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Cementing materials
These are Materials with additive and cohesive properties
They have capable of uniting and bonding solid particles
together
These are: Lime, gypsum, and Portland cement
Cement
Is additive substance
Which when mixed with water form paste
The paste
Is temporarily plastic and be molded or deformed
And later it sets and harden to rigid mass
Cement of this kind are known as calcareous cement
Calcareous cement
Non hydraulic cement
Are cement which are not able to set and harden (e.g.,
Non hydraulic lime) or stable (e.g. gypsum plaster) in
water.
Hydraulic cement
Are cement which are able to set and harden in water
And give a solid mass that dose not disintegrated.
Remain stable in water (e.g. Portland cement)
Lime
It is found in its natural form as rock of varying degree
of hardness
Mainly composed of calcium oxide(CaO)
Lime deposits are generally found mixed with
impurities (CO2, FeO3 and MgCO3 ), this acquire
different colors
Production of lime
It involves burning of the row materials and then
Slaking
Depending on the amount of heat and the method of
slaking, the product is hydraulic or non-hydraulic lime
Fig 1.
Wet-slacking
At the building site by mixing quick lime with an excess
of water
Passed through a fine sieve to remove slow slaking
particle
Left to mature for several days
Stirred by shovel or stick this - reduce all anhydrated
particles (causes popping, pitting and disintegration)
Dry-slacking
It is manufactured in a factory under controlled
condition.
Sufficient water is used to hydrate the quick lime
then the lumps break in to a dry powder known as
dry hydrate or hydrate lime
Depending on the impurities present the specific
gravity of hydrated lime varies from 2.08 - 2.4
Preserving quicklime
Is has much affinity for water and quickly absorb
moisture from atmosphere and air slacked and
loses its cementing qualities
Therefore kept in dry storage and carefully
protected from dampness
CaCO3 or limestone
2. Manganese lime(lean)
poor ,gray,
Gypsum plasters
It is used in arts and in building construction
A combination of sulphate of lime with water of
crystallization
It occurs as
Hydrous sulphate of lime (CaSO4.2H2O)
75% and 24%
Unhydrous sulphate of lime little or no water of
crystallization
lime (CaSO4.2H2O)
Generally gypsum is
Soft that it can be scratched with the fingernail.
Fire sensitive
Sets quickly
Light in weight
Never used in places exposed to the weather,
moisture, underground moist
Manufacture of plaster
Gypsum plasters are manufactured by heating the
row materials gypsum at either moderate or high
temperature, the result being plaster of paris or
hardfinish plaster
A. plaster of paris (stucco)-calcined gypsum
gypsum a good deal of water of
crystallization(24% by wt.)
If some of H2O is driven off at a temperature just
above the boiling point of water 100 0C, a semihydrated plaster is obtained which is known as
plaster of Paris.
CaSO4.1/2H2O +1/2H2O
Plaster of paris:
is white powder having a specific gravity of
2.57
known as low-temperature gypsum
derivative or semi-hydrated plaster.
Shrinkage
Rapid setting
Difficult to work
Used for ornamental works due to A & B
B. Hard-finish plaster
By burning gypsum to a considerably higher
temperature
Unhydrous sulphate or unhydrous plaster or hightemperature gypsum derivative is produced
CaSO4.2H2O (High heat)
CaSO4. + 2H2O
When mixed with water, plaster of paris sets very
rapidly whereas hard-finished plaster sets too slowly
It is reluctant to reabsorb water
Less soluble in water
Setting retardant s
a. Flour, glue
b. Borax or Alum is added to finely ground
calcinated gypsum to further improve
warkability and accelerate the eventual
setting
Calcination- the process of drying of water of
crystallization by heat.