Confidential

2013.02.25 2013.02.25

New Syndiotactic Elastomer with Crystalline Structure controlled in Nano Order

SN

SELLER WARRANTS TO THE BEST OF ITS KNOWLEDGE THAT THE USE OR SALE OF “NOTIOTMSN” WILL NOT INFRINGE UPON ANY PATENT COVERING THE PRODUCT ITSELF, BUT DOES NOT WARRANT AGAINST INFRINGEMENT BY REASON OF THE USE THEREOF IN COMBINATION WITH ANY OTHER PRODUCTS OR IN THE OPERATION OF ANY PROCESS.

Mitsui Chemicals, Inc. Elastomer Div.
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Confidential

Contents

2013.02.25 2013.02.25

1. What is NotioTM-SN? 2. Adapting for calendering of NotioTM-SN 3. Features of NotioTM-SN leather

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Resistance to Scratch and Abrasion 3/20 . Solubility.25 2013.1.02.25 NotioTM-SN is a Syndiotactic New Olefin Elastomer with Crystalline/Amorphous Structure Controlled in Nano Order AFM Image TEM Image 1000nm 50nm crystalline blocks heat resistance resistance to Scratch and Abrasion amorphous chain rubber elasticity/flexibility high melt tension resistance to Scratch and Abrasion Nano network of crystalline/amorphous segments Transparency.02. What is NotioTM-SN? Structure of NotioTM-SN Confidential 2013.

02.1.25 2013. What is NotioTM-SN? Features of NotioTM-SN(1) Heat Resistance/Elasticity Balance Good 180 140 100 60 20 40 30 20 10 0 Confidential 2013.25 Light Weight 1500 PVC PU (℃) NotioTM density (kg/m3) Heat Resistance 1000 500 0 NotioTM TMA C2 based elastmerSEBS Permanent set after 150% Extesion(%) Extesion(%) Good Elasticity Transparency Flexibility Compatibility with PP PP / NotioTM = 80 / 20wt% TEM Image 1μm 4/20 .02.

9.). What is NotioTM-SN? Features of NotioTM-SN(2) Abrasion Resistance Amount of Weight Loss (mg) 100 80 60 Confidential 2013.H-38 Load.1. rubbed by cotton duck Taber Abrasion Wear testing Weel. Load=1000 gf.25 2013.02. Load=1000gf.25 Scratch Resistance Ethylene – vinylacetate copolymer Ethylene based elastomer Good 40 20 0 PVC NotioTM-SN PU coated Olefin Leather NotioTM-SN Frictional wear test :JIS L 0849 compliant. 5/20 . reciprocating times=10(33times/min.8N(1kg) 70rpm. 1000cycles NotioTM-SN has high abrasion resistance and scratch resistance same as PU.H Weel.02.

Low-MFR and High abrasion resistance is features of NotioTM-SN. 6/20 .02. Kg/m3 Confidential 2013.25 2013.1.25 NotioTM SN-0285 1. What is NotioTM-SN? Physical properties of NotioTM-SN Item MFR Basic Properties Density Shore A Hardness Thermal Property Softening Temperature Tensile Strength Elongation of Break Mechanical Properties Young Modulus Permanent Set Compression Set Optical Property StressStress-Absorbing Property Abrasion Resistance ININ-Haze Falling Ball Test Weight loss @23°C @70°C °C Mpa % MPa % % % % cm mg Condition @230°C Unit g/10min.02. but not specification values.4 865 84 116 15 >700 34 15 25 61 8 3 0 ■The above figures are just representative value.

25 <Extrusion> <Calendering> NotioTM-SN is supplied as pellets and can be formed by extrusion or calendering process. 7/20 .02.1.25 2013. What is NotioTM-SN? Formability of NotioTM-SN TM-SN Pellet NotioTM- Confidential 2013.02.

02.02.1.25 2013.25 Applications Bag・Shoes Soft Sheets Car Interiors Stationery 8/20 . What is NotioTM-SN? Confidential 2013.

a duffle bag. wear resistance. In fact.25 Adaption examples 【(1)Honda:Freed Spike】 【(2)Hunting world】 Through this collaboration.html NotioTM-SN is used for surface leather.honda. and scratch resistance. ※http://www. As for attitude. as symbolized by Ryo Ishikawa’s strong resolve and ardent passion. two birds that are used as golf terms to indicate scores. such as PVC (vinyl chloride). the material used in these bags is 30% to 40% lighter than the plastics that are normally used. HUNTING WORLD wanted to express strong will. as well as an albatross and eagle motifs. For the main material. a tote bag. this has been expressed using a single.25 2013. a small tote bag.itochu.jp/ja/news/2012/121114. but none of the harmful substances that are often included in the materials normally used for bag applications.co. What is NotioTM-SN? Confidential 2013. The theme color is red – a color that Ryo Ishikawa also likes to wear – can be said to be the most appropriate color for representing this will.02. ※http://www. as well as the attitude of doggedly pursuing a dream. The lineup includes five items: a messenger bag.co. Everything from the design and style down to the smallest details has been developed in collaboration with Ryo Ishikawa. and a pouch.1. The inner lining is a deep red base material embossed with Ryo Ishikawa’s brand logo. these products use NOTIO™ NOTIO™ SN leather. a new material that brings several Japanese technologies together.jp/FREEDSPIKE/ 9/20 .02. NOTIO™ NOTIO™ SN leather is a revolutionary material with excellent heat resistance. But the best thing about this material is that it is extremely light. straight line.

Adapting for calendering of NotioTM-SN 3.02.25 1.02. What is NotioTM-SN? 2.Confidential Contents 2013.25 2013. Features of NotioTM-SN leather 10/20 .

25 Calendering conditions ②Calendering ④Cooling ①melting & mixing Process ① ② ③ ④ Temperature 160~185 185℃ (resin temperature) ⑤winding ③Laminating Points Temperature should be set to more than the melting point of the polymer Line speed Mixing time.02.25 2013. time. Adapting for calendering of NotioTM-SN Confidential 2013. less than 30min.2. 160~185 185℃ (resin temperature) 115~130℃ (sheet temperature) More than the softening temperature more than 10m/min. less than 35℃ (sheet temperature) 11/20 .02.

02. etc Car interiors NotioTM-SN/PP Heat Resistance Flexing Resistance Building Materials Nonslip goods NotioTM-SN/EVA and/or TafmerTM/ TafmerTM-PN. . ML.25 Formulation examples for leather good Taber Abrasion Resistance Shoes / Furniture NotioTM-SN and/or TafmerTM-PN. etc NotioTM-SN/PP and/or TafmerTM-PN. ML. Adapting for calendering of NotioTM-SN Confidential 2013.2.02.25 2013. ML. etc Ultrasonic Welder Scent Free NotioTM-SN/PE Stationary Bag/Case 60 Shore-A Hardness 90 12/20 We recommend the NotioTM-SN base compound as your request spec.

Adapting for calendering of NotioTM-SN Confidential 2013. 13/20 .25 Formulation examples for leather Items Abrasion resistance Physical property Flexibility (Shore-A) Flex resistance Ruck Flame resistance Calendering Workability Foaming Embossing NotioTM-SN SN-0285 ◎ ○ (84) ○ △ △ (with filler) △ ○ ○ NotioTM-SN base compound CH-18 ◎ ◎ (55) ○ △ ○ (with filler) ○ ○ ○ CH-18 is the softest formulation which we have already developed.02.25 2013.2.02.

02.25 1. What is NotioTM-SN? 2.25 2013.Confidential Contents 2013.02. Adapting for calendering of NotioTM-SN 3. Features of NotioTM-SN leather 14/20 .

000times Cloth>Resin layer (Depending on cloth properties) condition unit mm mm N N N N mg - LV leather 1.5 788 858 226 126 50 No change Crack NotioTM-SN leather 1.25 2013.8N. Features of NotioNotio-SN leather Compared PVC leather to NotioTM-SN leather Confidential 2013. 9.5 1263 1238 206 170 4 No change No change Tensile Strength Tear strength Abrasion resistance (weight loss) 50.1 0. 15/20 .25 Measurement item Thickness Total Cloth wrap weft wrap weft 23℃ -10℃ Flexion resistance -10℃ CS-10.1 0.000times 100.02.02.000times 23℃ No change No change ■The above figures are just representative value. but not specification values. abrasion resistance and flexion resistance in low temperature of NotioTM-SN leather are better than those of LV leather. Especially.3. 60rpm. 1000times 50.

200times Abrasion resistance of NotioTM-SN leather is the same as PU.02. but not specification values. ※ Taber Abrasion Wear testing :H22. 1kg. 60rpm. but NotioTM-SN leather don’t have it.25 NotioTM-SN leather Exposed cloth Pictures after testing※ PU leather NotioTM-SN leather Amount of weight loss※ 18 mg 26 mg ■The above figures are just representative value.25 2013. (PU leather has exposed cloth after test.) 16/20 . Features of NotioNotio-SN leather Compared PU leather to NotioTM-SN leather PU leather Confidential 2013.3.02.

25 2013. phthalate.02. Features of NotioNotio-SN leather Confidential 2013.02.3. and styrene.25 Environment safety NotioTM-SN leather PVC leather PU leather plasticizer solvent halide aromatic compounds free free free free use use - use use NotioTM-SN leather does NOT include plasticizers. and it is lower environmental load than PVC and PU leather. halide. 17/20 .

alkaline aqueous sol.02.02.) acid aqueous sol.25 2013. Features of NotioNotio-SN leather Confidential 2013.3. NotioTM-SN leather is stable against hydrolysis and Solvents. . hydrolysis.25 Durability . 5min. Solvents NotioTM-SN leather Naphthalene (Mothball) PVC leather PU leather good good good good NG NG NG NG NG NG NG NG 18/20 Water (100degreeC.

The growth of mold is not visible under the naked eye. Fungus NotioTM-SN PVC 2013. 19/20 .25 2013. 2. The bacterial thread often grows.3.The growth of mold is not visible under the naked eye and the microscope either.The growth of mold is not visible under the naked eye. Features of NotioNotio-SN leather Confidential *test condition;JIS Z 29112911-2010 appendix1 test of plastic methodB’ Durability . The area of the growth part is 50% or more of the overall product of the sample. 3. NotioTM-SN has strong Fungus Resistance. 5. 1. 4.02. the area of the growth part is less than 25% of the overall product of the sample. The growth of mold is not visible under the naked eye. The growth of the bacterial thread intensely covers the front side of the sample. but visible under the microscope. The area of the growth part is less than 50% of the overall product of the sample.02.25 PU Result: 1 Judgment Result: 3 Result: 4 0.

3.02.25 -30 ℃ Cold resistance test JIS K 6772 NotioTM-SN leather NotioTM-SN leather is superior to PVC leather in Cold resistance. Features of NotioNotio-SN leather Confidential *test condition;JIS Z 29112911-2010 appendix1 test of plastic methodB’ Cold resistance PVC Dropping 2013.25 2013. and it is not broken at -30℃. 20/20 .02.

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