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JABATAN
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PERCUBAAN 2011
SPM

KIMIA
Kertas
1
jam
Satu limabelas
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BUKAKERTAS
JANGAN
INI
SOALAN SEHINGGA
DIBERITAHU
1.
2.
3.

Kerfassoalan adalah
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4*1/,1

suuT
1

releases to thesurrounding?
heat
Vrrhich thefollowing
of
yang Mrikut,yangmanakah
membebaskan ke persekitann?
haba
Antara
A

Addacidto alkali
alkali
Tambah
asidRepada

Heata carbonate
salt
karbonat
Panaskan garam
satu

salt
Dissolve
someammonium in water
garamammonium dalamair
di
Larutkan
sedikit

oarbonate
hydrogen
acldto sodium
D Adddilute
naftiumlrydrqenkarfunat
asid
Tambah calrkepada
2

of
Name process soappreparation.
the
pross
penye aan eahn.
u
di
Namakan
A

Dehydration
Pendehidratan
Sulphonation
Pengsulfonan
Saponification
SaponflTkast
Polymerisation
Pempotirnenn

proron
proposed above
l/Vho
model?
the
yang mencadangkan
di
model atas?
Siapakah
A

Ernest
Rutherford

James
Chadurick

J.JThomson

Neils
Bohr

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The following
equationrepresents reaction.
a
Persamaanberikut mewakili satu tindak balas.
+
3H21d N2tu;

2NHqsy

What is the relativemolecularmass of the product?


atomicmass .'H=l; N=!4 ]
[Relative
Apakah jisim molekul relatif bagi hasil tersebut?
[Jisim atom relative: H=l; N=l4 ]
A2
817

c2 8
D34
5

\/V}rich the followingare the specialcharacteristics transitionelements?


of
of
Antara yang berikut, yang manakah merupakan ciri istimewa bagi togam
peralihan?
I

Formcoloured
compounds
Membentuk sebati n benuarna
a

ll Can be used as catalyst


Boleh digunakan sebagaimangkin
lll Have low meltingpoint
Mempunyaitakat lebur yang rendah
lV Haveonly one oxidation
number
Mempunyai satu nombor pengoksidaansahaja
A

lonly
I sahaja

land llonly
I dan ll sahaja

l, ll and lll only


I, ll dan tll sahaja

l, ll, lll and lVonly


I,ll,lll dan lV sahaja

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sul-rT

434trt

Diagram
t
Rajah
t
Diagram shows number atoms a molecute.
1
the
in
of
Whichof the followingcould
bethemolecule?
Rajah1 menunjul<Ran
bilanganatamdalam satumateku!.
Antarc yang berikut,
yangmanakah
mungkin
molekulitu?
A

Carbon
dioxide
Katbondioksida

Ammonia
Ammonia

Chlorine
Korin

Water
Air

Which thefollowing anelectrolyte?


of
is
yang berikut,
Antara
yangmanakah
merupakan
eteWrolit?
A

Copper sulphate
solution
{ll}
Larutan
(ll)
kuprum suffat

Molten
naphthalene
Lebunnnaftalena

Glucose
solution
glukosa
Larutan

Zincmetal
Lqam zink

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the pH valuesfor solutionP, Q, R and S with the same concentration.


Diagram shovrs
2
Rajah 2 menunjukkan nilai pH bagi larutan larutan P, Q, R, dan S dengan kepekatanyang
sama.
pH
scale
Diagram
2
Rajah2
\Mrat are the possible
solutions P, Q, R and S?
of
Apakah larutan yang mungkin bagiP, Q, R dan S?
Ethanoic acid Sulphuric acid
Asid etanoik
Asid suffurtk

Sodium hydroxide
Natrium hidroksida

Sodium chloride
Natrium klorida

o
o

reaction?
\Altrich the followingsalts can be preparedby precipitation
of
Antara garam yang berikut, yang manakah boleh disediakan melalui tindak halas
pemendakan?
A

Bariumsulphate
Barium sulfat

Sodiumchloride
Natrium kloida

Aluminium nitrate
Aluminium nitrat

Potassiumcarbonate
Kalium karbonat

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10 Alloy is madeby mixing withcarbon,


X
iron
chromium nickel.
and
what is X?
AloiX diperbuat
denganmencampurkan
besidenganRarbon,
kromiumdannikel.
ApakahX?
A
B

Pewter
Piuter

Bronze
Gangsa

11

Steel
Keluli

Stainless
steel
Kelulitahan karat

\Mich of the followingdoes not affectrate of reaction?


Antara yang berikut, yang manakah tidak mempengaruhikadar tindak balas ?
A

Concentration solution
of
Kepekatan larutan

Presenceof catalyst
Kehadiran mangkin

12

Total surfacearea of reactant


Jumlah luaspermukaan bahan tindak balas

Volumeof solution
lsipadu larutan

Wtich of the following


organiccompound undergohydrogenation
will
reaction?
Antara yang berikut, yang manakah sebatianorganik yang akan mengalami tindak
balas penghidrogenan?
A

Propene
Propena

Propane
Propana

Propanol
Propanot

Propanoic
acid
Asid propanoik

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13 \A/lrich the following


of
explains oxidation
process?
an
Antarayang herikut,yang manakah menerangkanproses
pengoksidaan?
Loss of oxygen
Kehilangan oksigen
Gain of electrons
Penerimaan electron
Loss of hydrogen
Kehilangan hidrogen
Decreasein oxidationnumber
N ombor pengol<sid an berkurang
a

14 Pickled mango is prepared by soakingmango in vinegar. What typ of food

additiveis vinegar?
Jeruk mangga disediakandengan merendambuah 'mangga di dalam cuka.
jenisbahantambah
Apakah
makananbagicuka?
Dyes
Pewama
Thickener
Pemekat
Antioxidant
Pengantioksidd
Preservative
Pengawet

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15

45d.1tI

The thermochemical
equation the decomposition calciumcarbonate,
for
of
CaCO3
is as follovus:
Persamaan termokimia bagi penguraian kalsium karbonat, caco3 adatah seperti
berikut:
CaCO3 +

CaO +

COz

AH=+l7gkJ

wrich of the followingenergylevel diagramrepresents equation?


the
yang berikut, yang manakah gambarajah aras tenagi mewakiti persamaan
lntlra
itu ?

trnergy
Tenaga
= +178
CaO + COz

Energy
Tenaga
= + 178
CaC03

c
Energy
Tenaga
AH= +178

Energy
Tenaga
AH= +178

8
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4841'1

to

ill

Diagram
3
Rajah3
Whatare thethreestates matter?
of
Apakahkeadaan
fizikaljirimdi atas?
tl
Liquid
Cecair

ill
Solid
Pepejal

Liqu
id
Cecair

Gas
Gas

Liquid
Cecair

Gas
Gas
Solid
Pepejal

Solid
Pepejal

Gas
Gas

Liquid
Cecair

Gas
Gas

Solid
Pepejal

17 Which the substance


of
below
contains samenumber atomsas in one mole
the
of
gas?
of chlorine
Antarabahan yang berikut,yang manakahmengandungi
bilanganatom yang
samadengansatumol gas klorin?
A

1 molneon
I rnolneon
Tzmolsodium
% mol natrium
T"mol carlcon
dioxide
% mol karbon dioksida

1 mol nitrogen
dioxide
1 mol nitrogen dioksida

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18

X
Diagram4
Rajah
4
Diagram 4
shovus parts of the periodic Tabre of Erements.
Tle symbols x, y andz are notthe actuar
w
symbors the erements.
of
\Mich of the following
shours correctarrangement elements X, y and Z in
the
of
w,
orderof increasing
atomic
size?
sebahagian
Jadua! Berkala
lJnsur.simbot-simbolw, x, y dan
laian + menuniukkan
Z tidakmewakili
simbo!sebenir unsur.
Altara yang berikut,yang manakahmewakilisusunan
yang betut pertambahan
saiz
atombagi unsur-unsurW, y dan Z ?
X,
A

W,X,Y,Z

X,Y,W,Z

Y, Z, X,W

Z,Y,WX

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19

5
Diagram
Rajah5
state.
\Mich statement
up
X
5,
In Diagram substance lights the bulbin the molten
the
bestexplains observation?
merrtotdalamkeadanleburan.Pemyataan
Dalam Rajah5, bahanX menyalakan
pemerhatian
tersebut?
palingbaikmenerangkan
yangmanakah
X consistsof ions
X terdiri daripada ion-ion.
X consistsof molecules
X terdiri daripada molekul-mole4ul
X has freely movingions
X mempunyaiion-ion bebas bergerak
X has ions in fixed position
X mempunyaiion-ion dalam kedudukan tetap

20

a
A studentconstructed chemicalcell using a copper rod, a zinc rod, copper (ll)
sulphate solution and connecting wires. \A/hichof the following will act as the
positive
terminal?
Seorang pelajar membina safu se/ kimia menggunakan rod kuprum, rod zink,
larutan kuprum (ll) sulfat dan wayar penyambung. Antara yang berikut, yang
m an akah akan m eniadi terminal positif?
Copperrod
Rod kuprum
Zinc rod
Rod zink
Connectingwires
Wayar penyambung
solution
Coppe(ll) sulphate
Larutan kuprum (ll) sulfat

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21 Diagram6 shouvs set-upof apparatus the titration 25 cm3 1.0 mol drn3 sodium
the
for
of
hydroxide
solution
with 0.5 mol dm-3 sulphuric
of
acid.
Rajah 6 menunjut<Ran
susunan radas bagi titratan 25 cmslarutan natrium hictroksida
1.0
^
mol dm' dengan asid sulfurik 0.5 moldm'".

0.5moldm-3 sulphuric
of
acid
0.5 mol dm'"asidsulfurik

25 cm31.0mol dm-3
sodiumhydroxide
+ phenolphthalein
solution
25 cm' larutannatium hidroksida1.0 mol dm'
3 + feno!ftalein
Diagrarn
6
Rajah 6
What is the volume of 0.5 mol dm-3of sulphuricacid solution requiredto completely
neutralize cm3 1.0 mol dm-3
25
sodiumhydroxide
solutions?
Berapakah isi padu 0.5 mol dm' asid sulfurik diperlukan untuk meneutralkan lengkap 25
cm3 larutannatrium hidroksida mol drn?
1.0
A

12.50cm3

25.00 cm3

50.00 cm3

75.50 cm3

t2
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22

4541t1

Wftichof the followingions form white precipitate


that dissolvesin excessamrnonia
solution?
Antara ion-ion berikut, yang manakah menghasilkanmendakan putih yang larut
dalam larutan ammonia berlebihan?
A
B

AI3*

znz*

D
23

Mgt*

Pb2*

The equationbelowshowsthe formationof a compositematerialfrom its original


component.
Persamaandi bawah menunjukkanpembentukan satu bahankomposit daripada
komponen asalnya.
Plastic +
Plastik +

Glass fibres
Gentian kaca --|

Fibreglass
Kaca gentian

Why is fibre glass betterthan common plastic?


Kenapakah kaca gentian lebih baik daripada plastik biasa?
A

Resistant corrosion
to
Tahan kakisan

Able to withstandheat
Tahan haba

24

Hightensile strength
Kekuatan regangan tinggi

Good conductorof electricity


Konduktor elektrikyang baik

Whichof the following makemeat last longer?


will
Antara yang berikut, yang manakah boleh menyebabkan daging tahan tebih lama?
A

Boilthe meatfor an hour.


Mendidihkan daging untuk satujam.

Dry the meat under the sun


Mengeringkan daging di bawah matahari

Keep the meat in a refrigerator.


Menyimpan daging di dalam petisejuk

Fry the meat and keep intoa container.


Menggorengkan
dagingdan menyimpan
didalam bekas,

13
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25

4541t1

The equationbelowshovvs reactionof alkene.


a
Persamaandi bawahmenunjukkan tindak balasalkena.
CH3CH=CH2+

+CH3CH2CH2Br

Which of the followingis Y?


Antara yang berikut, yang manakah Y?
A

Bromine,Br2
Bromin, Br2

Hydrogen
bromide,HBr
Hidrogen bromida, HBr

Sodiumbromide,NaBr
Natrium bromida, NaBr

Magnesium
bromide,
MgBr2
M agnesium bromida, MgBr2

26 The followingshows an ionic equation.


Yang berikut menunjukkansuatu persamaanion.
+
P 1s; Qtn("d *

P2*("0 +

Based on the equation,which of the followingis true?


Berdasarkanpersamaan tersebut,yang manakah benar?
A

P is oxidised.
P dioksidakan.

P2*is oxidised.
f
dioksidakan.

Qz* is a reducing
agent.
Q2*adalahagen peneurunan.

Q2' donateselectrons.
Q2*menderna elektron.

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27

4541t1

Diagram7 showsthe results


obtained
when metalX is addedintosolution
A.
Rajah 7 menunjukkan keputusanyang diperoleh apabila logam X ditambah ke
dalam larutan A.

Solution before addingmetalX


A
Larutan A sebelum ditambahkanlogam X

ffi
Solution after addingmetalX
A
Larutan 4 se/epas ditamhahkan logam
Diagram
7
Rajah 7
Which of the followingexplainsthe reaction?
Antara yang berikut, yang manakah menjelasRan
tindak balas tersebut?
A

Displacement endothermic
and
Penyesaran dan endotermik

Displacement exothermic
and
Penyesaran dan eksotermik

Precipitation endothermic
and
P emendakan dan endotermik

Precipitation exothermic
and
Pemendakan dan eksotermik

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tl

CHsf ( CHz ) r r t

o
o-

nl

tls
tl

IV

o-

Na*

o
8
Diagram
RaiahI

part
sulphate?
dodecyl
8
on
Based Diagram , whichis the hydrophilic in sodium
dalamnatium dodekil
hidrofilik
bahagian
Rajah8, yangmanakah
Berdasarkan
sulfat?
AI
Bll
c

lll

DIV

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29 Chlorine-35 chlorine-37 hruo
and
are
isotopes chlorine.
of
\Mratarethe differences
in theseisotopes?
Kortn4l dan klorin3T adalah dua isotopklorin. Apakahperhezaandi antara
isotopisotopini?
I

Proton
number
Nomborproton

ll

Nucleon
number
Nombor
nucleon

lll

Physicalproperties
Sifat-sifat
fizikal

lV

Chemicalproperties
Sifat-sifat
kimia

l an d ll
I dan ll

l l an dl l l
ll dan lll

l and lll
t danttt

l l a n dl V
ll danlV

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30 Diagram showsthe set-upof apparatus determine empirical


9
to
the
formulaof
metaloxide.
n/1h 9 menuniukkan susunan radas untuk menentukanformula empirik bagi
ol<sida
logam.
MethodI
Kaedah I
Crucible
tid
Penufup
mangkuk
p'jar

Methodll
Kaedah ll
Chemical
substance
Dryhydrogen
BahanKimia
Chemical gas
substance Gashidrogen
Bahan
kering
kimia

Diagram
9
Rajah
9
\Nhich thefollowing the correct
of
is
match Method and Method
for
I
ll?
Antarapadanan
beikut, yang manakah
betulunfukKaedahI danlt?
Method
I
KaedahI

Methodll
\aedah ll

(ll)
Copper oxide
Kuprum(ll) oksida

Lead (ll) oxide


plumbum (ll) oksida

Lead(ll)oxide
(ll)
Plumbum oksida

Copper(ll) oxide
Kuprum (ll) oksida

Magnesium
oxide
Magnesium
oksida

Lead (ll) oxide


Plumbum (ll) oksida

(ll)
Copper oxide
(ll)
Kuprum oksida

Magnesium
oxide
Magnesiumoksida

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4&',111

31
X
Y

Diagram10
Rajah 10
An atom of element X reacts with element Y to form a compound.\A/hatis the
formulaof the compoundformed?
satu atom unsur x beftindak balas dengan unsur y menghasilkan safu
sebatian.Apakah
formula bagi sebatianyang terbentuk?

AX Y
B
G

XYZ

D
32

X,Y

XzYz

Manycovalent
compounds usedas solvents.
are
\fthichof the following not a
is
solvent paint?
for
Kebanyakansebatiankovalen digunakansebagaipelarut. Antara yang berikut,
yangmanakah
hukan pelarutuntukcat?
A

Ether
Eter

Water
Air

Ethanol
Etanol

Turpentine
Turpentin

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33 Diagram showsthe apparatus


11
set-upIn flrs elec{roplating an iron spoonwith
of
silver.
Raiah 11 manuniul<kat
sosunanradasuntuk menyadursatu sudu fusi dengan
aryentum.

Silver foil /
kepingan
argenttmt
Solution
Yllarutan
Diagram
11
Rajil tl
IMratcouldbe solution
Y?
y?
Antanyangbeikut,yang manakah
larutan
A

lron(ll) sulphate
Ferum(ll)
sultat

lron(ll) chloride
(ll)
Ferum klofda

Sllver
chtoride
Argentum
klafida

Silvernitrate
Aryentunnttrct

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pH= 5.0

pH = 1.0

34

H
t-----t
t:_':F

1. 0 m oldm - 3
hydrochloric
acid

1.0 mol dm-r


ethanoicacid

Diagram12
Rajah 12
In Diagram12, the pH value of ethanoic
acid is higherthan the hydrochloric
acid.Which
of the following,
explain difference?
the
Dalam Rajah 12, nilai pH asid etanoik lebih tinggidaripada asid hidroklorik. Antara yang
berikut, yang manakah menerangkan perbezaan tersebut?
A

of
Ethanoicacid has low concentration H*
Asidetarnik mempunyaiRepekatanlf yang ren&h

Ethanoicacid is a strongacid
Asid etanoik iatah asid kuat

Hydrochloric
acid is a weak acid
Asid hidroklorik ialah asid lemalt

acid has highconcentration OH


of
Hydrochloric
kepekatan
OH-yangtinggi
Asid hidroklorik
mempunyai

2l
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35 Diagram shows series reaction involves


13
a
of
that
compound
G.
Rajah13 menunjukkan sii tindakbalas
satu
yang metibatkan
sebatian
G

Added with dilute hydrochloric


acid and
filtered.
Tambah asid hidroklorik cair dan dituras

Added
withammonia
solution
untilexcess.
Tambah
larutanammonra
sehinggaberlebihan

Whiteprecipitate
dissolves
putihmelarut
Mendakan
Diagram
13
Rajah 13
G is a mixture trrrc
of
salts.Among following,
the
whatis G?
G adalahcampuran garam.Apakah
dua
G?
A
Lead(ll) nitrate zinccarbonate
and
Plumbum(ll)nitrat dan zink karbonat
B

Lead(ll)
nitrate aluminium
and
nitrate
Plumbum(ll)nitrat dan aluminium
nitrat

Silver
sulphate copper carbonate
(ll)
and
Argentum
sulfatdan kuprum(ll)
karbonat

Magnesium
sulphate lead(ll)
and
carbonate
Magnesium
sulfatdanplumbum(il)
kahonat

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ffi111

36 Diagrum shorrnscamera,
14
a
Rajaht4 menunjukkan
sejeniskarnora.

Quarts
lens
Kantakuarba

Diagram
14
Rajah
t4

typeof
to
the
tens?
T/haJ jenisglassis used make quartz
Apakah
yangdigunakan
kaea
untukmembuat
kantakuartza?
A

glass
Fused
Kacasilika
tedakur
Sodalimegfass
Kacasoda
kapur
Borosilicate
glass
Kacabonsilikat
Lead
crystalglase
Kacaplumbum

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37

4541t1

A student carried out an experimentto determinethe rate of reaction behoeen


calcium carbonateand dilute hydrochloric
acid. The volume of carbon dioxidegas
collectedat intervalsof 0.5 minutesis recordedin Table 1.
Seorang pelajar menjalankan eksperimen untuk menentukan kadar tindak balas
antara kalsium karbonat dan asid hidroklorikcair. lsipadu gas karbon diot<siJa
yiig
terkumpulpada selang masa 0.Sminit direkod dalam Jadial I.
Time (min)
Masa (minl

0.5 1. 0 1 . 5 2.0 2.5 3.0 3.5 4.0 4.5 5 . 0

sas
F#i""orco2
f'#r,*sasco2

27 46

59

70

79

86

92

95

95

95

Table1
Jadual 1
What is the averagerate of reactionin the third minute?
Apakah kadar tindak balaspurata dalam minit ketiga ?
A

28.67cmsmin-1

.B

23.75 cm3min'1

16 cm3min'1

14 cm3min-

38 Propane,
CgHa
undergoes
complete
combustion produce carbon dioxide, COz
to
andwater,
H2O.
Propana, cslla mengalami pembakaran lengkap untuk menghasilkan karbon
dioksida, COzdan air, H2O.
calculate the volume of carbon dioxide producedwhen 0.5 mol propane burns
completely roomtemperature.
at
[Molarvolume = 24 dmsmol'latroomtemperature]
Kira isipadu gas karbon diaksidayang terhasil ipabila 0.5 mo! propana terbakar
dengan lengkap pada suhu bilik
molar= 24 dm3mollpadasuhu bilik]
fisipadu
I

72.0 dm3

36.0 dm3

24.0 dm3

12.5dm3

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39 \Nhat is the oxidationnumberof X in X,.'ot?ion?
Apakahnombor pengoksidaan
bagiX dalam ion XrOrz-?
A+3
B+4
C+5
D+6

40 Table2 shovrrs temperature


the
readings the reaction
for
between cm' of 0.1
25
moldm3hydrochloric and25 cm3 0.1moldm-3
acid
of
sodium
hydroxide
solution.
Jadual 2 menunjukkan
bacaan suhu untu? tindak batasdi antara 25 cm3 asid
hidroktorik mol dm'3 dan 25 cmr larutannatriumhidroksida mol dmn.
0.1
0.1
Averageinitialtemperature
beforebothsolutions mixed
are
Suhu awaI kedua-dua larutan sebelum dicampurkan

300c

Highest
temperature bothsolutions mixed
after
are
dicampurkan
Suhuteftinggi
larutanse/epas

43"C

Table2
Jadual2
Calculate heat produced
the
from the reaction.
Krakan haba yang terhasil daripada tindak balas tersebut.
A

oC-l x 13oC
25cm3 x 4.2J g-1

25cm3 x 4.2J g-1oC-l x 43oC

oc-1x 13oC
50cm3 x 4.2J g-1

50cm3 x 4.2J n-l og-r x 43oC

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4547t1

41 Diagram15 shovrethe molecularformulaof an organiccompound.


Rajah 15 menunjukkan formula moteku!hagi suafu sebatiai organik

csHz czHs
coo
Diagram
15
Rajah t5

Thecompound an ingredient making


is
jam.
in
pineapple l/r/trat the function the
is
of
compound?
sebatian itu adalah suafu bahandalam penyediaan
jem nenas. Apakahfungsi
sebatian
tersebut?
To make the jam thicker
Untuk memekatkan jem
To enhancethe flavor
Untuk menambah pertsa
To preventoxidation
Urttuk m engelakkan pep

ksidaan

To sweetenthe jam
Unfuk menambah kemanisanjem

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4s41t1

42
Substance
Bahan

Meltingpoint/oC
Takat lebur/" C

Boilingpoint/ "C
Takatdidih/ "C

-123

7B

,10

104

59

224

120

445

Table
3
Jadual3
Whatarethe physical
states substances X, Y andZat 11e"C?
of
W,
Apakahkeadaan
fizikalbahanW,X, Y dan Z pada 119 C?

Liquid
Cecair

Solid
Pepejal

Gas
Gas

Gas
Gas

Solid
Pepejal

Liquid
Cecair

Gas
Gas

Solid
Pepejal

Liquid
Cecair

Liquid
Ce air

Gas
Gas

Gas
Gas

Gas
Gas

Gas
Gas

Liquid
Liquid

Solid
Pepejal

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43 Table4 shornc percentage massof eachelement a compound their


the
by
in
and
relative
atomic
masses.
peratusanmengikutjisim bagi sefi.bpunsur dalam safu
Jadual 4 menuniukkan
sebatian jugajisim atomrelatifmasingrmasing.
dan
Elements
Unsur

Relativeatomic lmss
Jisim atom relative

26.70

Percentage(%)
Peratus(T)

2.20

71.10

12

16

Table4
Jadual 4
\Mrat is the empiricalformulaof the compound?
Apakah formula empiik untuk sebatian tersebut?
A

CHO

cH()2

cH20

CzHO

44 ElementZ forms an oxide with the chemicalformulaof 2203.\Attrich the following


of
is true aboutthis oxide?
Unsur Z membentuk oksida dengan formula molekul ZzOs. Antara yang beikut,
yang manakah henar tentang oksidaini?
A

The oxide of Z reactswith acid only.


Oksida Z bertindak balas dengan asid sahaja.

The oxide of Z reactswith alkali only.


Qksida Z beftindak balas dengan alkalisahaja.
The oxideof Z reactswith bothacid and alkali.
Oksida Z bertindak balas dengan kedua-dua asid dan alkali.
The oxide of Z does not react with both acid and alkali.
Oksida Z tidak bertindaKbalas dengan kedua-dua asid dan alkali.

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4541t1

45 Atom X has an electron


arrangement 2.4. Atom Y has protonnumberof 17.What
of
are the properties the compound
of
formedbetween
elements and Y?
X
Atom X mempunyai susunanelel<trom Atom Y mempunyainomborproton 17.
2.4.
Apakah ciri-ciri sebatianyang terbentuk antara unsur X dan unsur Y?
I

point.
lt has highboiling
la mempunyaitakat lebur yang tinggi.

ll

lt does not conductelectricity.


la tidak boleh mengkonduksi elektrik.

lll

lt does not exist as a solidat roomtemperature.


la tidak wujud sebagai pepejal pada keadaan bilik.

lV

lt is soluble organic
in
solvent.
la larut dalam pelarut organik.

I and ll only
I dan II sahaja

lll and lV only


lll dan lV sahaja

l, ll and lll only


l, ll dan lll sahaja

ll, lll and lV only


ll, lll dan lV sahaja

46 The electrolysisof copper (ll) sulphatesolution was carried out using copper
electrodes.What the observation anodeand the productat cathode?
are
at
Eleldrolisis larutan kuprum (ll) suffat menggunakan elel<trod-elel<trod
kuprum
pemerhatiandi anod dan hasildikatod?
dijalankan.Apakah
Observation anode
at
Pe,msrhatian
dianod

Productat cathode
Hasitdikatod

Electrodebecornes
thicker
Elel<trod
menjadi lebih tebal

Coppermetal
Logam kuprum

Electrode
becomes
thinner
Electrode
menjadilebihnipis

Coppermetal
Logam kuprum

gas bubbles
Colourless
Gelembung gas tidak berwarna

Oxygengas
Gas oksigen

gas
Colourless bubbles
gas
Gelembung tidak berwarna

gas
Hydrogen
Gas hydrogen

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47 The equationbelow shoue the reactionbetrrr,een


magnesium
and hydrochloricacid.
Persamaandi bawah menunjukkantindak batas di antara magnesium dan asid
hidroklorik.
Mg +

2HCl -'

MgCl2 +

Hz

lf 0'48 g of magnesium used,calculate volumeof 0.5 mol dm-3


is
the
hydrochloric
acid
needs be added complete
to
for
reaction.
atomicrnss : H=1: Mg=24;Cl=35.5]
[Relative
Jik10.a8 g magnesium
digunakan,
hitungkln isipaduasidhidroktonkO.S dm'3yang
mol
perluditambah
untuktindakbalas
yanglengkap.
fJisin atomrelatif.'H=1;Mg=24;Cl=35.5]
A

0.08cm3

0.8 cms

Scmo

B0 cm3

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48

4541t1

Diagram16 shows the set up of the apparatus


forthe action of heat on zinc carbonate,
After a few minuteslime water turns cloudy.
Rajah16 menunjukkansusunan
radas bagikasan habake atasbahan W.
Se/epas beberapaminft air kapur menjadi keruh.

tI

I
Lime
water

Heat
Panaskan

Diagram
16
Rajah'16
The mass of the boilingtube with the contentbeforeand afterthe heatingis recorded
in
Table 5 below.
Jisim tabung didih dengan kandungannya sebelum dan se/epas dipanaskan dicatatkan
dalam Jadual 5 di bawah.
Beforeheating
Sebelumpemanasan
Afterheating
Se/eoasDemenasan

31.25s
2O.259

Table 5
Jadual 5
Calculate volumeof the gas released dm3at roomtemperature.
the
in
[Rejativeatomic mass: c=12; o=16; Zn=65; Molar volume at room temperature= 24
dm'mol'tl
Hitung isipadu gas yang terbebas datam dmspada suhu bitik.
[Jisim atom relatif:c=12 0=16; zn=65; lsipadumolarpada suhu bilik= 24 dmsmoIl]
A3

11
12

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4(t Qiagrarn shoruE ironnailsintesttubes, e, R andS.
p,
18
four
menuniukkan
empatpaku
diletakkan oaam empat
ai
tabung
uji
laigh16
P,Q RdanS"

+
Hotjellysolution potassium
hexao/anofenate(lll)
solution
Larutan
+
panas larutan
agar-agar
kalfumheksdsilnofent(ilt)

#{\

lronnail
withsilver
Pakubesi
dengan
argentum
P

lronnail
withlead
Pakubesi
dengan
Plumbum

lronnail
lron naifwith
withzinc
magnesium
Pakubesi
Pakubesi
dengan
zink dengan
magnesium

Diagram
16
Rajah
16
whichtesttubeshows highest
the
intensity bluecolouration a day?
of
afier
TaPu!1g manakah
yang mempunyai
ieamatanwamabii yang tiiggi setepas
.uii
satuhari?
AP
BO
CR
DS

,i

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heated using methanol,


a
50 Table 6 shovrrs data recordedwtren 100 cm3of water rltras
CH3OH a fuel.
as
Jadual 6 menunjukkan data yang direkodkan apabita 100 cm3 air dipanaskan
dengan menggunakanmetanol, CH3OHsebagaibahan api.
Massof vrrater

JEim air

g
10O

of
I
Change temperature r,trater,
in
Perubahan
suhuair,0

20 0c

Massof methanolburnt
Jisimmetanolterbakar

0.32
s
Table 6
Jadual 6

\Alhatis the heat of combustionof methanolin the reaction?


Apakah haba pembakaran metanol di dalam tindak balas tersebut?
molarmass of methanol,
CHOH is
of
4.2
heat capacity solution: J g'1oC-1;
[Specific
32 g mol-l1
4.2
tHiba kapasffispesifik larutan: J g'1"CI;Jisim molar metanol,CH3OH adalah
32 g mofll
A

0.84 kJ nrcl-r

8.4 kJ mol-r

84 kJ mol'l

840 kJ mol'l

END OF QUES'IIQNPAPER
KERTAS SOALAN TAMAT

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Nam a:. . . . . . . , . .
.

Kelas:

n
t t lt

PELAJARAN
JABATAN
NEGERI
JOHOR

tl ttl

,
,

v r t a- l

w-

,L>

\---.-/

PEPERIKSAAN
PERCUBMN 2011
SPM
CHEMISTRY
Kertas
2
September

454112

2%jan
jam
Dua tigapuluh
minit
BUKA
JANGAN
KERTAS
SOALAN SEHINGGA
INI
DIBERITAHU
pada
1, Tuliskan
nama tingkatan
dan
yangdisediakan.
ruang
2. Kerfas
iniadalah
soalan
dalam
dwibahasa.
3. Soa/an
/nggens
dalam
bahasa
mendahului yangsepadan
soalan
dalam
bafiasa
Melayu.

Untuk
Kegunaan
Pemeriksa
Markah Markah
Bahagian
Soalan
Penuh Diperoleh
1

4 . Ca n dibe r{<ame ab
lo
na n njaw

kesel
uruhan sebahagian
atau
soalan
sa/na dalam
ada
bahasa
lnggeis bahasa
Melayu.
atau

10
10
2A
20

2A

10

20

5. Calon
membaca
dikehendaki

maklumat halaman
di
belakang
keftas
ini.
saalan

10
10
10
10

Jumlah

Kertas
soalan mengandungi29
ini
halaman
bercetak

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SectionA
Bahagian A
[50 marks]
160markahl
Ansvr,er questions thissection.
all
in
Jawab semua soalandalambahagian
ini.
1 (a)

Diagram showsthe manufacture ammonia.


1.1
of
pembuatan
Rajah 1.1dibawah menunjukkan
ammonia.

The unreacted and H2


N2
N2 dan H 2 yang tidak bertindak balas

-l
H2gas
Gas H2

_l

Mixture
of
Nzand Hz
200 atm

lroncatalyst

450r

Campuran
N2 dan H2

200atm

Mangkinbesi

45eC
Liquid
ammonia
Cecairammonia

Diagram
1.1
Rajah1.1
Based Diagram :
on
1.1
Berdasarkan
Rajah 1.1 :
(D

process.
Namethis industrial
Namakanprosesindustriini.
[1 mark]

(iD

State the names of reactantsused.

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3
Nyatakan nama unfuk bahan-bahan tindak balasyang digunakan.

[1 mark]
(iiD Theammonia formed condensed separated.Jhy?
gas
is
and
\
yang terhasildikondensasikan diasingkan.
Gasammonia
dan
Kenapa?
[1 mark]
(iv) Write two main uses of ammonia.
Tuliskan dua kegunaan utama ammonia,

[2 marks]
(b)

Diagram1.2 showsthree sourcesof traditional


medicines.
Rajah 1.2 menunjukkan tiga sumber ubat tradisional.

o
Diagram
1.2
Rajah1.2

Matchthe threesour@sof traditional


medicine theirusesby usinga line"
with
P adankan ketiga-tiga contoh-contoh sumber dengan keguna anny a.

Curesorethroat
Treatskinwounds
Merawatluka kulit

(c)

Thefollowing
shows
fourexamples modern
of
medicines.

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4
Di bawahmenunjukkan
empatcontohubatmoden.
Haloperidol n
Haloperidol Paracetamol l--l
Paracetamol

Barbiturates
Barbiturat

Streptonrycin t_]
Strefromysin

pain.
Tick({) in the boxprovided
above indicate
to
analgesics relieve
that
yang mengurangkan
Tanda(l) di dalam kotakdi atasuntukubat analgesik
kesakitan.
[1 mark]

(iD Nameanother
example analgesics is usedin headache
of
that
and
tablets in
Whatis the sideeffectof this medicine?
coughmedicines.
yang digunakan
Namakancontohlain analgesik
dalamubat sakitkepala
dan
ubat batuk Apakah kesansampingan
contohubat ini?

[2 marks]
(iiD An attention
deficithyperactivity
disorder
childmaytake dextro-amphetamine,
a
psychothera
peuticmedicine.
Stateits functio
n.
Seorangkanak-kanak
hiperal<tif bermasalah
dan
kurangtumpuanbolehdiberi
a
t
ny
ubat dertroamfetamin,satu contoh ubat psikoterputik . Nyaakan fun gsi a.

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2

5
Diagram showspartof the Periodic
2
Tableof Etenrents.
V, \N,X,Y,Z and U do not represent actualsymbols the elements.
the
of
Rajah2 menunjul<kan
sebahagian
daipada JadualBerkala.
V, W, X, Y, Z dan U tidakmewakilisimbolsebenar
unsur berkenaan.
1

18

Diagram2
Rajah2
Using letters diagram
the
in
2,answer following
questions:
the
Denganmenggunakan
huruf-huruf
dalamrajah2,jawab soa/an-soalan
berikut:
(a)

(D

Vvhich
elementis a halogen?
Unsuryang manakahadalahhalogen?

[1 rarkl

(iD tMich elementis transition


elernent?
Unsuryang manakahlogamperalihan?

[1 rmrkl
(iiD \Mich elementis monoatomic?
Unsuryang manakahmonoatom?
[1 markl

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(b)

(D

Writethe electron
arrangement an atomof element
for
X.
Tuliskansusunaneleldronbagi atom unsurX.
[1 mark]

(iD write theformulaof the ionformed


froman atomof erenrent
X.
Tuliskanformulabagi ion yang terbentukdaripada satuunsur X.
[1 mark]
(c)

(D

\Mry are elements Y andZ placedin the sameperiod?


X,
MengapakahunsurX, Y dan Z terletakdalam kalayang sama?
[1 mark]

(ii) furangeelernents Y andZ according the decrease the sizeof atoms.


X,
to
in
Susununsur X, Y dan Z mengikutpengurangansaizatom.
[1 markl
(d)

(D

Writethe balanced
chemical
equation the reaction
for
betureen
element and
X
gas.
oxygen
percamaan
Tuliskan
kimia seimbang
bagitindakbalas antara
di
unsurX dan gas
oksigen.

[2 marks]
(ii) Elernent dissolves waterto produoe solution.
Z
in
a
Complete equation the reac.tion.
the
for
Zz + HzO

'-+

........ . . . . . . . . .+. . .
.

[1 mark]

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pointof substance In
Diagram shovrrs apparatus up to determine melting
3
the
set
the
X.
thisexperiment, X is heated
untilit changes molten
solid
to
state.
Rajah3 menunjukkan
susunanradasuntukmenentukan
takatleburbahanX. Dalam
ekspermen pepejalX dipanaskan
ini,
sehingga berubahkepadacecair.
ia

Thermometer
Termometer
Water
Air
Substance
X
BahanX

t- -

Boiling
tube
Tabungdidih

D ipanaskan
Diagram
3
Rajah
3

questions.
Based diagram ansu,er following
on
3,
the
jawab soalan-soalan
Berdasarkan
berikut.
rajah 3,
(a) Whatis the nameof the process
whensolidchanges moltenstate?
to
Apakah prosesapabilapepejalberubahmenjadileburan?
[1 mark]

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(b)

SolidX hasa nrelting


pointof 90oC. a testtubeof molten at 150oC allora,ed
lf
X
is
to
coolat roomtemperature,
PepeialX mempunyaitakat
leburg}o2. Sekiranya
tabunguji yang mengandungi
leburanX pada suhu 150oC
pada suhu bilik,
disejukkan
0

Sketcha graphof temperature


against
timefor the cooling molten
of
X.
Lakarkangraf suhu melawan masaunfukpenyejukanleburanx.

[2 marks]
(iD

Howto avoidsupercooling
process?
Bagaimanauntuk mengelakkan
proses penyejukanlampau?
[1 mark]

(iiD Drawa labelled


apparatus
set-upfor the cooling
process substance
of
X.
Lukissusunan
radas berlabel
unfuk proses
penyejukan
bagi bahan
X.

[2 marks]
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(c)

I
Particles
consist atom,molecule ions.\A/hy an atomneutral?
of
or
is
Zarah-zarah
terdiridaripad atom,molekulatauion. Mengapakah
a
atom adalah
neutral?
[1 mark]

(d)

A bromine
atomhas35 protons
and 45 neutrons.
Writethe standard
representation
of bromine
atom.
protondan 45 neutron.Tuliskan
Satuatombrominmempunyai3S
perwakilan
piawai
untukatombromin.
[1 mark]

(e) (D

Whatare isotopes?
Apakahisotop?
[1 mark]

(iD

Phosphorus-31 phosphorus-32 isotopes phosphorus.


and
are
of
Stateoneuse
of phosphorus-32.
Fosforus-3 dan fosforus-32
|
adatahisotopuntuk fosforus.Nyatakan
satu
kegunaan
fosforus32.
[1 mark]

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4

10

Thethermochemical
equation
represent displacement
the
reaction copper
of
fromcopper(ll)
sulphate
solution zinc.
by
Persamaan
termokimia
berikutmewakilitindakbalaspenyesdran
kuprumdartpada
larutan
Ruprum(ll)sulfatoleh zink
Zn (s) + Cusoa (aq) +

(a)

ZnSoa(aq) + cu (s)

AH=-190kJ/molr

Statethe meaningof heat of displacement.


Nyatakan maksud haba penyesaran.

.1markl
(b)

ls it an exothermic
reaction endothermic
or
reaction?
Adakahia tindak balaseksotermik
atauendotermik?
[1 mark]

(c)

Statetwo observations this experirnent.


in
Nyatakan
dua pemerhatian
dalamtindak balasini.

[2 marks]
(d)

Drawan energy
leveldiagram thisreaction.
for
Lukisgambarajaharastenagabagitindak balasini.

[2 marks]
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SU L I T
(e)

11
In the experiment,
excess
zinc povrder reacted
was
with25 cmsof 0.2 rnoldm'3
copper(l sulphate
l)
solution.
Dalam.eksperimen serbuk
itu,
zinkbertebihan
ditindakbalaskan
dengan23 cm3
larutan kuprum(ll)sulfat 0.2 mol dm'?.
Calculate heatenergy
the
released thisexperiment.
in
Hitungkan
tenagahabayang dibebaskan
didalam eksperimen
ini.
heatcapacity solution:4.2J og't'Density solution: g crn3]
of
[Specific
g-t
of
1
haba tentularutan:4.2 J g't oc-,;Kefumpatanlarutan: g cm'-1
lMuatan
t

[2 marks]
(b)

In another
reaction, was replaced
zinc
with magnesium reactwithcopper(ll)
to
sulphate
solution.
Predicf valueof heatof displacernent, andexplain
the
AH
why.
Dalam satu tindak balaslain, zink telah digantikandenganmagnesiumuntuk beftindak
balasdenganlarutankuprum(ll)
sulfat.
Ramalkan
nilaihaba penyesaran, dan terangkan
LH
mengapa.

[2 marks]

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12

Diagram shovvs flowchartfor the qualitative


5.1
a
analysis substance
of
X.
Rajah5.1 menunjukkan
cartaalir analisis
kualitatffbagisebatian
X.
Blackpowder
X
Serbuk
hitamX
ProcessI
Proses /

Add hydrochloric
acid, HCIsolution
Tambah larutan asid hidroklorik, HCI

Bluesolution
Y
Larutanbiru Y

Process
III
ProsesIII

Processll
Prosesll

Solution + Sodium
Y
hydroxide,
NaOHsolution
LarutanY + larutannatrium
hidroksida,
NaOH

Solution + Silver
Y
nitrate,
AgN()3
solution
LarutanY + Larutan
argentum
nitrat,AgNOs

\Mriteprecipitate
putih
Mendakan

Diagram
5.1
Rajah5.1

(a)

Basedon Diagram
5.1,
BerdasarkanRajah5.1,
(i)

Name the black povrderX.


Namakan serbuk hitam X.

[1 mark]
(ii)

Name process
the
l.
proses/.
Namakan
[1 mark]

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13

(iiD Writea balancEd


chemicalequation the reaction.
for

Tuliskanpersamaan
kimiayang seimbang
bagitindakbarasyangberlaku.
t2 marksl

(iv)

\Nhyis the blackpovrder addedin excessin the reaction?


X
Mengapaserbuk
hitamX ditambah
secaraberlebihan
dalamtindak balas
ini?
[1mar k ]

(b)

Based process
on
ll,
Berdasarkan
kepadaproses
ll,
0

Name process.
the
Namakanproses /a.
[1 markl

(iD

Writethe ionicequation the reaction.


for
Tuliskanpersdmaan
ionikbagitindak balasitu.
[1 mark]

(iiD

Howto obtainthe wtriteprecipilate the process


in
ll?
Bagaimanamendapatkan
mendakanputih dalam prosesini?
[1 markl

(c)

Based the process and process statethe cationandanionpresent solution


on
1
lll,
in
Y.
proses I danproseslll, nyatakan
Berdasarkan
kationdan anionyang hadirdi datam
larutan Y.
Cation
:
Kation

Anion
Anion
[2 marks]

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14

Diagram showsan experiment investigate factorthat influences rateof reaction.


6.1
to
a
the
Theexperiment repeated tinresat different
is
five
temperatures.
Raiah 6.1 menuniukkan
suatuekspeimen unfuk mengkajisatu faktoryang mempengaruhi
kadartindakbalas. Eksperimen diulangi
ini
sebanyak
lima kalipada suhuyang berlainan.

50 cm3of sodiumthiosulphate
solution
0.2 mol dm'3+ 5 cm3of sulphuric
acid 1
mo ld rn 3 .
50 cm3larutan natrium ti\sutfat 0.2 mol
dm's + 5 cm3 asidsulfurik 1 mol dma.

:_

Diagram
6.1
Rajah6.1
Table6 shovr,s temperature timetakenfor "X' rmrk to disappear
the
and
fromviewwhen
observed
vertically
fromthe top.
Jadual6 menuniukkan
suhu dan masayang diambit
unfuktanda"X' hilangdaripandangan
biladiperhatikan atas.
dari
Experiment
ERsperimen
1

2
3
4

TemperatureoC Tinre/ s
I
Suhu
/oC
Masa/ s
30.0
55.5
40.0
33.0
50.0
23.O
60.0
17.A
70.0
13.0
Table6
Jadual6

(a) Stateone observation


fromthis experiment.
Nyatakansatupemerhatian
daripadaeksperimen
ini.
[1 mark]

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(b)

15
Complete chemical
the
equation the reaction occurred.
for
that
pkan peraa aan kimia untuktindak baIas yang berlaku.
Lengka
m
+
Na2S2O3 HrSO4 +

[1 markl
(c)

comparethe rateof reaction


betueenExperiment and Experiment
1
5.
Bandingkadartindak balasantaraEkspeimenI dan Experimen
5.
[1 mark]

(d)

youranswer (c) using Collision


Explain
in
the
Theory.
jawapdnandapada (c) denganmenggunakan
Jelaskan
Teoriperlanggaran.

[4 marks]

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(e)

16
By using datain table6, drawthegraph temperature
the
of
against
timefor this
experiment the graphprovided
in
below.
jadual 6, lukiskangraf suhumelawanmasabagi
Denganmenggundkan
data dalam
eksperimen di dalamkerfasgrafyang disertakan bawah.
ini
di
[1 mark]

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17

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(0

Diagram6.2 shov'lsa @nversationbetweenUmmu and QistinaRajah 6.2 menuniukkan perbualan diantara Ummu dan Qistfna.
When I placed a small sized
egg in boilingraaterat 100oC,
it becomehard boiledwithin
12 minutes.

whenI placed
ButUmmu,
sarrp sizedegg in hotwater
at 70oC, took me a much
it
timethanyours.
longer

Apabila saya meletakkan sebiii


telur bersaiz kecil ke dalam air
mendidih pada 10fC, ia
menjadi keras dalam temPoh
12 minit.

TapiUmmu,apabilasaya
teluryang sarna
meletakkan
saizke dalamair panas
pada 70"C,ia mengambil
lebihlama daripada
,??asa
awak

6.2
Diagram
Raiah6.2
to
temperatures prepare
the
aboveare investigating effectof different
Threestudents
between
above,
statethe relationship
on
eggs.Based the conversation
hardboiled
egg.
hardboiled
and
temperature timetakento prepare
Re
suhuyang berlainan atasteluryang
meng4ajikesan
di
Tiga pelajar atassedang
perkaitan
arfara suhu denganmasa
perbualan
diatas,nyatakan
Berdasarkan
direbus.
telur rebus.
yang diambil untuk menyediakan

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18

SectionB
Bahagian B
l2Omarksl
Ansr,rier one question
any
fromthis section.
Jawab mana-mana
satu soalan
daripada
bahagian
ini.
(a) A student
wantsto carryout an experirnent electroplate ironkeywith silver.
to
an
pelajaringinmenjalankan
Seorang
satu eksperimen
untukmenyadursatu kuncibesi
denganargentum.
(i)

Statethe anode,cathode
and electrolyte mustbe usedto carryoutthe
that
experiment.
yang mestidigunakanuntukmenjalankan
Nyatakananad, katoddan elel<trolit
eksperimen
tersebut.
[3marks]

(ii)

Writethe half-equations the reaction the anodeandthe cathode.


for
at
persamaan
Tuliskansetengah
bagitindakbalasdi anoddan katod.
[2marks]

(iiD

Suggest vralBto obtain smooth


two
a
and beautiful
coating the ironkey
of
withsilver.
penyaduranargenfumyang rata
Cadangkan dua cara untukmemperoleh
dan cantikpada kuncibesi.
[2marks]

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19

SULIT
(b)

of
the
set-upusedto investigate reaction metal
7
Diagram showsapparatus
obtained
the observations
and
by
from
displacement its salt solution somemetals
in
fromthe experiment 1 minute.
belas
yang diguna4an
untukmengkaiitinda?
susunanradas
Rajah7 menunjukkan
logamtertentu
garamnya
oleh beberapa
larutan
penyesaran
ienis
logam daripada
'dai
dalamtempah1 minit.
yang di perotehdaripadaeksperimen
pemerhatian

Apparatusand observationafter I minute


Alat radasdan panerhatin selepasI minit

solution
sulphate

solid
Brown
deposited
Pepejal
perang
terenap

25 cmslarutan
kuprum(ll)sulfat
0.1moldm'"

Chemical
formulafor
product
aqueous
solution

MetalP
LogamP

25 cmsof 0.1 mol

Pz(SOa)g

solid
Brown

25 cm3of 0.1 nrol


drn3of coppe(ll)
solution
sulphate
25 cmslarutan
kuprum(ll) sulfa!
0-1moldm''

25 cm3of 0.1mol
dm3of Q sulphate
solution
25 cmslarutanQ
A.1
sulfat moldma

7
Diagram
7
Rajah

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20
(i)

givenin Diagram compare differences


7,
the
Based the infornution
on
between:
yang diberikan
perbezaan
Berdasarkan
dalam Rajah7, bandingkan
maklumat
di antara:
.

I and
Experiment ll,
EksperimenI dan Il,

Experiment lll.
I and
Eksperimen dan lll.
t

youranswer termsof:
Explain
in
jaunpanandadarisegi:
Terangkan
r

Position the elecfrochemicalseries.


in
n
Keduduka dalam sirieleldrokimia.

o Observation allthree
experiments.
in
ri
Pemerhatian dalam ketiga-tigae kspe men.
[8 marks]
(iD

ldentify
metalP andQ.
Kenal pastilogamP dan Q.
[2 marks]

(iiD

copper(ll)
sulphate
ln experiment 25 cm3 0.1moldm-3
ll,
of
solution
react
completely metalQ.
with
produced.
Calculate massof copper
the
Dalam eksperimen 25 cms larutan
!!,
kuprum(tt)sulfat0.1 mol dm-3
bertindak
balaslengkapdenganlogamQ.
Krakan jisim kuprumyang terbentuk.
atomicrrnss:Cu = 64]
[Relative
lJisim atomrelatif:Cu = 641
[3 marks]

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21

(a) A covered jar contains molof ammonia


gas
gas,NH3.
1.5
gasbertutupmengandungil.Smolgas ammonia,NH3.
Satubalang
Howmanyammonia
molecules therein the gasjar?
are
Berapakah
bilangan
molekulammonia dalambalang gas tercebut?
di
[2 marks]
(b)

Urea,CO(NH2)2,
?rrltTlonium
nitrate,
NH+NOs hydrazine,
and
N2Ha fertilizers
are
that
are used in agriculture.
\Mich fertilizerhas the highest percentagemass of
nitrogen?
Urea, CO(NH)z, ammoniumnitrat, NHNO1 and hydrazin, Nzlta
adalah bajayang
digunakan dalam pertanian. Baja yang manakah mengandungi peratusjisim
nitrogenteftinggi?
[4 marks]

(c)

Diagram shorne electron


8.1
the
arrangement molecules and B.
of
A
Rajah8.'l menunjukkan
susunan
eleldron
bagimolekulA dan B.

eO eO
A
Diagram
8.1
Rajah8.1
Elased diagram
on
8.1:
Berdasarkan
rajah8.1;
Statethe typeof covalent
bondin eachrrclecule
and explain
why.
Nyatakanjenis ikatankovalendalam setiap
molekuldan terangkan
mengapa.
[4 marks]

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(d)

22
Diagram shorars formula trapdifferent
8.2
the
of
compounds.
Rajah8.2 menunjukkan
formulabagidua sebatian
berbeza.

KzO

SOe

Diagram
8.2
Rajah8.2
Based Diagram
on
8.2:
Berdasarkan
Rajah8.2:
(i)

Compare contrast two compounds termsof physical


and
the
in
statesat room
point,
temperature,
rnelting
electricalconductivity solubility water.
and
in
Bandingdan bezakedua-duasebatian
dari segi keadaan
fizikalpada suhu
bilik, takatlebur, kekonduksian
elektrikdan kelarutan
dalamair.

(iD

Explain differences the melting


the
pointfor the tvr,rc
of
compounds.
perbezaantakatleburbagikedua-duasebatian.
Terangkan
,

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23

SULIT

Section C
Bahagian C

BOmarksl
Ansvr,er onequestion thissection.
any
from
Jawab mana-manasatu soalandaripadabahagianini.

(a) Diagram showsa structuralformulabutene,


9.1
of
Rajah9.1 menunjukkan
formulastrukturbagi butena.

llrl
tl

HH

H- C- C- C:C- H
HH
Diagram
9.1
Rajah9.1
Drawanother structural
two
formulae butene writetheirrespective
of
and
names
according the IUPAC
to
nomenclature.
Lukisdua formulastrul<tur bagi butenadan tuliskan
lain
nama masing:masing
penamaan
berdasarkan
IUPAC.
[4 marks]
(b) Diagram shows structural
9.2
the
formula an ester.
of
formulastrukfurbagisuatuesfer.
Rajah9.2 menunjukkan
HHOHH

tti l

tl

H -C - C- C- O- C- C- H

rttl

HHHH
Diagram9.2
Rajah 9.2

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24
Based diagram
on
9.2:
Berdasarkan
rajah 9.2:
(D ldentify tvrrc
the
organic
chemicals
needed produce esterabove.
to
the
Kenalpasti
dua bahan kimia organikyangdiperlukanunfuk menghasitkanesterdi
afas.
[2 marks]
(iD Statetwo chemical
properties eachorganic
for
chemicats you statedin
that

e(bxD.

Nyatakan
dua sifatkimiabagisefiapbahankimiaorganikyang andanyatakan
datam9(b)(il.
[4 rmrksl
(c) You are givenan apparatus chemicals follow:
and
as
Anda diberikanalat radasdan bahan-bahan
kimia sepefti
berikut
Apparatus: tube,dropper.
test
Radas;tabunguji, penitis
chemica Bromine trichlo
ls:
in
roetha acidif potassium nganate(vl
ne,
ied
ma
l)
solution
Bahankimia:bromindalamtrikloroetana,
larutankaliummanganat(Vtl)berasid
Describe chemical
two
testsusingthe apparatus chemicals
and
givenaboveto
differentiate
between
hexane
and hexene.
Yourdescription
mustinclude procedure observation.
the
and
Huraikandua uiian kimia menggunakanalat radasdan bahan kimiayang diberikandi
atasuntukmembezakan
antara heksana
dan heksena.
Dalamhuraiananda mesiti
prosedurdanpemerhatian.
diseftakan
[10marks]

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10

25

(a) Diagram
10.1showsthe apparatus
set-up a voltaic
for
cetl.
Rajah 10.1menunjukkan
susunanradasuntuksafase/ voltan.

MetalA
LogamA

Copper
kuprum

Aqueous
solution
AYz
Larutanakueus
AYz

Aqueous
solution
CuY2
Larutanakueus
CuYz
Diagram
10.1
Rajah10.1

MetalA is rnoreelectropositive copper.


than
Suggest
one possible
cationfor X2*ion.
LogamA lebih eleffiropositif
daripadakuprum.
Cadangkansatu kationyang mungkinbagiion **.
Basedon the elec{rode
factorwhichaffeits the selec{ive
discharge ionsat the
of
electrode,
yang ma,nakah
Berdasarkan
fal<tor
elel<tod
pemilihan yang
mempengaruhi
ion
dinyahcaspada eleldrod,
(D Writethe halFequation the reactionat the electrode metalA.
for
of
Tuliskansetengahpersamaan
bagi tindak balasdi elel<tod
logamA.
(iD Statethe $pe,of reaction the anode.
at
jenistindak balasdi anod.
Nyatakan

[3 marks]

[1 markl

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(b)

26
Table10.1shotnrs result chemicaltests to change solution and
the
of
used
the
X
Solution
Y.
Jadual 10.1menunjukkan
keputusan
ujiankimiauntukmenukarkanlarutanX dan
larutan Y.
Experiment
Eksoerimen

Procedure
Prosedur
Bromine
urater addedintoX
is
solution warmed.
and
Sodium
hydroxide
solution addedinto
is
mixture
untilexcess.
Air brominditambahkan dalam
ke
larutanX dan dihangatkan.
Laruta natrium hidro ksid
n
a
ditambahkan dalamcampuran
Re
sehinggaberlebihan.

Observation
Pemerhatian

Green precipitate
formed
Mendakan hijau

brberrtuk

Zinc pourder addedintosolution


is
Y andthe mixture shaken.
is
Sodiumhydroxide
solution then
is
addedintothe mixture
until
precipitate
excess.
Brown
formed
SerbuKzink
ditambah dalam
ke
Mendakan
perang terbentuk
larutan Y dan digoneangkan
si,ehgga tiada perubshd tr.
in
Laruta natriumhidroksid
n
a
ditambahkan sehingg berlebi an
a
h
ke dalam campuran.
Table
10.1
Jadual10.1
Based Table10.1:
on
o ldentify solution andsolution
the
X
Y.
o Statethe reducing
agentin experimentandoxidising
I
agentin experimen
ll andgiveone reason eachof yourchoices
for
based the changes
on
of
oxidation
number.
Berdasarkan
Jadual I 0.I :
o Kenalpasti larutanX danlarutanY.
o Nyatakan
bahanyangbertindaksebagai
agenpenurunan
dalam
eksperimen dan agenpengoksidaan
I
dalam eksperimen serta beri satu
ll
pilihananda berdasarkan
sebabuntuk setiap
perubarhan
nombor
pengoksidaan.
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27

(c)
is
agent.
Chlorine goodoxidizing
yang baik.
agen pengoksidaan
Korin adalah
apparatus:
You are giventhe following
radasberikut:
Anda dibeikan alat-alat
galvanometer,
wires,stopper,
dropper,
carbonelectrodes
and
connecting
U-tube,
clamps.
retortstandwith
penyumbat,penitis,elektrod-eleldrod
wayarpenyambung,
TiubU, galvanometer,
karbondan Rakiretot dan pengapit.
an
chemicaland
describe experiment verifythe above
to
Suggest suitable
a
statement
usingthe givenapparatus.
untuk
Cadangkanbahan kimiayang sesual dan huraikan satu ekspertmen
yang diberi.
pernyataan atasdenganmenggunakan radas
alat
di
mengesahkan
[10marks]
ENDOF QUESTTON
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28

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Nama:

Tingkatan
:

JABATAN
PELAJARAN
NEGERI
JOHOR

PEPERIKSAAN
PERCUBAAN 2011
SPM
CHEMISTRY
Kertas
3
September

454t
t3

1%jax

Satujamtigapuluhminit

JANGAN
BUKAKERTAS
SOALAN SI|IilI'{GGA
INI
DIBERI.TATIU
1. Tuliskan
pada
namadantingkatan
yangdisediakan.
ruang
2. Keftas
ini
soalan adalah
dalam
dwtbahasa.
3. Soa/an
dalamBahasa
lnggerts
mendahului
yangsepadan
soalan
dalamBahasa
Melayu.
4. Calon
dibenarkan
menjawab
kesel
uruhan
afausebahagian
soalan
samaadadalamBahasa
lnggeris
atau
Bahasa
Melayu.
5. Calon
dikehendaki
membaca
maklumat halaman
di
belakana
kertas
soalan
ini.

UntukKeg
unaan
Pemeri
ksa
Soalan Markah Markah
Penuh Diperoleh
1

18

15

17

JUMLAH

Kertas
soalan
inimengandungihalaman
13
bercetak t halaman bercetak.
dan
tidak

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1 Table 1 shows the observations three test tubes used to investigate effectof
in
the
other metals on rusting.A mixtureof jelly solution,potassiumhexacyanoferrate(lll),
K3Fe(CN)6
solution and phenolphthalein
were used as mediumin each test tube. The
observations
luererecorded
afterone week.
Jadual I menunjukkanpemerhatian dalam tiga buah tabung ujiyang digunakan untuk
menyiasat kesan logam lain ke atas pengaratan. Medium yang digunakan di dalam
setiap tabung uji adalah campuran larutan agar-agar, larutan katium
heksasianoferat(lll), KsFe(CN)6dan fenalftalein. Pemerhatian direkod se/epas safu
minggu.
Testtube
Tabunq uii

Observation
Pemerhatian
1 week
1 minggu
4
--F\__

lron nailcoiledwith copperstrip


Paku besi dililit dengan
kepingan kuprum

1 week
I minggu
tl
lronnailcoiled
withzincstrip
Paku besi dililit dengan
kepingan zink

1 week
I minggu
ill

lronnail
Paku besi

Table 1
Jadual I
ReferenceiPetunjuk:lE*l
Blue spot I tompokbiru
r.TFf Pink spot I tompok merahjambu

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I
I

I
I

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E^F

for
(a) Stateone inference eachtesttubesl,.lland l1l.
Nyatakansatu inferensuntuksetiaptabung uiil, tl dan lll.

Examinefs
Use

Tesltube l:
Tabungujil:

Testtubell:
uji
Tabung It:

Testtubelll:
uji
Tabung IIt:

1(a)

tE
(b) Forthisexperiment,
state:
ini,
Bagi eksperimen nYatakan:
(i)

variable.
Thenunipulated
"
a
lehu
Pembo bah dimaniPYI si.

variable.
(iD The responding
k
u
Pem boleh bah bergera b alas.

(iiD The constant


variable.
Pembolehubahdimalarkan.

1(b)

m
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For
Examiner's
Use

(c) Statethe hypothesis theexperiment.


for
Nyatakan
hipofesls
bagi eksperimen
tersebut.

1(c)

m
(d) State the operational
definition the rustingof iron nail.
for
Nyatakan defrnisi secara operasibagi pengaratanpaku besi.

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(e) Diagram1 showsthe apparatus


set-up an experiment.
of
Rajah 1 menunjukkansusunanradasbagi satu ekspeimen.

rof

Examiner's
Use

Jellysolution Larutanagar-agar
/
+
potassium
hexacya
nofenate(ll K3Fe N)6solution
l),
(C
Iarutan kaIium he ksa anoferat(ttI), KsF CN)a
si
e(
Phenotphtha I fenotftatein
tJin

lronnailcoiled
withleadstrip
Paku besidililit dengankepingan
plumbum

Diagram1
Rajah I

Predict observation the experiment


an
for
aftera ueek.
Ramalkansatu pemerhatiandaripada eksperimen selepassatuminggu.
itu
1(e)

[E
Total
1

l1 |
I

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Fd

Examiner's
Use

Diagram shovra apparatus upforanexperimentdetermine endpoint


2
the
set
to
the
of
titration neutralisation
in
reaction.
Rajah menunjukkan
2
susunan
radas
satuekspeimen menenfukan akhir
bagi
takat
pentitratan
peneutralan.
dalam
tindak
balas

Burette
Buret

Hydrochloric
acid
Asidhidroklorik

Conical I kelalang
tlask
kon
50cm3 1.0rnol
of
dm-3
sodium
hydroxide
+
solutionphenolphthalein
50 cm3larutan
natium hidroksida moldm-3
1.0
+ fenolftalein

Diagram
2
Rajah2
(a) State
two observations youcould
that
obtain
during experiment.
the

yang
Nyatakan pemerhatian boleh
dua
andadapatisemasa
eksperimen.
,l

2(a)

[E

2.

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The experiment repeated


is
threetimesand the volumeof hydrochloric
acid usedfor
each set is shownin Table 2.
yang digunakanbagi setiap
Eksperimenitu diulangtiga kali dan isipaduasidhidroklorik
set ditunjukkanpada Jadual 2.
Set
Sef

Initial
reading
Bacaanawal

For
Examiner's
Use

Finalreading
Bacaanakhir

...cm'

,..cm'

.... cm3

......cm3

,..cm'

...cm'

II

ilt

Table 2
Jadual 2
(b)

Record burettereadings the spacesprovided Table 2.


the
in
in
Catatkanbacaanburetpada ruangyang disediakandalam Rajah2.

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For
Examinels
Use

(c)

Constructa table to recordthsdata from sets l, ll and lll.


The table shouldinclude
the initialreadlng,final readingand the volume of hydr,ochloric
used in the
titration.
Bina satujadual untuk merekod data bagisetl, ll danill itu.
Jadual tersebut
hendaklah mgngandungi bacaan awat, Sacaanakhir dan iipiii.asia
hidroktorik
yang digunakan dalam titratan.

14

W
1I
/

t4

/-

t/v
l/rl

rht

r-r

2(c)

rtr

ry

lft
(d)

The chemicalequationfor the reactionis shown below:


Persamaankimia tindak balasditunjukkandi bawai:"'
HCI + NaOH -,

N'
'1

NaCl + HzO

calculate the average,vorume hydrochroric


of
acid, HCrneededto neutrarise
-50 cm3of 1.0 mol dm-3sodiumtryciroxiOe,
NaOH ,of uiion.

Hitungkan isipa6.rl
pq!?tagagi aii d hidrokr
orik,i c i vii g'j iperrukan untu
k
meneutrarkan.s0rarutan
cm"
natrium
hidroksida mitd;-i, N;oH.'--'
t.o
2(d)

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(e)

ror
Examiner's
use

process,
During titration
statethe relationship
between concentration
the
the
NaOHsolution
withtimeuntiltheend
hydroxide OH-in sodium
ion,
hydroxide,
pointof titration.
Semasa prosespentitratan,nyatakanhubunganantarakepekatanion Ol-f dalam
larutansodiumhidroksida,NaOHdengan masasehinggatakat akhirpentitratan.

2(e)

m
(f)

and
Classify following
the
acidsintomonoprotic,
diprotic triprotic
acid.
berikutkepada asidmonoprotik,
diprotikdan triprotik.
Kelaskanasid-asid

Hydrochloric
acid
Asidhidroklorik

Sulphuric
acid
Asid sulfurik

Ethanoic
acid
Asid etanoik

acid
Nitric
Asidnitrik

Phosphoric
acid
Asid fosforik

acid
Monoprotic
Asidmonoprotik

Diprotic
acid
Asiddipratik

Triprotic
acid
Asid triprotik
2(f)

r-;
I

l3 l

Total
z

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10

Diagram shorus
2
some
samples battery.
of
Battery a voltaic thatcanbe built
is
cell
using trruo
any
different
metals suitable
and
electrolyte.
Raiah2 menuniukkan
heberapa
contohbateri.
Bateriialahse1'enr.s
yang
setkimia
boleh
dibina
mengguna&an
sebarang logamberlainan elektroft
dua
yang sesuai.
dan

Diagram
2
Rajah2
Voltmeter
reading voltaic depends thepairof metals
of
cell
on
usedas electrodes.
Bacaan
voftmeter
selRimia
pasangan
bergantung
kepada
logamyangdigunakan
sebagai
eleltrod.
Plan laboratory
a
experiment investigate different
pairs metalproduce
to
that
of
different
voltage a voltaic Yourplanning
of
cell.
should
include following
the
aspects:
Rancang
safu ekspermen
untuk menyiasat
pasangan
bahawa
logamyang berbeza
menghasilkanvoftan se/ kimia yang herbeza. Perancangan anda hendaklah
mengandungi aspeft-asp berikut:
ek
(a)
(b)

Hypothesis
Hrpofesrb

(d)

Listof material apparatus


and
Senarai
bahandanalatradas

(e)

Procedure
Prosedur

(t)

Allthevariables
pembolehubah
Semua

(c)

Problem
statement
Pernyataan
masalah

Tabulation data
of
Penjadualan
data
E HDOFQUE S T I OP A P E R
il
KERIAS SOALA,\,
TAMAT

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JABATANPELAJARAN
NEGERI
JOHOR

PERCUBAAN
SETARANEGERI
JOHOR2011
PEPERIKSAAN

SKEMAPEMARKAHAN
CHEMISTRY
PAPER1
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2011
JU LANG
JOHOR
CHEMISTRY
PAPERT
ANSWER

QUESTION
1

2
3
4
5
6
7
8

I
10
11

12
13
14
15
16

'17
18

19
20
21
22
23
24
25

ANSWER

QUESTION

26
27
28
29
30
31
32
33
34
35
36
37
38
39
40

41

42
43

A
C
A

B
B
B
A
D
A

D
D
A

c
D

ANSWER
A

B
C

B
D
A
A
A

c
B
D

B
D
B

45

46
47
48
49
50

D
B
D
B

c
c
A

c
B

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No.
Mark scheme
2 (a) (i)

Sub
mark
1

(ii)

(iii) W

(i)

2.8.1

(ii)

X*

(i)

Theyhavesamenumber shellsnbOloccupieO
of
witn
electrons

(ii)

x , Y , z il x > Y > z

(b)

(c)

Total
mark

(i)

(d)

4 X+ O ,
-* 2XzO ll
2 X + T "Q, + XeO

1+1

Conectreactants products 1
and
Conectlybalance 1
-

(ii)
Zz + HrO

---+ HZ +

HOZ

Total
Mark
No.

3 (a)

Markscheme
Melting

Sub
mark
1

10

Total
mark
1

3 (bxi)

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Correct
axiswithunits
graph and90oC stated
Correct
is

3(bxii)

Themolten is stirred
X
continuously
throughout
the
experiment

(iii)

4
I

Thermometer
Boiling
tube

Molten
X
Conicalflask
Labelleddiagram
Conect and func{ionalapparatus

1i
1l

3(c)

Because atomconsists an equalnumber


an
of
of
electronsand protons.

3(d)

80

Br
3(eXD

3(eXii)

35
Atoms of the same elementwith the same numberof
protons / proton number but different number of
neutronV
nucleon
number

Use in phosphate
fertilizers to studythe metabolism
//
of
I
phosphorus plants
in
Total mark

10

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Section A

(a) (i)

Haber

(iD

Nitrogenand Hydrogen

(iii)

To get a betteryield

(iv)

1. To make fertilisers
2. To produce nitric acid

1+ 1

(b)

Curesorethroat
Merawatsakittekak
Treatskin wounds
Merawatluka kulit
1
(c) (i)
(ii)

Paracetamor
lI

Codeine/ 3-methytmorphine

Addiction depressionnausea vomiting itching


/
/
/
/
/
drowsiness dry mouth / orthostatic
/
hypotension
/
urinaryretention miosis / constipation
/
(iiD

Activatelevelof alertness
//
Reduce
normalfatigue
ll
Elevate
mood
l/
Stimulate
activity brain centralnervous
of
/
system.

Total
mark

10

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MarkScheme

Sub
Total
Mark , Mark
:

Heatreleased
when1 moleof metal displaced its
is
from
saltsolution a moreelectropositive
by
metai.

44

t't:
ai

a: heatchange
exothermic
1. Brorrvn
soliddeposted.
2. Thecolour solution
of
change
fromblueto lightblue/
colourless.
3. Container
becomes
hot
4. Massof zinc decreased
5. Sizeof zincbecomes
thinner
two]
[Any
Energy

AH = -190 kJ mofl
ZnSOa+ Cu

o Conecttwo energy
levelsand axislabeled
energy.
. Conectreactants,
products valueof AH.
and
(0.2\(25]' 0.005
No.of mofe
CUSO+=
i/
mol
1000
=
Heatenergy
released 0.005
motx 190kJ mol'1il
= 0.95kJ / 950J
1. Valueof AH more higher
/
than-190kJ.
2. Magnesium moreelectropositive
is
compare in
zinc

electrochemical
series
/l
Distance
between
magnesium copper further
and
is
thanthe distance
between andcopper
zinc
in
electrochemical
series.

Total mark

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Sub
Mark

Total
Mark

5 (aXi) Copper(ll)
oxide

(ii) Neutralisation

4
t

No.

Mark Scheme

(iiD Conectreactants products


and
Balance equation
the
2 H C l+C u O)C u C l 2

+ HzO

(iv) To complete reaction


the

1
1

(ii)

(c)

Cation : Cu2*
Anion : Cf

1
1

(iiD Filtration

A g"+Cl-)A gCl

5(bXD DoubleDecomposition Precipitation


/
reaction

Total mark
No.
6 (a)

Mark Scheme

Yellowprecipitate

10

Sub
Mark
1

Total
Mark
1

(b)

+
NazSzOgHzSO+-+
NazSOe+ + HzO+ SO,
S

(c)

1. Rateof reaction Eiberiment is hiqher


for
5
than
Experiment (orviceversa).
1

(d)

1. Temperature Experiment is higher.


in
5
is
2. The kinetic
energy the particles higher.
of
2H*
3. Thefrequency collisions
of
between ionsandSzOr
ionsincreases
increases.
4, Thefrequency effective
of
collisions

1
1
4
I
I

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Temperature/oC

Time/s

(0

The higherthe temperature


the shorter timetakenfor the eggto become
the
hardboiledllvice versa

Section B
No,

Mark Scheme

7(a) (r)

(iD

Anode:Silver(rod/foil)
Cathde: lron key
Electolyte:Silvs nihatesolution
Anode : Ag +Ag' +s
Cathode: A g'+e*A g

(iiD 1. Usea smallelectricalcurrent


2. Uselow concentration the silvernitratesolution.
of
3. Turn the iron key slowlyduringexperiment.
out
beforecarrying
4. Cleanthe ironkeywithsandpaper
experiment.

Sub
mark
1
I
1

Total
Mark
3

1
1

Any two
7(b)

Experimentand ll
I

0
I

2. MetalP is more
in
1. Rateof reaction
experimentis higher
I
electropositive
with
in
compared metal
llThe reaction
experiment is faster
I
Q in the
elec'trochemical
series

1+1

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of
I 3. Deposit brown
metal morein
is
I
I

I
i
i

-.

expr;menl
I
compared
with
experiment
ll

Distancebetween
metals and Cu is
P
furtherthan metalQ
and Cu in the
electrochemical
series

1+1

Experiment and lll


I

Comoarison
5. Thereis a reaction
in
experimentand no
I
reaction
in
experiment
lll

Exolanation
6. MetalP is more
electropositive
compared copper
with
metalin the
electrochemical
series
7. Thereis brown
8. MetalPis placed
deposit experiment
in
higher
thancopper
in
I andno deposit
in
the electrochemical
experiment
fll
seriesl/ Coppermetal
is placedbelowmetal
R in the
electrochemical
series
Il metalP is more
electropositive
than Cu
(ii)

1+1

(iiD Molof CuSO+


=
solution t0.1\{SI ll 0.0025mol
1000
Ratio 1 molofCuSO+
:
produced molCu
1
produced
0.0025 of CUSO4
mol
0.0025 Cu
mol

1
1

MetalP :Aluminium,
Al
Me ta l Q:Z n l F e /S n
r: Pb

1+1

Massof copper = 0.0025


molx 64
= 0 .1 6
g

3
1
Total mark 2A

No.
8(a)
8(b)

Markscheme
=
The number molecules 1.5i6.0ZiT0F
of
= 9.03x 1023

Sub Total
mark mark
1
2
1

Urea,CO(NH2)2
2n4\
12 + 16 +(14+2)2

xl}Oo/o = 46.670/o

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Ammonium
nitrate,
NH4NO3
x 100o/o= 35.0olo

2(14],
14 +4 +1 4 +3(16)

N2Ha
Hydrazine,

zfi4\
+
2(14) 4(1)

lA9o/o = 87.5o/o

4
I

massof nitrogen
has
Hydrazine the highestpercentage
1. Double
bond
are
whentwo pairsof electrons sharedbetween
Formed
two non-metalatoms.

2- Triplebond
are
Formed
whenthreepairsof electrons shared
behreentwo non+netalatoms.

8(c)

8(d) (i)
Compound
1 Physicalslate
at
roomtemoerature
point
2 Melting
3 Eledrical
conductivity

KzO

Solid

SO,
Gas

1+ 1

High
Low
pointof KzO
Accept:A melting
SO,
is hiqherthan
Ganconduct Cannot
conduct
electricityin
moltenor
elecficityin all
state physicalstate
aqueous

Solubilitv water Soluble


in

1+1

1+1
1+1

lnsoluble

formto showcomparison.
can
Answers be in sentence
(d)

(ii)

KrO:
than
between
ionsin KzOis stronger
1. forcesof attraction
SO,
/
to
2. moreheatis needed overcome breakthe attraction
force
ll viceversafor SOz

1
1

Total mark

2
20
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9
Section G
No.

Sub Total
Mark Mark

Mark Scheme

9(a)

HHHH

tltl

But-2-ene

H - C - C :Q-C -H

tl

1+1

HH

HH

tl

H - C :C -C

- H

ll

IH
H- C-H

2-methylpropene
ll
2+netfrylpropl-ene

1+1

1+'t

H
(b)

acid, Ethanol
Propanoic

(ii) tAcceptif studentnamethe reactantsorthe productsl


properties propanoic
for
acid:
Chemical
producesalt and hydrogen
gas
1. Reactwithreadive metral
II
2. Reactwithbasesproduce and waterll
salt
metalprduce salt, carbon
3. Reactwith carbonates
gas
dioxide and waterll
4. Reactwithalcoholproduce
ester
[Anytwo answers]

1
1

properties ethanol:
for
Chemical
produce
1. Undergo
carbondioxide water
and
combustion
COzandHzO
// Bumtin orygento produce
produce
2. Undergo
oxidation
carboxylic
acidlethanoic
KzCrzOt
KMnOr to produce
acidIl Reactwith acidified
carboxylic
acid
produce
alkene ethene.
/
3. Undergo
dehydration
[Anytwo answers]

1
1

4
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with bromine
Reaction

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l0

1. Pourabout -5 cm"]of hexane a testtube.


into
[2
2. Add4-J dropsof bromine
waterandshake.
3. Observe changes repeat
any
and
withhexene.
Observation:
Hexane:
brown
colour
remains
unchanged.
Hexene:
Brown
colours
decolourise
/ turncolourless.
potassium
Reac'tion acidified
with
manqanate(Vl
l) solution
Procedure:
1. Pourabout 2-5cm3 of hexane a testtube.
into
[
]
2. Add 4-5 dropsof potassium
manganate(Vll)
solution
andshake.
3. Observe changes repeat
any
and
withhexene.
Observation:
Hexane:
Purple
colour
remain
unchanged
Hexene:Purplecoloursdecolourise.
[Anytwo tests]

No

l/lark scherne

10(aXD Sample
answer:

Sub
mark
1

Total
mark

MetalA: Magnesium/Mg
Mg -+ Mgt* + 2e
Readantand produc-t
conect
Balance equation
the
conectly
(ii)
(b)

1
4
t

Oxidation

Solution X : Ferum (ll) sulphatetreSOa

Solution Y : Ferum (lll) sulphate/ Fez(SO+h

!Ferum (ll) sulphate FeSOn lron(ll)


/
/
Reducingagent '. Fe2*
ion
Reason : oxidationnumber increasefrom +2 to +3

/
/
/
Oxidising
agent: Fe3* Ferum(lll) sulphate Fez(SO+)g
lron(lll)ion
numberdecreasefrom +3 to +2
Reason: Oxidation

1
1
.l
I

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l1

Galvanometer

Carbon
electrodes

Potassium
bromide
solution

Chlorine water

Dilutesulphuric
acid

U-tube

Conectand fundional apparatus


Conectly
labelled'

1
1

1. Suitable
chemical potassium
:
bromide
solution
//any
suitable
chemical
solution
2. Dilutesulphuric
acidis pouredintoa U-tube
3. A dropperis usedto fill one arm of the U-tubewith
chlorinewater
4. Potassium
bromidesolutionis addedcarefullyto
anotherarm of the U-tube
5. Botharm of the U-tlbe is fitted with carbonelectrode
6. Reducing
agent: potassium
bromide
solution
7. At negativeelectrode,
bromideions are oxidizedto
bromine
8 . 2BrBrz + 2e
9 . At positive
electrode,
chlorine reduced chloride
are
to

rcns

1
1

1
1
1
1
1
1

Max=
10

1 O .Cl2 +2e+2Cf

Totalmark

20

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4s4r/3(PP\

SULIT

JABATAN
PELAJARAN
NEGERI
JOHOR

PEPERIKSAAN
PERCUBAAN
SPM2011
CHEMISTRY
Kertas 3
September

4s4u3

SKEMA PEMARKAHAN

UNTT]K KEGTINAAI\IPEMERIKSA SAHAJA

pemarkahan SIILIT dan Hak Cipta Jabatan Pelajaran Negeri Johor.


Peraturan
ini
Kegunaannyaldtusus untuk pemeriksa yang berkenaansahaja.Sebarangmaklurnat
dalam peraturan pemarkahanini tidak boleh dimaklumkan kepadasesiapa.Peraturan
pemarkahanini tidak boleh dikeluarkan dalam apa-apabentukmedia.

Peraturan pemarkahan ini mengandungi18 halaman bercetak

454113 o 2011 Hak Cipta JabatanPelajaranNegeri Johor

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SULIT

4s41l3(PP)

Marking Scheme
Paper3

Question
1(a)

MarkScheme
Able to stateone inference each experimentfor

Score

Sampleanswers:
I

Testtube |

: lronrusuoxidised
lliron atomreleased
electron//
iron(ll)
ions/ Fe2*formed
//
iron(ll)
ionspresenU/rusting
occur

Testtubell : lrondoesnot rust// iron(ll)ionsarenot present


//
zincconodesIIzinc atomreleased
electron//
zincionsformedllzinc oxidised
Testtube lll

: lron rusuoxidised ironatomreleased


ll
electron//
iron(ll)ions/Fe2*formexJ
tlrustingoccur
ll
iron(ll)
ionspresent

Able to state any two inferences


Able to state any one inference
No response
orwrong response

4541/3 o 201 I Hak Cipta labatanPelajaranNegeri Johor

2
1
0

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SULIT

4541/3(PP)

MarkScheme
Question
1(b)
Able to statethe hypothesis
accurately

Score

Sample
answer
\A/hen morefless
a
electropositive
metalis in contact
with
ironfferum/Fe, metalinhibitV(speeds rusting/corosion
the
up)
of
iron ll
Whena more/less
electropositive
metalis in contact
with
iron/ferumlFe,
rusting ironlferumlFe faster/slower
of
is
ll

lf the metalin contact


withironis higherflower ironlferum/Fe
in
than
electrochemical
series, rusting/conosion ironis slower/faster
the
of
tl
The higherllower mdal in contactwith iron in electrochemicaf
the
is
series/thaniron/brum/Fe, rustingfconosion ironfierum/Fe
the
of
slower/fiaster
Able to state the hypotesis conectly
Sampleanswer
lMren a morcy'less
elec-tropositive
metal,the metalinhibits(speeds
up) rustinglconosion
otironll
lf the metalin contact
withironis higherthanironlferumlFe
in
reactivity
of
series,the rusting/conosion iron is slorerlf,aster//

is
The rustingof iron/ferumlFe faster/slower, a more/less
if
with ironfferum/Fe
electropositive
metalis in contact
Able to state the idea of hypothesis
Sampleanswer
withiron,will causeironto rust//
Different
metalin contact

Metalcancauseironto rust.
No responseor wrong response

:lt itl:,.

Pr lr i:,ir n

\g

g' i .1..i .
'

:ti-l-r:
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.SLIL[T

4541/3(PP)

Question
Mark Scheme
1 ( c)
Able to statethe threevariablescorrectly

Score

Sample
answer:
(i) Manipulatedvariables:
Type/different
metals position metalin electrochemical
//
of
series
a
J

(ii) Responding
variable:
Rusting conosion presence blue/pink
/
//
of
colour
(iii)Constant
variable:
Size/mass iron nail lltype of nailll cleanironnails//
of
temperaturemedium whichthe ironnailsarekept
//
in
Able to state any two variablescorrectly.

Able to state any one variablecorrectly.

No responseorwrong response

S{ILIT

I i:,1.
i'

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4s41l3(PP)

SULIT

MarkScheme
Question
Able to give the operationaldefinition accurately
1(d)

Score

Sampleanswer
withmetallowerthanironin electrochemical
\A/hen is in contact
iron
//
rusting
indicates
bluecolouration
series,

a
J

fless
with copper/tin
whenironnailis in contact
occurs
Rusting
metalandformbluecolouration//
electropositive
with metallower
is
Bluecolouration formedwheniron is in contact
series
thanironin electrochemical
Able to give the operationaldefinition correctly.
Sampleanswer:
ll
rusting
indicates
Bluecolouration

lless
withcopperftin
whenironnailis in contact
occutrs
Rusting
metal
electropositive
Able to give an idea of the operationaldefinition '

ggpte

l:

//
changes.
whenthe colourof solution
occurs
Rusting
occurs
Rusting
No responseorwrong rcsponse

PelajaranNegeri Johor
454113 @ 2011 Hak Cipta Jabatan

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4s4U3GP)

SULIT

MarkScheme
Question
Able to predic'tany one the obseruationsbasedon the
1(e)
laboratoryexperiment correctlY

Score

Sampleanswers
/l
BluespoUcolouration

//
smaller
lronnailbecomes
unchanged
Leadstripremains
Able to predict one observationsless correctly.
$ampleanswgl:

PinkspoUcolouration
Able to give an idea of observations.
Sampleansuter;

lron rus{s// BrowndeposiUspot


No responseorwnong response

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4s4113(PP)

SULIT

MarkScheme
Question
2(al
Able to state both two observationsaccuratelyduring the
experiment.

Score

Sampleanswer:
3
tumscolourless.
1. Pinksolution
warm/hot.
2. Conicalflask
becomes
during the
accurately
Able to state one obseryation
experiment.

Able to state any idea of obseruation.


Samoleanswer:
1- Volumeincreases
1

2. Pink
3. Colourless
4. Warm/hot
No responseor wrong response

454113 o 201I Hak Cipta Jabatan


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4s41l3(PP)

SULIT

MarkScheme
Question
2(b)
Able to recordthe burettereadingsaccurately
with 2 decimal
points.

Score
3

Answer
Set

Initialreadinq

Finalreadinq

0.00

26.00

0.50

24.50

til

5.50

30.50

Able to recordthe burettereadingscorrectly.

Answer
Set
I

lnitialreadino

Finalreadinq

0 // 4.0

26// 26.0

il

0.5

24.5

Iil

5.5

30.5

Able to record any readingfrom the the burctte completely.

SampleAnswer:
Set

Initialreadinq

Finalreadino

26

II

1 .5

25.5

ill

6.5

31.5

No response
orwrong response

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4s41l3(PP)

SULIT

Mark Scheme
Question
Able to makea tableto recordthe the datafrom three
2(c)
with units.
accurately
experiments

Score

SampleAnswer:
Set

lnitialreading/
cm-

Final reading/
cm-

0.00

26.00

HCI/
Volume
cmu
26.00

il

0.50

24.50

24.00

ilr

5.50

30.50

25.00

Able to makea table to recordthe data from three experiments


accuratelywithout units or correctlywith units.

Answer:

1.

Set

Initialreading

Finalreading

Volume HCI

0.00

26.00

26.00

il

0.50

24.50

24.00

ilI

5.50

30.50

25.00

Set

Initialreading/
cm-

0 // 0.0

ll

0.5

24.5

24// 24.0

III

5.5

30.5

25// 25.0

answer:

2.

Finalreading/
cm"
26// 26.0

HCI/
Volume
cm'
26// 26.0

Able to make a table to record any data including the


following:
-

Readingfrom 2(b)
Headingwithoutunits
Set of experimenl

or
No response wrongresponse

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Question

2td)

4s4r/3(PP\

10

SULIT

Score

MarkScheme
acid
volumeof hydrochloric
the
to calculate average
Able
accurately.
Answer:

+
+
cm3
26.00 24.00 25.00= 25.00
3
Able to state the averagevolume of hydrochloricacid
accuratelywith units,
2

@r:
25.00 cm3

acid.
volumeof hydrochloric
Able to state the ideaof average
: ' r ' :r

S a m p l e an sw e n

'

datafrorn2b)i + v {2
25.00 ll25.Ott25 tt (Awragereading
3
orwrongresponse
No response

' :'

'
0

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t1

SULIT

4s41l3(PP)

Mark Scheme
Question
Able to state the relationshipbetweenthe concentrationof
2(e)
with time until
NaOH
hydroxideion, OH-in sodium hydroxide,
point of titration accurately.
the end

Score

Sampleanswer:
with
ions/OHdecreases time. //
of
The concentration hydroxide

of
The longerthe timetaken,the lowerthe concentration hydroxide
ions/OHAble to staG tre relationship betweenfie concenfation
hydroxide ion, OH-in sodium hydroxide,NaOHwith time until
the end point of titration inaccurately.
Sampleanswer:

with
decreases time- //
The concentration
The longerthe timetaken,the loter the concentration
Able to state an idea of the relationship beturcenthe
concentrationhydroxideion, OH'in sodium hydroxide,NaOH
with time until the end point of titration.
Sampleanswer:

'l

//
decreases Lowerconcentration
Concentration
orwrongresponse
No response

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4s41l3GP)

l2

SULIT

Score
MarkScheme
3
diproticand triprotic
monoprotic,

Question
2(fl
acid accuratelY.
Answer:

Dioroticacid

acid
Monoprotic,

acid
Hydrochloric
acid
Ethanoic
Nitricacid

acid
Sulphuric

Trioroticacid
acid
Phosphoric

diProticand
to monoProtic,

into monoProtic,diProtic and

triprotic acid accuratelY.


triprotic acid accuratelY.
No responseor wrong response

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I3

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454u3(PP)

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MarkScheme
Question
give statement the problemaccuraGly.
of
Able to
3(a)

Score

Sampleanswer:
two
between metalsin electrochemical
Doesthe position/distance
ce?
differen II
reading/voltage/potential
series affectthe voltmeter
pair
between of metalsin
Doesthe positionldistance
reading/voltage/
seriesaffectthe voltmeter
electrochemical
potential
//
difference?
of
Doesthe furtherthe distance two metalsin electrochemical
potential
difference?
increase
the
series.
Able to give statementof the problem correctly.

Sampleanswer:
metalsin Electrochemical
between
Doesthe positionidistance
ge/potenti differen |I
ce?
al
n
readi g/volta
Seriesaffectthe voltmeter
affect
in
Doespairof metals electrochemicalseries the voltmeter
difference?
reading/voltage/potential
Able to give an idea of statementof the problemcorrectly

answer:
Sample
series
two
between metalsin reactivity
Doesthe position/distance
ce?
al
ltage/potenti differen II
read
affectthe voltmeter ing/vo
produce voltage.
a
Metals
orwrong response
No response

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t4

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4s41l3(PP)

eUe to state the three variablescorrectly


Sampleanswer:
variable: Pairsof metals
Manipulated
//
reading potential
//
variable:'Voltage voltmeter
Responding
difference
//
variable : Electrolyte the metalas the
Constant
//
positive/negative
terminal
of
volume concentration electrolyte
and
Abletbstate any two variablescorrectly
Able to stateany one variablecorrectly
No responseor wrong response

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l5

SULTT

4s41l3(PP)

variable
the
between manipulated
Able to statethe relationship
variableand statethe directionaccurately.
and the responding
Samplqanswer:
in
of
Thefurther distance the pairof metals the electrochemical
the
/
difference
reading potential
/
the
series, voltage voltmeter
greater.
//
becomes
the
series,
of
Thefurtherthe position twometalsin electrochemical
reading
difference
higherthe voltage/ potential
betweenthe manipulatedvariable
and without stating tfie direction.
and the respondingvariable
S3mpleanswer:
Series.
The distance the pairof metalsin the Elmtrochemical
of
readingI potentialdifference
the
inffuences voltage/ volfrneter
Able to state the idea of hypothesiscorrectly
Sampleanswer;
Series,
in
of
the
Thefurther distance electrodes the Electrochemical
potential
becomesdifference
reading
/
/
the voltage voltmeter
greater/smaller
/
reading potential
givedifferent
/
voltage voltmeter
metals
Different
difference
or
No response wrongresponse

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t6

SULIT

Question

3(d)

4s4113GP)

Mark Scheme

Able to give adequate of materials


list
and apparatus
that
involvesthe following
-

Score
3

Threesuitable
metals
calcium]
[below
Onesuitable
electrolyte
Voltmeter,
beaker,
connecting
wires,sandpaper
.

Onlytwo materials
and/orapparatus list outfrom
can
diagram.

Sampleanswer:
Aluminum,
zinc,copper,
copper(ll)
solution,
voltmeter,
beaker,
connecting
wires,sandpaper
Able to give a list of materialsand apparatusthat involvesthe
Following 3 items:
-

Two suitable
metals[belowcalcium]
One suitable
elec.trolyte container
and
Voltmeter

Sampleanswer:
Silver,iron , sivernitratesolution
voltmeter,
basinltest
tube
Able to give a list of materialsthat involvesthe following 2
items:
-

Two metals
Any namedelectrolyte

Sampleanswer:
Lithium potassium
and
llSilverandlead
Hydrochloric
acid
No response wrongresponse
or

454113 O 2011 Hak Cipta Jabatan


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L7

4s41l3(PP)

Question
MarkScheme
3(e)
Able to state the following 6 steps correctly.

Score

Sampleanswer:
1. Pour copper(ll)
sulphate
solution suitable
/
electrolyte
intoa container/beaker
2. Clean metalstrips/aluminium copperwith
the
and
sand
paper
3. Dip bothmetal/aluminium copperintothe electrolyte
and
4. Connect metals/aluminium copperto
the
and
the
voltmeter//complete circuit
the
5. Recordthe voltmeterreading
6. Repeat
steps1 to 5 by subtituting metalfor .
one
another/aluminium zinc
with
Able to state the following steps corectly basedon scoie &
-

Steps 1 or 3
Step4
Step5
Step6

Able to state the following steps conectly basedon score &

Step 1 or 3
No responseorwrong response

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Question

3tf)
I

18

4541/3GP)

MarkScheme
Able to exhibitthe tabulationof datawhich includesthe
following three information

Score
2

1. Heading the manipulated


for
variable
2. Examplesof two pairs of metals
3. Heading the responding
for
variable
with units
Sampleanswer;
Pairof metals/Electrodes

VoltageA/

Aluminium copper
and
Zincandcopper

Able to exhibit the tabulationof data which includesthe


following information

1. Heading manipulated
for
variable/responding
variable
without unit
2. Examplesof one pair of metals
Sampleanswer:
MetalVElectrodes

Voltage

Aluminium copper
and

No response
orwrong response

END OF MARKING SCHEME

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