SUB: CHEMISTRY

PAVAN KUMAR KASU

(A)
(B)
(C)
(D)

3:

ET

aq KOH
alc KOH
Product I
C2H5Br
Product II, the correct statement is

Product I is obtained by the elimination reaction

Product II is obtained by the substitution reaction
The molecular formula of Product I is C2H4, while the molecular formula of Product II is C2H6O
Product I is the isomer of dimethyl ether, while Product-II is the dehydrated compound of Product-I

.N

2:

Alkyl halide reacts with an alcoholic solution of ammonia to give a mixture of:
(A) 1 and 2 amine
(B) 1, 2, 3 & quaternary
(C) 1, 2 & 3 amines
(D) 1 & 3 amine

TV

1:

ALKYL AND ARYL HALIDES

(CH3 )2 NH
H 2 / Pd
NO2
X
Y ;
DMF /

CH3
(A) H2N

(B) H

(C) H3C N

(D)

CH3
CH3

NaF
H3C

H3C

(X) ; CH3
O

CHCl

.K

Br

AB

CH3

NH2

4:

Y is :

NaF
H2 O

NH2

H3 C
N

NO2

H3 C

(Y) ; (X) + (Y)

(Z)

CH3

Compound (X) and (Z) are respectively

CH3

(a)

(c)

5:

CH3
CH3

and
OCHMe2

CH3

(d)

CH2 and

CH3

and

(B) More reactive than ethyl bromide

(D) More reactive than isopropyl chloride

Following equation illustrates

200 2500 C

(A) Dows process

(C) Carbylamine test

CH3

OCHMe2

OCHMe 2

C6H5ONa + NaCl
C6H5Cl + 2NaOH
200 atm

7:

(b)

OCHMe2

Chlorobenzene towards hydrolysis is,

(A) Less reactive than benzyl chloride
(C) Nearly as reactive as methyl chloride

6:

and

W
W

CH3

+ H2O
(B) Kolbes process
(D) Haloform reaction

Alkyl halide on heating with alc. NH3 in a sealed tube results

(A) 10 amine
(B) 20 amine
0
(C) 3 amine
(D) all of these

Carbylamine is liberated when . . . . is heated with chloroform and alcoholic potash

(A) An aldehyde
(B) A primary amine
(C) A secondary amine
(D) A phenol

9.

Which of the following substrate(s) upon treating with a base at higher temperature will yield predominantly
Hoffmanns product
a)

CH3CH2CH2 CHCH3

b)

CH3 C H C H CH3
|

Ph

Br

Which of the following (s) aryl halide will react with sodamide / liquid ammonia leading to sustitution via
bezyne mechanism

b)

AB

a)

d)

.K

c)

An alkyl halide of formula C6H13Cl on treatment with potassium t-butoxide gives two isomeric alkenes
(C6H12). Both alkenes on hydrogenation give 2, 3, dimethyl butane. Isomeric alkenes are

W
W

11:

TV

10.

d)

CH3CH2CH2 CHCH3

.N

c)

ET

8:

H3 C

H3C

CH3

CH3

(A)

H2C

and

H3C
CH3

CH3

H3C

H3C

CH3

(B)

(C)

H2C

and
CH3

CH3

H3C

CH3

H3C

CH3

H3C

CH3

and

CH3

H3C
CH3
H2C

and

H2C

CH3

CH3

ET

(D)

Br

12:

NaNH 2
i) alc. KOH

A CH

B. A and B
ii) NaNH
CH Cl
2

(B)

(C)

(D)

None of these

CH 2

CH 3

CH 3

TV

CH2

(A)

CH

CH

On treatment with aqueous KOH gives

13:
H3C

CH3

OH

OH

(A)
CH3

W
W

H3C

.K

CH3

(C)

CH3

H3C

15:

AB

Br

14:

.N

Br

CH3

(B)

H3C

CH3

OH
CH3

(D)

OH

CH3

3-methyl -2-pentene on reaction with HOCl gives

(A) 3-chloro-3-methyl pentanol-2 (B) 2,3-dichloro-3-methyl pentane
(C) 2-chloro-3-methyl pentanol -3 (D) 2,3-dimethyl butanol-2
Silver benzoate reacts with bromine in acetone to form

(A)

Br
(B)

COOAg

(C)

Br

(D)

16:

ET

Br

The reaction described below is

CH3(CH2)5

Conc. OH
Br CH (CH ) CH = CH - CH
3
2 4
3

H3C

(B) E2
(D) SE2

(A) SE1
(C) SN1

Which of the following ether will give always SN2 mechanism in acidic as well as basic conditions?
O

(A)

H3C

(B) C6 H5

CH3

H3C

(C)

AB

(II)

(III)

(A) I < II < III < IV

(C) IV < III < II < I

(IV)

(B) I < IV < II < III

(D) I < II < IV < III

The addition of HBr is easiest with

(A) CH2 = CHCl
(C) CH3 CH = CH2

.K

(B) ClCH = CHCl

(D) (CH3)2C = CH2

W
W

Which one of the following will produce a primary alcohol by reacting with CH3MgI ?
(A) Acetone
(B) Methyl cyanide
(C) Ethylene oxide
(D) Ethyl acetate
KEY
2. D
(A)
18.

1. B
11

Br , (CH3)3CBr

Br ,

(I)

20.

CH3

Order of hydrolysis of the following in increasing order is

Br ,

19:

(D) All of these

O

18:

CH2

TV

17:

.N

3. A
12
(A)

4. B
(C)
19.

5.A
13.
(D)

6. A
(C)
20.

7. D
8. B
14.
(C)
15.
(C)

9. A,C 10. B,D

(B)
16.
(B)

17.

(A)