc kt lun sau: a). X v Y l 2 xicloankan vng 3 cnh b). X v Y l mt anken v mt xicloankan vng 4 cnh c). X v Y l 2 anken ng ng ca nhau d). X v Y l mt anken v mt xicloankan vng 3 cnh e). X v Y l mt xicloankan vng 3 cnh v mt xicloankan vng 4 cnh Cc kt lun ng l: A. a, c, d B. a, b, c, d C. a, b, d D. a, b, c, d, e Cu 19: em ha tan hon ton m gam Mg trong dung dch cha ng thi a mol H2SO4 v b mol HCl, sau phn ng hon ton thu c dung dch cha 2 mui c tng khi lng l 4,1667m. Thit lp biu thc lin h gia s mol ca 2 axit: A. b = 6a B. b = 4a C. b = 8a D. b = 7a HCl khan Cu 20: Cho cc phn ng sau: glucoz + CH3OH X + H2O 2X + Cu(OH)2 OH Y + 2H2O Vy cng thc ca Y l: A. (C7H14O7)2Cu B. (C7H13O7)2Cu C. (C6H12O6)2Cu D. (C6H11O6)2Cu Cu 21: t chy hon ton 1,6 gam mt este E n chc c 3,52 gam CO2 v 1,152 gam H2O. Nu cho 10 gam E tc dng vi 150 ml dung dch NaOH 1M, c cn dung dch sau phn ng thu c 16 gam cht rn khan. Vy cng thc ca axit to nn este trn c th l: A. HOOC-CH2-CH(OH)-CH3B. CH3-C(CH3)2-COOH C. HOOC(CH2)3CH2OH D. CH2=CH-COOH Cu 22: S sp xp no sau y ng vi chiu tng dn tnh axit? A. axit phenic < axit p-nitrobenzoic < axit p-metylbenzoic < axit benzoic B. axit p-nitrobenzoic < axit benzoic < axit phenic < axit p-metylbenzoic C. axit p-metylbenzoic < axit p-nitrobenzoic < axit benzoic < axit phenic D. axit phenic < axit p-metylbenzoic < axit benzoic < axit p-nitrobenzoic Cu 23: Ha tan hon ton m gam hn hp gm Na, Na2O, NaOH v Na2CO3 trong dung dch axt H2SO4 40% (va ) thu c 8,96 lt hn hp kh c t khi i vi H 2 bng 16,75 v dung dch Y c nng 51,449%. C cn Y thu c 170,4 gam mui. Gi tr ca m l:
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A. 37,2 gam B. 50,4 gam C. 23,8 gam D. 50,6 gam Cu 24: Ha tan hon ton 30 gam hn hp X gm Mg, Al v Zn trong dung dch HNO3, sau phn ng hon ton thu c dung dch Y v hn hp gm 0,1 mol N2O v 0,1 mol NO. C cn dung dch sau phn ng thu c 127 gam hn hp mui. Vy s mol HNO3 b kh trong phn ng trn l: A. 0,40 mol B. 0,30 mol C. 0,45 mol D. 0,35 mol Cu 25: Hn hp X gm: HCHO, CH3COOH, HCOOCH3 v CH3CH(OH)COOH. t chy hon ton hn hp X cn V lt O2 (ktc) sau phn ng thu c CO2 v H2O. Hp th ht sn phm chy vo nc vi trong d thu c 30 gam kt ta. Vy gi tr ca V tng ng l: A. 5,60 lt B. 8,40 lt C. 7,84 lt D. 6,72 lt Cu 26: Trong cc chui phn ng ha hc sau, chui no c phn ng ha hc khng th thc hin c? A. P P2O5 H3PO4 CaHPO4 Ca3(PO4)2 CaCl2 Ca(OH)2 CaOCl2 B. Cl2 KCl KOH KClO3 O2 O3 KOH CaCO3 CaO CaCl2 Ca C. NH3 N2 NO NO2 NaNO3 NaNO2 N2 Na3N NH3 NH4Cl HCl D. S H2S SO2 HBr HCl Cl2 H2SO4 H2S PbS H2S NaHS Na2S
+ KMnO4 , t Dung dch HCl d Cu 27: Cho s sau: p-xilen X1 axit terephtalic. Hy cho bit tng i s cc h s cht (2) (1)
0

trong phng trnh phn ng (1)? A. 8 B. 16 C. 14 D. 18 Cu 28: Cho cc nhn xt sau: (1). C th to c ti a 2 ipeptit t phn ng trng ngng hn hp Alanin v Glyxin (2). Khc vi axt axetic, axt amino axetic c th tham gia phn ng vi axit HCl hoc phn ng trng ngng (3). Ging vi axt axetic, aminoaxt c th tc dng vi baz to mui v nc (4). Axt axetic v axt -amino glutaric c th lm i mu qu tm thnh (5). Thy phn khng hon ton peptit: Gly-Phe-Tyr-Gly-Lys-Gly-Phe-Tyr c th thu c 6 tripeptit c cha Gly (6). Cho HNO3 c vo ng nghim cha anbumin thy to dung dch mu tm C bao nhiu nhn xt ng? A. 3 B. 5 C. 6 D. 4 Cu 29: X l este to t axit n chc v ancol a chc. X khng tc dng vi Na. Thy phn hon ton a gam X cn dng va 100 gam dung dch NaOH 6% thu c 10,2 gam mui v 4,6 gam ancol. Vy cng thc ca X l: A. (CH3COO)2C3H6 B. (HCOO)2C2H4 C. (HCOO)3C3H5 D. (C2H3COO)3C3H5 Cu 30: Trong mt bnh kn dung tch 10 lt nung mt hn hp gm 1 mol N 2 v 4 mol H2 nhit t0C v p sut P. Khi phn ng t n trong thi cn bng thu c mt hn hp trong NH3 chim 25% th tch. Xc nh hng s cn bng KC ca phn ng: N2 + 3H2 2NH3. A. 25,6 B. 1,6 C. 6,4 D. 12,8 Cu 31: Cho 2,8 gam bt st tc dng hon ton vi V ml dung dch HNO3 0,5M thu c sn phm kh NO duy nht v dung dch X. X c th tc dng va vi dung dch cha 0,03 mol AgNO3. Gi tr ca V l: A. 280 ml B. 320 ml C. 340 ml D. 420 ml Cu 32: t chy hon ton m gam hn hp X gm 2 ancol a chc, mch h, c cng s nhm -OH thu c 11,2 lt kh CO2 (ktc) v 12,6 gam H2O. Mt khc nu cho m gam hn hp X tc dng vi 10 gam Na th sau phn ng thu c a gam cht rn. Gi tr ca a v m ln lt l: A. 13,8 gam v 23,4 gam B. 9,2 gam v 13,8 gam C. 23,4 gam v 13,8 gam D. 9,2 gam v 22,6 gam Cu 33: Cho 672 ml kh clo (ktc) i qua 200 ml dung dch KOH a mol/l 1000C. Sau khi phn ng xy ra hon ton thu c dung dch X c pH = 13. Lng cht rn thu c khi c cn dung dch X l: A. 1,97 gam B. 3,09 gam C. 6,07 gam D. 4,95 gam Cu 34: Thu phn dung dch cha 34,2 gam mantoz mt thi gian. Ly ton b sn phm thu c sau phn ng thu phn cho tc dng vi lng d dung dch AgNO3 trong NH3, sau phn ng hon ton thu c 31,32 gam Ag. Hiu sut ca phn ng thu phn mantoz l: A. 50% B. 45% C. 72,5% D. 55% Cu 35: Thm t t tng git ca 100 ml dung dch cha Na2CO3 1,2M v NaHCO3 0,6M vo 200 ml dung dch HCl 1M, sau phn ng hon ton thu c dung dch X. Cho dung dch nc vi trong d vo dung dch X th thu c bao nhiu gam kt ta. A. 10 gam B. 8 gam C. 12 gam D. 6 gam Cu 36: Cho cc monome sau: stiren, toluen, metylaxetat, vinylaxetat, metylmetacrylat, metylacrylat, propilen, benzen, axt etanoic, axt -aminocaproic, caprolactam, etilenoxit. S monome tham gia phn ng trng hp l:
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A. 5 B. 6 C. 7 D. 8 Cu 37: Hp cht X c CTPT l C5H13N. Khi cho X tc dng vi HNO2 thu c cht Y c CTPT l C5H12O. Oxi ha Y thu c cht hu c Y1 c CTPT l C5H10O. Y1 khng c phn ng trng bc. Mt khc, hirat ha Y thu c 2 anken l ng phn hnh hc ca nhau. Vy tn gi ca X l: A. pentan-3-amin B. pentan-2-amin C. 3-metylbutan-2-amin D. isopentyl amin Cu 38: X v Y l hai hp cht hu c ng phn ca nhau cng c cng thc phn t C 5H6O4Cl2. Thy phn hon ton X trong NaOH d thu c hn hp cc sn phm trong c 2 mui v 1 ancol. Thy phn hon ton Y trong KOH d thu c hn hp cc sn phm trong c 1 mui v 1 anehit. X v Y ln lt c cng thc cu to l: A. HCOOCH2COOCH2CHCl2 v CH3COOCH2COOCHCl2 B. CH3COOCCl2COOCH3 v CH2ClCOOCH2COOCH2Cl C. HCOOCH2COOCCl2CH3 v CH3COOCH2COOCHCl2 D. CH3COOCH2COOCHCl2 v CH2ClCOOCHClCOOCH3 Cu 39: Cho cc nguyn t sau 13Al; 5B; 9F; 21Sc. Hy cho bit c im chung trong cu to ca nguyn t cc nguyn t . A. u l cc nguyn t thuc cc chu k nh B. Electron cui cng thuc phn lp p C. u c 1 electron c thn trng thi c bn D. u c 3 lp electron Cu 40: Khi t chy mt polime sinh ra t phn ng ng trng hp isopren vi acrilonitrin bng lng oxi va thu c hn hp kh cha 58,33% CO2 v th tch. T l mt xch isopren vi acrilonitrin trong polime trn l: A. 1:3 B. 1:2 C. 2:1 D. 3:2 Cu 41: Cho m gam kim loi M tan hon ton trong 200 ml dung dch HCl 0,5M thu c dung dch X v 2,016 lt H2 (ktc). Cho dung dch AgNO3 d vo dung dch X th thu c bao nhiu gam kt ta? A. 23,63 gam B. 32,84 gam C. 28,70 gam D. 14,35 gam Cu 42: ng vi cng thc phn t C7H8O c bao nhiu ng phn l dn xut ca benzen v s ng phn u tc dng c vi cc cht: K, KOH, (CH3CO)2O: A. 5 v 2 B. 5 v 3 C. 4 v 2 D. 4 v 3 Cu 43: X c cng thc phn t l C4H8Cl2. Thy phn X trong dung dch NaOH un nng thu c cht hu c Y n chc. Hy cho bit X c bao nhiu cng thc cu to? A. 5 B. 3 C. 2 D. 4 Cu 44: Cho axeton tc dng vi HCN thu c cht hu c X. Thy phn X trong mi trng axit thu c cht hu c Y. hirat ha X thu c axit cacboxylic Y. Vy Y l cht no sau y? A. CH2=C(CH3)COOH B. CH2=CH-COOH C. CH2=CHCH2COOH D. CH3CH=CHCOOH Cu 45: Ho tan Fe3O4 trong lng d dung dch H2SO4 long thu c dung dch X. Dung dch X tc dng c vi bao nhiu cht trong s cc cht sau: Cu, NaOH, Br2, AgNO3, KMnO4, MgSO4, Mg(NO3)2, Al? A. 5 B. 6 C. 7 D. 8 Cu 46: t chy hon ton 0,1 mol cht hu c X c cng thc tng qut CxHyO2 thu c khng n 17,92 lt CO2 (ktc). trung ho 0,2 mol X cn 0,2 mol NaOH. Mt khc cho 0,5 mol X tc dng vi Na d thu c 0,5 mol H 2. S nguyn t H c trong phn t X l: A. 6 B. 8 C. 10 D. 12 Cu 47: T l khi lng phn t gia oxit cao nht ca nguyn t R v hp cht kh ca n vi hiro bng
5,5 . Khi 2

lng mol nguyn t ca R l: A. 32 B. 12 C. 28 D. 19 Cu 48: Cho 100 gam glixerol tc dng vi 3 mol HNO3 c (xt: H2SO4 c). Tnh khi lng sn phm cha nhm nitro thu c. Bit rng c 80% glixerol v 70% HNO3 phn ng. A. 174,5 gam B. 197,9 gam C. 213,2 gam D. 175,4 gam Cu 49: Cho s sau: etanol X. Hy cho bit trong cc cht sau: etilen, etylclorua, etanal, axit etanoic, etylaxetat, buta-1,3-ien, glucoz. Bao nhiu cht c th l cht X? A. 6 B. 5 C. 4 D. 3 Cu 50: Nung hn hp gm 3,2 gam Cu v 17 gam AgNO3 trong bnh kn, chn khng. Sau phn ng hon ton thu c hn hp kh X. Cho X phn ng ht vi nc thu c 2 lt dung dch Y. pH ca dung dch Y l: A. 0,523 B. 0,664 C. 1 D. 1,3
Th sinh khng c dng bt c ti liu no (k c Bng h thng tun hon)
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----- HT ----H v tn th sinh:................................................................... S bo danh:....................

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