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Abstract
The author presents a personal view that production of bulk chemicals and the attendant risks are being transferred from developed to
developing nations. Some evidence is presented on the transfer of production. The transferred risk is increased because of the larger scale
plants that are now built in locales that are less able to cope with the increased hazards. Bhopal was an example of an inherently unsafe plant,
with major hazards that could have been avoided or drastically reduced by design. It behoves the industry to adopt the inherently safer
philosophy and practice in the new plants that it builds, in order to minimise the opportunity for another accident like Bhopal and the threat to
our industry that such an accident would pose.
q 2005 Elsevier Ltd. All rights reserved.
Keywords: Bhopal; Chemicals production; Risk transfer; Inherent safety; Plant location
1. Introduction
0950-4230/$ - see front matter q 2005 Elsevier Ltd. All rights reserved.
doi:10.1016/j.jlp.2005.06.014
D.W. Edwards / Journal of Loss Prevention in the Process Industries 18 (2005) 254260
(a)
CH3OCN
+ 2HCl
Methyl Isocyanate
(MIC) +
CH3NH2
+ COCl2
Methylamine +
phosgene
R1
R2
STEP 1
40 tons
OCONHCH3
OH
CH3OCN
MIC
-naphthol
carbaryl
R3
I
Raw material
STEP 2
Intermediate
Product
(b)
OCOCl
OH
COCl2
+
-naphthol +
phosgene
R3
chloroformate
I
R2
OCOCl
+
chloroformate +
I
CH3NH2
methylamine
R1
HCl
HCl
STEP 1
OCONHCH3
+ HCl
carbaryl
P
HCl
STEP 2
Fig. 1. The Bhopal plant chemistry and an alternative route to the product,
carbaryl, that does not make methyl isocyanate (MIC). (a) The reaction
route used at the Bhopal plant. (b) Alternative route, using the same raw
materials (R1, R2, R3), that des not make the MIC intermediate (I).
255
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D.W. Edwards / Journal of Loss Prevention in the Process Industries 18 (2005) 254260
3. Risk transfer
Given that the capacities of the new plants are increasing
and that they mostly use existing designs, the size of the
hazards is increased either in proportion to the necessary
inventory increases or over and above this. For example,
piping inventories increase more than linearly with
capacity. If equipment, for example columns, heat
exchangers and flare systems, has to be duplicated or
tripled, etc the inventory and therefore, the hazard will rise
more than in proportion to the capacity increase. However,
the risks are increased even more.
Windhorst and Koen (2001) make the case that, while the
designs of new plants are simple linear extrapolations of
existing designs of much smaller plant, the risks increase
exponentially. To justify this assertion they made quantified
risk assessments of ethylene plants. They concluded that the
individual risk of the most exposed person increases to
the power 1.33 of capacity and that risk is proportional to
the square of capital.
They state a number of reasons for this effect. Some of
these are:
larger equipment and nozzle sizes result in larger release
rates and amount released and also increased probability
of ignition;
bigger maximum rate of energy release;
D.W. Edwards / Journal of Loss Prevention in the Process Industries 18 (2005) 254260
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D.W. Edwards / Journal of Loss Prevention in the Process Industries 18 (2005) 254260
D.W. Edwards / Journal of Loss Prevention in the Process Industries 18 (2005) 254260
259
Acknowledgements
The author gratefully acknowledges the helpful comments made by Trevor Kletz and Jan Windhorst during the
writing of this paper.
References
Edwards, D. W. (2004). Are we too risk-averse for inherent safety? An
examination of current status and barriers to adoption, hazards XVIII
process safety- sharing best practice IChemE Symposium Series No
150. Manchester: IChemE (p. 250).
Gupta, J. P. (2003). Bhopal: .Eighteen, going on nineteen and fading?
Transactions of the Institution of Chemical Engineers: Process Safety
and Environmental Protection, 81B, 81B(4), 227228.
Gupta, J. P., & Edwards, D. W. (2002). Inherently safer designpresent
and future. Transactions of the Institution of Chemical Engineers:
Process Safety and Environmental Protection, 80B(3), 115125.
INSIDE Project (1997). Inherent SHE: The cost effective route to improved
safety, health and environmental performance. London: IBC UK
Conferences Limited.
Jones, D. A. (Ed.). (1992). Nomenclature for hazard and risk assessment in
the process industries2nd ed.. Rugby: IChemE.
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