03

-1

xm = n ( I 2 ) = 2,5 102 0,08 = 2 103 mol

2SO4 2

S 2O8 2 8 103 2 xm 0

0,04C2 xm = 0

-2

xm
( = 1 mmol
2

C2 = 5 102 mol / L

2x

2 xm

xm

t1/ 2 = 16 mn

) x ( mmol

1
dx
1
2 103
=

= 1,08 103 mol.L1.mn 1

V
+
V
dt
0,08
23
)( 1 2

I2

S 2O8 2 + 2 I
=
0,04C2
8 103
0,04C2 x
8 103 2x
0,04 C2 xm 8 103 2 xm

= vvol

-3
: )

( S 2O8

: t = 0 ) ( C3 > C1
: ) (

) t ( mn

16

YA E : u AM = E ). (1
-1
YB : u BM = u R u R = Ri i ). (2
-2

UR
5
=
= 0,05 A
R 100

=I

)(1

( U AB = E U R = 7 5 = 2V

duR
- 3 t = 0
dt
duR
di
5

= =R
= 25000V . s 1
dt
dt 0, 2 103

U AB
2
=
= 40
I
0,05

=r

di
t = 0 u AB = E
dt
E
7
=L
=
= 2,8 102 H
di 250
dt

) u (V

)(2
di 25000
=
= 250 A.s 1
dt
100

u AB = ri + L :

) t ( ms

di
- 4 R + r = R0 = E :
dt
di
) (1 :
= k Ae kt
dt
R
E
=B
R0 kL = 0 k = 0
L
R0

R0 i + L

)(1

Ae kt ( R0 kL ) + BR0 = E

E
t = 0 i = 0 i (t ) = Ae k t + B
R0
R
140
= 5000 s 1 :
5
= k= 0
L 0,028

. A = B =

1
: = 0, 2 103 s = 5000 s 1
3
0, 2 10

0,2

=. k

C AVAE 0,1 10
=
= 0,02 mol / L
50
VB

-1

= CB

m
= CBV
M

= n m = MCBV = 31 0,02 0, 2 = 0,124 g

-2
CH 3 NH 2 + H 2O = CH 3 NH 3+ + OH
pH E = 6,3 < 7 :

1011,4 14
= 0,12 :
0,02

pH 0 14

CB

( )

pH

11,4

OH 10
=
=
CB

CH 3 NH 2 + H 3O + , Cl = CH 3 NH 3+ , Cl + H 2O

-3

-4

VA = 58 50 = 8 mL pH = 10,1

] [CH 3 NH 2

10,1

= pH pK A = 0,6
CH 3 NH 3+

[CH 3 NH 2 ] = 100,6 = 0, 25
CH 3 NH 3+

CBVB x f
[CH 3 NH 2 ] = VA + VB = CBVB x f
(
xf
xf
CH 3 NH 3+

VA + VB

log

) V A ( mL

CH 3 NH 2 + H 3O + = CH 3 NH 3+ + H 2O
CBVB
C AVA
0

CBVB x
C AVA x
x

CBVB x f
C AVA x f
xf

( : C AVA xm
xm = C AVA = 0,1 0,008 = 8 104 mol
:

x f = 8 104 mol

0,02 50 103 x f
xf

8 104
=1
8 104

CBVB x f

= 0, 2

xf

xf

xm

C AVA xm

CBVB xm

xm

1
2
3
4

: ) 84 124 (
: ) ( m 0
: ) (
: ) ( 87 1 88

5 : = 0,125

0,69
11,4
3,8

6 : + x 10 e + y 24 He :

0,6 9

t
N
= e 1/ 2 = e
N0

226
88 Ra

238
92 U

x = 2 . y = 3

3 .
- 7 :

Rn

3,75 103
= 1,78 109
6
2,1 10

9 1016 = 78,75 1014 J = 4,9MeV

8 :

222
86

He +

4
2

Ra

30

226
88

Elib = mi m f c = 8,75 10
A

= N

N
1,78 109
=
3 1015 mol
23
N A 6,02 10

=n

G
f

G
f

-1

G
P

-2
-3

G
P

= ( m2 m1 ) g = 20 103 10 = 0, 2 N
(

L 0, 26
=
= 1,3L
t 0, 2

= vl

( f = P = k v 2 :
m = Al V : 20 mL . 1g / mL
)(1

m = 2,7 103 20 = 54 103 kg . P = 54 103 10 = 0,54 N

)= 0, 2 kg.m 1 : (1
-4

0,54 0, 2
2

)(1,3

( :

dv
( t = 0, 2 s = 2,8 m / s 2
dt

P
2

=k

dv
k
= g v2
dt
m m

dv
= 6 , 3 3, 7 v 2
dt

=. a

) a(m / s 2

2,8 = 6,3 3,7v 2

v = 0,97 m / s
2,8

06
-1

) t (s

P0V 4,638 104 0,5 103

=
= 8,8 103 mol
RT
8,31 318

= n0

-2

2N 2O 5 = 4NO 2 + O 2
n0
0
0
n0 2 x
x
4x
n0 2 xm
4 xm
xm

n0 2 xm = 0 xm = 4, 4 mmol
-3
)(1
P0V = n0 RT
PV = ( n0 2 x + 4 x + x ) RT

0,2

)(2

) (1 ) (2 :

) x ( mmol

3x
P n0 + 3x
=
=1+
P0
n0
n0

3x
P

t = 100s = 2, 422
n0
P0

2, 422 = 1 +

x = 4,17 103 mol . xm

- 4 .

2, 2

t1/ 2 = 20 s

-5

1 dx
1 5, 2 103
=

= 3 104 mol.L1.s 1
35
V dt 0,5

= vvol
) t (s

20