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A. CAHNE
2,944,917
10203040
607080!)
I NVENTOR
Armand Ca/m
B/Mm/WM
ATTORNE Y5
2,944,917.
Patented July 12, 1960
2
2,944,917
POLYIETRAFLUORGETHYLENE
cracking.
10
In opposition,
The present invention relates to methods for coating 15 some materials, such as pure copper, are uniformly at
surfaces and it particularly has for its object an improved
tacked and the attacked surface remains smooth without
method for coating metal surfaces with a very thin layer
of polytetra?uoroethylene.
mediary layer.
, r.
v.
40
tory treatment are comprised within the rather severe 65 ticular, these cavities must have a narrow or throttled en
2,944,917
dredths of a millimeter, an attacked surface was suitable
C. (700-750 F.).
Example 2
The surface to be treated is made of an alloy designated
mixturerof sulfuric acid and chromic acid, may also be 20 in the trade under the name of _Duralum'in (an alloy
In order that those skilled in the art may better under 25 15% diluted hydro?uoric acid; the plate is washed with
stand how the present invention may be carried into prac
water, then dipped into a 40% solution of hydrochloric
tice' effect, the following illustrated examples are given.
acid at a temperature of 20 C. (68 F.), during 2-5
(the starting acids are technical acids, e.g. technical hy
minutes; the plate is then cooled down, either by taking
drochloric acid at 23 Baurn).
it out of the bath from time to time, or by cooling down
30 the bath. The plate is freed from the chlorides by dip
Example 1
nitric acid.
167
8, minutes.
60
140
20 minutes.
20-25
6877
0a. 2 hours.
. = .
Example 4
table below: .
Percent
Duration of
45? C.
60 0.
20 C.
60
-5-10
immersion
167? F.
140 F.
68 It.
sm'mutes.
20 minutes.
2 hours.
added.
Grams
Sulfuric acid _
_......
5O
20
and a few minutes, theaqueous dispersion of Te?on is
allowed to remain in contact with the metal surface,
which has already been treated as previously mentioned,
The attack is performedat 50-80" C. (:12-2-176" F.)
thus, providing on said metal surface a Te?on layer, the
during ca. ten minutes, and the layer of Te?on is then
thickness of which is in the order of1-3 hundredths of a 75 deposited as described in Example 1.
Water
_.____
150
Example 6
Grams
Example 7
Example 13
fact, as previously explained, that copper is uniformly 25 an aluminum alloy, is directly treated with a ?rst layer
comprising a Te?on dispersion mixed with 10% of the
attacked by acids.
sulfochromic solution indicated below:
Example 8
Grams
l The metal surface to be treated is a stub steel (with 1%
Sulfuric acid ______________________ -1 ______ __
50
carbon, .5% chromium and .l% vanadium).
30 Chromic acid _____' _______________ __ _______ -_ -20
'
>
,1
Water
____________________________________ .._
35
followingmixture:
Example 9
'
' Example 15
150
45
'
Grams
50
--_..-
Example 10
For treating half-cold-hardened low carbon steel hav
ing .10% carbon and .4~.6% manganese, the attack is 55
made with nitric acid at 20 C. (68 F.) during 12
-._
'
150
tion:
__
Grams
50
20
2,944,917
.the
mumminimum
temperature,
time the
and timeemployed
the maximum for
timeany
forparticular
the
attack varying upward from the lower limit to the up
per limit as the temperature employed varies downward
from its upper limit toward its lower limit, and subse
mentary layers of Te?on increase from one elementary 15 a continuous ?lm consistingessentially ,of'polytetra?uoro
ethyleneanchored into said base comprising the steps of
layer to the next one, so that advantage is taken of the
providing anchoring cavities having an average size less
strong anchoring produced by the diluted innermost ele
than 30 microns and a throttled entrance in said base
mentary layer of Te?on laid on the metal base as well
by ?rst attacking the metal with hydrochloric acid and
as of the high non-adhesiveness or hydrophobic charac
teristic given to the whole layer of Te?on by the more 20 then with a sulfochromic solution containing, by weight,
1 tion costs.
ting tool. Said layer can stand the squaring test, which
comprises tracing two perpendicularly disposed groups of
exposed surface; ?nally, the ?lm of Te?on remains strong 35 essentially of polytetra?uoroethylene anchored into said
ethylene in situ.
scale.
'
posited.
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