Thit k m hnh thu hi CO2 t kh l thi

Lhdk52

B GIO DC V O TO
TRNG I HC M A CHT
B mn Lc Ho Du
-----------------------

N MN HC:
M PHNG QU TRNH THU HI CO2 T KH L THI S
DNG DUNG DCH MEA HP TH

Gio vin hng dn: Ks. on Hun

Nhm sinh vin thc hin:
Nhm 1

LP: LC - HA DU K52

H Ni, thng 11,nm 2011

1

Thit k m hnh thu hi CO2 t kh l thi

Lhdk52

Ni dung chnh:

Chng 1 : tng quan qu trnh hp th

Chng 2 : c s thit k tnh ton
Chng 3: m phng qu trnh thu hi CO2 t kh l thi s dng phn
mm Hysys
Chng 4: ph lc
Ti liu tham kho

Thit k m hnh thu hi CO2 t kh l thi

Lhdk52

Chng 1: tng quan qu trnh hp th

1.1 Mc ch
Thit k c m hnh ti u thu hi kh CO2 t kh l thi v loi b bt CO2
trong cc sn phm du m v trong cc m kh c nng CO2 cao p dng
vo thc t sn xut.
1.2. ngha ca vic loi CO2
Carbon dioxide l kh c kh nhiu trong cc sn phm du m v trong cc kh l
thi. S c mt ca CO2 trong cc sn phm du m gy kh khn cho vic vn
chuyn v tng cha do gy tng th tch v gy n mn thit b. Chnh v vy vic
loi kh CO2 l 1 phn on khng th thiu trong qu trnh ch bin du m.
Trong nhiu m kh ca Vit Nam c hm lng CO2 qu cao (trn 70%) nn cha
c cng ngh no khai thc c cc m kh ny. Cho nn cn loi bt CO2
trong cc m kh t nng CO2 trong mc cho php c th khai thc c.
Nh chng ta bit: Kh CO2 l nguyn nhn chnh gy hiu ng nh knh,
chim 50% trong c cu cc cht kh gy hiu ng nh knh lm tri t ngy cng
nng ln.
Hn na, CO2 l nguyn nhn gy nhiu tai nn cht ngi trn th gii cng nh
Vit Nam , c trong i sng cng nh trong sn xut.Tuy CO2 l mt cht khng
gy c tnh vi con ngi nhng n c th l mt cht gy ngt n thun.
Bn cnh khi chng ta thu hi v tinh ch c CO2 th n li c nhiu ng dng
trong thc t :
c tnh c bit ca carbon dioxide l tnh tr v ha tan trong nc cao nn
CO2 l mt kh h tr l tng a dng trong cuc sng hng ngy v trong cng
ngh mi trng.
Trong cng ngh thc phm, CO2 c dng to gas cho nhiu thc ung, rt
hu dng trong vic iu ha nc ung v trung ha nc thi. th lng c
lm lnh hoc th rn ( kh), CO2 c s dng nh mt mi trng lm lnh
nhit -79 C.

Thit k m hnh thu hi CO2 t kh l thi

Lhdk52

Lm lnh thc phm: c dng ging nh Nit lng, v ph hp nht cho

cc ng dng trn lnh s dng tuyt kh.
ng gi thc ung.
Du phc hi tng cng: ha tan ca hydrocarbon lng c dng
lm tng s lu thng ca du bng cch gim nht, tng th tch v kch
thch s lu thng. CO2 l mt sn phm tt yu ca cc nh my ch bin
du.
Sn: carbon dioxide siu hn c s dng nh mt cht pha lng dng
trong sn phun, lm gim 80% dung mi hu c.
Chit xut thc phm: supercritical carbon dioxide c s dng trong
vicchit xut mu v hng v trong thc phm nhm loi b du v cht
bo.
Tch v chit xut trong cng nghip: carbon dioxide siu hn c dng
trong cc qui trnh dc phm v ha cht, hoc l cht thay th cho dung
mi gc hydrocarbon trong vic ty nhn kim loi.
Tinh ch v nung chy kim loi: dng trong vic khun v c, tuyt
carbon dioxide c dng lm gim s hnh thnh oxide st.
X l nc.
X l cht thi.
1.3. s cng ngh:

Thit k m hnh thu hi CO2 t kh l thi

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Hnh 1: S dng tng quan ca mt quy trnh loi b CO2

1.4 c im qu trnh hp th MEA:
1.4.1 c im ca MEA
MEA c tnh bazo mnh nht so vi cc ankanolamin khc nn c
kh nng hp th CO2 mnh nht , dng loi b H2S v CO2 ra
khi hn hp kh.
MEA c tnh n nh ha hc cao
MEA d ti sinh
MEA c kh nng phn ng cao
Cng ngh v thit b n gin , bn cao khi vn hnh ng
Dung dch MEA kh hp th cc hydrocacbon nn c kh nng lm
tng hiu qu sn xut lu hunh t cc kh axit lm sch bng
MEA.
u im:
lm sch trit H2S v CO2
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Thit k m hnh thu hi CO2 t kh l thi

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n nh ha hc cao
d ti sinh
cng ngh n gin
nhc im:
mc bo ha ca dung dch thp
khng loi c COS, CS2, HCN
thut ton ln dn tng chi ph
1.4.2 qu trnh tng tc ca MEA vi CO2:
Phng trnh phn ng:
CO2 + HOCH2 CH2 NH2 CO3(CH2CH2NH2)2 + H2O H= -1917 kJ/kg
Trong xy ra theo hai giai on
CO2 + 2RNH2 + H2O (RNH3)2CO3
CO2 + (RNH3)2CO3 + H2O 2RNH3HCO3

Chng 2 : c s thit k tnh ton:

Trong chng ny a ra cch tnh ton nhng thng s thit k ca cc thit
b chnh trong s m phng . cc thit b c bn c tnh ton nh di y
2.1.Tnh ton cc thng s c bn ca thp hp th CO2 dng MEA
Bc 1: C th ha cc yu t u vo
Nguyn liu :3-Fuel oil
Thnh phn kh nguyn liu: 3-Fuel oil vi thnh phn mol l:CO2 0,037,
H2O 0,07, N2 0,893.
Nhit : 39,5oC , p sut :1,03at.
Hm lng CO2 trong kh u ra l : 0,00487%mol.
Cht hp th l dng Amine ngho 21-lean amine vi nhit l 40oC, p
sut 1,01 at, lu lng khi lng l 3,6.10^6 kg/h.
Bc 2: Tnh p sut lm vic ca thp hp th
p sut lm vic ca thp hp th : P PCO2/b
Trong :
PCO2 l p sut hi ring phn ca CO2 trong dung dch amin ngho ti nhit
lm vic ca thp. C th c tnh theo phng trnh Antoine:

Thit k m hnh thu hi CO2 t kh l thi

Lhdk52

Lg PCO2 = A B/(T+C)
T l nhit lm vic ca thp l 40oC
A,B,C l 3 h s ca pt tng ng vi amin MEA ln lt l 7,4; 1140,8; 236
PCO2 = 0,018.10^5 pa.
b l hm lng ca CO2 cn li trong kh u ra (phn trm) l 0,487
P 0,037.10^ 5pa
Vy ta chn p sut lm vic ca thp nh l 1 at v y l 1,2 at.
Bc 3: tnh lu lng dng amin giu i ra y thp
mrich amin = mlean amin + mCO2(hp th)
Trong : nCO2(h.th) = nCO2(fuel oil) nCO2(kh ra nh) =3543 kmol.
mrich amin = 3,7.10^6 kg/h.
Bc 4: tnh lu lng ca kh ngt ra nh thp
m(kh ra) = m(fuel oil) - mCO2(h.th) = 6,63.10^6 kg/h.
Bc 5: tnh nhit dng amin giu ra y thp T(da trn nh lut baot
ton nng lng Qthu= Qta).
Nhit ta : l nhit ta ra khi xy ra phn ng gia amin MEA v CO2
Qta = mCO2(h.th) .qCO2
qCO2 l nhit ta ra khi 1kg CO2 tc dng vi MEA v = 1917 kj/kg
Qta = 3.10^8 kJ.
Nhit thu vo bao gm:
. Nhit un nng dng amin ngho t Tvo n nhit T
Q1 = (namin.Mamin/C%amin).Cp(amin).( T Tamin)
Trong : Cp(amin)= 1,48 (kj/kg.oC)
. Nhit un nng CO2 b hp th
Q2 = nCO2(h.th).Cp(CO2).(T- Tfuel oil)
Trong : Cp(CO2) = 0,8778 (kj/kg.oC).
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Thit k m hnh thu hi CO2 t kh l thi

Lhdk52

. Nhit un nng CO2 c sn trong dng lean amin

Q3 = nCO2(lean amin).Cp(CO2).(T Tlean amin)
. Nhit tht thot ra bn ngoi: ly bng 5% nhit ta
Q4 = 5%.Qta = 1,5.10^7 kJ
Qthu = Q1 + Q2 + Q3 + Q4.
Cho Qta = Qthu ta tnh c nhit ca dng rich amin ra y thp l 46oC.
Bc 6: tnh s a l thuyt ca thp
Nlt = [ ln (1/q(A-1))/lnA] +1
Trong :
A l yu t hp th : A= a(1 + R.r).(1-q)/(P1/P).
q = s mol CO2 trong kh ra/ s mol CO2 trong fuel oil = 0,13.
a l phn mol ca CO2 trong fuel oil = 0,037
R l s mol amin/s mol CO2 (ta chn R=3)
r l s mol CO2/1mol amin = 0,03/1
P p sut lm bn trong thp =1,1.10^5 pa
P1 l p sut ring phn ca CO2 tnh theo pt Antoine = 0,018.10^5 pa
A = 1,64
Nlt = 6 a
Bc 7: s a thc ca thp
Nthc = Nlt/ trong l hiu sut a (chn = 0,35)
Nthc = 17 a.
Bc 8: tnh ng knh ca thp
D= 0,0114.[(0,1.Q.T)/(.P)]1/2
Trong : D ng knh thp(m)
Q lu lng dng fuel oil (m3/h)
T nhit dng fuel oil (oK)
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Thit k m hnh thu hi CO2 t kh l thi

Lhdk52

P p sut lm vic (Mpa)

vn tc tuyn tnh ca kh trong thp (chn = 0,13m/s)
D = 16 m.
Bc 9: tnh chiu cao thp
H = Nthc .d +h
d l khong cch gia cc a (chn d=0,5m)
h l chiu cao b tr (gm chop trn v chop di chn h = 1,5m)
H= 10m.
Cc kt qu tnh cng gn vi cc kt qu m HYSIS tnh ra.
2.2. Tnh ton thp chng ct gii hp
Cn bng vt liu
1,529.105.

= 6153 kmole/h

W = F P = 1,529.105 6153 = 146746 kmole/h

Lch khng nhiu so vi s tnh ton ca HYSYS
Tnh ton Rmin
T s liu s tay ha cng tp 2 ta c gin lng hi ca hn hp cu
t. T gin ta xc nh c m, vy ta c:
= m = 0.075
Vy

Rmin = 0.5714

M theo gi thit m phng trong HYSYS ta chn gi tr R = 0,6

= 1,28
1,28 l gi tr chp nhn c
2.3.Tnh ton thit b trao i nhit dng amin Giu / amin ngho:
Gi thit :
Hn hp i trong ng : dng amin ngho
Thnh phn hn hp:
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Thit k m hnh thu hi CO2 t kh l thi

Lhdk52

H2O: 0.855
CO2: 0.030
MEA: 0.115
T1: 120,2oC

T2= 54oC

P1: 700 KPa

P2 = 400 KPa

Lu lng hn hp : 3.496.106 kg/h

Hn hp i ngoi ng : dng amin giu
Thnh phn hn hp:
H2O: 0.837
CO2: 0.053
MEA: 0.110
T1: 44.4oC
P1: 750 KPa

T2 = 110oC
P2 = 450 KPa

Lu lng hn hp : 3.691.106 kg/h

Tnh ton :
Vi dng amin ngho vo ng trao i nhit :
Khi lng phn t trung bnh hn hp = 23.73
Lu lng mol = lu lng khi lng / khi lng phn t trung bnh
= 3.496.106/ 23.73= 1.47.105 kmol/h
Ta c t trng trung bnh hn hp = 41.76
lu lng th tch dng amin ngho = 1.47.105/ 41.67 = 35.28 ( m3/h)
Tng t ta cng tnh ton cc thng s nh trn ca dng amin ngho ra
khi thit b trao i nhit
Vi dng amin giu vo v trao i nhit :
Khi lng phn t trung bnh hn hp = 24.14
Lu lng mol = lu lng khi lng / khi lng phn t trung bnh

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Thit k m hnh thu hi CO2 t kh l thi

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= 3.691.106/ 24.14= 1.53.105 kmol/h

Ta c t trng trung bnh hn hp = 43.69
lu lng th tch dng amin giu = 1.53.105/ 43.69 = 38.52 ( m3/h)
Tng t ta cng tnh ton cc thng s nh trn ca dng amin giu ra
khi thit b trao i nhit
Tnh nhit trung bnh 2 lu th ; vi 2 lu th i ngc chiu nh
o
120oC
54 C
o
110oC
44 C

10 o C

ttb =

10 o C

t d t c
= 10oC
2

Ttb1 =87 oC
Ttb2 =77 oC
Tnh h s cp nhit ca dng hn hp bn trong ng
Do khng c yu cu c bit nn ta chn ch chy xoy n nh,
chn Re= 35000
Theo cng thc : 3.32 sch cc qu trnh thit b trong cng ngh ha
cht v thc phm :
Nu = 0.021 k Re 0.8 Pr0.43 (

0.25

Pr/Prt)

= 0.021 (l/d)k Re 0.8 Pr 0.43 (Pr/Prt)0.25

Trong :
Prt : chun s Prandtl tnh theo nhit trung bnh ca v, cn cc thng s khc
tnh theo nhit trung bnh ca dng.
k : h s hiu chnh tnh n nh hng ca t s gia chiu di l v ng knh d
ca ng.
Tnh Pr theo cng thc ;
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Thit k m hnh thu hi CO2 t kh l thi

Lhdk52

Pr= Cp. /
Trong :
Cp: nhit ring hn hp ttb
: nht hn hp ttb
: h s dn nhit ca hn hp ttb
thay s ta c :
Pr3=.871 0.5391
Pr = 3.94

0.5298

Tnh chun s Prt

Prt= Cpt t/ t
Thay s ta c Prt = 3.463

1= 0.021 (l/d)k Re 0.8 Pr 0.43 (Pr/Prt)0.25

= 0.021(6/0.02)350000.8.3.940.43(3.94/3.463)0.25
= 50600 W/m2.
Tng t ta cng tnh c

2 = 45682

W/m2.

Vy h s truyn nhit
vi thp l h s dn nhit ca thp =45W/m

1
U=
.1 thp 1
1 thp 2

Thay s ta c U= 1.6.106 KJ
h.m 2C

Tnh b mt truyn nhit

F=

Q
Qtb

= 60.65 m2

Tnh s ng truyn nhit :

n=

F
.d .H

60.65
= 161 ng
3.14 0.02 6
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Thit k m hnh thu hi CO2 t kh l thi

Lhdk52

nu chn tng s ng v cch sp xp theo hnh lc gic ta quy chun l n =169

, s ng trn ng xuyn tm l 15 ng
Tnh ng knh trong ca thit b un nng
D= t(b-1) =4d
t: bc ng, t = 50mm
b : s ng trn ng xuyn tm lc gic u
D = 50(15-1) + 4.0,02
D = 0.7 m = 700 mm
vy kch thc ca thit b trao i nhit E101:
F= 60,25 m2
n= 169 ng
D= 700 mm
H= 6m
Nh vy tnh ton thc nghim gn st vi Hysys tnh ton
Sai s l do tra cc gi tr nhit dung, dn nhit, ti cc nhit .
Tng kt thit b trao i nhit trong HYSYS nh sau :
Loi ( TEMA)

ALE

ng knh v thit b, mm 796

S ng

160

B tr ng

Kiu tam gic

ng knh ngoi ng, mm 20

ng knh trong ca ng, 16
Chiu di ng, m

B mt trao i nhit (m2) 60.25

Bc ng, mm

50
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Thit k m hnh thu hi CO2 t kh l thi

Lhdk52

2.4. Tnh ton thit b lm lnh trc tip DDC

Thit b lm lnh trc tip DDC l mt phn xng bao gm 3 quy trnh thit
b: Thit b lm lnh nc tun hon, b cha thng trc tip, bm nc tun
hon.
Thit b lm lnh nc tun hon:
Nhit u vo: t1=300C
p sut: P=103 kPa
Lu lng khi lng: 6.058106 kg/h
Khi lng phn t: 18,02
>lu lng mol =lu lng khi lng/ khi lng phn t
=6.058106 / 18,02=3.612106 kmol/h
T trng ca nc: 55.23
>lu lng th tch = 3.612106 /55.23=65399 m3/h
B cha thng trc tip:
Nhit vo ca nguyn liu:t2= 123.70C
p sut: P=121kPa
Lu lng khi lng: 3.073106 kg/h
Khi lng phn t trung bnh: 27.95
Lu lng mol=lu lng khi lng/khi lng phn t trung bnh
=3.073106/27.95=1.10105 kmol/h
T trng trung bnh ca hn hp nguyn liu vo: 3.667 10-2 kmol/m3
Lu lng th tch: 1.10105/3.667 10-2=2.999106
Bm nc tun hon
Gi T l nhit ca dng ra
Nhit m dng nc mang vo l
Qnc=m1 c 1(T-30)= 6.0581061.002(T-30)=6.070106(T-30)
Nhit m dng nguyn liu mang vo l
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Thit k m hnh thu hi CO2 t kh l thi

Lhdk52

Qnglieu=m2 c2(123.7-T)= 3.0731061.386(123.7-T)=4.259106(123.7-T)

Nhit dng ra l:
Qra=m3c3T=6.5011061.123T=7.301106T
Ta c phng trnh cn bng nhit nh sau:
Qnglieu - Qnc = Qra
4.259106(123.7-T) - 6.070106(T-30)= 7.301106T
T=40.10C
p sut :103 kPa
Lu lng khi lng: 6.501106 kg/h
Lu lng mol=lu lng khi lng/khi lng pt trung bnh
=6.501106/27.91=2.239105
So vi kt qu do hysys tnh ton th kt qu tnh ton bng tay st vi kt qu
tnh ton bng hysys.
2. 5. Thit k bnh tch:
Bnh tch ny c thit k theo nguyn l trng lc
Cng thc xc nh kch c bnh tch theo nguyn l trng lc da trn tc
cho php ca dng kh s cun cc git lng theo pha kh khng xy ra:
V = Ks[(1 g)/g]0,5
1 khi lng ring pha lng iu kin bnh tch lm vic Kg/m3
g khi lng ring pha kh iu kin bnh tch lm vic Kg/m3
V l vn tc cho php ca dng kh m/s
Ks h s bnh tch m/s h s ny ph thuc vo kch c git lng c th tch,
kiu bnh tch, thit b bn trong bnh.
Mc phn ly

Thit b phn ly thng

ng Ho >=0.6m

Thit b phn ly nm
ngang Lo >=3

Sch

0.03

0.075

Trung bnh

0.047

0.117

Th

0.061

0.15

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Thit k m hnh thu hi CO2 t kh l thi

Tnh ton :theo bi ra ta c :

.P=2atm, Ks=0.037 , t=4.6p
qa=4822

=1.35

=1048kg/

ql =32.08

=0.535

=3.338kg/

Lhdk52

T =313K

Vl= ql.t=2.459
H s phn ly
n=

(Gnc,Gnd lu lng cui v u ca pha lng ti li ra v vo

n=88% ph hp vi thp tch dng ng

=0.656m/s
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Thit k m hnh thu hi CO2 t kh l thi

Lhdk52

=1.6189m tng ng trong hysys

Chiu cao thp
V=(3.14

/4).H vi V=5

,d=1.619m

H=2.431m tng ng vi hysys

Chng 3 thit k s :
3.1 thao tc thit k trn hysys:

S quy trnh
3.1.1 thao tc trn mi trng simulation basis manager:
Thao tc
Component/add/tradional
Fluid pkgs/add/amine Pkg

Gi tr
CO2, MEAmin,H2O, Nitrogen
Kent-Eisenberg
Non-idel

3.1.2 thao tc trn mi trng Enviroment

a. Nhp mt dng nguyn liu vi cc thng s sau:
Stream name
Flue gas-1
Temperature (oC)
100
Pressure ( kpa)
101
Mass flow (kg/h)
3.073e+6
Component/mole faction
CO2
0.0375
MEAmin
0.0
H2 O
0.0667
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Thit k m hnh thu hi CO2 t kh l thi

N2

0.8958

b. Qut vn chuyn kh:

Chng ta nhp mt my nn kh compressor vi cc thng s:
connection
Name
Fan 101
Inlet
Flue gas 1
Outlet
2-flue gas
Energy
E fan1
Parameter
Adiabatic Efficiency
80
Operading mode
centrifugal
Curve input option
Single curve
wordsheet
Pressure /2-flue gas
121
c. Phn xng lm lnh trc tip DCC:
Bnh tch:
name
inlet

V-100
2-flue gas
water
3-flue oil
CU-2

Vapour Outlet
Liquid outlet
Bm hi lu y:
name
inlet
Outlet
Energy
CU-3 pressure (kPa)

design
P-100
CU-2
CU-3
E pump1
worksheet
301

Thit b lm mt:
L loi thit b trao i nhit heat exchanger:
Design/conection
Tube side inlet
Tube side outlet

CU-3
CU-4
18

Lhdk52

Thit k m hnh thu hi CO2 t kh l thi

Shell side inlet

Shellside outlet
Design/parameter
Heat exchanger model
Delta P tube side
wordsheet
Tempature(oC)/ CU-4
Thit b iu khin hi lu

Lhdk52

CU-5
CU-6
Exchanger design (Weighted)
198
30

Chn loi Recycler:

Inlet
CU-4
outlet
water
Chuyn sang mc parameter v in cc thng s sau:

d. Thp hp th:
Nhp mt dng amin vi thng s sau:
name
21-lean amin
o
Temperature ( C)
40
Pressure ( Kpa)
101
Molar flow(kgmol/h)
1.529e+5
Composition/ mole fraction
CO2
0.0291
MEAmine
0.1106
H2 O
0.8602
nitrogen
0
Sau nhp phi thp hp th vi cc thng s sau:
Design/conections
name
Adsorber
Top stage inlet
21-lean amin
Bottom stage inlet
3-flue oil
Top stage outlet
4-flue gas to atmosphe
Bottom stage outlet
Rich amin to pump
Pressure top (kPa)
106
Pressure bottom(kPa)
121
Temperature top(C)
49.71
Temperature bottom(C )
44.13
Number stage
18
Parameter/ amin
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Thit k m hnh thu hi CO2 t kh l thi

Weir length(m)
Tray diameter( m)
Parameter/solver
Solving Method
Fixed damping factor
Parameter/efficiencies/reset H2S,

Lhdk52

Modified HYSIM inside-out

0.4

CO2
e. Bm giu amin:
name
inlet
outlet
Energy
Adiabatic efficiency
Pressure 6-rich amin

Pump-2
Rich amin to pump
6-rich amin
E pump2
75%
750 kPa

f. Thp gii hp:

name
Inlet steams/inlet stage
Condenser Energy stream
Vapour outlet
Bottom liquid outlet
P cond (kPa)
P reb (kPa)
T cond(oC)
T reb(oC)
Number stages
Delta P
Design/monitor
Add spec/comp
fraction/reb/liquid/
Add spec/reflux radio

De-adsorber
Rich amin 8/ 1_mair
Condenser11
CO2 recover
Lean amin to pump 2
200
200
90.5
125
12
0
Mole fraction=3.01e-002
0.6

g. Thit b trao i nhit dng amin giu v ngho:

name
heat exchanger 1
Tube inlet
Lean amin to heat exchanger
Tube outlet
Lean amin out heat exchanger
Shell inlet
6-rich amin
Shell outlet
rich amin 7
Worksheet
Lean amin to heat exchanger
700 (kPa)
Lean amin out heat exchanger
400(kPa)
6-rich amin
750(kPa)
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Thit k m hnh thu hi CO2 t kh l thi

rich amin 7

Lhdk52

450(kPa)

h. Giai on hi lu dng amin ngho:

Giai on ny quan trng nht l thit b trn mix-100 b xung dng nc v
amin.
Nhp dng nc nh sau:
name
Water fresh
Temperature ( c)
53.55
Pressure ( kPa)
150
Molar flow (kgmol/h)
5517
Molefaction
CO2
0.012
H2 O
0.9998
Nhp dng amin ngho
name
Amin fresh
Temperature ( c)
53.55
Pressure ( kPa)
150
Molar flow (kgmol/h)
94.63
Molefaction
MEAmin
0.8622
H2 O
0.1378
Nhp mt my trn vi cc thng s sau:
name
MIX-100
Inlet
Amin fresh
Water fresh
16-lean amin
outlet
Lean amin 19
i. Lm lnh tch thu hi CO2:
Thit k vi thng s sau:
name
V-101
inlets
10-CO2 recover
Vapour outlet
11-CO2 recover
Liquid outlet
12-Water make up
3.2 ti u ha :
Qu trnh thc hin ti u ha dng Databook v spreadsheet
3.2.1 kho st trong castudy nh hng ca lu lng kh nguyn liu ti nng
CO2 trong kh i ra thp hp th:
Thit lp trn case study chng ta c kt qu sau:

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Thit k m hnh thu hi CO2 t kh l thi

Lhdk52

4.80E-03
4.60E-03
4.40E-03

%mol CO2

4.20E-03
4.00E-03
3.80E-03
3.60E-03
3.40E-03
3.20E-03
3.00E-03
109000 109500 110000 110500 111000 111500 112000 112500 113000
flow rate fuel (kmol/h)

Nh vy vi mt lng amin khng i trong iu kin thp lm vic n nh

th khi tng lu lng nng u vo nng ca CO2 trong kh sau khi i qua thp
hp th tng ln.
3.2.1 kho st nh hng ca p sut y thp hp th ti hiu sut tch CO2
Khi chng ta thay i p sut ca y thp hp th tc l thay i p sut qua
tng a vi s a ca thp khng i chng ta thu c s nh hng nh sau:
0.94
0.93

Co2 remover degree

0.92
0.91
0.9
0.89
0.88
0.87
0.86
100

200

300
pressure (KPa)

Trong dch chuyn CO2 c tnh theo cng thc:

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400

Thit k m hnh thu hi CO2 t kh l thi

Lhdk52

nCO2 .richa min nCO2leana min

nCO2 . fuel , gas

N c tnh ton nh thit b logical:

V p sut c thay i y thp
Da vo th ta thy khi p sut hp th tng th lng CO2 c loi b cng
ln. hay n c hp th bi amin cng ln. tuy nhin trong iu kin vn hnh
thit k m bo tnh an ton v tnh kinh t th khng nn tng p sut cao. Do
p sut lm vic ca thp cn c cn i thu c kt qu ph hp. s liu
c a ra trn y vi thp gii hp c hi lu 1.27 v nng y ca CO2
khng thay i l 0,028.
3.2.2 kho st s nh hng ca nCO2/namin ti tng nng lng cn cung cp
cho mt tn CO2.
kho st s nh hng ny chng ta cn c nh dch chuyn ca CO2
trong phn th a ra di y chng ta c th ph thuc nh sau:
1.60E+07
1.50E+07
1.40E+07

kj/ton CO2

1.30E+07
1.20E+07
1.10E+07
1.00E+07
9.00E+06
8.00E+06
7.00E+06
6.00E+06
0.15

0.17

0.19

0.21

0.23

0.25

0.27

nCO2/nAmin

Trong t l s mol nco2/namin c ly t dng amin i ra y thp gii hp.

tng nng lng ca ton b qu trnh tnh cho mt tn CO2 c sn xut ra s
ph thuc vo t s ny. Nh ta thy khi m l s mol nco2/namin tng th nng lng
cn thit sn xut 1 tn CO2 gim trong khong kho st. Tuy nhin gim
nng lng nh dn khi nng CO2 tng. Nng lng cung lun i hi nh nht
tuy nhin chng ta cng cn cn i vi thi gian sn xut c 1 tn CO2 v mc
d nng lng gim nhng thi gian sn sut 1 tn CO2 li tng

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Thit k m hnh thu hi CO2 t kh l thi

Lhdk52

3.2.3 kho st s nh hng ca l s mol nco2/namin ti thi gian sn xut 1 tn

CO2 :
24.5
24
23.5
time(s)

23
22.5
22

Series1

21.5
21
20.5
20
0.15

0.2

0.25

0.3

nCO2/nAmin

Ta thy s nh hng ca l s mol nco2/namin ti thi gian sn xut 1 tn CO2

tng nhanh theo t l s mol. Do gim ti thiu thi gian th t l ca
nco2/namin phi c la chn ph hp.
Kt lun: nh vy m bo nng CO2 trong kh thi ra mi trng cho php
chng ta phi quan tm ti t l ca amin hp th vi CO2 trong nguyn liu. c
nhiu yu t nh hng n dch chuyn CO2 lin quan ti thp hp th, p sut
lm vic ca thp l mt yu t cn quan tm. Ngoi ra cn c tinh khit ca
dng amin, nhit lm vic, s a, khong cch a ti u ha nng lng ca
quy trnh i hi nng lng thp nht vn m bo thng s kh thi ra mi trng
v lng CO2 c sn sut ra trong thi gian thch hp. da vo th khi cn i
gia thi gian to ra 1 tn CO2 v nng lng cn thit ta cn t l ca
nCO2/nAmin= 0,27. Khi iu kin lm vic ca thp gii hp s l hi lu
nh l 1.27 v nng CO2 y thp hp th l 0,03.
3.3 so snh kt qu m phng v kt qu tnh ton:
Nhn chung tuy c sai lch do phng php tnh v sai s trong qu trnh tnh
ton. Nhng kt qu nhn chung c th chp nhn c tc l m phng hysys tnh
ton gn st vi kt qu tnh c trong chng 2. thy r hn c th so snh
kt qu ph lc chng 4 v kt qu tnh ton chng 2.

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Thit k m hnh thu hi CO2 t kh l thi

Lhdk52

Chng 4 ph lc

Hnh 1: PFD ca qu trnh hp th CO2 c m phng trong Aspen

Hysys

Hnh 2 : Thp hp th kh dng MEA

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Thit k m hnh thu hi CO2 t kh l thi

Hnh 3: Thp ti sinh MEA

26

Lhdk52

Thit k m hnh thu hi CO2 t kh l thi

Hnh 4: Thng s hot ng ca cc thit b

27

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Thit k m hnh thu hi CO2 t kh l thi

28

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Thit k m hnh thu hi CO2 t kh l thi

Bng 1 : iu kin hot ng cc dng

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Thit k m hnh thu hi CO2 t kh l thi

Bng 2: Thnh phn cc dng

30

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Thit k m hnh thu hi CO2 t kh l thi

Lhdk52

Ti liu tham kho

1. CO2 capture from power plants part 1. Aparametric study of the
technical performance based on monoethanolamine
2. Cost estimation of CO2 removal in HYSYS-candidate: ove Braut
Kallevik ( chapper 2and chapper 3)
3. Bi ging tin ng dng Ks on Hun
4. Hng dn hc Hysys- Nguyn Th Minh Hin- H Bch Khoa H
Ni.
5. Cng ngh ch bin kh thin nhin v kh du m- bn dch ca
Nguyn Vn Phc, Hong Minh Nam, Nguyn nh Soa , Phan
Minh Tn
6. Gas conditionining and processing by John M. Campbell
7. S tay qu trnh v thit b trong cng ngh ha cht tp 2 Ts
Trn Xoa. Pgs,Ts Nguyn Trng Khung, Ts Phm Xun Ton

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