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org - 2013
(34 25 )

25

d
0, 20
vl =
=
= 0, 21 m / s
t 0,956
dv
+ Av n = B
dt

dv k n
+ v = g 1 2
dt m
1

B = g 1 2
1

g 1 2
1
B
vn = =
27
A
4 1r 2
.

f = kv n = 1

( 0, 21) n

mg k v n 2Vg = ma
A=

2
2
4 g 1
1r

1
=

27

-1
-2

k
9 r
27
=
=
m 4 r 3 4 1r 2
1
3

dv
= 0 - 3
dt

1, 26
2
4 9,81 1
2,7 10 3 ( 0,01)

2,7

=
= 0, 21
27

-4

26
. 142 92 1
El = ( 92 1,00728 + 142 1,00866 234,0409 ) 931,5 = 1731,3MeV
-2
.

34
92 U

230
90Th

ln 2
t
t1/ 2

-4

N (U )

-5

N (Th ) = N 0 (U ) N (U ) = N 0 (U ) 1e

e t =

N (Th )
+1 = r +1
N (U )

N (Th )
= e t 1
N (U )

t=

ln ( r + 1)
= 1, 2 10 5 ans
ln 2
t1/ 2

) (

t = ln ( r + 1)

27
1

.21

m
0, 450
=
= 60 g / mol n A = C A V0 = 1,5 10 2 0,5 = 7,5 10 3 mol
n A 7,5 10 3
CH 3COOH n = 1 12n + 2n + 1 + 12 + 32 + 1 = 60

CH 3COOH + H 2O = CH 3COO + H 3O +
CV

0
0
x
x
CV x
//
//
CV x f
xf
xf
xm

e t

C B VBE 10 2 15
=
= 1,5 10 2 mol / L
10
VA

CV xm

N (U )

.11

) = H O

V = 10
V . 1 2

[CH 3COOH ] = C A H 3O + = C A 1 = C 10 pH 1
A
CH 3COO
H 3O +
H 3O +

x f = n H 3O

//

N (Th ) =

C n H 2 n +1COOH + Na + , OH = C n H 2 n +1COO , Na + + H 2O

CA =
M=

+ 24 He - 3

pH

CH 3COO
1

=
= 0,034
[CH 3COOH ] C A 10 pH 1

xm
pK A1 = 4,76

.22

CH 3COO
= pH pK = Log 0,034 = 1, 46
Log
A1
[CH 3COOH ]

3
+

.13

+ NH 4

= CH 3COO

CH 3COOH + NH 3

CH 3COOH + NH 3 = CH 3COO + NH 4 +
0
0
n0
n0
x
x
n0 x
n0 x
n0 x f
n0 x f
xf
xf

CH 3COO NH 4 + K

= A1
=K
[CH 3COOH ][ NH 3 ] K A2

.23

K = 10 pK A2 pK A1 = 10 9,2 4,76 = 2,7 10 4

x 2f

.33

1

xf

2,7 104
1 + 2,7 104

(n

=K

xm

=
1 1

1
n0
1
xf

xf

= K

n0 x f

n0 xm

xm

n0 xm

K
=
1+ K

= ) ( K

28
1 :

G
M m G
G
FT / S = G T2 u = m a
r
G
G
a = K u K .
G
a .

-2

G MT
4 2 r 3
v2
2 r
= T
= v 2
= a = an
GM T
r
r
v

-3

4 2
GM T

G
FT / S

=T2

G
u

=K

4 2 r 3
:
GM T

=T2

4 2 rT 3

GM S

) (1

= TT 2

) (1 ) (2 = 3,3 10 5 :

)(2

24 2
2

) ( 365, 25 24

)
)

(
(

8
M S T 2 rT 3 1, 496 10
=
=
.
M T TT 2 r 3
4, 24 10 4

29
- 1( ......
( Z = 34 x = 5 :
( = ( 234,9934 145,8782 84,9033 4 1,00866 ) 961,5 = 165,1 MeV :

1
= 4, 23 10 23 MeV
235

: 1g
(
-2

1
= N 0e t
100

N0

+ 13 H 24 He + 01 n

Elib

E 'lib = 165,11 6,02 10 23

4,6
90 mn t = ln100
5,13 10 2

=t

2
1H

(
( : .
: ) ( .
GUEZOURI Aek , Lyce Maraval Oran
Site : www.guezouri.org
, e-mail : guezouria@gmail.com
Tl : 07 73 34 31 76

 30
2

-1

3,5 10
= 0,895 mol / m 3 = 8,95 10 4 mol / L
3
39,1 10

1
+

CH 3COO

H 3O +

= H 3O +

pH 1 = Log H 3O + = Log 8,95 10 4 = 3,05

1

1,1 10 2
= 0, 281 mol / m 3 = 2,81 10 4 mol / L
39,1 10 3

2
+

CH 3COO

H 3O +

= H 3O +

pH 2 = Log H 3O + = Log 2,81 10 4 = 3,5 5

2

( pH .
) ( .
2

H 3O + CH 3COO
H 3O +
10 6,1

= K1
=
=
= 1,62 10 5
3,05
] [CH 3COOH
C1 H 3O + 0,05 10
2

H 3O + CH 3COO
H 3O +
10 7,1

=
=
= 1,68 10 5
= K2
3,55
] [CH 3COOH
C 2 H 3O + 0,005 10

K1  K 2 .
-2

( )

CH 3 COOH + Na + , OH = CH 3 COO , Na + + H 2O

CBVBE 1,5 02 15,5

=
( = 1,17 102 mol / L
VA
20
100
( = 100
= F C0 = 1,17 102 100 = 1,17 mol / L
1
1L m = n M = 1,17 60 = 70, 2 g :
= Cs

70, 2 g

) V ( g

100 g

100 70, 2
= 7,02
1 1000

= X

31

1
0 + mghA = mv 2O + mghO
2

- 1 EcA + E ppA = EcO + E ppO :

) v 2O = 2 g ( hA hO . v0 = 2 gh

dvx
- 2 = 0 :
dt
g
1
-3
=y
. x 2 + ( tn ) x y = g t 2 + v0 sin .t x = v0 cos . t
2
2
2
2v0 cos

= g

dv y
dt

) (

4 C ) C (10m ; 0,5m :

(10 ) + 0,57 10

= 0,5

h = 5, 4 m

) 2 2 gh ( 0,866
h 5, 4 m C h = 5, 4 m .
2

GUEZOURI Aek , Lyce Maraval Oran

Site : www.guezouri.org
, e-mail : guezouria@gmail.com
Tl : 07 73 34 31 76

 32
-1

S2O82 + 2 I = I 2 + 2 SO4 2

- 2 ) S 2O82 (
I :

2SO4 2

I2

. n I = I (V1 + V2 ) = 5 20 103 0, 2 = 0,02 mol

2x

I :

2 xm

xm

) (

= S2O82 + 2 I
0,1 C1
0,1 C2
0,1 C1 x
0,1 C2 2 x
0,1 C1 xm
0,1 C2 2 xm

) (

n0 I = I (V1 + V2 ) = 10 20 103 0, 2 = 0,04 mol

0,04 0,02
0,1 C2 2 xm = 0,02 : 0,1 C2 = 0,04 = 0,01 mol
2
x
0,01
- 3 0,1 C1 xm = 0 : = 0,1 mol / L
= . C1 = m
0,1 0,1
4 S2O82 = C1V1 = 0,1 0,1 = 0,05mol / L = 50 mmol / L : S2O82

V +V
0, 2
1
2
= xm

) : S 2O82 = g ( t . 1

- 5 .

200 + 100
2 = 150 mmol / L
= = 3,3mn I

2

) I ( mmol / L

t1/ 2

[....] mmol / L

150

S2O82

20

20
) t ( mn

) t ( mn

3,3

) (

0,04 2 x
6 n I = 0,04 2 x
VT

= I :

d I
d I
1 dx

= 2 dx

:

= vvol = 2 vvol
dt
dt
VT dt
VT dt
3
d I
= 17 10 10 = 0,021
dt
8

1 d I
vvol =
2 dt

1
vvol = ( 0,021) 0,01 mol.L1.mn 1
2

 33
1 .
-2

H 2O2 + 2 H + + 2e = 2 H 2O
H 2O2 + = O2 + 2 H + + 2e

- 3 :

2 H 2O2 = O2 + 2 H 2O

n ( H 2O2 ) = n0 2 x

n0 2 x n0 2
2
=
x = [ H 2O2 ]0
VO2
V
V V
V VM

2 H 2O

= ] [ H 2O2

: VO2 = 30cm3

O2

2 H 2O2

n0

xm

n0 2 x
n0 2 xm

2
30 103 = 1,6 102 mol / L
0,1 25
1 dx
-4
= (1) vvol
V dt
VO
dx
1 dVO2
1 dVO2
=
)(1
x = n ( O2 ) = 2 :
= vvol
dt VM dt
V VM dt
VM

3
dVO2 50 10
1
= vvol
1,67 103 = 6,7 104 mol.L1.mn 1

=
= 1,67 103 : t = 0
dt
0,1 25
30
dV
1
20 103
O2
= vvol
0, 22 103 = 9 105 mol.L1.mn 1

=
= 0, 22 103 : t = 1h
dt
0,1 25
90

[ H 2O2 ] = 4 102

(
(

[ H 2O2 ] max
2

5
(

= ] [ H 2O2

)( B

t1/ 2 = 20 mn

t '1/ 2 = 40 mn

( t '1/ 2 > t1/ 2 .

34
-1
-2
3

G
G 0
G
P = ma
a
g
G v0 cos
v
gt + v0 sin
)(1
)(2

8,66
8,66 = v0 sin 5 = v0 cos = 1,73
: 5
8,66
: g = g = 9,84 m / s 2
) ( g ) (2
0,88
- : v y . t = 0,88 s

= tn = 60

: t ' = 2 0,88 = 1,76 s x = vx t ' = 5 1,76 = 8,8 m5

= v0 y = 0,197 x 2 + 1,73 x
4 = 10 m / s :
0,5
g
= y v0 = 22, 4 m / s
- 5 y = 0 x = 8,8 5 = 44 m x 2 + x tn
2
2
2v ' 0 cos

GUEZOURI Aek , Lyce Maraval Oran

Site : www.guezouri.org
, e-mail : guezouria@gmail.com
Tl : 07 73 34 31 76