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2. INTRODUCTION
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2.1 HISTORY
Jan Rudolph Deiman and Adriaan Paets van Troostwijk used in 1789 an electrostatic
machine to produce electricity which was discharged on gold electrodes in a Leyden jar
with water. In 1800 Alessandro Volta invented the voltaic pile, and a few weeks later
William Nicholson and Anthony Carlisle used it for the electrolysis of water. When
Znobe Gramme invented the Gramme machine in 1869 electrolysis of water became a
cheap method for the production of hydrogen. A method of industrial synthesis of
hydrogen and oxygen through electrolysis was developed by Dmitry Lachinov in 1888.
2.2 PRINCIPLE
An electrical power source is connected to two electrodes, or two plates (typicly made
from some inert metal such as platinum, stainless steel or iridium) which are placed in the
water. Hydrogen will appear at the cathode (the negatively charged electrode, where
electrons enter the water), and oxygen will appear at the anode (the positively charged
electrode). Assuming ideal faradaic efficiency, the amount of hydrogen generated is twice
the amount of oxygen, and both are proportional to the total electrical charge conducted
by the solution. However, in many cells competing side reactions dominate, resulting in
different products and less than ideal faradaic efficiency.
Electrolysis of pure water requires excess energy in the form of over potential to
overcome various activation barriers. Without the excess energy the electrolysis of pure
water occurs very slowly or not at all. This is in part due to the limited self-ionization of
water. Pure water has an electrical conductivity about one millionth that of seawater.
Many electrolytic cells may also lack the requisite electro catalysts. The efficiency of
electrolysis is increased through the addition of an electrolyte (such as a salt, an acid or a
base) and the use of electro catalysts.
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Currently the electrolytic process is rarely used in industrial applications since hydrogen
can currently be produced more affordably from fossil fuels.
3.EQUATIONS INVOLVED
In pure water at the negatively charged cathode, a reduction reaction takes place, with
electrons (e) from the cathode being given to hydrogen cations to form hydrogen gas
(the half reaction balanced with acid):
Reduction at cathode: 2 H+(aq) + 2e H2(g)
At the positively charged anode, an oxidation reaction occurs, generating oxygen gas and
giving electrons to the anode to complete the circuit:
Oxidation at anode: 2 H2O(l) O2(g) + 4 H+(aq) + 4e
The same half reactions can also be balanced with base as listed below. Not all half
reactions must be balanced with acid or base. Many do, like the oxidation or reduction of
water listed here. To add half reactions they must both be balanced with either acid or
base.
Cathode (reduction): 2 H2O(l) + 2e H2(g) + 2 OH(aq)
Anode (oxidation): 4 OH(aq) O2(g) + 2 H2O(l) + 4 e
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4.THERMODYNAMICS
Decomposition of pure water into hydrogen and oxygen at standard temperature and
pressure is not favorable in thermodynamic terms.
Anode (oxidation): 2 H2O(l) O2(g) + 4 H+(aq) + 4e
E0OX = -1.23 V
E0RED= 1.23
Cathode (reduction): 2 H+(aq) + 2e H2(g)
E0RED = 0.00 V
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Thus, the standard potential of the water electrolysis cell is -1.23 V at 25 C at pH 0 (H+
= 1.0 M). At 25 C with pH 7 (H+ = 1.0107 M), the potential is unchanged based on the
Nernst equation. The thermodynamic standard cell potential can be obtained from
standard-state free energy calculations to find G and then using the equation: G=
-nFE(where E is the cell potential). In practice when an electrochemical cell is "driven"
toward completion by applying reasonable potential, it is kinetically controlled. Therefore
activation energy, ion mobility (diffusion) and concentration, wire resistance, surface
hindrance including bubble formation (causes electrode area blockage), and entropy,
require a greater applied to potential to overcome these factors.
5.ELECTROLYTE SELECTION
If the above described processes occur in pure water, H + cations will accumulate at the
anode and OH anions will accumulate at the cathode. This can be verified by adding a
pH indicator to the water: the water near the anode is acidic while the water near the
cathode is basic. The negative hydroxyl ions that approach the anode mostly combine
with the positive hydronium ions (H 3O+) to form water. The positive hydronium ions that
approach the negative cathode mostly combine with negative hydroxyl ions to form
water. Relatively few hydronium (hydroxyl) ions reach the cathode (anode). This can
cause a concentration overpotential at both electrodes.
Pure water is a fairly good insulator since it has a low autoionization, Kw = 1.0 x 1014 at
room temperature and thus pure water conducts current poorly, 0.055 Scm 1. Unless a
very large potential is applied to cause an increase in the autoionization of water the
electrolysis of pure water proceeds very slowly limited by the overall conductivity.
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6.ELECTROLYSIS TECHNIQUE
Two leads, running from the terminals of a battery, are placed in a cup of water with a
quantity of electrolyte to establish conductivity in the solution. Using NaCl (table salt) in
an electrolyte solution results in chlorine gas rather than oxygen due to a competing halfreaction. With the correct electrodes and correct electrolyte, such as baking soda,
hydrogen and oxygen gases will stream from the oppositely charged electrodes. Oxygen
will collect at the positively-charged electrode (anode) and hydrogen will collect at the
negatively-charged electrode (cathode). Note that hydrogen is positively charged in the
H2O molecule, so it ends up at the negative electrode. (And vice versa for oxygen.)
Note that an aqueous solution of water with chloride ions will, when electrolysed, either
result in either OH if the concentration of Cl is low, OR in chlorine gas being
preferentially discharged if the concentration of Cl is greater than 25% by mass in the
solution.
7.EFFICIENCY
7.1 THERMODYNAMICS
The electrolysis of water in standard conditions requires a theoretical minimum of 237 kJ
of electrical energy input to dissociate each mole of water, which is the standard Gibbs
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free energy of formation of water. It also requires energy to overcome the change in
entropy of the reaction. Therefore, the process cannot proceed below 286 kJ per mol if no
external heat/energy is added.
Since each mole of water requires two moles of electrons, and given that the Faraday
constant F represents the charge of a mole of electrons (96485 C/mol), it follows that the
minimum voltage necessary for electrolysis is about 1.23 V. However, observing the
entropy component (and other losses), voltages over 1.48 V are required for the reaction
to proceed at practical current densities (the thermoneutral voltage).
In the case of water electrolysis, Gibbs free energy represents the minimum work
necessary for the reaction to proceed, and the reaction enthalpy is the amount of energy
(both work and heat) that has to be provided so the reaction products are at the same
temperature as the reactant (i.e. standard temperature for the values given above). An
electrolyser operating at 1.48 V would be 100% efficient.
7.2 OVERPOTENTIAL
Real water electrolysers require higher voltages for the reaction to proceed. The part that
exceeds 1.23 V is called overpotential or overvoltage, and represents any kind of loss and
non ideality in the electrochemical process.
For a well designed cell the largest overpotential is the reaction overpotential for the fourelectron oxidation of water to oxygen at the anode; electrocatalysts can facilitate this
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reaction, and platinum alloys are the state of the art for this oxidation. Developing a
cheap, effective electrocatalyst for this reaction would be a great advance, and is a topic
of current research, there are many approaches among them a 30 year old recipe for
molybdenum sulfide, graphene quantum dots, carbon nanotubes and perovskite.The
simpler two-electron reaction to produce hydrogen at the cathode can be electrocatalyzed
with almost no overpotential by platinum, or in theory a hydrogenase enzyme. If other,
less effective, materials are used for the cathode (e.g. graphite), large overpotentials will
appear.
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option is the introduction of hydrogen gas into the combustion process of an IC engine.
Hydrogen gas is an example of a renewable energy source that can be used to partially
supplement diesel or petrol fuel by enriching supply air. Advantages of introducing
hydrogen gas include higher net heating value and diffusivity of hydrogen in air
when compared to fossil fuels. This means that including it in the combustion
process can lead to a more complete combustion of the fuel air mix. A more complete
combustion can result in the reduction of harmful exhaust emissions such as
hydrocarbons (HCs), nitrogen oxides (NOx) and carbon monoxide (CO). In addition,
better diffusivity produces a much faster flame velocity (on the order of 10x) that
can lead to a better acceleration and torque output from the engine.
Musmar and Al-Rousan conducted detailed research on the performance of a single
cylinder Honda G200 engine using air enriched with HHO gas. The HHO generator
used was box shaped, with electrodes made of stainless steel grade 316-L,
electrolysing water. The water was enhanced using sodium bicarbonate. The
engine speed was varied from 1000 rpm to 2300 rpm. This work demonstrated the
feasibility of introducing an HHO generator into the engine compartment as the
generator was about the size of a standard 12V car battery. In addition introduction of
HHO resulted in 54% reduction in NOx and20% reduction in CO. It was also noted
that HHO concentration varied with engine speed. This could have been a result of
no control on electric current fed to the generator. No information is given on the
performance of the HHO generator used.
In more recent work, Leelakrishnan and Suriyan investigated the effects of HHO gas
enriched air on the performance of a single cylinder, four stroke, 5.4 kW SI petrol
engine. Enriched air was supplied to the engine through a passage between the air filter
and the carburettor. Results reported indicate 5% improvement in brake power, 7%
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test.
Furthermore, the
engine used
is
9.WORKING DIAGRAM
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10.3 BATTERY
12 volts bike battery is used in air booster.
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11.SAFETY PRECAUTIONS
Before getting into the details of how to construct the booster,you must be aware of
what needs to be done when using a hydrogen generator of any design. Firstly, hydroxy
hho gas is highly explosive. If it wasnt, it would not be able to do its job of improving
the gas milege your vehicle is getting, Hydroxy gas needs to be treated with care and
caution. It is important to make sure that it goes into the engine as designed and
nowhere else. It is also important that it gets ignited inside the engine and nowhere else.
To make this happen, a number of common-sense steps need to be taken. Firstly, the
hydrogen generator must not make hydrogen gas when the engine is not running. The
best way to arrange this is to switch off the electricity going to the booster. It is not
enough to just have a manually-operated dashboard On/Off switch as it is almost certain
to be forgotten one day. And the generator will be left on making gas while the engine is
off Instead, the electrical supply to the booster is sent through the ignition switch of the
car. That way, when the engine is turned off, we can be sure that the hydrogen generator
is turned off. So as not to put too much amp load through the ignition switch, and to
allow for the possibility of the ignition switch being on when the engine is not running,
instead of wiring the hydrogen generator directly to the switch, it is recommended that
you wire a standard automotive relay across the oil pressure sending unit and then the
relay carry the amp load electricity.
The fuel pump is powered down automatically when the key is off, and so this will also
shut off the hydrogen generator.
An extra safety feature is to allow for the (very unlikely) possibility of an electrical
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short circuit occurring in the Hydrogen generator or its wiring. This is done by
putting a fuse or contact-breaker between the battery and the new Wiring As shown
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12.REFRENCES
1. A. Al-Rousan, "Reduction of fuel consumption in gasoline engines by introducing
HHO gas into intake manifold," International Journal of Hydrogen, vol. 35, pp. 1293012935, August 2003
2.M. S. Yadav, S. M. Sawant, and H. V. Chavan, "Investigations on generation methods
for oxy-hydrogen gas, its blending with cenventional fuels and effect on the performance
of internal combustion engine," Journal of Mechanical Engineering Reserach, vol. 3, no.
9, pp. 325-332, September 2011.
3. S. A. Musmar and A. A. Al-Rousan, "Effect of HHO gas on combustion emissions in
gasoline engines," journal of Fuel and Energy, vol. 90, pp. 3066-3070, 2011.
4. WWW.WIKIPEDIA.COM
5. WWW.HHOGENERATOR.COM
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