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Giải chi tiết đề 392
Giải chi tiết đề 392
o
t
CaO + CO
2
(k)
, AH > 0
cn bng trn chuyn dch theo chiu thun cn tng nhit phn ng v gim nng
kh CO
2
. p n ng l B
Cu 11. Cp tn ca cng mt hp cht l
Ancol isobutylic v 2 metylpropan 1 ol
CH
3
-CH-CH
2
OH
CH
3
p n ng l C
Cu 12. Gi s crackinh 1 mol C
4
H
10
(58 gam C
4
H
10
). Suy ra, s mol hn hp sau phn ng:
n
hh (sau p/)
= 58/36,25 = 1,6 (mol)
(v tng khi lng cc cht sau phn ng bng khi lng C
4
H
10
v bng 58 gam)
Trong phn ng crackinh, ta thy c 1 mol C
4
H
10
phn ng th sinh ra 2 mol ca hai
hirocacbon, do s mol C
4
H
10
tham gia phn ng ng bng s mol hirocacbon tng sau phn
ng. Vy:
4 10
C H (p/)
n = 1,6 - 1 = 0,6 mol
Hiu sut phn ng: H =
0,6
.100% = 60%
1
p n ng l D
Cu 13. PTHH: C
x
H
y
2
+O
xCO
2
+
2
y
H O
2
V nguyn t C, H c bo ton, nn:
X Y X Y X Y 2 2
C (C H ) H (C H ) C H C (CO ) H (H O)
m + m = m = m + m
m =
11 9
.12 + .2.1 = 4,0 (gam)
44 18
p n ng l A
3
Cu 14. p n ng l B
Cu 15. Cc loi lin kt hiro c th c hnh thnh
C
2
H
5
OHOHC
6
H
5
; C
2
H
5
OH.OHC
2
H
5
C
6
H
5
OHOHC
2
H
5
; C
6
H
5
OH.OHC
6
H
5
C th c 4 loi lin kt hiro
p n ng l D
Cu 16. Xt cc phng n:
A. ng: CH
3
CH
2
COOCH=CH
2
+ Br
2
CH
3
CH
2
COOCHBr-CH
2
Br
B. ng CH
3
CH
2
COOCH=CH
2
+ NaOH CH
3
COONa + CH
3
CHO
C. ng nCH=CH
2
T.H
(-CH-CH
2
-)
n
CH
3
CH
2
COO CH
3
CH
2
COO
D. Sai CH
3
CH
2
COOCH=CH
2
khng cng dy ng ng vi
CH
2
=CHCOOCH
3
p n ng l D
Cu 17. p n ng l C
Cu 18. Cc cht A, B, C l:
A. H
2
N-C
3
H
6
-COOH: nguyn t N c lai ha sp
3
B. C
4
H
9
-NO
2
; nguyn t N c lai ha sp
2
C. C
3
H
5
COONH
4
nguyn t N c lai ha sp
3
*Cc PTHH xy ra:
H
2
N-C
3
H
6
-COOH + HCl ClH
3
N-C
3
H
6
-COOH
2H
2
N-C
3
H
6
-COOH + Na
2
O 2H
2
N-C
3
H
6
-COONa + H
2
O
C
4
H
9
-NO
2
+ 6[H] C
4
H
9
NH
2
+ 2H
2
O
B B
C
4
H
9
NH
2
+ HCl C
4
H
9
NH
3
Cl
B B
C
4
H
9
NH
3
Cl + NaOH C
4
H
9
NH
2
+ NaCl + H
2
O
B B
C
3
H
5
COONH
4
+ NaOH C
3
H
5
COONa + NH
3
+ H
2
O
p n ng l A
*Ch : xc nh (d on) trng thi lai ha ca nguyn t cn da vo tng s lin kt o (zich
ma) v cp electron cha chia (cp electron ha tr cha tham gia lin kt):
o
(n + n cp e cha chia) = A
Nu A = 4 lai ha sp
3
; A = 3 lai ha sp
2
; A = 2 lai ha sp.
Cu 19. c im cu to ca monome tham gia phn ng trng hp l c lin kt bi (thng l
lin kt i). p n ng l A
Cu 20. Kh H
2
, nhit cao kh c cc oxit ca cc kim loi yu (CuO), kim loi trung bnh
(sau Al, nh Fe
2
O
3
, ZnO):
H
2
+ CuO
o
t
Cu + H
2
O|
3H
2
(d)
+ Fe
2
O
3
o
t
2Fe + 3H
2
O|
H
2
+ ZnO
o
t
Zn + H
2
O|
MgO + H
2
o
t
khng phn ng (vn cn MgO)
Sau phn ng, trong cht rn c Cu, Fe, Zn, MgO
p n ng l B
Cu 21. Theo bi ra:
2 3
Cr O
15,2
n = = 0,1 (mol)
152
4
Trong phn ng nhit nhm: m
Al
+
2 3
Cr O
m = m
hn hp rn sau phn ng
m
Al
= 23,3 15,2 = 8,1 (gam) n
Al
= 0,3 (mol)
PTP: 2Al + Cr
2
O
3
o
t
2Cr + Al
2
O
3
Ban u: 0,3 0,1 (mol)
Phn ng: 0,2 0,1 0,2 (mol)
Cn li: 0,1 (mol) 0,2 (mol)
Al + 3HCl AlCl
3
+ 1,5H
2
|
0,1 (mol) 0,15 (mol)
Cr + 2HCl CrCl
2
+ H
2
|
0,2 (mol) 0,2 (mol)
2
H
n = 0,15 + 0,2 = 0,35 (mol)
2
H
V = 0,35.22,4 = 7,84 (lt)
p n ng l C
Cu 22. Theo bi ra:
2 4
H SO
n = 0,5.0,1 = 0,05 (mol)
S phn ng xy ra: Oxit + H
2
SO
4
mui sunfat + H
2
O
- p sng nh lut bo ton nguyn t (cho nguyn t H), ta c:
2 2 4
H O H SO
n = n = 0,05 (mol)
- Theo nh lut bo ton khi lng, ta c:
m
oxit
+
2 4
H SO
m = m
mui
+
2
H O
m
m
mui
= m
oxit
+
2 4
H SO
m -
2
H O
m = 2,81 + 0,05.98 0,05.18 = 6,81 (gam)
p n ng l D
Cu 23. Cch tt nht l dng dung dch NaHCO
3
d:
HCl + NaHCO
3
CO
2
| + NaCl + H
2
O
p n ng l C
*Ch :
- Khng dng nc ct, tuy HCl tan tt trong nc, cn CO
2
tan rt t trong nc nhng CO
2
s li cun HCl i theo
- Khng dng dung dch AgNO
3
, v:
HCl + AgNO
3
AgCl + + HNO
3
CO
2
s li cun HNO
3
i theo
Cu 24. trng gng, trng rut phch, ngi ta s dng phn ng:
CH
2
(OH)[CH(OH)]
4
CHO + Ag
2
O
3
NH
2Ag+ + CH
2
(OH)[CH(OH)
4
]COOH
Glucoz
Bc sinh ra mt cch t t, u n v bm chc vo gng, rut phch
p n ng l A
*Ch : Ngi ta khng s dng anehit trng gng, trng rut phch, v phn ng xy ra
nhanh, bc sinh ra khng u v tnh cht c hi ca anehit
Cu 25. Z = 17: 1s
2
2s
2
2p
6
3s
2
3p
5
([Ne] 3s
2
3p
5
) c 7 electron ha tr nguyn t phi kim. p
n ng l B
Cu 26. p n ng l A
Cu 27. phn cc ca lin kt ph thuc vo hiu m in gia 2 nguyn t tham gia lin
kt
- Da vo s bin thin hiu m in ca cc nguyn t trong cng chu k, cng nhm
hiu m in tng i trt t phn cc tng i ca lin kt
p n ng l C
Cu 28. Phn ng trao i lun khng phi l phn ng ha kh (v s oxi ha ca cc nguyn t
khng thay i)
5
p n ng l D
Cu 29. Cc cht u phn ng c vi dung dch HCl, dung dch NaOH l:
- 2Al + 6HCl AlCl
3
+ 3H
2
- 2Al + 2NaOH + 6H
2
O 2NaAl(OH)
4
+ 3H
2
- Al
2
O
3
+ 6HCl 2AlCl
3
+ 3H
2
O
- Al
2
O
3
+ 2NaOH + 3H
2
O 2NaAl(OH)
4
- Zn(OH)
2
+ 2HCl ZnCl
2
+ 2H
2
O
- Zn(OH)
2
+ 2NaOH Na
2
[Zn(OH)
4
]
- NaHS + HCl NaCl + H
2
S
- NaHS + NaOH Na
2
S + H
2
O
- (NH
4
)
2
CO
3
+ 2HCl 2NH
4
Cl + CO
2
| + H
2
O
- (NH
4
)
2
CO
3
+ 2NaOH 2NH
3
+ Na
2
CO
3
+ H
2
O
c 5 cht
p n ng l A
Cu 30. Xy ra phn ng: 3O
2
(k)
phng in
2O
3
(k)
Ta thy 3 th tch kh O
2
phn ng to ra 2 th tch kh O
3
gim 1 th tch kh
Nh vy c gim 1 th tch kh th to ra 2 th tch kh O
3
. Do khi gim 9 lt kh th to ra x
lt kh O
3
x = =
9.2
18
1
(lt)
p n ng l C
Cu 31. Gi s th tch ca h bng 1 lt
CH
3
COOH + C
2
H
5
OH
CH
3
COOC
2
H
5
+ H
2
O
Ban u: 1 mol 1 mol
Phn ng: 2/3 mol 2/3 mol 2/3 mol 2/3 mol
Cn bng: 1/3 mol 1/3 mol 2/3 mol 2/3 mol
Hng s cn bng ca phn ng:
K
C
=
| | | |
| | | |
3 2 5 2
3 2 5
CH COOC H . H O
2/3.2/3
= = 4
CH COOH . C H 1/3.1/3
CH
3
COOH + C
2
H
5
OH
CH
3
COOC
2
H
5
+ H
2
O
Ban u: 1 mol x mol
Phn ng: 0,9 mol 0,9 mol 0,9 mol 0,9 mol
Cn bng: 0,1 mol (x 0,9)mol 0,9 mol 0,9 mol
V T = const nn K
C
= 4, do :
K
C
=
0,9.0,9
= 4
0,1.(x - 0,9)
0,81 = 0,4.x 0,36 x = 2,925 mol
V V = 1 lt
2 5
C H OH
n = 2,925 (mol) . p n ng l D
*Ch :
+) Phn ng este ha: RCOOH + ROH
RCOOR + H
2
O
Ni dung: K
C
=
| | | |
| | | |
2
RCOOR' . H O
RCOOH . R'OH
Khi dung dch long th [H
2
O] coi l hng s, do :
K
C
=
| |
| | | |
RCOOR'
RCOOH . R'OH
6
+) Khi cho axit cacboxylic v ancol nguyn cht (khng dng dung dch) phn ng vi nhau th
nh:
+ Tnh nng cc cht (c th gi s th tch ca h bng 1 lt)
+ [H
2
O] c mt trong biu thc hng s cn bng ca phn ng
Cu 32. Xt cc phng n:
A. loi, v c phng trnh ion rt gn:
Ba
2+
+ 2OH
-
+ 2H
+
+ SO
4
2
BaSO
4
+ + 2H
2
O
B. loi, v c phng trnh ion rt gn
Ba
2+
+ 2CH
3
COO
-
+ 2H
+
+ SO
4
2
BaSO
4
+ + 2CH
3
COOH
C. ng
Ba
2+
+ SO
4
2
BaSO
4
+
D. loi, v c phng trnh ion rt gn:
Ba
2+
+ 2OH
-
+ Mg
2+
+ SO
4
2
BaSO
4
+ + Mg(OH)
2
+
p n ng l C
Cu 33. Phn ln supephotphat n c thnh phn:
Ca(H
2
PO
4
)
2
v CaSO
4
.2H
2
O
p n ng l A
*Ch : Phn ln supephotphat n c sn xut qua 1 giai on
Ca
3
(PO
4
)
2
+ H
2
SO
4
(c) 2Ca(H
2
PO
4
)
2
+ CaSO
4
Cu 34. Theo bi ra:
2
CO
6,72
n = = 0,3 (mol)
22,4
; n
NaOH
= 0,8.1 = 0,8 (mol)
V
2
NaOH
CO
n 0,8 8
= = > 2
n 0,3 3
To ra Na
2
CO
3
; NaOH d
PTHH: CO
2
+ 2NaOH Na
2
CO
3
+ H
2
O
mol 0,3 0,6 0,3
2 3 2
Na CO CO
n = n = 0,3 (mol)
2 3
Na CO
m = 0,3.106 = 31,8 (gam)
n
NaOH
(d) = 0,8 0,6 = 0,2 (mol) m
NaOH
= 0,2.40 = 8 (gam)
Vy, khi lng cht rn sau phn ng l
m
rn
=
2 3
Na CO NaOH (du)
m + m = 31,8 + 8 = 39,8 (gam)
p n ng l C
Cu 35. Hp cht cha C, H, O
2 2
CO H O
n = n
Hp cht c CTPT dng C
n
H
2n
O
a
Xt cc phng n:
A. Axit cacboxylic no, a chc:
C
x
H
2x+2-y
(COOH)
y
C
x+y
H
2x+2
O
2y
C
n
H
2n+2-2y
O
2y
V y > 2 C
n
H
2n+2-2y
O
2y
= C
n
H
2n
O
a
Hp cht khng phi l axit cacboxylic no, a chc
B. Anehit no, h, n chc:
C
X
H
2x+1
CHO C
X+1
H
2x+2
OC
n
H
2n
O
tha mn
C. Este n chc to bi axit no, h v ancol no, h:
C
X
H
2x+1
COOH + C
y
H
2y+1
OH C
X
H
2x+1
COOC
y
H
2y+1
+ H
2
O
C
X
H
2x+1
COOC
y
H
2y+1
C
X+Y+1
H
2x+2y+2
O
2
C
n
H
2n
O
2
tha mn
D. Ancol khng no cha mt ni i, mch h
C
x
H
2x-y
(OH)
y
C
x
H
2x
O
y
C
n
H
2n
O
a
C
x
H
2x
O
y
tha mn
p n ng l A
7
Cu 36. Xt cc phng n:
A, B ng: Ankan
C
n
H
2n+2
(n> 1)
C, ng: (cc loi lin kt n C-C v C-H)
D, sai. V d H-O-H ch c lin kt n trong phn t nhng khng phi l ankan
p n ng l D
Cu 37. Gi s t chy hon ton x mol hirocacbon A thu c 2 mol CO
2
v 1 mol H
2
O
Suy ra * m
A
=
2 2
C(CO ) H(H O)
m + m = 2.12 + 1.2.1 = 26 (gam)
*
2
O
n va t =
2 2 2 2
O (CO ) O (H O)
n + n = 2.1 + 1.0,5 = 2,5 (mol)
2
O
n
( ly d)
= 0,2.2,5 = 0,5 (mol)
2 2
CO O
n + n
(d)
= 2 + 0,5 = 2,5 (mol) n
A
= 2,5/2,5 = 1 (mol)
Vy M
A
=
A
A
m 26
= = 26
n 1
(C
2
H
2
). p n ng l C
Cu 38. p n ng l C
Cu 39. Quy tc tch Zaixep: Trong phn ng tch nc ca ancol, nhm OH u tin tch ra cng
vi H nguyn t C bc cao hn bn cnh to thnh lin kt i C=C
CH
3
-CH-CH-CH
3
o
2 4
H SO d,170 C
CH
3
-C=CH-CH
3
+ H
2
O
CH
3
OH CH
3
3- metylbutan 2 ol 2 metylbut 2 en
p n ng l B
Cu 40. Tnh lng Ag sinh ra:
PTP: 3Ag + 4HNO
3
3AgNO
3
+ NO + 2H
2
O
0,3 (mol) 0,1 (mol)
n
NO
= 2,24/22,4 = 0,1 (mol)
Theo PTP: n
Ag
= 3.n
NO
= 3.0,1 = 0,3 (mol)
t anehit n chc X l RCHO (R= H):
PTHH trng gng:
RCHO + Ag
2
O
o
3
NH , t
RCOOH + 2Ag+
0,15 (mol) 0,3 (mol)
n
RCHO
=
Ag
1 0,3
.n = = 0,15 (mol)
2 2
Suy ra: M
RCHO
=
m 6,6
= = 44
n 0,15
R + 29 = 44 R = 15 (CH
3
)
Vy X l CH
3
CHO (anehit axetic). p n ng l B
*Ch : Nhiu bi ton cn c thm trng hp X l anehit fomic (HCHO)
Anehit n chc, cn chia 2 trng hp:
+ TH
1
: HCHO
2 3
+Ag O/NH
4Ag+
+ TH
2
: RCHO
2 3
+Ag O/NH
2Ag+
Cu 41. p n ng l D
Cu 42. p n ng l C
Cu 43. Polime khng c nhit nng chy xc nh, do polime l hn hp nhiu phn t c phn
t khi khc nhau (tc l c h s trng hp n khc nhau)
p n ng l C
Cu 44. Ta c:
[Dng oxi ha] Fe
2+
Cu
2+
Fe
3+
Ag
+
[Dng kh] Fe Cu Fe
2+
Ag
8
Do , chiu gim dn tnh oxi ha: Ag
+
> Fe
3+
> Cu
2+
> Fe
2+
p n ng l B
Cu 45. Nguyn t ca cc kim loi trong nhm IA (kim loi kim) ging nhau v:
- S electron ngoi cng ca nguyn t (s electron ha tr)
- S oxi ha ca nguyn t trong hp cht
+1
- Kiu mng tinh th ca n cht (kiu mng tinh th lp phng tm khi)
Khc nhau v cu hnh electron nguyn t. p n ng l D
Cu 46. Xt cc phng n:
A. Khng ng: V ch c Cr
2
O
3
, Cr(OH)
3
(crom c s oxi ha +3) c tnh lng tnh; cn
CrO, Cr(OH)
2
c tnh baz (khng th hin tnh axit)
Th d: Cr(OH)
3
+ 3HCl CrCl
3
+ 3H
2
O
Cr(OH)
3
+ NaOH Na[Cr(OH)
4
]
B. ng. i vi cc hp cht ca crom:
S oxi ha + 2 +3 +6
Tnh cht Tnh kh Va c tnh kh, va Tnh oxi ha
c trng c tnh oxi ha mnh
Th d: 2CrCl
2
+ Cl
2
2CrCl
3
K
2
Cr
2
O
7
+ 14HCl 3Cl
2
+ 2KCl + 2CrCl
3
+ 7H
2
O
C. ng. i vi cc oxit, hiroxit ca crom:
S oxi ha + 2 +3 +6
Tnh cht Tnh baz tnh lng tnh Tnh axit
D. ng: CrO
4
2
+ 2H
+
Cr
2
O
7
2
+ H
2
O
Cromat icromat
Khi thm kim (OH
-
) th H
+
+ OH
-
H
2
O
[H
+
] gim cn bng trn chuyn sang tri, tc l mui icromat s chuyn thnh mui
cromat. p n ng l A
Cu 47. Hu ht cc hp cht ca natri tan nhiu trong nc v khng c mu, nn ngi ta khng
dng phn ng ha hc, nhn bit ion Na
+
m dng phng php vt l th mu ngn la nh
sau: Tm bt t mui rn hoc dung dch mui natri ln dy platin ri a dy vo ngn la n
kh khng mu, ta s thy ngn la nhum mu vng ti. p n ng l D
Cu 48. Mt trong nhng tc nhn ch yu gy nn nao, au u, khi ung ru l do trong ru c
ln etanal (anehit axit) CH
3
CHO. p n ng l B
Cu 49. Theo bi ra n
NO
=
0,56
= 0,025 (mol)
22,4
0 3+
Ta c s : Fe 3e Fe
Fe
0 -2
O + 2e O
3 - m
(mol)
8
FeO, Fe
3
O
4
, Fe
2
O
3
, Fe (d)
+5 +2
N + 3e N
3 . 0,025(mol)
Fe(NO
3
)
3
3m
(mol)
56
Ta c:
3m 3 - m
= + 3.0,025
56 8
3m = 21 7m + 4,2
10m = 25,2 m = 2,52. p n ng l C
Cu 50. Theo bi ra:
2
H
5,6
n = = 0,25 (mol)
22,4
9
Xy ra qu trnh: 2H
+
+ 2e H
2
0,5 (mol) 0,25
+
2
H
H
n = 2.n = 2.0,25 = 0,5 (mol) = n
HCl
- +
HCl
Cl H
n = n = n = 0,5 (mol)
Khi lng mui khan: m = m
kim loi
+
-
Cl
m = 20 + 0,5.35,5 = 37,75 (gam)
p n ng l B