H$moS> Z.

Series OSR/2

Code No.

amob Z.

56/2/2

narjmWu H$moS >H$mo Cma-nwpVH$m Ho$ _wI-n

>na Ad` {bIo &

Roll No.

Candidates must write the Code on the

title page of the answer-book.

H$n`m OmM H$a b| {H$ Bg Z-n _o _w{V n> 15 h &

Z-n _| Xm{hZo hmW H$s Amoa {XE JE H$moS >Z~a H$mo N>m Cma -nwpVH$m Ho$ _wI-n> na
{bI| &
H$n`m OmM H$a b| {H$ Bg Z-n _| >30 Z h &
H$n`m Z H$m Cma {bIZm ew$ H$aZo go nhbo, Z H$m H$_mH$ Ad` {bI| &
Bg Z-n H$mo nT>Zo Ho$ {bE 15 {_ZQ >H$m g_` {X`m J`m h & Z-n H$m {dVaU nydm
_| 10.15 ~Oo {H$`m OmEJm & 10.15 ~Oo go 10.30 ~Oo VH$ N>m Ho$db Z-n H$mo nT>|Jo
Ama Bg Ad{Y Ho$ XmamZ do Cma-nwpVH$m na H$moB Cma Zht {bI|Jo &
Please check that this question paper contains 15 printed pages.
Code number given on the right hand side of the question paper should be
written on the title page of the answer-book by the candidate.
Please check that this question paper contains 30 questions.
Please write down the Serial Number of the question before
attempting it.
15 minutes time has been allotted to read this question paper. The question
paper will be distributed at 10.15 a.m. From 10.15 a.m. to 10.30 a.m., the
students will read the question paper only and will not write any answer on
the answer-book during this period.

agm`Z {dkmZ (gmpVH$)

CHEMISTRY (Theory)

{ZYm[aV g_` : 3 KQ>o

A{YH$V_ AH$ : 70

Time allowed : 3 hours

56/2/2

Maximum Marks : 70
1

P.T.O.

gm_m` {ZX}e :
(i)

g^r Z A{Zdm` h &

(ii)

Z-g`m 1 go 8 VH$ A{V bKw-Cmar` Z h & `oH$ Z Ho$ {bE 1 AH$ h &

(iii)

Z-g`m 9 go 18 VH$ bKw-Cmar` Z h & `oH$ Z Ho$ {bE 2 AH$ h &

(iv)

Z-g`m 19 go 27 VH$ ^r bKw-Cmar` Z h & `oH$ Z Ho$ {bE 3 AH$ h &

(v)

Z-g`m 28 go 30 VH$ XrK-Cmar` Z h & `oH$ Z Ho$ {bE 5 AH$ h &

(vi)

Amd`H$VmZwgma bmJ Q>o~bm| H$m `moJ H$a| & H$Hw$boQ>am| Ho$ Cn`moJ H$s AZw_{V Zht h &

General Instructions :
(i)

All questions are compulsory.

(ii)

Questions number 1 to 8 are very short-answer questions and carry

1 mark each.

(iii)

Questions number 9 to 18 are short-answer questions and carry 2 marks

each.

(iv)

Questions number 19 to 27 are also short-answer questions and carry

3 marks each.

(v)

Questions number 28 to 30 are long-answer questions and carry 5 marks

each.

(vi)

Use Log Tables, if necessary. Use of calculators is not allowed.

1.

YmVwAm| Ho$ OmoZ n[aemoYZ H$s {d{Y H$m AmYma_yb {gmV `m h

On what principle is the method of zone refining of metals based ?

2.

Cg VmnH$_ H$m Zm_ {b{IE {Oggo D$na {_gob

(micelles) ~ZVo

h &

Name the temperature above which the formation of micelles takes

place.

56/2/2

3.

{ZZ H$mo BZHo$ ~T>Vo hE jmar` H$_ _| `dpWV H$s{OE

NH3, PH3, AsH3, SbH3, BiH3

Arrange the following in the increasing order of their basic character :
NH3, PH3, AsH3, SbH3, BiH3
4.

{ZZ gH$a {H$g H$ma H$s g_md`dVm {XImVm h

[Co(NH3)5SO4]Cl
What type of isomerism is exhibited by the following complex :
[Co(NH3)5SO4]Cl
5.

f.c.c.

EH$H$ gob Ho$ {H$Zmao H$s b~mB (a) Ama na_mUw {`m (r) H$m Amngr g~Y
{b{IE &

Express the relationship between atomic radius (r) and the edge
length (a) of the f.c.c. unit cell.
6.

BZ XmoZm| _| go H$mZ-gm A{YH$ jmar` h Ama `m|

CH3NH2

AWdm

NH3

Which of the two is more basic and why ?

CH3NH2 or NH3
7.

Cg `m{JH$ H$m Zm_ {b{IE Omo ~hbH$sH$aU na {ZAmoorZ XoVm h &

Name the compound which on polymerisation gives neoprene.

8.

{ZZ{b{IV `m{JH$ H$m AmB.`y.nr.E.gr.

(IUPAC) Zm_

{b{IE

Write the IUPAC name of the following compound :

56/2/2

P.T.O.

9.

{ZZ{b{IV Ho$ H$m` {b{IE

(i)

{ZH$b Ho$ emoYZ _|

CO H$m

(ii)

Eobw{_{Z`_ Ho$ {dwV-YmVwH$_ _| Jo\$mBQ> N>S> H$m

Write the role of the following :

10.

(i)

CO in the purification of nickel

(ii)

Graphite rod in the electrometallurgy of aluminium

{ZZ g_rH$aUm| H$mo nyam H$s{OE

(i)

2 MnO 4 + 5 NO2 + 6 H+

(ii)

Cr2O7

+ 14 H+ + 6 e

Complete the following equations :

11.

(i)

2 MnO 4 + 5 NO2 + 6 H+

(ii)

Cr2O7

+ 14 H+ + 6 e

gH$a [Ni(CN)4] 2 H$s gH$aU AdWm, AmH${V Ama

(Ni H$m na_mUw H$_mH$ = 28)

IUPAC Zm_

{b{IE &
2

Write the state of hybridization, shape and IUPAC name of the complex
[Ni(CN)4] 2. (Atomic no. of Ni = 28)
12.

amgm`{ZH$ g_rH$aU {b{IE O~

(i)

_o{Wb bmoamBS> H$s

(ii)

{ZOb

AlCl3 H$s

AgNO2 go

A{^{H$`m H$s OmVr h &

CnpW{V _| ~mo_mo~oOrZ H$s

CH3Cl go

A{^{H$`m H$s OmVr h &

Write chemical equations when

56/2/2

(i)

methyl chloride is treated with AgNO2.

(ii)

bromobenzene is treated with CH3Cl in the presence of anhydrous

AlCl3.
4

13.

{ZZ A{^{H$`mAm| _| `w$ A{^H$_H$m| Ho$ Zm_ {b{IE :

(i)
\$sZmb H$s ZmBQ>oeZ mam 2,4,6-Q>mBZmBQ>mo\$sZmb ~ZmZm
(ii)
`yQ>oZb go `yQ>oZmb ~ZmZm
(iii) Eo{Zgmob H$m \$sS>ob H$mQ>g Eogr{Q>brH$aU
(iv) mW{_H$ EoH$mohmb Ho$ AmgrH$aU go EopS>hmBS> ~ZmZm

Name the reagents used in the following reactions :

14.

(i)

Nitration of phenol to 2,4,6-trinitrophenol

(ii)

Butanal to Butanol

(iii)

Friedel Crafts acetylation of anisole

(iv)

Oxidation of primary alcohol to aldehyde

(a)

{ZZ `w_m| go {H$g EopH$b hobmBS> H$s Amn SN2 {H$`m{d{Y mam A{YH$ VrdVm
go A{^{H$`m H$aZo H$s Amem H$a|Jo Ama `m| ?
CH3 CH2 CH CH3

Br

(b)

SN1 A{^{H$`mAm|

(a)

Which alkyl halide from the following pairs would you expect to
react more rapidly by an SN2 mechanism and why ?

(b)

15.

CH3 CH2 CH2 CH2 Br

_| ao{g_rH$aU hmo OmVm h & `m|

CH3 CH2 CH CH3

CH3 CH2 CH2 CH2 Br

Br
Racemisation occurs in SN1 reactions. Why ?

{ZZ A{^{H$`m H$s {H$`m{d{Y {b{IE

HBr
CH3CH2OH
CH3CH2Br H2O
Write the mechanism of the following reaction :

HBr
CH3CH2OH
CH3CH2Br H2O
56/2/2

P.T.O.

16.

Ho$ EH$ {db`Z H$m b{Q>Z_ Ho$ BboQ>moS>m| Ho$ ~rM 5.0 Eonr`a {dwV Ymam go
20 {_ZQ> VH$ dwV AnKQ>Z {H$`m J`m & H$WmoS> na {ZH$b H$m {H$VZm `_mZ {Zjo{nV
hmoJm ?
({X`m J`m h : {ZH$b H$m na_mUw `_mZ = 58.7 g mol1, 1 F = 96500 C mol1)
Ni(NO3)2

A solution of Ni(NO3)2 is electrolysed between platinum electrodes using

a current of 5.0 ampere for 20 minutes. What mass of nickel will be
deposited at the cathode ?
(Given : At. Mass of Ni = 58.7 g mol1, 1 F = 96500 C mol1)
17.

A{^{H$`m H$s AY Am`w H$s n[a^mfm {b{IE & {ZZ Ho$ AY Am`w Ho$ {b`o `OH$
{b{IE :
(i)

ey` H$mo{Q> H$s A{^{H$`m

(ii)

W_ H$mo{Q> H$s A{^{H$`m

Define half-life of a reaction. Write the expression of half-life for

18.

(i)

zero order reaction and

(ii)

first order reaction.

g\$a Ho$ Xmo A{V _hdnyU Ana$nm| Ho$ Zm_ {b{IE & BZ XmoZm| _| go H$mZ -gm H$j Vmn
na Wm`r hmoVm h ? `m hmoVm h O~ Wm`r $n H$mo 370 K go D$na Ja_ {H$`m OmVm h ?

AWdm
(i)

gnH$ {d{Y go H2SO4 H$s m{ H$mo A{YH$V_ ~ZmZo Ho$ {V~Y {b{IE &

(ii)

Ob _o

H2SO4 Ho$

{bE

Ka << Ka
2

`m| h

Name the two most important allotropes of sulphur. Which one of the two
is stable at room temperature ? What happens when the stable form is
heated above 370 K ?
OR

56/2/2

(i)

Write the conditions to maximize the yield of H2SO4 by contact

process.

(ii)

Why is Ka << Ka for H2SO4 in water ?

2

19.

bmpQ>>H$ Ho$ Wbm| na {V~Y bJ OmZo Ho$ CnamV, EH$ Hy$b Ho$ N>mm| Zo {ZU` {b`m {H$
dh bmoJm| H$mo dmVmdaU Ama `_wZm ZXr na bmpQ>>H$ Ho$ Wbm| Ho$ hm{ZH$maH$ ^mdm| go
gy{MV H$a|Jo & ~mV H$mo A{YH$ ^mdr ~ZmZo Ho$ {bE, Chm|Zo Xgao Hy$bm| Ho$ gmW {_bH$a
EH$ abr aMr Ama gpO`m ~oMZo dmbm|, XH$mZXmam| Ama {S>nmQ>_oQ>b Q>moam| _| H$mJO Ho$
Wbo ~mQ>o & g^r N>mm| Zo U {H$`m {H$ do `_wZm ZXr H$mo ~MmZo Ho$ {bE ^{d` _| nmbrWrZ
Ho$ Wbm| H$m `moJ Zht H$a|Jo &
Cn`w$ boIme H$mo nT>H$a {ZZ Zm| Ho$ Cma Xr{OE

(i)

N>mm|o Zo {H$Z _y`m| H$mo Xem`m h

(ii)

Od-{ZZrH$aUr` ~hbH$ `m hmoVo h ? EH$ CXmhaU Xr{OE &

(iii)

`m nmbrWrZ EH$ g_ (hmo_mo) ~hbH$ h AWdm gh

(co-) ~hbH$

After the ban on plastic bags, students of one school decided to create
awareness among the people about the harmful effects of plastic bags on
the environment and the Yamuna river. To make it more impactful, they
organized a rally by joining hands with other schools and distributed
paper bags to vegetable vendors, shopkeepers and departmental stores.
All students pledged not to use polythene bags in future to save the
Yamuna river.
After reading the above passage, answer the following questions :

56/2/2

(i)

What values are shown by the students ?

(ii)

What are biodegradable polymers ? Give one example.

(iii)

Is polythene a homopolymer or copolymer ?

P.T.O.

20.

{ZZ nXm| H$s n[a^mfmE {b{IE

(a)
nmbrgHo$amBS>
(b)
Eo_rZmo Ab
(c)
EOmB_

Define the following terms :

21.

(a)

Polysaccharides

(b)

Amino acids

(c)

Enzymes

(i)

EoQ>r{hQ>m_rZ H$s EH$ CXmhaU g{hV n[a^mfm {b{IE &

(ii)

{ZZ Amf{Y`m| _| go H$mZ-gr {VO{dH$ h :

_m\$sZ, Bdm{Zb, bmoaEo\${ZH$mob, Eopn[aZ &

(iii)

EonmQ>o_ H$m Cn`moJ R>S>o ^moOZ Ama no` nXmWmo VH$ gr{_V `m| hmoVm h

(i)

Define Antihistamine with an example.

(ii)

Which one of the following drugs is an antibiotic :

Morphine, Equanil, Chloramphenicol, Aspirin.

(iii)
22.

Why is use of aspartame limited to cold food and drink ?

{ZZ A{^{H$`mAm| _|

A, B Ama C H$s

gaMZmE ~VmBE :

(i)

HNO2
LiAlH4
KCN
CH3Br A
B
C
273 K

(ii)

NH3
CHCl NaOH
Br2 KOH
CH3COOH
A

B 3
C

Give the structures of A, B and C in the following reactions :

56/2/2

(i)

HNO2
LiAlH4
KCN
CH3Br A
B
C
273 K

(ii)

NH3
CHCl NaOH
Br2 KOH
CH3COOH
A

B 3
C

23.

(i)

KCl {H$g

(ii)

{g{bH$mZ H$mo

(iii)

{ZZ _| go H$mZ-gm AmpdH$ R>mog H$m CXmhaU h

CO2 AWdm SiO2

(iv)

BZ_| go H$mZ-gm A{YH$ AN>o Mw~H$ ~ZmEJm, \o$amoMw~H$s` nXmW AWdm

\o$arMw~H$s` nXmW ?

H$ma H$m agg_rH$aU{_Vr` Xmof {XImVm h Ama `m|

As go

S>mo{nV H$aZo na {H$g H$ma H$m AYMmbH$ ~ZVm h

(i)

What type of stoichiometric defect is shown by KCl and why ?

(ii)

What type of semiconductor is formed when silicon is doped with

As ?

(iii)

Which one of the following is an example of molecular solid :

CO2 or SiO2

24.

(iv)

What type of substances would

ferromagnetic or ferrimagnetic ?

(i)

gmYmaU gob H$s VwbZm _|

(ii)

ZrMo Xr JB gob A{^{H$`m Ho$ {b`o gm` pWamH$

H2 O2

make

better

magnets,

BYZ gob Ho$ Xmo bm^ {b{IE &

(Kc) 10

h & BgHo$ {b`o

n[aH${bV H$s{OE &

gob
3

(i)

Write two advantages of H2 O2 fuel cell over ordinary cell.

(ii)

Equilibrium constant (Kc) for the given cell reaction is 10.

o

Calculate Ecell .

56/2/2

P.T.O.

25.

pWa Am`VZ AdWm _|

hE Wo :

SO2Cl2

Ho$ W_ H$mo{Q> Ho$ D$_r` AnKQ>Z _| {ZZ AmH$S>o m

SO2Cl2 (g) SO2 (g) Cl2(g)

g_`/s1 gH$b Xm~/atm

`moJ
1

0 .4

100

0 .7

doJ pWamH$ n[aH${bV H$s{OE &

({X`m J`m h : log 4 = 0.6021,

log 2 = 0.3010)

The following data were obtained during the first order thermal
decomposition of SO2Cl2 at a constant volume :

SO2Cl2 (g) SO2 (g) Cl2(g)

Experiment

Time/s1

Total pressure/atm

0 .4

100

0 .7

Calculate the rate constant.

(Given : log 4 = 0.6021, log 2 = 0.3010)
26.

(a)
(b)
(c)

56/2/2

R>mogm| na Jgm| Ho$ A{YemofU Ho$ {bE \$m`S>{bH$ A{YemofU g_Vmnr

(isotherm) Ho$ {bE EH$ g_rH$aU Ho$ $n _| `OH$ {b{IE &
_IZ Ho$ n[a{j mdWm Ama n[ajon _m`_ `m h ?
g_w Ama ZXr Ho$ {_bZo Ho$ WmZ na S>oQ>m ~ZVm h & `m| ?

(a)

Write the expression for the Freundlich adsorption isotherm for

the adsorption of gases on solids, in the form of an equation.

(b)

What are the dispersed phase and dispersion medium of butter ?

(c)

A delta is formed at the meeting place of sea and river water.

Why ?
10

27.

(a)

bWoZm`S> H$mZ-H$mZ gr {d{^ CnMm`r AdWmE {XImVo h

(b)

gH$_U Vdm| H$s Xmo {deofVmE {b{IE &

(c)

3d-bmH$
`m| ?

Ho$ Vdm| _| go {H$Z-{H$Z H$mo gH$_U Vd Zht _mZm Om gH$Vm h Ama

3

AWdm
{ZZ Ho$ {bE Cn`w$ H$maU {b{IE

+3

AmgrH$aU AdWm H$mo m H$aZo Ho$ {bE

2+
Mn `m{JH$ A{YH$ Wm`r hmoVo h &

Fe2+

(a)

AnZr

(b)

Sc (Z = 21)

(c)

Obr` {db`Z _|o

(a)

What are the different oxidation states exhibited by the

lanthanoids ?

(b)

Write two characteristics of the transition elements.

(c)

Which of the 3d-block elements may not be regarded as the

transition elements and why ?

go Zn (Z = 30) VH$ Ho$

na_mUwH$aU H$s EoWnr g~go H$_ hmoVr h &
Sc3+ aJhrZ

hmoVm h O~{H$

3d

`m{JH$mo H$s VwbZm _|

grarO Ho$ Vdm| _| go

Ti3+ aJrZ

Zn

H$s

hmoVm h &

OR
Assign suitable reasons for the following :
(a)

The Mn2+ compounds are more stable than Fe2+ towards oxidation
to their + 3 state.

(b)

In the 3d series from Sc (Z = 21) to Zn (Z = 30), the enthalpy of

atomization of Zn is the lowest.

(c)

56/2/2

Sc3+ is colourless in aqueous solution whereas Ti3+ is coloured.

11

P.T.O.

28.

(a)

EoWoZb Ho$ {ZZ A{^H$maH$m| Ho$ gmW A{^{H$`m H$aZo na ~Zo CnmXm| H$mo {b{IE :
(i)
CH3MgBr go Ama {\$a H3O+ go
(ii) Zn-Hg/gm HCl go
(iii)

VZw

NaOH H$s

C6H5CHO go

CnpW{V _|

{ZZ `m{JH$ `w_mo _| nana ^oX H$aZo Ho$ {bE gab amgm`{ZH$ narjU Xr{OE
(i)
~oOmoBH$ Ab Ama E{Wb ~oOmoEQ>
(ii) monoZb Ama `yQ>oZ-2-AmoZ
AWdm

(a)

{ZZ Ho$ H$maU {b{IE :

(i)
HCN Ho$ gmW A{^{H$`m H$aZo _| CH3COCH3 go CH3CHO A{YH$
A{^{H$`merb hmoVm h &
(ii) go_rH$m~oOmBS> (H2NNHCONH2) _| Xmo NH2 Jwn hmoVo h & {\$a ^r
go_rH$m~mOmoZ ~ZmZo _| Ho$db EH$ NH2 Jwn {H$`mH$mar hmoVm h &

(b)

{ZZ Zm_Ymar A{^{H$`mAmo Ho$ {bE amgm`{ZH$ g_rH$aU {b{IE

(i)
amoOoZ_wS A{^{H$`m
(ii) hob-dmobmS>-Oo{bH$s A{^{H$`m
(iii) H$ZrOmamo A{^{H$`m

(a)

Write the products formed when ethanal reacts with the following
reagents :
(i)

CH3MgBr and then H3O+

(ii)

Zn-Hg/conc. HCl

(iii)

C6H5CHO in the presence of dilute NaOH

Give simple chemical tests to distinguish between the following

pairs of compounds :
(i)

Benzoic acid and Ethyl benzoate

(ii)

Propanal and Butan-2-one

OR

56/2/2

(b)

(b)

12

(a)

Account for the following :

(i)

CH3CHO is more reactive than CH3COCH3 towards reaction

with HCN.

(ii)

There
are
two
NH2 groups
in
semicarbazide
(H2NNHCONH2). However, only one is involved in the
formation of semicarbazone.

(b)

29.

(a)

(b)

Write the chemical equation to illustrate each of the following

name reactions :
(i)

Rosenmund reduction

(ii)

Hell-Volhard-Zelinsky reaction

(iii)

Cannizzaro reaction

dmnerb Ad`dm| dmbo {db`Z Ho$ {bE amCQ> {Z`_ {b{IE & g^r gmUm|o Ama
VmnH$_m| na amCQ> {Z`_ AZwgma ahZo dmbo {db`Z H$m Zm_ {b{IE &
Ob _| 10 g CaCl2 KmobZo go m hE {db`Z Ho$ {bE dWZmH$ C`Z
H$mo n[aH${bV H$s{OE & (Ob Ho$ {bE Kb = 0.512 K kg mol1,
CaCl2 H$m _moba `_mZ = 111 g mol1)

200 g

AWdm
(a)

(b)

56/2/2

{ZZ nXm| H$s n[a^mfmE {b{IE :

(i)

pWadmWr (Eo{O`moQ>mon)

(ii)

namgaUr (Amog_m{Q>H$) Xm~

(iii)

AUwg` (H$mo{bJo{Q>d) JwUY_

9.8% (w/w) H2SO4

Ho$ {db`Z H$s _mobaVm n[aH${bV H$s{OE `{X Bg {db`Z

H$m KZd 1.02 g ml1 hmo & (H2SO4 H$m _moba `_mZ = 98 g mol1)
13

P.T.O.

(a)

State Raoults law for a solution containing volatile components.

Name the solution which follows Raoults law at all concentrations
and temperatures.

(b)

Calculate the boiling point elevation for a solution prepared by

adding 10 g of CaCl2 to 200 g of water. (Kb for water =
0.512 K kg mol1, Molar mass of CaCl2 = 111 g mol1)
OR

(a)

(b)

Define the following terms :

(i)

Azeotrope

(ii)

Osmotic pressure

(iii)

Colligative properties

Calculate the molarity of 9.8% (w/w) solution of H2SO4 if the density

of the solution is 1.02 g ml1. (Molar mass of H2SO4 = 98 g mol1)

30.

(a)

{ZZ Ho$ H$maU ~VmBE :

(i)
+ 5 AdWm _| Bi ~b CnMm`H$ hmoVm h &
(ii) PCl5 Vmo OmZm OmVm h naVw NCl5 Zht &
(iii) bmh HCl _| KwbH$a FeCl2 ~ZmVm h, FeCl3 Zht &

(b)

{ZZ H$s gaMZmE ~ZmBE :

(i)

XeOF4

(ii)

HClO4

AWdm
(a)

56/2/2

{ZZ H$s gaMZmE ~ZmBE :

(i)

H2S2O8

(ii)

bmb

P4
14

(b)

(a)

(b)

{ZZ Ho$ H$maU {b{IE

(i)

dmn AdWm _| JYH$ (g\$a) AZwMw~H$d X{eV H$aVm h &

(ii)

OrZmZ go {^, hr{b`_ H$m H$moB nQ amgm`{ZH$> `m{JH$ kmV Zht

h &

(iii)

H3PO3 go H3PO2 EH$

A{YH$ ~b AnMm`H$ h &

Account for the following :

(i)

Bi is a strong oxidizing agent in the + 5 state.

(ii)

PCl5 is known but NCl5 is not known.

(iii)

Iron dissolves in HCl to form FeCl2 and not FeCl3.

Draw the structures of the following :

(i)

XeOF4

(ii)

HClO4
OR

(a)

(b)

56/2/2

Draw the structures of the following :

(i)

H2S2O8

(ii)

Red P4

Account for the following :

(i)
Sulphur in vapour state exhibits paramagnetism.
(ii) Unlike xenon, no distinct chemical compound of helium is
known.
(iii) H3PO2 is a stronger reducing agent than H3PO3.

15

2,800
P.T.O.