r onthe ur Z -- Organic Compo andX itl. pan cH ono) “. quo saamnah« =Ki : (peat sa and kaenes )3. Seah matt oh pasa op abaya tae » By cridatar a} alcohols _ 4d Key, 94 | eey =) atk Gue KNMOG CD CLO, Chinmic Arnydtide A) Cogtina rreag-em™ Contomicins Chica de -Pyridiuecnfs aot Cho, . Aig N Spain entoouitsbate Chee) Ho, . CoHeN. HQ Mild Giotto agents whide convert }alroho) fo aildlakyae” qarof a? ottehal te Rebone Ratatiage al, there pene OVAL &Ci50, jA that mee wegen Abs}s ancicdlacttiqw et Aldehyde Boe anal preven eter aids Qh allele to Gearbox yWic, aad. on eds deo nob attack clouble bound. pp Ce). aiderysde Qe — keur Loy Crh Oy OF 4- [0] tye [soy OHO +O | on ky 64,04 )4. 60 CHO oy Ce a BEY wtapa]esy ‘er 10 Bengaide 7 CBerien Cl BS ez5 HD oe On, “ge kaaser}sy onea Lyon Kot ian (> a0 +0 q clohexanond_ Reno +(e] —5 RCooH Oe Lig. coi dbigh nf Kk, Cn, 04 / KtKO 9 ao, ageuts fe commer ahaleryde te asics *y Peat cod letter Ch MH UEOQON fa’ er Oy wo Bailes -- 00 V gettan to? BP. ak) cae ugk 5 Be. eh des ore. Lower than core sboneling eC altohof , go a . > fou Moleentar mors Can be @e Jog obi eti£0 oft Qi Roow as Hi que Rormceal Q (Ka ett, Wek ascadithes oper CHS gegen CERES Koro VP alcohol am ees Ok 20 On so Cycteh er -Rocer\- of cytchenen eneSi & 84 C cehydiegenedow ob altohold 1° alconel — ve rm ae Ch, CH, © _ SAS, eHO + Hy See > Srhanol Coy 818K Cu onon TES BS.20 4M F OR Aeefare (Rosenmu ud 7 edtutHon) Os Tropohatl adeohol 3\* Fron acid chlorides ~ ont to aldehydes, Pd, Gs0u/$ oro +HQ Cig Coch “Betty, ie. ou Keele Ohteriche Fowmatda hyde. Csrmok BL ye eb) tg momnad Aine MOC freee YR unitrhle atk oom Kan per okie, Q. woh Ba Soy and Surpiur Cquinesoe ) We adeled.? faa ee a Ba soy and & persona Yo pabtacuy Catelyst - ame dvet nob pont the Thane sadanion aan Aheoho.From Gy word a &y adcition of nibslea oe Hg tn 3, -doogen, Butanowg = Nhe t ° Gee EN fp one we {Sgt erg LB ne Bo AddiHien thoduer “Ih cots phenone, H-cen + oyNer SE cn cy er i } x Hr 0 MgHeegante add sete | i GL HO 2A Be, From oespeed a) a4 estate ie 2 Od [oSoytHgloy ery Oe a or, Cy BO +O 5 Oy ete I Winphattavel Acelaldety de Ueto Q ai | bteuM9Sey Gh- cu oH, ChOE CH THO jleaeuiy LL — a BBak on Prop-\- eno-a-0f gubcmotersar areci abi dur fe cbpole— pole OmtecacHons bebwees He obpeslte owls af 70=9 dipole | oe $7 ~s a- Sk ge =O --- [C=O --3e=0--- ain du lole - obs pbs gutiae kes Keene, = Aholey Kotor neve Ws Bp, then abatebyr® Be corre in Ketones fr Os donak. atkyf Group proven aroug| cao group re makes Peri met poker + @, woh BP. al fotos arg fower tha v7 Qos aud alcohols? Ru: Ai poke — Difpole OntecacH on 4 Arg wesker— than gntermolecuir- He bending. 8 alcone] avol acidh We bone eo AA~ do Hoy BP TA weaonents according $0 thee OP 1 oO a : : BPR py Cycoot, SLCooy OA,014 oor GA, Coon 7 4 O40 > CH Cou 7 Chon o7 Oger, 7 MAME Sobadibl _ and Refanea Grtaining up As Jour. Grbew atte Anew Ga mee nod, ethanol , Mopanc ua are Soluble Vw ulate One tw H- bonds polar Corberal qe and Salis vali R R\ gs oe eee — Hf ae = Af " BE st Ry _ AS _ Zk e ego BI Oe CV! Rg he He Lise ah atkyl ger} (etme 3 Ss ut becomes Vn Sohudote Yn wtot , Hey fetal qh rotor one PIG sofas x" 7 ——— : - In @sganic Lolve arent Lowe a howe. peng ent Lrrord , \y tho 3e (ctor CAaowL Becomes — fers porns inate aug woe Regvatd Ping Jfaku dial ahollagde aud kirura : Ore ~ wreel tho pevbamu aud Hiren Geek C Benpo premone )Chou cof poperbes A, alolelr pote auf Keoleined 8. wh aldehyde and kelener Show Grnumbr_ OP ~ common YeacHon’ 7 An: Both the castes Of organic CompounclA have Aame tunckenal group be: pokestsed Casben een ‘ they Ahow Q Nun of LOmmen Keaton,’ | ©. wh een ae more Yeachve thar Ketones 7 And: The. presence of H- ate @n the Carbon Group of AWdehyded makea them More! Seadhve yan kone. Presence of Hoon ik In Adel A wer Ailerensiale from kehe Fed - Commean creations Of Aldehyde and ketenes ) Nacleophib'e addition veacHons | Na rope addition veactons Poetowes by elimination of, Qa wat molecule. 2) oxidation veackond, ») Redu chon rea cond ) Hole nen alon ; Reaction with atkobed +) MisceReuemuk YeactiondNB addition veacHons! Rdfenes Ate Uunsalsroted Ao addition weacHom, | i) Nucteojbiic > Alolchyde ane thea panies 2 3n de and ketene —arbony? Which Th polo Dor tes qantas he Atoneg.ctivs eh oxygew clas of Grbonyt group acquires g Buia ove Charge white Carbon attus 14 AL ave charg 4. Ths posites 2 eatil Gttacked ob equesenphl le > b vedo” Carbon alone 14 The nuctoblic attack Can Occur either Gey hove Or Beloo the plane of the Carben ob 6 CAH in Loymabou Of owiow J deh eepe Cob ar ex oh ESE atone . by Complelt Carben- Ou double bend 4O © The anion Pos med dikes Qa prolew dom Jolventr oF Jrom the eee ts gue addon Jrocku of : @. wh mucico pl Li ¢ addon rer Comied aut ™ ava ™E Ans: Sy presence a audi , Cosbon gre us get proto mated oh du Mnoveages the Ave chow on carbonatl Carbon SO Weak Huckeo bts Cammen'a aud dativellv) can atta = the aabeg? Corba Mow. | aH on SAAR aes Lian?os A N- ~22! fy * ay = [pease ston] Hechant An | Nuckeofbibic addition TeadHfons Na 14, OF 1, 8 ge a Ne Aled tee ue q C-oO ath % iE oS “ow _ = tng Planes, oF A on tetvahedial Addi . Snternediale a Reacluity | . pews M. wh Otolehydis Gra Mowe eceadtive than kéfona 7 And: aldehycle Canes ene hyaaoge and One aakyt qeey while Rane Gwe fave otegk gay Adkyf gery has e8 cheno og metus, Ye Alolaby che one ek den ating yet hte ketones Jaro abet get ‘present awl So AT efheet 1) amewe in andebyeted as Compare to Refers, ef deny, on carbon geet ik owe im Kefones Compars tO at dely ds §o Celaya OMe mot TRASH. Com|sati Sow d ALpuaKe aldehyde and Retoncs ‘gs0 7 * Ry a ,20 7 es 47 4 Qe Yee 2 Le Retonsd SndatGve et Viale, the ne. of abbyh qiesp arracked To catbony? group great, Vg bx bean an Gibeny? Corben hence. esa, 1s 1 seackuily — towards ructeap hie addutien ~veatHons- Stic eter—9 AS the Croweling Treacared>’ the veactrwity Accocosen | aH - ¢ Nae Ma > aN ea > We A On CoH), cH a >= o 7 @),¢ ——— Cs) @9,° e Aa the number af athye group frnecates, the attack of nucteobhise O17 the Carb ong Proup become move and more OG Byl Cust~ due ts ste hindionte, $0 O4 vhe cronsla Vn crtareds veadouila Aecseated— @ ah move yeackive tha p. 4 Aomatic all and, ketone ? Sty COGH Ans Ga, HO 7 Gusto 7 Nmongat aromelbie Bidahyde. and Rater Qromealic atelebs are “more Teackue than Ratenes whicly {ry Tans wre MoT Rates dua t5 +7 weaetve. than =U ethect. AA the FT ephect fmecoes ai Aecyenses , QR. Asomalic Qhelens and Refenes Ate [era ral then Cowves bondiy au proke and Relones 2 Ans us oe es clo wacko wesomance effrct ( ctbeet) oh — BengermreN Xing Inontosed,th engi en = Carbon ufo dines ey antl he ama gest = ee = £8; Re eo Or = gS ear Ss — SS sf S © o ge a Q. bee PolQourin Gathon of compond Ty Vn encod osdu of thaw “it olan nUclrophsU co? addi tien seach ond | (@ ethanal, Propanal, propanone, Butanone ob) BengandenAe, p-doluotdehy as Jj Pritobersatdahyts, Geet phenone Srecntes “Ar eb et And (@deranal > bepengl— pisponone—9 puutinene HE efter’ or a pers ‘Bigs! < ethanal ) ot otkyt B {rotors es aleuctie. or the Carbon ni of Gabon qo Tagereoted hence atrack b mucha bite becomes Alower and own - Hence, the rea chal ly Srcreased 19 ord Rutanone < \wobanone < propane? < etha mop (>) Acetophenone < po foluaddehyscte < Beng aldol L pe nittobengatdoh Ae Acetophenone fea ~ RBne whe are obur— One Atakelyolt Ao tt Va least fea chive Sn p- tela atdehyols thre 14 2 —% Yrore Gk pedi S fo atbeny gree whchimewtaned Hao ef deity on He cies of Corkenase Poup by hybercens 4 akiten efhect there bu making if leat Reack¥e. han dengaldens de. Sn b-mitto bengatoh ye the - Nog geop 1a es uuthcowtng get St vsithdaws es both bY indquchve ehfect™ And weromance ether tare be Aecotott the ef - densi On G@sbor Clow oh © Gleub . This Jaciptates Me attack of Hee Nuclespile And makes Homo weg ive How deus agolen de, Neckeo pie Gddston meachionA | aoaation of, SNSan Fa ial a onto, Acaciend GR, Addition a on a) fdditn of REN uate DY Additien of adceonol& . — - Seng nt]50 ss el a eigtont Cesk He (i) Pantone ‘he! a) % ONa ow, e hen Bs nang, TR\ 7 = yy 28 Ped Coy eco =—— on Ne wt ff nN Prato rs uM So, ie ¢ 4 he Acdadaly Acetate Reon gti w]e bisapire ain Copanohyadiw hs me ra a0, 3 8 Vy . Precku Hee PORE gucot, Cb Dons es eel aa ot Fe +40 ae ae NMG Fson Seen, Herriacetok Nata H7 Coon ee adic audReadiot af cole Oar 70" 4 Hy “ re Coon : ao Ha) oH OSS 04 AcdIrue cy a No 08" SCN Cay Gan be hytalgel 2 aed) taew te give oh ope = 5) Pu gto na en 78 P Reign “Sen © + NaHs0, = NF ca’ _ oe ‘sn ox $0, Sq Isr (ut on oy NoveaWas ow e oe aR (wo Ketat fosafen) O%’ nae, Sg Saltoho} Nadtt "0 ‘Keleeex: do not yeack wily enon dure. aeohol as Bul acad usith Aihg re - cystic Reads . whl Kiuyle A050 usihy SoHo stenoand hihyelat <. atone! s. Om Ho ve ers, o O-cH ant ale4 ~ Aube ay! oy OF 44a dnerngl 1), Vodewe FR catat Bketag rie OAL nd Laon CA cyte gaat >) Oe me regen aches q “Rea oy ema Noe” ers, ty A NCE cates Noah * Sry 085" a Son =P ay fo x Wen, flux vy Mino eke, one ers ae & Mathyt 13-cidzane a AP Sucon nee p-Foluene tugphon ic. cic Sa te yr Y easy A Saeice nyo , meee + 8G HoH19, Nacteoph ic addsten veadtona Poll ow eo| ea CUminoton of csdty molecule, — Addi bro, a Ng eri vauived, Qmohy contol of Py Vas Oh” ammonia Any Addition mecerd Awrng addition devuativea to Adlahy ce ma Raenes 7 of Ammonia desualives to alee Gnq ketones a alates} ae adds, ow Gadic median, cyan ue ony Proup get profenated whicls tn > tuo YCaoNan ce Mnertaseh He +2 char on Corb Carboy Nuckroeles Lke Q@mmonia Qthack tHe Corb , SO WeTk Auiwokiyes Aeaskl pore +t = [e561 OG bd Hon + on Profonamel orb 3¢ -OH + OU NHZ —) rae 4 yg se Seis rans es “tod tee Median TA too aeiclic, the ammonia duivatic being emg Batic im nébue wwe form —ammeniuy Aalhs Que’ t ablence of e@F en nilte Chon | there ammeniuus Aatk uN uo leuga be Nackeope’lic hemee the veaon Uw WW nok Ocenm. / 4 medias 1S Alighity aodic Or boc to vodtow of , Hy acidic ox baw, Ae i) Sate a ao 7 vot occu Tt Usigd not Wnatosc iguaeer}s cca cond ot dent tes chase) on coabonsgl you, Hence werk Focdhaebiile Dre wh, derivable wwe vot be able to reget fo opbman valuc Of fy Le. 3.5 13 embbow.ee)4. Reaction usith hgataaniostai NOH —_" @ CH droxyt amine) Coxime’) Wig. ~ ey cz! + SNOW nu” eT LR ae We vethanad Hydtergtonine 4 ce = NOH Hethanael ome O3\. =NoH +h G bod = 8 Sexe + Neh —2 V/ M “srnanal erhan af oxime BN. not +0 PSceb FANON ==) = Pre Fanon oe * Propanowe_ @ ReadTons with hgdte eine Mr Nig 3 Hagteaenes iyetna zine e oxime vo my , WNe-6 4 ney —— ene - Merhaual hytha 2%e ORN O Che ao + igen, ——> aa enn, +f vod Wye sont 4 Merhanad - hy sbagal oe aN ena ou + AMM # . a a OR “s PRapanone Vuysaas ore 7 3c E Ney, +50(es) XI. « Reaou, Ud Phemyhs AWS Ae GHANA, ~— —9" PRemyk hystagone_ Phew hudiag ine eee W wo i Ae NHGHe 3 ge ere vethono{ Memanad phengl Rysttagone, a _ Se=0 HIS MH Gite — BN. 8 SNNKGH. +O / a Peppa dana oa Ehanal Phengt hasessong_ CH, Me 7 Sorl6 BR SAH — wae NN CH FLO gs 3 A Yropomene Phenssiy diane Readtio He abi he (Brady's renee eadlow uri Qa Lnitof ae ( y " “eos =o + ano wi Loy eS ee romidoyest ‘a “7 +o e dintoph: Hegre ayer ae wer 03 Selo # gwen _Loyng —F we por “5 OS 6 = mH—-Loy-89 ~ brwhanone ar Ualiapren ge - ReaBew, why Lercitarbartde. ngeaaen. CSS c=0 + YNNACONY—> vO SENN Cony F4 ae Brana) Acre Corbyony, SaSe=0 + HAIN co Wh —9 SBNe = ENOKONY +O O47 “4 Popansno Anu Gute zoukQ. why Armmoniq Aeciuctevea tag acel shor Tolenipication And Characterizabow of; Q de and Rotenes? Ary dekrnalves Q ny Coximes, hydaa gone | AY AiniGe}hen Nydsazones’) Gra wee defined Crystalting fois weity Ahatf mMekH ry point. eS Mey are ured for identibi cibonw ans Charocterizction Oh aldehyde and Kelner. @. wn thove. Aaviuabves Are Us eal Per forificalin of aldehyde and Rédlenes 7. Am§". There ~deriusitives can be decomporerl & Boiling usity Aue wineral acids fo vepeniale the linet carbons’ qpoup So were derivative are ed fer purification of Adlelyss 4 Retard, Patiala ene A lu ay aanly oxidtsed +o Grbaryk'c adds Contedlug floaue — nuudsu- of, Corben Aken, r-e7* + [0] 9 Re ~4 se °o Qheleryolts Con be eon'l oiol sed duc ts presence oF} mgene w lee «On HY Contomy? Corbor. whicls Can de Convertes| futir =H) Quai wsthouw — fyualaing Chong oh an Chu beucl . So gan be oxidizes! net avi by Adin ost £m agent CHa, Keuoy ‘and k,G,0,) aut ~ alto bay wuk,as, Goud si w tg gue Bs, Set Lh n dels ack aL 4 I agents . Aeslur C aa Seer BS} ~ to riealc ilar,” CS eet ti) > Toltent A reas joletion to 4 aed ai) Fehuing olution or Bend \re eso tote oh Caplous Gui hd Reduction. of Tolbenls weagerrt™ @ e roo + a[fig @y, ]ya + aon — 9 Reoo + aha * 4Qrry + QO Silver” HOY q ran Zo WA Silver deposited Qin Like ay Avr am WF Apart Rmow * Both apne and axomae Abhay ht Ass Toten s reagent” Raductow of Fehting, aolulow z gut SoH a Reoo + C40 +30 Caap hoes HAL RUO Chad ret) Coen AokuGovs Prromatc Akdakydte ado nit reduce Bhai ah Bend gotten yeas or Fenbly golutow - in Same mannr— @. difhunce belwers Fev yy aud Bool ot Aolution Axi: Fenti y Bouck ct atkoline Co®t tend Comptes es} atk obine Solute of Curt Sons Complens yur tastrof jong 7 : ga cittate yokaxidabas of ketones’ ys ang h ketenes do not Corfe ppg Gowns Gawas +0 CHO pimp hemee t Cannot be exiditesl Wei houtine Clow ob Corben bond. So etre Cannot he Oxi ds sca woegk Qh se QQws Aue ad olen s aud PAu Aclubtom, Go Tere Aseg ois are vared Sov diana a atelalyche Grow Keldned, CH) Axidatar, bug ov oxi HR age, Popofbute / 2 Rs (natur patts) Ont Cc Loan Oh — Hy pecbane pero group | a i oT conten DF conf b Peulita-2 one— auwsys : Ae Seat adky) coor, ne eutanhs, vest Os e neeteeaed CH, Ot 4 Cool aed Ca, Ch Coo = oy 23 ON popanoie acd doo Cfosrs'cade} Mower ¢ Major) ak) Boduk akwarys Condo Ue we ob fuss ofa GL Combe fo vedetauts Bec e-c bond Say Occms | Reng cool coe, +308) —— @ coo + U4 “ee & 2 7 eee Acefreoelt Peat sone Ky Ce, o7 —— Yoeoy M coon 4 HC904 CH CO Oy + ale) on coor! S vi : crycoot 4 Co, YO (i) Gidea unite Sodium tyboh alte (Naox er + Naof) —Watlornt wegnionwlrieengee and Keene“ Qntotain @ co = uss om treatement uit excers of halogen tu, presence of adkad) produee Q hale dora () CH EHO + Belo Naor, CCH + gH i cadiaiiilihaB Chlovinabin, tiehtoroa cakatdehyole CCR CHO + Naon fgdulgae Citl, + Mcoanle ‘oor Ohterepores — declan formate N@ot (i) C§LCO OE + Ber aera, (BH COG FEN CBR COOL +NaoH 2 CBr, + %ycoong Hydaol i Lodelcen Tart on ) Gxetet ep, Net, eTycHo ant i - godiuabar AS ocloo cotadstelyhe CE, CHO 4-NaoH 2 CHT, 1 Cong C gators vet.) fv) O4 co C4 far, Naot, CFL Coy + ant CTCOGR + Nao 9 CHT, + G4 COONy Secdefory Pour aetatt Ot Oy Coen, 4+ 3 Naor =) U4, CaO G 4 CAE, NAN Hono + ay, 704 No wee. Sodofora teat 1S usesl fox Combo unohs Salad RCo = Prop o Oneloty wher Gis be canty cod Bi tal +o Us CoO — Yo up ba hasoge Xr Chore ct atfoolurtows 26, Reduclanu to alcoho} ALolehypcle _is|mieird PP akeokofh ¢ Cilittg, Nasty ketone Reduction ae alcoho ‘horuataebayde Recluctiog 1° akcene | Merkutey Pannderf, verte APA, & ad ecw (Gap, <5) OS a Q a ae Caen R Be alcohof Kole Qlustiniun Usopropaiele Edopropuf atcaho @ ah bebe LIAM aud Meaty Asdiction. 5 ua os of og ureryort aM — IE Ger 7 eae Oy ey Coo GH — acy oy EOS cong He Cig sor Na ong t! inns. Naaliat og age m3 Raclurtion, to Pinatel ~ vs \ Ha-Ha - wo Ge + te Oy + afr) eal Oh ¢ Hi i ty be, o4 oO 5° aya donotey? —_ frecTone— 22H? (Awe wiolecuted) e ee tol Reolurbin be hyalvo Carbo - D) Chemerers ey veolu dos i) twolp bitior Assent: CRammerteus ey vio + 4H) Bohan ono +H © eycooy + Uti) Erma On cep Ot THO que Cova + ate aad s guages + 140 bement_ aaa ey, Ag el Helin, yb eg, Sean,24. (49 tool - kishne Acolued ous CaCO Oo Ni nn konpa Oy Oy On +O US3 - WRK prepare Genero, FESBINY CoHoope +20 usa Sng bemgeme_ wot} ighur = Atelurboro 1s crssl os Cosbon Compounds GAL Semriive FOAIA, @) pate HD + e Rack”) | Rad P4221 ee ee en,cHo + WHY a PEK, Oy- Us ho a a CH gut ar Pyoak - CAcows + WHT teh, Guo +O ee Habogenation Cx rydrog een rategeinabin~’) CH, HO + a GERSON 2 egw CHO +H ~ eke Choro accra raler pr OyeoOy tary CseO , pg ey co, FA O— OL BRom oO CAMAe_ Reaction, uit atkabied C Acie of x- helio gous ) f) Ako — conden for Ger, d Cross alcol Cond emote x) CLoarian - echmidt Condeaucsha,, 4) Camnizzaro Aes Vow S\ Goat — Cynmiz20r© AGSALdof Condensers Ca ot A, ob hyenges) 28, Grbonyl Comporrd A Cowmied hystto geaw Ais Whieke Qe present on cuben athirg nest te Corb qerp. Thit Carbon $4 Callesf X- Carben amd the hgdregow, ast ached +o It aha Cadel a hydro wd There ot-hastieg Qe adhe im mote . The @ad of X- Inger rs poaktag Cue he the -Tekbeet Oh the Carbony® qeep whitey Weakend the | bond and pay alue he Yesonamre AlabU zdbows. of the resuthng enokete. anion. Ndlel conduuaboas ' Two melecute of an aflalabyshs ord Kilene Condente In Presence Of ailuite alkab’ @iNaoH, No, to, Bator) to tos QB hyde: do ay p-hycrer Ketiinn hasnt is" eons as 6 ai|Nee} oH oe eo & Hopeno = Hb HO x vlbo 3S a erhaval eeael puter Ory, “S ebony OG chtde®) che o10 > yoby eno AilN aed, “ es - o,-%4 “HA ery oh en Ot bog << SPS ig LHdhf Pert arene 4a24. “=o + = Up Coty Bales, a Of CoO G “ 4 _ ae very Ppentan -A-OKWR | hd , Se 4 aes 0 4 song feree genedone UR7 FS a eat 6, . ie Giicd F Fowmatdehyche o as oe Rempoprencne— alon't os ‘ ah a Moo Zo do nct show ate! Condenaaltony Mecham! Sm yea f) gH7 fon abstracts @ne of qeidia & h qe to fom enolate Von phtes 18 BreabLird by Veronance . = ies as - WO 4 4H Moy — 8 i Hos [an-« dHe Y= Las 2) emokale jon axKacks the Corvones? gop of A€cond evel saat ch eat toform AniouT beng Q Sto NU Qeopti Ae § wa cheshire iQe7 _3. peor see ae ‘O: Rall } o égehay Buy gat Sh \ 4 oy 2 _ d-apcno + CHBo Cw0ss - aldo — Condentaton ' An aldol Condewsaa, bokweers tuto cdifhaat Chale 12, Or hwo KEES O— behwerdw alotely Gr ong Rete Ts Carled Grose Aldo Cndentation i} one of the Gubonyh compound aloes not possesa a- alow Chormateteryelo begat chokwlo’) thes Cast allolol Condenrtoia,, area oa ay oHote UHL Yr utile vee dew ane Soy Home Of CH naaitigia ieonauanp hyde onaaalee @) oy- Boy + nbn alata ry E04 -esoy Reet — Hyddoty bul aved-© BY boldly Seip Se Rania (0 Ste 4 + Cero let Gig oat oBK Ail NaH = |-nHe & He eee CH-CAD . Cinna roadateligd Claman vreucGeu, ‘@) Base Catrlyard rvoss- aldeal Gndwuolea, bebweew A Aromatic aud ay ahifphotc QAMoleuyche O Polere 1A CatLed) Ua rian ~Seheticl- Cmdadobiwn or Wana Gndewsobusoo ONO KeaCHong | A6dek whi ely clonof Gntesns o- hyclie gow Alor “whew treated uit, Cone, alka” Lo kuhon , Undergoes Agrh ouclabay, Avcluctton Aa a mune one molecule of Ae 12 Redluceel +o an aud another TA oxrdised| to Carboy bre acid RHCHO L Nao —3 GOH + 1 COONG Natsuol cf) juin Lediun formate AGHeHO + Naor —35 SE HEPLOH FH COON (sos Soa ales) — Boctian beysoate. CR Ne fare Bran SH. OH + Na oti — 44, Tea OH Show i gu cto - CooH + ¥6 ese nel at Hr WweuufuL s0S8-~ ardol Bde! Condeusa WE, Sree Coon GH PhOd Modvn benzoate “ast sy enc, Bebw ew bolwew tim od diffu AA OAhalurnriste A Loco +HOO + Naoy —) f- i eee BOLO yon + cooneubsktubao vuders: fromafe cihchar ght and Retone Condesa ts) eke ctiap yt G Avubittabo.. weacHons Sh bengene nuckeuns Auch as hologeratan, i ri bakies , La dphova bers —CoR Prorp We ea asithdiowies —CcHo ard do deachuak and ™- OU rgckhor, electropr We Bobs tatuGew pes cious us aromabe po MH on, Alotogate g Rolauus geek: ak ich CHO 6HO CHO | Ce? Hy Loy on +h o@ ws |O a IS a 80,4 NO iC ¢ - Ben Lg SeeQp hone ae mn gatcehye Sey *B"G0 4 thee” funy SS . a, wy, m-nittodenzalden ag \ om 2 RE, coh q eon 4) ah ° OY tH fensogl Mon'chQ Beyegl Onenchs | CoOL AL, coerh, CoO’, ra She 213K RAL. Hct Sea 48% “He, Gadalyte em Atel % : cedeans AN, arietur) Phemacyh bride M-Bronoa cobs phewons eer s! © Wey ey & 2 hive, eniteaelspenone © co," AHO om Ace phenone sudkhenic 4 cidSusport aut Corbonyst Compounds ~ . Comme cial Methanal Cheno) . Fowmafdehy de Agoy Cu Cro des A CHO Og ware QHD +Qth_ © Weak CHyt % Te Wore +H 0 CHLOH AgorGr » Hao + Hy c Heol Ropu: : nc i DY when formate if aie -trioxane Lo 1A adlowed ts stand or amet Formatdel yt, GP a tidneed ts wo e \ ore ¢ Grn Mw : Azo ae Fow-motdeds © semole cakes) “wiorame OF mactibornatlaky XD) BTA dokuble in osdte ste Cue | a prea Boluke. id Caited Qos main hem famate, TA etopratesl ts olaymer’ ana vreke babs , tk givug whit sold codtns| Paraben emataleh yt ‘ miwo sas» Hoe), bo Aq. adi faantmatsatngshe on heating. Foraformatsian ye ‘vagentints Peoria bins Used DFormatin va wee) fer premucvin, © Priotogs cof Mew: A MH te Ussh IH monudadtir ef Bakelite etnaethanaQ CAcetafaersste’ Chr oO — O twack. ak = Pd a _frsce a Ob= Ob + rh +30, Pd oxoro aye . e ‘4, $13 » ©. " wes TRON CAR CHO 4 Hy 9 Se icsnol Behepltoy chal. Acekasalatg ale ProprDes Dd ° 2 OH Cone & CY a at ° eth £04 ae Oo an oH 2VEK \ : ‘ % CH 4 oF NG oy & Sei So, {AAcetatdehyoe Pazag Cthree mole cites) Ca cyee Grmer) = or — 0 3) ce =O 4 *h 1 Cm CH OB ~O Acet atael Chour mole tes) HQ aAlZ18k Leuk v4 te yas 273% on = Oy HOH A= Oy \y ° Metildakget cebao bay Cacytertcooned Pasa Quop met emrrot athoworP Gn UAHLoGe, ust Aluti H Soy . UAE 1 Poralalerysle VA hyp ofie RX) fcetoatderyote 1a weal pn manute Tite Oh Ving aedeate, Ohryf alate, Qeteacid,42 wR = g@sr= Propanone C Acebuc. , URCOOR ) d _ oro CuSTAK, on EF Lent, hy - 8 Sateen a “L30}ropy we 2) Wacker \rocad Acetone Packs 4 v . Oy —OHy = eH, t+Ho tyr, Gea ae + 8) Come Agercen Ce prectuet 1s 4 Cetine) Onser" Solvent her paints 7 CedCulte Qedete) Vorntshed , Contttuent of Gipud nail polite , Bemgatdchyole ers cH) ae Rn a Lo ers a 4 may “Alle. Chose ehleon nator Uses: Pes, Yuu and 2 \nduary Hi sHoeWe, chOears Tear Bengal ehleriche Beng. agota4 hh wv ALolety and Rete, Miotehydle Laie hive Silver taro No ath'or) Toles Asou fending Solulo. Realurctier wit LAH y Acker oily alcohols yw digi 3a Beli ffls Bort “Ss Give ved pphayo oo Cakiphatic atolen Y alcohols Aec-attoho] & fers aed cond tery Pink Colowe No Athen, Rawsalclalycls. Foyrd Uretning CourplorSmpeslent weactons of Canbony? grep . oF Hen ~N a > Fa ¢ Neen Nawse. Sey ot ? C ~~ 80,Nq = ® >C=o0 [RNG Ne a ao? # Now BEES Se ENG (G2 0H, -8 a, RNG, HN Cont) eo ae. Ne oS for, A Se © Pots. ye Ok Gaeiela on ae Revo R- c=0 . RCooH + Ng (Silver Nivror) | re tal rene eatTonts, ReooH + Curo Cred bpr) Fehtivg Solute. Kelonea mb ean antl’ fea| Aut undue dratle Condi Honk hay axe wuebise| to Corborytic avdd asity Arphne Yof bond baker Garber Carbo Quel ot- Carbon. Sy Cole of Undy nT cork RebsHo cava oceuvsA fn fut @ ubt Hit Corb ra Avkosues} Avot ate tho fa catees ™ ‘4 Ga ™ ns . Cone HNO, OL eo U1, Boog — 4 Og Coon + coh 14! Coo Nojer Reduction Sez0 > rhoOGnit (Qa I Conboy c agdy Hcoort soe Yeomica cid) Cook . meat acd Coxakicacid) Ethane |, Wolcaud CH Coot 3. bo 4 3 : 1 Cacatiz aed’) Oy 3 C Hodonic aud) Eben ¢ aud Coon, CH, HCOOH Propane 1,3 - Bore acid pro} anoi ca we Qh Coot ;2 on? Cy - Coon Ory CooH 2 %, 0% _— 00 (Sucein'c acd) Bulkwe (4 oi c aed Ae cool aaa Bo @ MO, oes femtane |, 6 -dhoic au Bengot c aad Benitio bengoi ¢ acid (ooh oy Cool (oor Pomsihary beige! cov fol coor ol (Patratic aud) (Tioktstabe.) eon ¢. ya Rengena Licarbong hc 1,8 Mergene (rey epurods avd Mrcouboryee ‘egies |9m corboyte add one af He Tito ep hy briebses} ovbilal of Grbonyk Cather - head om bends wHe genie atten, pduduae TL 8 it —neutiet ome et Cone lout ae resonance . ww Comes 6 medi & Cex onl a a oOo gee ce & N —c¢ Ho -- OL aN Noutteal 4 &Yo-4 YO-H noried Te mm Modt Behke4 Prepasclion of Corboarph'c audd : ) oxiddbow of ff alcohol and otdekyche on OL OH Kin ogior CH, Coo Di Hey Ethanoic aad CAcebre acid KMnoy [kort — Atkaline kKHnoy tor orichalian ; / one One kway, | S04 aadc KM Ao y he Qw Site OYOH kee lst on 00 Rla, italy oH COOH 1 genoicaci a. ProM abkah dengens and "1 K MnO. +808 was 6 - Joa, 40, Coy Bengoi caadq CH, Oh ‘ \ ac vagy (i kewego ©) it P @ Qi) BIAsoy Bugeie aed Koide cha 1d abure axidi sed to Coot ei ote of ollengite ot the haw Sey . a cuesnmilon, orm Phtralic aciof Coo 4 Gusi| Hsoy 4, LOY % (iseeg So Cooy +20 ~ for Gi) i) 4204 Tuephinal: cove AlKened oporcore, OMIM, go coo4 But-reng CY ail 480y ethane eid2. Fou nitiles Coy “yet eyes Sn 4. Qo iy Crt, Coon + NAy Sthanenitile shane c acd 4 CEN Org + 2Hho ifs cengteed ANH B enzonitale Beweicacd 4. From arignerd Aisa Ot aye “Ong Crna Br -eReer- Ba 4 op (oul) oot + Ss ae Q. Convar cent adcohet ts “es erhanoi¢ 049 N (0 Cet FON Ere ete Chr. SEED Soils os. je lse Sits CH coo Phenyl ephanoica .. cot, kenog|koH 70904 qi) io ae? Jal oo gmatyh acbhensng §=— 1 Renee y ne (i) ene q O “hala ae Rengonol, 6 a Cyetalen cut Oy ogeyegours “aii? rnd, Dg soot (Y) Cte HHA SHH g OL fry crc et io Bersoic ae!re eRe, ” Smet” The firdt Huse cathodic Qeila ara. lowers puny eu Anatliiog Lypusd 4 The net Ye diel oge Cq 2 Coloulers Silke Lge | WarHe Unpbleaiant Cdout , The hrat Tehs ere Aclida anol aro aclourlers dite tr fou alld Gating point ° the o.¢ of Grborghre. Adda org. muh be as than those of hyduocartons, ap Kolding ancl ALeones? of Comparable mole cuter muy This ys dur te more eobemtive alto a atton © Ch Cotbayte acid molecutus Hedougins Snbersoleceay dngtass Honiley _ The nyolee bends ar.o_ ot boeken J eves “in the Vapor prose . Hott a) Corbarbre acids exist ad Aww dy Vapous |ahorve and I abc selvect p= 3 20 --- H-o “ %, i? ge a ER So -H--0o7 ONenzavo, ee Sit ee quod ate Lhy Solabke dus te pe hyslio Carbon pour. Pe ie d- se Se <= AL —@ «= a a 4 R 4 lowr ao'ds Ore toluble fy atoloE Benge, Uae. bs He Banding Seaeliee Ged Oe Pub TD ofa wrold,M-pP—> altanabow eect or oselalan 7 Sra | a} an acid contain evew 10-64 Corben atsus 1d Lo, hi than pro next ewe and heat bt hortalege a Os, i coo cabal ed® ue. ves. a ‘a. at “% oy Conlasud eV No. of c-dhews tita che neher , hoa WW wR . Chuniuad mpeupa are ow Obborite L'dles) “5 Ne i Centoins odd no. of c- aheHs Lita peowly, hat lows mf. Prexstusl poups ae on Me Aqme Aide) Cute 6) acide ratine of a and Her Suda ee eg Ro ES R= Cosbeaytoti anton, CorboryuBe acid and Grbdauytabe Anow At AkobLired ba Beronance. but He ruonants en of GrbeugtoLe, anion Th more Man prot Bh undo Gate, Grbaryere acid, THA s dung tsthe Jack Hat conde) shud TT Gadi. ser Corba Ke Amijon GAL epuiv abet ano} do not jnuslve Acharabiens Of tre and - ve Chorges whooas the Comlubiittng abu cturd LT and 1 Jer unditrsociatial gad are nif epuivotout anol ablro INwtases separakeon o} VA And —ve ehorgh.. Q.wh Corbory hic @cddA ere Bhovge aula Hhan aleonol a. And. Recuuse bolo Corbautc acid and Gubapslile Anion orc AtabUized bo weronante bubnatu the alcohol nor axkedcle fon Con-) ars Alabiire) | wuonance . a Q@mnien ete Nore rable Man Carb © aads so Hey have Q Abe bendenc to Ackeare Q preten, go QheonelS aro werker aad Hen Carborydre add Q. Compare acidlic charac ch aPhenol arrol Grboyee aad. Md Corboraplhc, Qeards Ade Atle ng acds Tran phenols. ar _ ? re - . ae re 2 Or - ci © . “6: ie @: ~ ¢: ee NS . er a wo io oO On ef Iie On a = L a =tuiie Sew Cys on the \ers election ative. Corbon ato . Thor Cont bust ovy foward, re ~ Yeronance habGraten of Pherenide ton YA ved Bro so Un be wejeced qi =, “Me am. ere hacia etne cog gene Phenoxicta +o ave th Ap foaled oble ty Bachan and W Aledo calized Qo Corbet) ports nance pieabiired than prenooichs ton oti, gud TY, Buk Sn icin Ww mM ost Vero p wer ob ajanading, ter wed yo been ar = . sone, CH oer) THA wt ak - er ~ _ So raha Tneeose Wo Oh dew aT op HF vons Yom acdc add ods Compare TO dermte aciol , 30 Abang avd tw aute avy, 4) etper of ex wuts coin Substituents (otosers) CACOeH Zz cy eH, CooH Boe avd Aus fe -F afhet Bo wT Gm be Aemovssl cooly.Tether Fr wz M7 Foy coon > CREE Coon 7 PA U4tooy py Teyteoy a thet oh no. oh Halegew acidls ae te ono. of holngems dee ARowgn re sath Accor 7 cy Urteoon 7 ROL Coo —> etek of botiton of Hake gers ate. Snductie, ebheck clecratrs wr ob Lance co 4 a ce Los Ut -cooH - U4 &4 O4,cooH ee {oy O44, C904 —> Heonpy GHecoon 7 Ugcoor wend eect Freyeum etcacd Bemoic aud is Ate aud Huw abe become =r etek of Phenyl? Gp - epee ot Substituents on the aud aie of Aomabe avols. d es donaHn Substituents lore decrtotraA whle a Ut Hola Aubs uents pnercorc He acid ftrengti a Coo} ge o> OG oH Noy oa, QD O- substtwer bemgoic acid org bong — Qciol than bemole aud C regadias af nator +I m-5 TRA 14 Coded @riko effect S) Qbid wejrening efbect— of er denaH a acd Ate ong eHect Oh ex us osIg move pronounces} at ob then m bearto” " coor} peer Coe cy en 7 @ ? Ch? @ waned beugolc aud cooy cooW oo} Coot 6 7 ey" > Coy? o4 Met ma Grmot exulm Raber Nite bel ¢ a val 5 (004 C004 casy eer] 2 a 3 > ol > lo On - 7 le SS MO, ae Amino b he @ ming bwyZelc acid. cot award coor > (ly? eo Q (co) > wore otf eur ar dite ke cs ww Awd wo mel oS wd rAastht exo} ow Firat” position,Chamiah xegctonds db Corberybre adds aL & Mongu- acid than pha] @-wnte q cued efuallon 7 shows aibuence bekween phencld ahd cotbory le acids , A, . Ans * en, coo, + Nak co, —? Cr, CoONG FH OCA, mot procs ca eft aves cence uit of NaH co, $° Hoy Agrchen no) FON Corba yo Phenols do Oipicesntas: Solution Con be Used to dsking wah phe aad. BD ReacTan ute motos G4 cooy +Na cr,coo Na +4 Jodian Glau Fon unity askalles (neritiy Lgokes) 3) Reack CACood + NaoH —7 on, coon + 14-0 te, Kas Sodan ABR heatic a4 4 gnuolves promod ol H hove Hore dogelo ud Fon add. Na coo NO aay iva Rees Or, Coll —7 Cacoona —— +0 +o | o¥ =f UW CH, cooNe + roReadow, tnuelts ta —oH grep of Gabayhre acis| db Fosmat on of avd Chlonidlef B04 coor + fe, PQ, J 3racoe +H POg CH, CoO S He oD) rte Ng, / rag Co4 Cor < cHcoot Ag 3 VA cock +Hetftsol 2 ad vrs | PQ, a,P Y coc’ + H Poa CAconH,_ Peed h cateniche : AcOQ acest amide © eteitiudie. wito me chan! UY Hs CH, coer Ho Ge = G4 co0Gg He HO Nechansam | ® Proton ation of aoe Yous O12 2 R ~7 fat \ RR ef 4, a-e vol o4 r OY Ny (CW) Nuctopiitic attack by the alcohol, ooeH oH R- at Oe 43 R—< —-8! oye (iti) “loss of wall molecule. Qnd a | pia oH a $- as ged-or! q Oa = aL cae J aie On & OR fice! am |/ » ReacHond alee the —CcooH peorp ase whole Dd Decarboouyhat on CH COONG + Nao¥ AAS, CHy + Na,co & ™methane 2) theataly te dlecarhorsptoleus. Ckolbls Steedial pe wsatic) acy cooNq —5 AY4 COO ~+- QNah —s = yr M40 = gon + an Anode RCO ~ _ 9g — BeBe 8 + ay Coftede gH 4.ge- __y Hii 3) Deearbos ct la lion, of Bilver 2abe of Cathe tce. anit Coty, Rablx K cH nail +8y sin By ae Hundacecker Rerebiac, a) Reduction CH CooH =a Oy Gy, OH Gay y Jere or Byte | Oke ™ be UAro} But- NaBiy new veduut adda (Gabuegtr) Cycroy tour SMP oy OW + ayo gsr Dan 2. Rea cton of Cy 1 as oLo Urs mh V2. (Hero - gvalhaas! Geeta) on ) a ceory _hap red a cooy C44 c001 2) of cco Seer es ey orl or eS“eed ov, tt & Gr, ) reel P ts Hy CH, OF, coon ee Os Gt “ll Gale << C4 - c@y Coo} 21 2-dib4ono prepancicac R- &- holoacid.s meng Aa OBE, kon) apriks Da, o ooh Ne-oycooy S o eaeon =, : cngong a | “I0 os d a Zoot NH -o4- Coody Calyone) N\CooH K- Amino acebic aud Matonic aud Readions of eub, dled Ve Subct fubien Coot ————— ble on FHA Bonivelion /~ PA 3-Rronabemmeole 4 a Coo coor Nea hse? (ol ae DP Ceone-) ~ & Z-nitobengolc aad oO} om ani GL v8 +4Ho Su dpron Gan &.= Rualadbengal cand Dug te DBeackvatton of benzene Aen oy the — Coo group , Careneeeley Sepor tnt Corday be adds, ty Methanolc acid (coo) dorm ic Fd | 2 Naow +co YEK, Hoong Ty Hoot \oat om Gam oi Cad} d+ tha powehet Jol r dus prerence ah baled c rysaagers . SF eeu Tots aud Fenlin Aol ow Q erhamsic acid CoxCoot) Aedte acid enero ite. Vn Oy Sette Cr, coon as ORon +0 Rr okey” C.cooH| Mion 28 cad acdc acid | sot Pree a eke ace) obtained ky monty ot Ongst ots Cice Mee) of ethane) acid Bar stn on : te, Teast Carbeouyk c aud Phano] | AcooH 4. NaH Coy) No rection” coota +Horcg | bw ak ofpavacence Naver, Peed agcod FFD 3 CACooH + Fee 2 @ coe) Fe aH & 0), Fe aud pyc a Dale Petus c preveald. Ceubh colouasl pr) avons)