DIAGRAM BLOK INDUSTRI SEMEN PORTLAND

FLUE GAS: CO2 : ... % mole

Batu kapur

Tanah Liat

H2O: ... % mole

.... kg

100 kg

SO2: ... % mole

Gypsum: 50 Kg

O2 : .... % mole
N2 : ... % mole
CaCO3
PULVERIZER

..... kg

Klinker

KLIN
CaCO3

CaO + CO2

CaO + SiO2 + Al2O3

SEMEN

..... kg

1000 Kg
PERIPHERAL SCREEN

Campuran C2S, C3S,

C3A (Klinker)

Fuel gas: 50 Kmol

C2 = 86 %
Udara Excess : 30 %

O2 = 6 %
S =1%
N2 = 2 %
H2 = 5 %

Gypsum: 50 Kg

Klinker..... Kg

SEMEN
PERIPHERAL SCREEN

PERIPHERAL SCREEN

1000 Kg

Semen

= Klinker + Gypsum

1000 Kg = X + 50 Kg
Klinker

= 1000 Kg 50 kg
= 950 Kg

Konversi ke mol:
n

= 1,418 kmol

Neraca massa di peripheral screen

Komponen
Klinker
Gypsum
Semen
Total

Input (kg)
950
50
1000

Output (kg)
1000
1000

FLUE GAS: CO2 : ... % mole

H2O: ... % mole
SO2: ... % mole
CO2= ... kg

O2 : .... % mole
N2 : ... % mole
Fuel
KLINgas: 400 Kg

CaCO3: .... kg

CaCO3

CaO + CO2

CaO + SiO2 + Al2O3

Klinker: 950 kg

Campuran C2S, C3S,

C3A (Klinker)

Flue Gas: 50 kmol

C2 = 86 %
Udara Excess : 30 %

O2 = 6 %
S =1%
N2 = 2 %
H2 = 5 %

KLIN

8CaO + 2SiO2 + Al2O3

Mula- mula :

C2S, C3S, C3A

kmol

Bereaksi

: 11,34

2,836

1,418

1,418

kmol

Sisa

: -

2,836

1,418

1,418

kmol

BM

: -

60

102

670

kg/kmol

Massa

: -

170,16 144,636

950

kg

CaCO3

CaO

Mula- mula :

CO2
-

kmol

Bereaksi

: 11,34

11,34

11,34 kmol

Sisa

: -

11,34

11,24 kmol

BM

56

44

Massa

635,04

498,96

CaCO3 :11,34 kmol

= 11,34 kmol X 100 kg/ kmol
= 1134 kg

kg/kmol
kg

Flue gas
Komponen C
C=

X 50 kmol = 43 kmol

C = 43 kmol x 12 kg/mol = 516 kg

Komponen H2
H2 =

X 50 kmol = 2,5 kmol

H2 = 2,5 kmol x 2 kg/kmol = 5 kg

Komponen S
S=

X 50 kmol = 0,5 kmol

S = 0,5 kmol x 32 kg/kmol = 16 kg

Komponen O2
O2 =

X 50 kg = 3 kmol

O2 = 3 kmol x 32 kg/kmol = 96 kg
Komponen N2
N2 =

X 50 kmol = 1 kmol

N2 = 1 kmol x 28 kg/ kmol = 28 kmol

Reaksi Fuel Gas dengan Udara

C
Mula- mula:

O2

CO2

43

kmol

43

43

kmol

Bereaksi

43

Sisa

43

43

kmol

BM

12

32

44

kg/kmol

Massa

2H2

1376

1892

kg

O2

2H2O

Mula- mula:

2,5

kmol

Bereaksi

2,5

1,25

2,5

kmol

Sisa

1,25

2,5

kmol

BM

32

18

kg/kmol

Massa

40

45

kg

O2

SO2

Mula- mula:

0,5

kmol

Bereaksi

0,5

0,5

0,5

kmol

Sisa

0,5

0,5

kmol

BM

32

32

64

kg/kmol

Massa

16

32

kg

Total O2 bereaksi = (43 + 1,25 + 0,5) kmol = 44,75 kmol

Udara excess

=130 % x Total O2
x 44,75 kmol = 58,175 kmol

= 58, 175 x 32 kg/kmol

= 1861,6 kg
N2

x 58,175 kmol

= 218,848 kmol
= 218, 848 kmol x 28 kg/kmol = 6.127,744 kg
O2 Keluar

= ( Udara excess +oksigen dari udara) - O2 dari reaksi

= (58,175 kmol + 3 ) kmol 44,75 kmol = 16,425 kmol
= 16, 425 kmol x 32 kg/kmol = 525,6 kg

Neraca Massa di Klin

KOMPONEN

C2S, C3S, C3A

CaCO3

SiO2
Al2O3
C
H
S
CO2
SO2
H2O
O2
N2

INPUT
kmol
11,34
2,836
1,418
43
2,5
0,5
-

gram
1.134
170,16
144,636
516
5
16
-

kmol
1,418
(43 + 11,34) = 54,34

1.957,6
6.155,744

0,5
2,5
16,425
(1 + 218,848) =
219,848
295,031

(1 + 218,848) =
219,848
281,442

TOTAL

Output

10.099,14

gram
950
2.390,96
32
45
525,6
6.155,744
10.099,304

KOMPOSISI FLUE GAS

FLUE GAS
O2
CO2
SO2
N2
H2O
TOTAL

kmol
16,425
54,34
0,5
219,848
2,5
293,613

kg
525,6 kg
2.390,96
32
6.155,744
45
9.149,304

% mole
5,594
18,507
0,170
74,876
0,85
99,997 100

FLUE GAS:
CO2 : 18,507 % mole
H2O: 0,85 % mole
SO2 : 0,170 % mole
CO2= 498, 96 kg

O2 : 5,594 % mole
N2 : 74,876 % mole
Fuel
KLINgas: 400 Kg

CaCO3: 1134 kg

CaCO3

Klinker: 950 kg

CaO + CO2

CaO + SiO2 + Al2O3

Campuran C2S, C3S,

C3A (Klinker)

Flue Gas: 50 kmol

C O2 = 86 % = 43 kmol
Udara Excess : 30 %

O2

= 6 % = 3 kmol

O2= 58,175 kmol

= 1 % = 0,5 kmol

N2 = 218, 848 kmol

N2

= 2 % = 1 kmol

H2

= 5 % = 2,5 kmol

Batu Kapur

Tanah Liat

...kg

100 kg

CaCO3 : 1134 Kg
PULVERIZER

PULVERIZER

CaCO3 = Total batu kapur + Total tanah liat

1134 kg = X + 100 kg
X

= 1134 kg 100 kg
= 1034 kg

Mol Batu Kapur =

Tanah Liat

= 10,34 kmol

= 1 kmol

Neraca Massa di PULVERIZER

KOMPONEN
Tanah Liat
Batu kapur
CaCO3
TOTAL

INPUT
kmol
1
10,34
11,34

OUTPUT
kg
100
1034
1134

kmol
11,34
11,34

kg
1134
1134

Batu Kapur

Tanah Liat

1034 kg

100 kg

PULVERIZER

CaCO3 : 1134 Kg

DIAGRAM BLOK
KESELURUHAN ALAT
FLUE GAS: CO2 : 12,04 % mole
Batu kapur

Tanah Liat

H2O: 4, 12

.... kg

100 kg

SO2: 0,0525 % mole

CaCO3
PULVERIZER

% mole

O2 : 4,55

% mole

N2 : 79,15

% mole
Klinker

KLIN
CaCO3

CaO
+ +COCO
CaO
2 2

CaO + SiO2 + Al2O3

Gypsum: 50 Kg

SEMEN

950 kg

1000 Kg
PERIPHERAL SCREEN

Campuran C2S, C3S,

C3A (Klinker)

Flue Gas: 50 kmol

C O2 = 86 % = 43 kmol
Udara Excess : 30 %

O2

= 6 % = 3 kmol

O2= 58,175 kmol

= 1 % = 0,5 kmol

N2 = 218, 848 kmol

N2

= 2 % = 1 kmol

H2

= 5 % = 2,5 kmol