I HC BCH KHOA TPHCM

B MN: QU TRNH & THIT B

BI THUYT TRNH
S DNG PHN MM PRO/II M PHNG QU TRNH CHNG CT GIN ON

NGUYN V NAM NGUYN TH LINH

MSSV: 61002048 MSSV: 61002048

CBHD: THY TRN TN VIT

MC LC

I. II. III. IV. V. VI. VII.

M PHNG V THIT K M PHNG CC PHN MM M PHNG TRONG CNG NGH HA HC TNG QUAN V PHN MM PRO/II FLUID PACKAGE THIT B BATCH DISTILLATION YU CU M PHNG KT QU

I.

M PHNG V THIT K M PHNG. M phng c th c nh ngha l mt qu trnh to mt m hnh (chng hn nh m t mt khi nim tru tng) ca mt h thng c sn (nh mt d n, kinh doanh, qung m, khu rng, c quan trong c th) xc nh v hiu r nhng nhn t iu khin h thng, hay d on/d bo hnh vi hot ng ca h thng trong tng lai. Phn ln cc h thng iu c m t nh lng da trn phng trnh hoc nguyn tc c m phng. M phng l qu trnh "bt chc" mt h thng c thc. Cc chng trnh my tnh c th to ra cc m phng nh m phng v thi tit, cc phn ng ho hc, thm ch l cc qu trnh sinh hc. M phng l mt cng c hiu qu v quan trng bi n a ra phng thc cc thit k la chn (hoc k hoch, chnh sch) c th c nh gi m khng cn phi thc nghim trn h thng thc (iu ny c th tiu tn nhiu kinh ph, thi gian, nguy him v khng thc t). N cho php bn tr li cu hi iu g s xy ra nu? v mt h thng m khng cn tri nghim tht s trn chnh h thng y. Thit k m phng l thit k vi s tr gip ca my tnh vi cc phn mm chuyn nghip. Thit k m phng thng c s dng : Thit k mt qu trnh mi Th li, kim tra li cc qu trnh ang tn ti Hiu chnh cc qu trnh ang vn hnh Ti u ha cc qu trnh hot ng

II.

CC PHN MM M PHNG TRONG CNG NGH HA HC. Trong cng ngh ha hc, c nhiu phn mm m phng c s dng. Mi phn mm m phng c nhng u im ring v c s dng cho cc mc ch khc nhau. V d: DESIGN II (WINSIM): s dng trong cng nghip ha hc ni chung HYSIM (HYSYS): s dng trong cng nghip ch bin kh OLGA 2000: s dng thit k m phng ng ng PRO II (SIMSCI): s dng trong cng nghip du kh.

III.

TNG QUAN V PHN MM PRO II

giao din khi khi ng PRO II

Pro II l mt trong nhng sn phm ca t hp SIMSCI, c thnh lp t nm 1957 chuyn v thit k cc phn mm m phng trong cng ngh ha hc, c bit l v nn cng nghip lc ha du. Hin nay sn phm ca t hp ny kh a dng, bao gm cc phn mm v thit k cc thit b, ng ng, tnh ton kinh t. Pro II l sn phm u tin ca SIMSCI, l kt qu ca bn ln nng cp t chng trnh u tin nm 1967 n nm 1988 th chnh thc ra mt. Chng trnh ny khng ngng c nng cp, b sung v hin nay c phin bn mi nht l 9.2 Phn mm ny c th ng dng vo nhiu qu trnh: - X l du, kh - Tinh ch - Ha du - Polymer - Dc phm So vi cc phn mm m phng khc, Pro II c u im l giao din thn thin, trc quan. Th vin cu t phong ph v s. Tuy vy hin nay, cc ti liu hng dn bng ting Vit cha nhiu. y l mt kh khn cho nhng ngi mi lm quen vi phn mm ny.

IV.

Cc bc thc hin mt qu trnh m phng bng phn mm Pro II: - La chn h n v. - V lu qu trnh - Xc nh cc cu t trong qu trnh - Chn phng php nhit ng thch hp - Cung cp cc d liu cho dng - Cung cp cc iu kin lm vic cho qu trnh - Chy m phng - c v phn tch kt qu FLUID PACKAGE Cc tnh cht nhit ng l c s d liu quan trng nht cho vic tnh ton qu trnh ton h thng. Cc tnh cht ny thay i lin tc theo cc yu t khc nh nhit , thnh phn, p sut. Do vy, cn phi thnh lp cc phng trnh biu din s tng quan gia cc yu t ny. T , cc m hnh nhit ng ra i. Cho n nay, cha c m hnh nhit ng no c th m t ton b tnh cht ca tt c cc cht. Mi m hnh nhit ng ch thch hp nhng iu kin v thnh phn, nhit , p sut khc nhau. Do vy, la chon m hnh nhit ng thch hp l yu t quan trng nht, gip cc phn mm c th tnh ton chnh xc. C nhiu phng php tnh ton cc tnh cht ny, trong , quan trng nht l hai phng php: - Phng php tng quan API v Rackett - Phng php phng trnh trng thi: phng trnh bc ba tng qut, cng thc alpha, cc qui lut hn hp, phng trnh SKR, phng trnh PR, . Phng php API v Rackett tnh ton kh chnh xc t trng pha lng, cn cc tnh cht nhit ng khc c tnh ton rt chnh xc bng cc phng trnh trng thi. Mi m hnh nhit ng cho php tnh ton cc thng s: Hng s cn bng pha K: th hin s phn b ca cc cu t gia cc pha iu kin cn bng. Enthanpy ca cc pha lng v pha hi: xc nh nng lng cn thit chuyn mt h t trng thi nhit ng ny sang trng thi nhit ng khc. Entropy ca pha lng v pha hi: nhm tnh ton cc thng s trong cc qu trnh nn, dn n. T trng pha lng v pha hi: tnh ton qu trnh truyn nhit, chng ct, ngng t

la chn m hnh nhit ng thch hp, nn da vo cc thng s:

Bn cht cc c trng nhit ng ca h nh: hng s cn bng lnghi ca cc qu trnh Thnh phn hn hp Phm vi nhit v p sut Tnh sn c ca cc thng s ca thit b

Cc m hnh nhit ng sn c v cch vit y trong phin bn Pro II 8.1: IDEAL GS CS IGS GSE CP BK10 JG LK API RACKETT COSTALD LIBRARY SKR PR SRKKD SRKH SRKP SRKM SRKS PRH PRP PRM UNIWAAL BRWS HEXAME LKP NTRL UNIQUAC UNIFAC UFT1 UFT2 UFT3 UNFV WILSON VANLAAR MARGULES REGULAR FLORY HOCV Ideal Grayson-Streed Chao_Seader Improved Grayson_Streed Erbar Improved Chao-Seader Curl-Pitzer Braun K10 Johnson-Grayson Lee-Kesler API Liquid Density Rackett Liquid Density COSTALD Liquid Density Library Liquid Entropy Soave-Redlich-Kwong Peng-Robinson SRK Kabadi-Danner SRK Huron-Vidal SRK Panagiotopoulos & Reid SRKP Modified SRK Ssmsci PR Huron-Vidal PR Panagiotupoulos & Reid PRP Modified UNIWAALS Benedict-Webb-Rubin-Srarling Associating EOS for HF systems Lee-Kesler-Plocker NTRL UNIQUAC UNIFAC UNIFAC Lyngby UNIFAC Dortmund Modified UNIFAC UNIFAC Free Volume option Wilson equation Van Laar equation Margules equation Regular solution theory Flory Huggins Hayden-OConnell vapor fugacity

TVIRIAL Truncated virial vapor fugacity IDIMER IDIMER vapor fugacity ALCOHOL Alcohol package GLYCOL Glycol package SOUR Sour water package GPSWATER GPA sour water package AMINE Amine package la chn m hnh nhit ng thch hp, ta c th tham kho trong cc ti liu i km. V. THIT B BATCH DISTILLATION L thit b m phng qu trnh chng ct gin on.

Batch Distillation Dialog Box Number of Theoretical: s a l thuyt, ti thiu l 2. Thit b ngng t condenser mc nh l a u tin, thit b ung nng reboiler l a cui cng. Maximum Simulation: thi gian m phng ti a. Khi ht thi gian ny, qu trnh m phng s kt thc. Batch Cycle Time: thi gian thc hin mi giai on.

Thit lp p sut cho h thng.

Thit lp li cun cht lng

Thit lp cc thng s nhit ng ca h. Phi chn gi nhit ng oVLE hoc VLLE. VI. YU CU M PHNG M phng qu trnh chng ct phn on thu c ethanol 95o t dung dch ln men tinh bt c nng ethanol 8o, cc tp cht khc khng ng k. VII. KT QU Lu lng nhp liu: 100 m3/m. Nhp liu lng si 1atm. Thi gian mi m l 1h. Thi gian m phng l 10h. Phng php nhit ng la chon l UNIFAC.