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Chapter 1
c i
[1]
100
[2]
[1]
[1]
[1]
= 91.3
20
80
;H=
1.0
12.0
C = 6.67; H = 20
divide by lowest
4 a C =
[1]
[1]
[1]
[1]
Total = 6
2 a 262.5
180
b 72 Hf
[1]
[1]
Total = 10
6.67
20
= 1; H =
= 3
6.67
6.67
empirical formula is CH3
b empirical formula mass = 15
15n = 30; n = 2, so molecular
formula is C2H6
c any 4 of:
volume of gas proportional to number
of moles;
mole ratio is 50:300:200
1mol hydrocarbon:6mol oxygen:4mol
carbon dioxide
Since 4 moles of carbon dioxide from
1 mole of hydrocarbon, hydrocarbon has
4 carbon atoms
4 carbon atoms will react with 4 moles of
oxygen molecules, leaving 2 moles of oxygen
molecules (4 moles of oxygen atoms) to react
with the hydrogen
so 4 moles of water formed, meaning
8 hydrogen atoms in hydrocarbon
equation is C4H8+6O2 4CO2+4H2O
b 2
c i 184.2
ii Fe has several isotopes.
e 0.2mol
f 0.224 = 4.8dm3
[1]
[1]
C =
600
= 0.025mol
24000
0.02544.0 = 1.1g
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
d moles propane =
[1]
[1]
Total = 10
5 a 4Na+TiCl4 4NaCl+Ti
[2]
[1]
[1]
[1]
[1]
[1]
[1]
4.80
= 0.200mol
24.0
b moles of NaOCl = moles of Cl2 = 0.200mol
mass of NaOCl = 74.50.200 = 14.9g
c moles of NaOH = 2moles of
chlorine = 0.400mol
6 a i 0.0150dm3
ii 0.0200dm3
b 0.02000.0500 = 0.00100mol
c 0.00100mol
0.00100
= 0.0667moldm1
0.0150
[1]
[1]
[1]
[1]
[1]
Total = 5
7 a 80.0 (gmol1)
[1]
0.800
b
[1]
80.0
= 0.0100mol
[1]
c moles nitrogen(I) oxide = 0.0100
[1]
volume = 0.010024.0 = 0.024dm3 / 240cm3 [1]
Total = 5
1.20
8 a i moles of HCl =
= 0.0500mol
24.0
moles
0.0500
ii concentration =
=
3
volume in dm
0.100
= 0.500moldm3
25.0
b i 0.500
1000
= 0.0125mol
ii moles NaOH = moles of HCl
= 0.0125 mol
volume =
=
[1]
[1]
volume of NaOH =
[1]
[1]
[1]
0.400
= 0.200dm3
2.00
[1]
[1]
[1]
[1]
[1]
d Cl2(g)+2OH(aq)
Cl(aq)+OCl(aq) + H2O(l) [1]
Total = 6
[1]
28.05
28.05g CaO 111.1
g CaCl2
56.1
= 55.5g CaCl2
b 1 mole of CaO reacts with 2 mole of HCl
56.1g CaO reacts with 73.0g HCl
28.05g CaO reacts with
[1]
28.05
73.0
= 36.5g HCl
56.1
[1]
c mass of water is
28.05
18.0 = 9.0g
56.1
[1]
[1]
Total = 5
11 a NH3(g)+HCl(g) NH4Cl(s)
[2]
b NH3 = 17.0gmol1
HCl = 36.5gmol1
NH4Cl = 53.5gmol1
[1]
[1]
[1]
[1]
moles
concentration
0.0125
= 0.0625dm3
0.200
9 a moles of Cl2 =
10.7
= 0.2mol
53.5
moles of NH3 and of HCl = 0.2mol
0.224.0 = 4.8dm3 of NH3 and HCl
c 10.7g NH4Cl =
[1]
[1]
[1]
Total = 8
[1]
Total = 7