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Espectroscopa
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Q U IM IC A O R G AN IC A II.
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ESPECTRO ELECTROMAGNTICO
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Q U IM IC A O R G AN IC A II.
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An absorption band due to a particular functional group always appears in the same general region.
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wavenumber = v
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Generalizations
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k M
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N-H > CspH > 3300 3550-3200 cm-1 3400-3200 intense (polar) less intense less broad very broad NH2 has 2 (H bonding) H NH has 1 O-H
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CH3CH2
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2150-2100 less intense less polar For symmetrical alkynes, this band can be very weak.
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C C CH2CH3
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C N
C C
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Triples enlaces
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~1700 cm-1 very intense (polar) very useful
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lower wavenumber (uncommon)
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C C
1660-1640 less intense (nonpolar)
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four bands near 1600, 1580, 1500, and 1450 variable position and intensity (use caution)
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A O G AN IC A II. R
Csp3-H (<3000)
Q U IM IC
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Q U IM IC A O R G AN IC A II.
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Csp-H
Q U IM IC A O R G AN IC A II.
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Csp2-H
Q U IM IC A O R G AN IC A II.
Csp3-H
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II.
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Q U IM IC A O R G AN IC A II.
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IM IC
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IM IC
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CH3 CH3
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CH3 CH3
CH3 CH3
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RMN
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1H
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Inductive Effects
X C H
Electronegative X pulls electrons away from H; H is deshielded; appears more downfield
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Table 14.1
Q U IM IC A O R G AN IC A II.
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IM IC
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DU = 1
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