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CONFIDENTIAL
4541/2
(a)
(b)
(c)
(d)
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(e) (i)
(ii)
(f)
1
1.. 2
1
1
1
1.. 2
1
TOTAL
2
(a)
2.7
(b) (i)
(ii)
Period 2
Atomic size of X is smaller than V // Atomic size of V bigger than
X.
The number of proton in atom X is more than V.
The attraction by the nucleus on electron in atom X is stronger than
V.
or
The number of proton in atom V is less than X.
The attraction by the nucleus on electron in atom V is weaker than
X.
1
1
(iii)
(c) (i)
(ii)
(d) (i)
1
1
1
1...2
VW4
has low melting / boiling point // cannot conduct electricity
in any state // soluble in organic solvent
Ionic compound
(ii)
1
1
10
MARKING SCHEME
CONFIDENTIAL
(a)
(b)
4541/2
1
G
e
e
Electrode P
Potassium iodide
solution
Electrode Q
Chlorine water
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(c) (i)
(ii)
1
1
1
(d)
1
1
(e)
Cl2 + 2e 2Cl-
(f)
(g)
0 to -1
(a) (i)
(ii)
(b) (i)
(ii)
(c)
(a)
(b)
(c)
(d)
1
10
1
1..2
1
1..2
1
1
1.. 2
1
1
1..3
10
1
1
1
1
1
MARKING SCHEME
CONFIDENTIAL
(ii)
(e)
(i)
(ii)
4541/2
0.1 x 20 = 1
Mb x 25 1
25 Mb = 2
Mb = 0.08 mol dm-3
10 cm3 // half the volume of hydrochloric acid
Sulphuric acid is a diprotic acid whereas hydrochloric acid is a
monoprotic acid.
So, the sulphuric acid used has twice the number of hydrogen ions
compared to hydrochloric acid .
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Total
No
6(a)
(b)
Marking criteria
1
1
1
1
10
Mark
Experiment I :
Rate of reaction =
22
= 0.183 cm3 s-1
2 60
37
= 0.308 cm3 s-1
2 60
Experiment II :
Rate of reaction =
(c)
Volume of
CO2, cm3
II
time, s
(d)
1
1
1
1
1
1
MARKING SCHEME
CONFIDENTIAL
4541/2
(e)
Water
1
1
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TOTAL
11
Section B
Questions
7
(a) (i)
Marking criteria
Marks
(iii)
(b)(i)
(b)(ii)
(b)(iii)
(b)(iv)
Temperature : 450 C
Pressure : 1 atmosphere
Catalyst : Vanadium(V) oxide
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
TOTAL
2
2
2
20
MARKING SCHEME
CONFIDENTIAL
Question
s
8 (a)
4541/2
Marking criteria
Marks
1. Hydrogen(gas)
2. 2H+ + 2e H
1
1
(b)
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Properties
1. Type of cell
2. Energy change
3. Electrodes
Cell B
Electrolytic cell
Electrical chemical
Anode: Copper
Cathode: Copper
1
1
1
1
1
1
1
1
1
1
4. Ions in
electrolyte
5. Half equation
6. Observation
Cell A
Voltaic cell
Chemical electrical
Positive terminal:
Copper
Negative terminal:
Magnesium
Cu2+, SO42-, H+ and
OH- ions
Positive terminal:
Cu2+ + 2e Cu
Negative terminal
Mg Mg2+ + 2e
Positive terminal:
Copper plate
becomes thicker
Magnesium becomes
thinner/dissolve
(c)
(i)
(ii)
1
1
1
1
1
TOTAL
MARKING SCHEME
max
8/9
20
CONFIDENTIAL
4541/2
SECTION C
Question
s
(a)
(i)
Marking criteria
Marks
Saturated hydrocarbons hydrocarbons that contain only carboncarbon single bonds or single covalent bond.
Example : hexane
By Hydrogenation process.
Ethene reacts with hydrogen at 1800 C in the presence of nickel or
platinum catalyst to form ethane.
1
1
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(ii)
+ H2
(b)
(i)
2
- esterification reaction carboxylic acid reacts with alcohol with
the presence of concentrated sulphuric acid as a catalyst
(ii)
a)
b)
2
2
e)
Max
8
20
MARKING SCHEME
CONFIDENTIAL
Question
s
10 (a)
(i)
4541/2
Marking criteria
Marks
energy
Zn + CuSO4
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H = -152 kJmol-1
ZnSO4 + Cu
1. Y-axes : energy
2. Two different level of energy
(ii)
(b)
(i)
(ii)
1
1
1
1
1
1
1
1
1
3
MARKING SCHEME
CONFIDENTIAL
(c)
1.diagram
2.procedures
3.calculation
4541/2
:2m
:6m
:2m
Sample answer :
thermometer
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water
Metal container
Spirit lamp
Name of
alcohol
- functional diagram : 1 m
- labeled diagram
: 1 m (thermometer, metal container,
spirit lamp, alcohol)
Procedures :
1.100 cm3 of water is measured and poured into metal
container
2.the initial temperature of water is recorded
3.the #name for one alcohol# is poured into spirit lamp and is
weighed
4.the spirit lamp is put under the metal container and is burnt
5.the wick of lamp is lit and water is heated until temperature
increases by 30 0C.
6.the spirit lamp is weighed again
1
1
1
1
1
1
MARKING SCHEME
CONFIDENTIAL
4541/2
Table of data :
Initial temperature of the
1
o
water ( C)
2
Highest temperature of
o
the water ( C)
Mass of spirit lamp before m1
burning (g)
Mass of spirit lamp after
m2
burning (g)
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Calculation :
mole of ethanol =
m2
m1
46
-
-1
kJmol
= y kJmol-1
10
TOTAL
20
MARKING SCHEME