XIII RT 6 PCM-16!02!2013 Advance Paper-2 Solution

XIII (XYZ) RT-6 JEE Advanced [Paper-II] Code-A Page # 1
PHYSICS
PAPER-2
PART-A
[SINGLE CORRECT CHOICE TYPE]
Q.1 to Q.6 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct.
[6 3 Marks = 18]
Q.1 A particle of mass m moving along a straight line is acted on by a retarding force (always directed against
the motion) F = be
!v
, where b and ! are positive constants and v is the velocity. At t = 0 it is moving
with velocity v
0
. At what time does it come to rest ?
(A)
b
m

" #
0
v
e 1
! $
$
(B*)
" # 1 e
b
m
o
v
$
!
(C)
b
m
0
v
e
!
(D)
b
m

0
v
e
! $
[Sol. m
dt
dv
= be
+!v
% & &
$ ' $
! $
0
0
t
0
0
v
v
dt
m
b
) v ( d e
1 e
0
v
$
!
=
m
bt
]
Q.2 A pebble is stuck to the edge of the uniform disc of radius R. The masses of both pebble and the disc is
same. Initially the pebble is at the topmost point. What is the maximum speed of the centre of disc during
the motion? (here disc does not slip on floor)
C
P
(A)
3
gR 4
(B)
3
gR 2
(C*)
3
R g 8
(D)
3
gR 16
[Sol. mg (2R) =
2
1
2
3
mR
2
(
2
( =
R 3
g 8
]
Q.3 The figure shows the elliptical orbit of a planet with the Sun at the focus. The areas of regions 1 and 2 are
the same. If the planet takes times t
1
to go from one end to the other end of region 1 and t
2
to go from
one end to the other end of region 2, then what is the relationship between t
1
and t
2
?
1 2
(A) t
1
< t
2
(B*) t
1
= t
2
(C) t
1
> t
2
(D) Cannot be determined
XIII(XYZ) RT-6 JEE ADV. PAPER2 DATE : 16-02-2014
PHYSICS
Q.4 A monatomic ideal gas is used as the working substance for the
Carnot cycle shown in the figure. Processes AB and CD are isothermal,
while processes BC and DA are adiabatic. During process AB, 400 J of
work is done by the gas on the surroundings. How much heat is expelled
by the gas during process CD?
(A) 1600 J (B) 400 J
(C) 200 J (D*) 100 J
Q.5 In the circuit (Fig), ) =5 V, r = 1 ohm, R
2
= 4 ohms, R
1
= R
3
= 3 ohms and C = 3 F. Find the charge
on the plates of each capacitor.
R
1
R
2
R
3
C C
C C
*
r
(A*) 6 C (B) 4 C (C) 2 C (D) Cannot be determined
Q.6 As pher i cal bob of mas s mand char ge q s us pended f r oma s t r i ng of l engt h
identical to that of the bob (Fig.). The angle between the string and the vertical is +. Find the angular
velocity of uniform rotation of the bob. It is given that
g
m
q K
2
2
'
(A*)
) ec cos (sec
g
3
+ $ +
(B)
+ sec
g
(C)
+ sec
g
(D)
g
PHYSICS
Sol.
T
F
E
mg
q
,sin+F
E
=m(
2

mgtan+
0
q 4
1
-
m ) sin (
q
2
2
+
=(
2

+ sec g

+ -
3 3
0
2
sin m q 4
q
= (
2
]
[PARAGRAPH TYPE]
[2 3 Marks = 6]
Paragraph for question nos. 7 to 8
For a given optical system, the principal axis is x-axis and coordinates of object are (30, +1, 0) and
coordinates of image are (+20, 2, 0). All coordinates are in cm.
Q.7 If the optical system is a concave mirror, it is located (x-coordinate) at what point ? [3]
(A) origin (B*) 80 cm (C)
3
40
$
cm (D)
3
40
cm
Q.8 If the optical system is a convex lens, what is its focal length ? [3]
(A) 12 cm (B) 10 cm (C)
3
100
cm (D*)
9
100
cm
[3 3 Marks = 9]
A mass m
1
is attached to the end of a light, rigid rod of length R. The rod is pivoted about its other end,
at a point height R above the surface of a horizontal, frictionless table. m
1
is initially held vertically above
the pivot point. A second mass m
2
, of mass equal to m
1
is at rest on the table, directly below m
1
, m
1
is
released from rest and swings down, counterclockwise as shown, making an elastic collision with m
2
.
R
m
1
m
2
h
PHYSICS
Q.9 Describe the motion of m
1
and m
2
after the collision.
(A*) m
1
comes to a stop and m
2
flies off in a parabolic path
(B) m
1
moves in clockwise direction now and m
2
flies off in a parabolic path.
(C) m
1
continuous to move in anticlockwise direction with lesser velocity and m
2
flies off in a parabolic
path.
(D) both m
1
and m
2
come to a stop.
Q.10 After m
2
is struck. it flies off the table, which is a height h above the floor. What is the speed of m
2
when
it hits the floor ? Express your answer in terms of R, g, and h.
(A) ) h R ( g 4 . (B) ) h R ( g 2 . (C*) gh 2 gR 4 . (D) gh 4 gR 2 .
[Sol. v =
gh 2 U
2
.
= gh 2 gR 4 . ]
Q.11 If instead of elastic collision, the two balls stick to each other, what is the maximum height reached by the
two masses after they collide in this case ?
(A*)
2
R
(B)
2
R
(C)
2
R 3
(D) R
[Sol. gR 4 m = 2mv / v = gR
MgH = 0
2
1
Mv
2
H =
g 2
v
2
=
2
R
]
PART-B
[MATRIX TYPE]
Q.1 has four statements (A, B, C, D) given in Column-I and five statements (P, Q, R, S, T) given in Column-II.
Any given statement in Column-I can have correct matching with one or more statement(s) given in Column-II.
[1 3+3+3+3 Marks = 12]
Q.1 A parallel beam of light of equal intensity consisting of two wavelengths 0
1
= 4000 and 0
2
= 8000
is incident perpendicular to the plane of both the slits in a typical Young's double slit experiment. The
separation between both slits is d = 2mm and the distance between slits and screen is D = 1 meter. In
each situation of column-I a point P on screen is specified by its distance 'l' from central bright fringe on
screen. Match each situation of column-I with the corresponding statements in column-II.
P
S
2

S
1

D
l
Central line
PHYSICS
Column-I Column-II
(A) At P such that l = 0.1 mm (P) Intensity is maximum for 0
1
= 4000
(B) At P such that l = 0.2 mm (Q) Intensity is minimum for 0
1
= 4000
(C) At P such that l = 0.4 mm (R) Intensity is maximum for 0
2
= 8000
(D) At P such that l = 0.6 mm (S) Intensity is minimum for 0
2
= 8000
(T) Intensity is maximum
[Ans. (A) Q (B) PS (C) PRT (D) PS ]
PART-C
[INTEGER TYPE]
Q.1 to Q.4 are "Integer Type" questions. (The answer to each of the questions are Single digits)
[4 4 Marks = 16]
Q.1 In the capillary tube of radius R = 0.5 mm a liquid rose to a height h = 11 mm. Estimate the density in (10
3
kg/m
3
) of the liquid, if its surface tension is 0.22 N/m. Take contact angle to be 60.
[Ans. 4]
[Sol. h =
g r
m 2
0 0
1
-
1 =
3 3
2
10 11 10 10 5 . 0 2
1 10 22 2
$ $
$
2 2 2 2 2
2 2 2
1 = 4 10
3
]
Q.2 Conductive rod OA rotates about the point O in the plane perpendicular to the magnetic field B = 1 T,
with an angular velocity ( = 300 rad/s. The free end of the rod slides along a circular arc of radius
R = 0.1 m (Fig). The arc between point C and point mounting rod included battery with EMF ) and the
internal resistance R, the direction of rotation rod and the direction of the magnetic induction are shown.
Resistance of rod, arc and contact is not taken into account. Determine the voltage V (in Volts) at the
terminals of the battery. (Write '2V' in OMR Sheet)
B
1
A
+
I
2
O
*3 r
C
R
5
[Ans. 3 ]
[Ans. 3 ]
[Sol.
2
1
B(R
2
]
Q.3 A pendulum consists of a disk of mass M and radius R and a massless rod of length l. Find approximate
time period (in sec) of the system if the disk is mounted to the rod by a frictionless bearing so that it is
PHYSICS
perfectly free to spin? Assume small amplitude. (Take : = 0.993 m, g = 9.8 m/s
2
)
R
M
0
[Ans. 2]
[Sol.
g
2 T - '
]
For Y1 , Y2 & Y3
Q.3 ,d vkn'kZ xSl pkj "ek xfrdh f;kvksa ds }kjk pf; ize dks iwjk djrk gSA bu lHkh izeksa ls lEca f/kr "ek,sa
e'k% Q
1
= 5960 J, Q
2
= -

5585 J, Q
3
= -

2980 J vkSj Q
4
= 3645 J gSA rFkk xSl }kjk fd;k x;k dk;Z
W
1
= 2200 J, W
2
=

825 J, W
3
=

1100 J

vkSj W
4
gSA rks ph; ize dh n{krk dk izfr'kr yxHkx eku
1 X izkIr gksrk gSA rks X dk eku fudVLFk iw.kkZd ds :i esa OMR Sheet esa Hkfj;sA
[Ans : 1]
Q.4 The concave side of a thin plano-concave lens with a radius of curvature of 50 cm is silver-plated to
obtain a convex mirror. An object is located at a distance of 100 cm in front of this mirror. If focal length
of equivalent mirror is 50/x cm. Fill the value of x in OMR. [Ans. 3]
[Sol.
) 1 5 . 1 (
f
1
$ '

6
7
8
9
:
;
$
50
1
=
100
1
$
f
1
=
f
2
+
m
f
1
=
6
7
8
9
:
;
$ $
100
1
2
+
50
2
1m
0
<=1.5
R=50cm
=
100
4 2 .
=
50
3
F =
3
50
]
PHYSICS
PART-D
[INTEGER TYPE]
Q.1 to Q.3 are "Integer Type" questions. (The answer to each of the questions upto Four digits)
[3 5 Marks = 15]
Q.1 A cylinder contains hot oil (density 1 = 2400 kg/m
3
, Specific heat S = 2100 J/kgC) at 70C. The
curved walls of the cylinder are adiabatic but the flat parts are made of conducting material. The area of
each flat parts = 7 cm
2
, k = 3W/mK, thickness of each flat part = 1mm and surrounding is at temperature
of 27C. Estimate the time (in sec.) in which the temperature of the container drops by 1C. (Round off
to nearest integer).
1m
[Ans. 0020]
[Sol.
dt
dQ
= ms
dt
dT
=
t
kA 2
(69.5 27)
2400 7 10
4
1 2100
t
1
=
=
3
4
10 1
10 7 3 2
$
$
2
2 2 2
(42.5)
=t =
5 . 42
10 700 1200
3 $
2 2
=
5 . 42
7 1202
~ 20 sec. ]
Q.2 Metal rod with a mass m = 10 g, and length L = 0.2 m is suspended by two light wires length l = 10 cm
in a magnetic field induction B = 1 T which is directed vertically downwards (Figure). A capacitor of
capacitance C = 100 F charged to a voltage of 100 V s connected as shown. Determine the maximum
deflection (in degree) of the rod from the initial position after the switch is closed. Resistance of wire and
rod is not taken into account.
[Ans. 37 ]
PHYSICS
[Sol. Bi L dt = mv ..........(1)
2
1
mv
2
=mg ..........(2) ]
Q.3 The primary winding of the transformer to power the radio receiver has 1200 turns with input voltage of
120 V. What should be the number of turns of the transformer secondary winding to power the lamp
filament, if it requires 3.5 V voltage and current of 1 A? Secondary resistance of 0.1 ohms. The loss in
the primary winding neglected.
[Ans. 0036 ]
[Sol.
2
1
2
1
n
n
'
*
*
*
2
= U
2
+ I
2
r
2
n
2
=
1
2 2 2 1
U
) r I U ( n .
; n
2
= 36 ]
CHEMISTRY
PAPER-2
PART-A
[6 3 Marks = 18]
Q.1 For the given conversion :
Me C OH
O
Me C H
O
Suitable options are :
(A) Reduction by LiAlH
4
(B*) Reaction with SOCl
2
followed by H
2
/ Pd-BaSO
4
(C) Catalytic reduction by H
2
/ Ni
(D) Reaction with PCl
5
followed by H
2
O
Q.2 Which of the following complex will give white ppt. with BaCl
2
(aq)?
(A) [Co(NH
3
)
5
SO
4
]NO
2
(B) [Cr(NH
3
)
5
SO
4
]Cl
(C*) [Cr(NH
3
)
5
Cl]SO
4
(D) Both (B) & (C)
Q.3 An element crystallizes in FCC with edge length equal to 1600 pm. Calculate maximum radius of an
atom which can fill the tetrahedral void without distorting the lattice.
(A)
pm 2 45
(B*)
pm 2 90
(C)
pm 2 180
(D)
2 90
Sol. For FCC
4r =
a 2
r =
4
a 2
= pm 2 400
4
1600 2
!
"
To fill the tetrahedral void without distorting the lattice,
radius of atom = 0.225 2 400 =
pm 2 90
Q.4
3
AlCl
MeCl
# # $ #
AA
A is
(A) (B) (C) (D*)
[Sol. Nitrobenzene do not react with an electrophile at room temperature. It is used as solvent for FC
reactions. ]
CHEMISTRY
Q.5 X + H
2
SO
4
#$ #
%
Y a colourless gas with irritating smell.
Y + K
2
Cr
2
O
7
+ H
2
SO
4
#$ Green solution.
[X] & [Y] are
(A*) SO
3
2
, SO
2
(B) Cl, HCl (C) CO
3
2
, CO
2
(D) All of these
Q.6 The value of Henry's constant for three different gases A, B & C at 298 K are 40.3 K bar, 1.67 K bar
& 1.83 10
5

K bar. Which of the following order is correct increasing order of solubility of the gases
in water?
(A) B, A, C (B*) A, B, C (C) C, B, A (D) C, A, B
Sol. As value of henry's constant K
h
increases, solubility of gases in water decreases. So order of solubility
A < B < C
[PARAGRAPH TYPE]
[2 3 Marks = 6]
In order to explain extent of adsorption theoretically Langmuir proposed an isotherm on the basis of
following assumptions.
(a) The adsorbed gas behaves ideally.
(b) Only a monolayer is formed by the adsorbed gas.
(c) Every adsorption site is equivalent and the ability of a particle to bind is independent of whatever
or not nearby sites are occupied.
(d) The adsorbed gas molecules are localised, i.e., they do not move around on the surface.
By considering equilibrium between the two opposite processes of adsorption & desorption, Langmuir
obtained that extent of adsorption (x/m) can be obtained as.
bp 1
p . a
m
x
&
!
where 'a' & 'b' are constants.
Based on this info, answer the questions that follow.
Q.7 Which of the following options is correct for Langmuir isotherm.
(A) At very low pressure
m
x
will become constant.
(B) At moderate pressures
m
x
will be linearly dependent on pressure.
(C*) At high pressures
m
x
should be constant independent of pressure.
(D) At high pressures
m
x
should be varying linearly with pressure.
Sol.
bp 1
p . a
m
x
&
!
At very high pressure
b
a
m
x
!
which is constant independent of pressure.
CHEMISTRY
Q.8 The graph of
x
m
v/s
p
1
has Y intercept equal to 2 10
2
& slope = 10
1
atm. What would be values of
a & b respectively in atm
1
.
(A) a = 10, b = 2 (B*) a = 10, b = 0.2
(C) a = 1, b = 0.2 (D) a = 1, b = 2
Sol.
a
b
ap
1
ap
bp 1
x
m
& !
&
!
' Slope =
a
1
Y intercept =
a
b
10
1
=
a
1
a = 10 atm
1
Also,
a
b
= 2 10
2
b = 2 10
2
10 = 2 10
1
= 0.2 atm
1
[3 3 Marks = 9]
Observe these compound and give answer of following questions.

OH CH
|
OH C H
|
OH C H
|
OH C H
|
CHO
2
( (
( (
( (

OH CH
|
OH C H
|
OH C H
|
H C HO
|
CHO
2
( (
( (
( (

OH CH
|
OH C H
|
H C HO
|
OH C H
|
CHO
2
( (
( (
( (
OH CH
|
OH C H
|
H C HO
|
H C HO
|
CHO
2
( (
( (
( (
D-ribose D-arabinose D-xylose D-lyxose

allose ) ( D
OH CH
|
OH C H
|
OH C H
|
OH C H
|
OH C H
|
CHO
2
&
( (
( (
( (
( (

altrose ) ( D
OH CH
|
OH C H
|
OH C H
|
OH C H
|
H C HO
|
CHO
2
&
( (
( (
( (
( (

glucose ) ( D
OH CH
|
OH C H
|
OH C H
|
H C HO
|
OH C H
|
CHO
2
&
( (
( (
( (
( (

mannose ) ( D
OH CH
|
OH C H
|
OH C H
|
H C HO
|
H C HO
|
CHO
2
&
( (
( (
( (
( (
gulose ) ( D
OH CH
|
OH C H
|
H C HO
|
OH C H
|
OH C H
|
CHO
2
(
( (
( (
( (
( (
idose ) ( D
OH CH
|
OH C H
|
H C HO
|
OH C H
|
H C HO
|
CHO
2
(
( (
( (
( (
( (

galactose ) ( D
OH CH
|
OH C H
|
H C HO
|
H C HO
|
OH C H
|
CHO
2
&
( (
( (
( (
( (

talose ) ( D
OH CH
|
OH C H
|
H C HO
|
H C HO
|
H C HO
|
CHO
2
&
( (
( (
( (
( (
Q.9 In the given Aldose which can form same osazone
(I) D-glucose (II) D-gulose (III) D-mannose (IV) D-galactose
(A*) I & III (B) I, III, IV (C) I, II (D) III, IV
[Sol. All C-2 epimers give same osazone. ]
CHEMISTRY
Q.10 A carbohydrate undergoes the following conversion.
D-Lyxose
HCl
NaCN
# # $ # 'A' # # # # # $ #
(
4 2
BaSO Pd / H
'B'
# # $ #
)
O H
3
'C'
'C' can be
(A) D-Galactose (B) D-Talose (C*) Both (D) None of these
Q.11 Which of the following is correct presentation of L-Gulose.
(A)
OH CH
|
H C HO
|
H C HO
|
H C HO
|
OH C H
|
CHO
2
&
( (
( (
( (
( (
(B)
OH CH
|
OH C H
|
H C HO
|
H C HO
|
OH C H
|
CHO
2
( (
( (
( (
( (
(C*)
OH CH
|
H C HO
|
OH C H
|
H C HO
|
H C HO
|
CHO
2
( (
( (
( (
( (
(D)
OH CH
|
OH C H
|
H C HO
|
OH C H
|
H C HO
|
CHO
2
( (
( (
( (
( (
[Sol. D-Gulose and L-gulose are enantiomers. ]
PART-B
[MATRIX TYPE]
[1 3+3+3+3 Marks = 12]
Q.1 Column I Column II
(Name of the compound) (Formula)
(A) Dead burnt plaster (P) CaCl
2
(B) Quicklime (Q) Ca(OH)
2
(C) Slaked lime (R) CaO
(D) Gypsum (S) CaSO
4
(T) CaSO
4
.2H
2
O
[Ans. (A) S (B) R (C) Q (D) T]
PART-C
[INTEGER TYPE]
[4 4 Marks = 16]
Q.1 Number of compounds, which can evolve CO
2
on heating, are.......
O
COOH
H C CH COOH
3
NO
2
H C CCH COH
3 2
NH O
CHEMISTRY
O
OH
H C CH COOH
3
CH COOH
2
COOH
COOH
Ph CH CH COOH
2
OH
HO C C OH
O O
H
3
C CH
2
COOH
[Ans.6 ]
Sol. (i)
O
COOH
*-Keto acid gives CO
2
+
(ii)
H C CH COOH
3
NO
2
*-Nitro acid gives CO
2
+
(iii)
H C CCH COH
3 2
NH O
*-imino acid gives CO
2
+
(iv)
O
OH
*-, unsaturated CO
2
+
(v)
COOH
COOH
1,6 dioic acid gives CO
2
+
(vi)
HO C C OH
O O
1,2,dioic acid gives CO
2
+
Q.2 Calculate at what approximate pH will 10
2
moles of Al(OH)
3(s)
will dissolve in 1 litre of solution if
K
sp
Al(OH)
3
= 8 10
33
& K
f
Al(OH)
4
=
8
10
36 &
. [Ans. 9]
Sol. Al(OH)
3(s)
! Al
3+
(aq)
+ 3OH
(aq)
; K
sp
= 8 10
33
Al
3+
(aq)
+ 4 OH
(aq)
! Al(OH)
4
; K
f
=
8
10
36
On adding two equations,
Al(OH)
3(s)
+ OH
(aq)
! Al(OH)
4
(aq)
, K = K
sp
K
f
= 8 10
33

8
10
36
K = 10
3
As K is very large Al(OH)
4
= 10
2
moles
Al(OH)
3(s)
+ OH
(aq)
! Al(OH)
4

(aq)
; K = 10
3
x M 10
2
M
10
3
=
x
10
2 (
- x = 10
5
M
' pOH = 5 - pH = 9
CHEMISTRY
Q.3
(A)
dil. HCl
(B)
g
H O
2 2
(C)White turbidity
Sodium nitroprusside
(D) Purple/Violet
Sb(NO )
3 3
Orange ppt.
Difference of the oxidation state of centre atom of Sodium nitroprusside and 'D' (Purple/Violet) are
[Ans. 0]
Q.4 An aqueous solution of TCl (Tritium chloride) dissociates to give T
+
& Cl. Tritium is radioactive
(*( emitter) with half life of 13 years. 2 litre of freshly prepared sample freezes at 0.744C. If TCl
undergoes 100 % dissociation then calculate number of * particles emitted in 26 years.
Express your answer as X 10
23
& fill X in the OMR.
K
f
for H
2
O = 1.86 kg mol K
1
, N
A
= 610
23
.
[Ans. 2]
Sol. %T
f
= i. K
f
.m
- 0.774 = 2 1.86 m
m = 0.2
0.2 =
2
n
TCl
- n
TCl
= 0.4
' &
T
n
= 0.4
After 26 year or 2 half lives, &
T
n
dissociated = 0.3
' number of moles of * particles = 0.3 moles
' number of * particles = 0.3 6 10
23
= 1.8 10
23
. 2 10
23
PART-D
[INTEGER TYPE]
Q.1 to Q.3 are "Integer Type" questions. (The answer to each of the questions upto Four digits)
[3 5 Marks = 15]
Q.1 Select the given code of reagents for following conversion and write your answer as abcd. If reagent is
used once then you need not to take it again.
#$ Monomer of polystyrene
(1) H
2
SO
4
(2) Zn(Hg) / HCl
(3) HNO
3
/ H
2
SO
4
(4) NaNO
2
/ HCl 05C
(5) N
2
H
4
/ H
2
O
2
(6) NBS
(7) Cl C Me
| |
O
( ( / AlCl
3
(8) Me
3
CO
!
Na
)
/%
[Ans. 7268]
CHEMISTRY
[Sol.
CH=CH
2

# # # # # $ #
( (
3
AlCl / Cl C Me
| |
O

CMe
# # # # $ #
&HCl ZnHg

CH CH
2 3

# # $ #
NBS
CHCH
3
Br
Me CO Na
3
! )
/%

CH=CH
2
]
Q.2
(A)
dil.HCl
HgCl
2
excess (B)
P
h
e
n
o
p
h
t
h
e
l
e
n
e
Phenophthelene
(B) Colourless
odourless gas
+ + H O (C)
2
gives
golden
yellow
flame
Ca(OH)
Lime water
2
(E)
(F)
Pink
colour
Brown
compound
White ppt.
(D)
No change
+ H O
2
Find :
Number of / bond in (A)
Number of 0 bond in (B)
Number of 0 bond in (A)
Number of / bond in (B) respectively
[Ans. 3212]
Sol. (A) = Na
2
CO
3
(B) = CO
2
(C) = NaCl
(D) = Ca(HCO
3
)
2
(F) = HgCO
3
.3HgO
Number of / bond in (A) = 3
Number of 0 bond in (B) = 2
Number of 0 bond in (A) = 1
Number of / bond in (B) = 2
CHEMISTRY
Q.3 At 298 K,
o
Combustion
H % (Sucrose) = 5737 kJ/mole &
o
Combustion
G % (Sucrose)= 6333 kJ/mole.
Estimate additional non PV work that is obtained if temperature is raised to 310 K. Assume %(nC
P
)
reaction
= 0 for given temperature range. Express answer in kJ. [Ans. 0024]
Sol. At 298 K,
%G = %H T%S
6333 = 5737 298 %S
298 %S = 596
' %S = 2 kJ/mol
If (%C
P
)
r
= 0
1 2
T T
S S % ! %
&
1 2
T T
H H % ! %
' At 310 K
%G = %H T%S
= 5737 310 2
= 6357 kJ / mol
' Additional non PV work = 6357 6333
= 24 kJ /mol
Only For Y3
Q.3 Born-Haber i in il ilni -i i~| | nii - li ini r| l +in
+-i Na = 26 kcal/g. atom, i li +i Cl
2
= 54 kcal/mole |, Na
(g)
| i +i =
117 kcal/ mol, Cl
(g)
| ;-i nri i~| = 84 kcal/g atom , NaCl | -i i~| = 99 kcal/
mole r ni NaCl i +i i l-ii (K. cal/mole) - i rini|
[Ans : 0185]
[Sol
LE
54
99 27 117 84 H
2
( ! & & ( & %
LE
H % = 185]
XIII_(XYZ)_RT-6_JEE ADVANCE_PAPER-II CODE-A PAGE # 17
MATHEMATICS
PAPER-2
PART-A
Q.1 The equation of common tangent to the curves y
2
= 20x and
120
y
25
x
2 2
! = 1 having positive gradient
is
(A*) 5 y = x + 25 (B) 5 y = x 25 (C) 5 y = x + 5 (D) 5 y = x 5
[Sol. y = mx +
m
5
(m > 0) .(1)
"
2
m
25
= 25m
2
+ 120 (using condition of tangency) # m =
5
1
. ]
Q.2 If the equation
x
1
x p
x
1
x
2
! !
$
%
&
'
(
)
* + 29 = 0 (p + R) has exactly four distinct real solutions,
then the true set of values of p is
(A*) $
%
&
'
(
) *
, *
2
29
,
- { 10} (B) { 10}
(C) $
%
&
'
(
) *
, *
2
29
,
(D)
$
%
&
'
(
)
,
*
,
2
29
[Sol. Put
x
1
x ! = t, we get, f(t) = t
2
+ pt + 25
Case-I: Now, one root is greater than 2 and other is less than 2.
So, f(2) < 0. Hence, p + $
%
&
'
(
) *
, *
2
29
,
Case-II: Both roots greater than 2 and equal.
Hence,
a 2
b *
> 2 and D = 0, p > 2
" p < 2 and D = 0 # p
2
100 = 0 # p = 10
So, p = 10
" The range of p is $
%
&
'
(
) *
, *
2
29
,
- { 10}.
Hence, the greatest integral value of p is 10. Ans.]
MATHEMATICS
Q.3 In triangle ABC, if (sin B + sin C)
2
sin
2
A =
2
R
4.
, then tan A is equal to
[Note: All symbols used have usual meaning in triangle ABC.]
(A)
2
3
(B)
2
1
(C)
17
8
(D*)
15
8
[Sol. We have,
.
* ) a s ( s
= 4 #
2
A
cot = 4. So, tan A =
15
8
. Ans.]
Q.4 The total number of words with three letters which are formed by using the letters of word IITJEE
such that no two vowels are together, is
(A) 12 (B) 16 (C) 18 (D*) 20
[Sol.
vowels
2 E , 2 I / / ; T = 1, J = 1
" Number of words formed = (
2
C
1
3!) + 2 (1 + 1) + (
2
C
1
2!) = 20. Ans.]
Q.5 If
dx
dy
=
2 x 2
3
y e
y
!
and y (0) = 1, then
(A*) y
2
= e
2x
2e
2x
lny (B) y
2
= e
2x
+ 2e
2x
lny
(C) y
2
= e
2x

2
1
e
2x
lny (D) y
2
= e
2x
+
2
1
e
2x
lny
[Sol.
dy
dx
=
3
2 x 2
y
y e !
# e
2x
dy
dx
=
x 2
3
e
y
1
y
1
*
!
put e
2x
= t #
y
t 2
dy
dt
! =
3
y
2
(L.D.E.)
t y
2
=
0
dy y
y
2
2
3
+ C
e
2x
y
2
= 2ln y + C Now y (0) = 1
# C = 1
" e
2x
y
2
= 2ln y 1 # y
2
= e
2x
2e
2x
ln y. Ans.]
Q.6 Let P (x, y) be a variable point on the curve 4x
2
+ 9y
2
8x 36y + 15 = 0,
then min. (x
2
2x + y
2
4y + 5) + max. (x
2
2x + y
2
4y + 5) is equal to
(A)
325
36
(B)
13
25
(C)
25
13
(D*)
36
325
[Sol. We have,
9
25
) 2 y (
4
25
) 1 x (
2 2
*
!
*
= 1
So, min. ((x 1)
2
+ (y 2)
2
) =
9
25
and max. ((x 1)
2
+ (y 2)
2
) =
4
25
. ]
MATHEMATICS
[PARAGRAPH TYPE]
Paragraph for question nos. 7 & 8
Let PQ be a variable focal chord of the parabola C
1
: y
2
8x = 0 and A be its vertex.
The locus of centroid of triangle APQ is another parabola C
2
.
Q.7 The length of latus-rectum of parabola C
2
is
(A)
3
2
(B)
3
4
(C*)
3
8
(D)
3
16
Q.8 The area of quadrilateral formed by tangents and normals at ends of latus-rectum of parabola C
2
, is
(A)
3
32
(B*)
9
32
(C)
3
16
(D)
9
16
[Sol.
(i) Centroid (h, k)
"
2
h 3
=
$
$
%
&
'
'
(
)
!
2
1
2
1
t
1
t .(1)
and
4
k 3
=
$
$
%
&
'
'
(
)
*
1
1
t
1
t .(2)
y
A
x
Q
(h,k) S(2, 0)
G Focus
(0, 0)
P(2t , 4t )
2
1 1
$
$
%
&
'
'
(
)
*
1
2
1
t
4
,
t
2
# Locus of G (h, k) is C
2
: y
2
=
$
%
&
'
(
)
*
3
4
x
3
8
(another parabola)
(ii) Area = 8
2
3
2
$
%
&
'
(
)
=
9
4 81
=
9
32
(square units). ]
Consider a plane 2 : x + y z = 1 and the point A (1, 2, 3). A line L has equations
x = 1 + 3r, y = 2 r, z = 3 + 4r, where r is parameter.
Q.9 The coordinates of a point B on line L such that AB is parallel to the plane 2 is
(A) (10, 1, 15) (B) ( 5, 4, 5) (C) (4, 1, 7) (D*) ( 8, 5, 9)
Q.10 The equation of plane containing the line L and the point A has the equation
(A) x 3y + 5 = 0 (B) 3x y 1 = 0 (C*) x + 3y 7 = 0 (D) 3x + y 5 = 0
Q.11 The distance between the points on the line L which are at a distance of
3
4
from the plane 2 is
(A*) 4 26 (B) 20 (C) 10 13 (D) 5 13
MATHEMATICS
[Sol.
(i) A (1, 2, 3); B (1 + 3r, 2 r, 3 + 4r)
" 1 (3r) + 1 ( r) 1 (4r + 6) = 0 [As AB is parallel to plane 2.]
# r = 3. So, B ( 8, 5, 9)
(ii) The equation of plane is
4 1 3
6 0 0
) 3 z ( ) 2 y ( ) 1 x (
*
* * *
= 0
A
(
1
,

2
,

3
)
L
<
3
,

1
,

4
>
(
1
,

2
,

3
)
# x + 3y = 7. Ans.
(iii) 2 : x + y z 1 = 0
P (1 + 3r, 2 r, 3 + 4r)
Now,
3
| 1 r 2 | !
=
3
4
# r =
2
3
or
2
5 *
. So, points are
$
%
&
'
(
)
9 ,
2
1
,
2
11
and
$
%
&
'
(
)
*
*
7 ,
2
9
,
2
13
.
# Distance between them = 4 26 . ]
PART-B
[MATRIX TYPE]
Q.1 Column-I Column-II
(A) If 5x
2
+ 5y
2
+ ax + by c = 0 is the equation of smallest circle (P) 1
which is passing through points of intersection of circle x
2
+ y
2
= 4
and line 3x + 4y = 5, then the value of (2c + a + b) is equal to (Q) 2
(B) Number of solutions of the equation sin x +
2
1
cos x = $
%
&
'
(
) 3
!
4
x sin
2
in x + (0, 3) is equal to (R) 4
(C) Suppose n is a natural number such that
| i + 2i
2
+ 3i
3
+ . + ni
n
| = 18 2 where i = 1 * , (S) 5
then n is equal to
(D) If S =
4 5
6
,
/
* ! *
!
1 k
k 1 k 1
2 2 cot
, then cot (S) is equal to (T) 6
[Ans. (A) T ; (B) Q ; (C) T ; (D) Q]
[Sol.
(A) S + 7L = 0 # (x
2
+ y
2
4) + 7 (3x + 4y 5) = 0; Centre
$
%
&
'
(
)
7 *
7 *
2 ,
2
3
Now, 3
$
%
&
'
(
) 7 *
2
3
+ 4 ( 27) = 5 # 7 =
5
2 *
" The equation of required circle is 5x
2
+ 5y
2
6x 8y = 10.
(B) sin x +
2
9
cos x = $
%
&
'
(
) 3
!
4
x sin
2
# (1 cos x) (1 2sin x) = 0 # cos x = 1 or sin x =
2
1
MATHEMATICS
" x =
6
3
,
6
53
+ (0, 3).
(C) Let z = (i + 2i
2
+ 3i
3
+ 4i
4
+ . + ni
n
.)
As, (i + 2i
2
+ 3i
3
+ 4i
4
) = 2 2i = 2 (1 i)
# n = 36. So, n = 6
Aliter: | z | =
i 1
ni
2
1 i
1 n n
*
*
$
$
%
&
'
'
(
)
*
!
(D) S
n
= 6
/
!
!
*
$
$
%
&
'
'
(
)
!
*
n
1 k
k 1 k
k 1 k
1
2 2 1
2 2
tan
= 4 5
6
/
* ! *
*
n
1 k
k 1 1 k 1
2 tan ) 2 ( tan = (tan
1
(2
n+1
) tan
1
2)
" S =
n
n
S Lim
, :
=
2
3
tan
1
2 = cot
1
2 # cot (S) = 2. Ans.]
PART-C
[INTEGER TYPE]
Q.1 Find the number of solutions of equation sin
1
(4sin
2
; + sin ;) + cos
1
( 1 + 6sin ;) =
2
3
,
in ; + [0, 53]. [Ans. 0006]
[Sol. We must have, 4sin
2
; + sin ; = 1 + 6sin ; # sin ; = 1,
4
1
# 6 solutions.]
Q.2 If k
) z 4 ( j
y i
) x ( a ! ! 7 / , k
) y 3 ( j
x i
y b ! ! / and
4 5k
x ) 1 ( j
) z 2 ( i
z c ! 7 * * * / are sides of the triangle as shown in

figure, then find the value of 7 (where x, y, z are not all zero.)
a
b
c
[Ans. 0000]
[Sol. As, c b a / !
So, 7x + y + z = 0
x + y + 2z = 0
(7 + 1) x + 3y + 4z = 0
" For non-trivial solution, put . = 0
#
4 3 1
2 1 1
1 1
! 7
7
= 0 # 7 = 0. Ans.]
MATHEMATICS
Q.3 If
0
3
!
2
0
4 4
dx
x cos x sin
x 2 sin x
= k
2
4
5
4 4
dx
x cos x sin
x 2 sin
$
$
$
$
%
&
'
'
'
'
(
)
!
0
3
3
, then find the value of k. [Ans. 0002]
[Sol. Let I
1
=
0
3
!
2
0
4 4
dx
x cos x sin
x 2 sin x
=
8
2
3
(Using King and Queen property)
Also, I
2
= k
2
period with Periodic
4
5
4 4
dx
x cos x sin
x 2 sin
$
$
$
$
$
%
&
'
'
'
'
'
(
)
$
%
&
'
(
)
!
3
3
3
0
= k
2
4
$
%
&
'
(
) 3
=
16
k
2
3
So, k = 2. Ans.]
Q.4 Let a < b < c be three integers such that a, b, c is an arithmetic progression and a, c, b is a geometric
progression, then find the smallest positive value of c. [Ans. 0002]
[Sol. a = A d,
b = A
I d , A where +
<
=
>
c = A + d
c
2
= ab
(A + d)
2
= (A d) A
A
2
+ d
2
+ 2Ad = A
2
Ad
d
2
= 3Ad
d = 0, d = 3A
c = A + d = 2A
" c
min
= 2. ]
PART-D
[INTEGER TYPE]
Q.1 to Q.3 are "Integer Type" questions. (The answer to each of the questions are upto 4 digits)
Q.1 Let A and B be two points on the major axis of the ellipse
16
y
25
x
2 2
! = 1, which are equidistant from
the centre. If C and D are the images of these points in the line mirror y = mx, m ? 0 then find the
maximum area of quadrilateral ACBD. [Ans. 50]
[Sol. Image of A(h, 0) in the line mirror mx y = 0
$
%
&
'
(
)
!
* /
*
*
/
*
1 m
mh
2
1
0 y
m
h x
2
x =
2
2
m 1
) m 1 ( h
!
*
, y =
1 m
mh 2
2
!
A
B
D
C
(h, 0) (h,0)
y
x
y = mx
MATHEMATICS
" C @
$
$
%
&
'
'
(
)
! !
*
1 m
mh 2
,
m 1
) m 1 ( h
2 2
2
Similarly D @
$
$
%
&
'
'
(
)
!
*
!
* *
1 m
mh 2
,
m 1
) m 1 ( h
2 2
2
AC =
2 2
2 2
2
2
2
) m 1 (
h m 4
m 1
) m 1 ( h
h
!
!
$
$
%
&
'
'
(
)
!
*
* =
2 2
2 2
2 2
2 4
) m 1 (
h m 4
) m 1 (
h m 4
!
!
!
=
) m 1 (
m 1 mh 2
2
2
!
!
AD =
2 2
2 2
2
2
2
) m 1 (
h m 4
m 1
) m 1 ( h
h
!
!
$
$
%
&
'
'
(
)
!
*
!
=
2 2
2 2
2 2
2
) m 1 (
h m 4
) m 1 (
h 4
!
!
!
=
2
2
m 1
) m 1 (
h 2
!
!
" Area = AC AD =
2 2
2 2
) m 1 (
) m 1 ( mh 4
!
!
=
m
1
m
h 4
2
!
Area|
max
=
2
25 41
= 50 Ans. ]
Q.2 Consider the curves C
1
: | z 2 | = 2 + Re(z) and C
2
: | z | = 3 (where z = x + iy, x, y + R and i = 1 * ).
They intersect at P and Q in the first and fourth quadrants respectively. Tangents to the C
1
at P and Q
intersect the x-axis at R and tangents to the C
2
at P and Q intersect the x-axis at S. If the area of .QRS
is 2 7 , then find the value of 7. [Ans. 0010]
[Sol. Let z = x + iy
Then C
1
: | z 2 | = 2 + Re(z)
# | (x 2) + iy | = 2 + x
# (x 2)
2
+ y
2
= (x + 2)
2
R
P
(
1
,2
2
)
(3,0)
O
(0,0)
Q
(1
,
2
2
)
S
x
y
# y
2
= 8x
and C
2
: x
2
+ y
2
= 9
For point of intersections of C
1
and C
2
x
2
+ 8x = 9
# x
2
+ 8x 9 = 0
# (x + 9) (x 1) = 0
# x=1(
" y
2
= 8 # y =
2 2
" P =
4 5 2 2 , 1
and Q
4 5 2 2 , 1 *
Equation of tangent at P on parabola is y
2 2
= 4 (x + 1) ....(1)
Equation of tangent at Q on parabola is
y
2 2
= 4 (x + 1) ....(2)
Solving (1) and (2) , R = (1, 0)
Equation of tangent at P on circle is
9 y 2 2 x / !
......(3)
MATHEMATICS
Equation of tangent at Q on circle is
9 y 2 2 x / *
.....(4)
Solving (3) and (4)
S @ (9, 0)
Area of .QRS =
height base
2
1
1 1
= 2 10 2 2 10
2
1
/ 1 1 @ 2 7
" 7 = 10. Ans.]
Q.3 Suppose an ellipse and a hyperbola have the same pair of foci on the x-axis with centres at the origin
and they intersect at M (2, 2). If the eccentricity of ellipse is
2
1
and eccentricity of hyperbola is
n
m
where m, n are coprime, then find the value of (m + n).
[Ans. 0010]
[Sol. Let E :
2
2
2
2
b
y
a
x
!
= 1 and H :
2
2
2
2
B
y
A
x
*
= 1
#
2 2
b
1
a
1
!
=
4
1
; e
E
2
= 1
2
2
a
b
#
2
2
a
b
=
4
A
So, a
2
=
3
28
and b
2
= 7
# E :
7
y
3
28
x
2 2
! = 1
Now, slope of tangent at M (2, 2) on ellipse =
4
3 *
So, slope of tangent at M (2, 2) on hyperbola #
2
2
A
B
=
3
4
As, e
h
2
= 1 +
2
2
A
B
# e
h
2
= 1 +
3
4
=
3
7
So, e
h
=
3
7
. [Note that ellipse and hyperbola are confocal.] ]

XIII RT 6 PCM-16!02!2013 Advance Paper-2 Solution

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XIII RT 6 PCM-16!02!2013 Advance Paper-2 Solution

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XIII (XYZ) RT-6 JEE Advanced [Paper-II] Code-A Page # 1

z c ! 7 * * * / are sides of the triangle as shown in

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